Study of 3He Nuclei by Polarization Observables in Quasi-Elastic Electron Scattering

In a recent set of measurements at Jefferson Laboratory, we have studied the missing-momentum dependence of beam-target asymmetries in exclusive \({\overrightarrow{^3{{\rm He}}}({{\rm e}},{\rm e}'{\rm p}){\rm pn}, \overrightarrow{^3{{\rm He}}}({{\rm e}},{\rm e}'{\rm p}){\rm d} }\) , and \({\overrightarrow{^3{{\rm He}}}({{\rm e}},{\rm e}'{\rm d}){\rm p}}\) channels at a previously unattainable level of precision and unreached range in missing momenta. We have also measured single-spin asymmetries in the processes \({\overrightarrow{^3{{\rm He}}}({\vec{{\rm e}}},{\rm e}')}\) and \({\overrightarrow{^3{{\rm He}}}({{\rm \vec{e}}},{\rm e}'{\rm n})}\) , where the nuclei were polarized vertically. Preliminary results are presented.     

Structure of some FeII − III hydroxysalt green rusts (carbonate, oxalate, methanoate) from Mössbauer spectroscopy

The abundances of Fe^II and Fe^III environments within green rusts one, GR1s, that intercalate carbonate, oxalate and methanoate (formate) anions are found from Mössbauer spectra for compositions corresponding to [Fe $^{\rm II}_{6}$ Fe $^{\rm III}_{2}$ (OH)₁₆]^2?+??[CO $_{3}^{2-}$ ?5H₂O]^2???, [Fe $^{\rm II}_{4}$ Fe $^{\rm III}_{2}$ (OH)₁₂]^2?+??[CO $_{3}^{2-}$ ?3H₂O]^2???, [Fe $^{\rm II}_{6}$ Fe $^{\rm III}_{2}$ (OH)₁₆]^2?+??[C₂O $_{4}^{2-}$ ?4H₂O]^2??? and [Fe $^{\rm II}_{5}$ Fe $^{\rm III}_{2}$ (OH)₁₄]^2?+??[2HCOO^????3H₂O]^2???. These formulae correspond to orders α, β and γ where cation distances are (2 × a ₀), ( $\surd 3$ × a ₀) or a mixture of both leading to (7 × a ₀), where ratio x = {[Fe^III]/[Fe_total]} = 1/4, 1/3 and 2/7, respectively. Anion distributions within interlayers are also devised and long-range orders determined accordingly.     

A Theoretical Study of Pure and Mixed Spin-Polarized Tritium and Helium Triatomic Systems Using Hyperspherical Coordinates

Pure and mixed spin-polarized tritium ( ${{\rm T}\uparrow}$ ) and helium (He) triatomic systems are studied using hyperspherical coordinates. A slow variable discretization approach is adopted to solve the nuclear Schrödinger equation, in which the Schrödinger equation in hyperangular coordinates is solved using basis splines at a series of fixed FEM-DVR hyperradii. By using the best empirical interaction potentials, we study comparatively the bound states of ( ${{\rm T}\uparrow}$ )₃, ⁴He( ${{\rm T}\uparrow}$ )₂, ${^4{\rm He}_2{\rm T}\uparrow}$ , ⁴He₃ and ${^4{\rm He}_2^3{\rm He}}$ in the J ^Π = 0⁺ symmetry. The bound state energy levels are calculated for all these molecular species except ⁴He( ${{\rm T}\uparrow}$ )₂, for which we have found no bound state. The calculated wave functions of these species are found all to exhibit a very large spatial extension, indicating the diffuse nature of these bound states. The molecular structure of these species will also be calculated and analyzed in detail.     

The Charmonium-Molecule Hybrid Structure of the X(3872)

In order to understand the structure of the X(3872) the effects of the ${{\rm c\overline{c}}}$ charmonium core state coupling to the ${D^0\overline{D}^{*0}}$ and D ⁺ D ^*? molecule states are studied. The obtained structure of the X(3872) is about 9 % of ${{\rm c}\overline{{\rm c}}}$ charmonium, 75 % of the isoscalar ${D\overline{D}}$ molecule and 16 % of the isovector ${D\overline{D}}$ molecule which explains observed properties of the X(3872) well.     

Measurement of all Deuteron Analyzing Powers for {\overrightarrow{d} + p} Elastic Scattering at 294 MeV/Nucleon

We have measured all deuteron analyzing powers ${(A_{y}^{d}, A_{yy}, A_{xx}, A_{xz})}$ for deuteron-proton elastic scattering at 294 MeV/nucleon in order to study the properties of three nucleon forces (3 NFs). Measurement was made at in an angular range of ${\theta_{{\rm c.m.}} = 35.6^{\circ} - 163.0^{\circ}}$ . Obtained data were compared with Faddeev calculations with and without the 3 NFs. At ${\theta_{{\rm c.m.}}\lesssim 120^{\circ}}$ all the data have general agreement with the calculations, while the measured data at ${\theta_{{\rm c.m.}} \gtrsim 120^{\circ}}$ are not explained by any theoretical calculations. These results were consistent with those at 250 MeV/nucleon.     

Study of Light Hypernuclei by the (e,e′K +) Reaction

We have been performing Λ hypernuclear spectroscopic experiments by the (e,e′K ⁺) reaction since 2000 at Thomas Jefferson National Accelerator Facility (JLab). The (e,e′K ⁺) experiment can achieve a few 100 keV (FWHM) energy resolution compared to a few MeV (FWHM) by the (K ^?, π ^?) and (π ⁺, K ⁺) experiments. Therefore, more precise Λ hypernuclear structures can be investigated by the (e,e′K ⁺) experiment. ${^{7}_{\Lambda}{\rm He}}$ , ${^{9}_{\Lambda}{\rm Li}}$ , ${^{10}_{\Lambda}{\rm Be}}$ , ${^{12}_{\Lambda}{\rm B}}$ , ${^{28}_{\Lambda}{\rm Al}}$ , and ${^{52}_{\Lambda}{\rm V}}$ were measured in the experiment at JLab Hall-C. In addition, ${^{9}_{\Lambda}{\rm Li}}$ , ${^{12}_{\Lambda}{\rm B}}$ , and ${^{16}_{\Lambda}{\rm N}}$ were measured in the experiment at JLab Hall-A.     

Theoretical Investigation into Production of Double-Λ Hypernuclei from Stopped Ξ − on 6Li

We have investigated theoretically a feasible nuclear reaction to produce light double-Λ hypernuclei by choosing a suitable target. In the reaction from stopped Ξ ^? on ⁶Li target light doubly-strange nuclei, ${^5_{\Lambda\Lambda}{\rm H}}$ and ${^6_{\Lambda\Lambda}{\rm He}}$ , are produced: we have calculated the formation ratio of ${^5_{\Lambda\Lambda}{\rm H}}$ to ${^6_{\Lambda\Lambda}{\rm He}}$ for Ξ ^? absorptions from 2S, 2P and 3D orbitals of Ξ ^?–⁶Li atom by assuming a d?α cluster model for ⁶Li. From this cluster model the d?α relative wave functions has a node due to Pauli exclusion among nucleons belonging to d and α clusters. Two kinds of d?α wave functions, namely 1s relative wave function with a phenomenological one-range Gaussian (ORG) potential and that of an orthogonality-condition model (OCM) are used. It is found that the probability of ${^5_{\Lambda\Lambda}{\rm H}}$ formation is larger than that of ${^6_{\Lambda\Lambda}{\rm He}}$ for all absorption orbitals: in the case of the major 3D absorption their ratio is 1.08 for ORG and 1.96 for OCM. The dominant low momentum component of the d?α relative wave function favors the ${^5_{\Lambda\Lambda}{\rm H}}$ formation with a low Q value compared to the ${^6_{\Lambda\Lambda}{\rm He}}$ formation with a high Q value. We have also calculated momentum distributions of emitted particles, d and n, displaying continuum spectra for single-Λ hypernuclei, ${^4_{\Lambda}{\rm H}}$ and ${^5_{\Lambda}{\rm He}}$ , and line spectra for the ${^5_{\Lambda\Lambda}{\rm H}}$ and ${^6_{\Lambda\Lambda}{\rm He}}$ nuclei. Thus, our present theoretical analysis would be a significant contribution to experiments in the strangeness ?2 sector of hypernuclear physics.     

One-range Addition Theorems for Noninteger n Slater Functions using Complete Orthonormal Sets of Exponential Type Orbitals in Standard Convention

By the use of complete orthonormal sets of ${\psi ^{(\alpha^{\ast})}}$ -exponential type orbitals ( ${\psi ^{(\alpha^{\ast})}}$ -ETOs) with integer (for α ^* = α) and noninteger self-frictional quantum number α ^*(for α ^* ≠ α) in standard convention introduced by the author, the one-range addition theorems for ${\chi }$ -noninteger n Slater type orbitals ${(\chi}$ -NISTOs) are established. These orbitals are defined as follows $$\begin{array}{ll}\psi _{nlm}^{(\alpha^*)} (\zeta ,\vec {r}) = \frac{(2\zeta )^{3/2}}{\Gamma (p_l ^* + 1)} \left[{\frac{\Gamma (q_l ^* + )}{(2n)^{\alpha ^*}(n - l - 1)!}} \right]^{1/2}e^{-\frac{x}{2}}x^{l}_1 F_1 ({-[ {n - l - 1}]; p_l ^* + 1; x})S_{lm} (\theta ,\varphi )\\ \chi _{n^*lm} (\zeta ,\vec {r}) = (2\zeta )^{3/2}\left[ {\Gamma(2n^* + 1)}\right]^{{-1}/2}x^{n^*-1}e^{-\frac{x}{2}}S_{lm}(\theta ,\varphi ),\end{array}$$ where ${x=2\zeta r, 0<\zeta <\infty , p_l ^{\ast}=2l+2-\alpha ^{\ast}, q_l ^{\ast}=n+l+1-\alpha ^{\ast}, -\infty <\alpha ^{\ast} <3 , -\infty <\alpha \leq 2,_1 F_1 }$ is the confluent hypergeometric function and ${S_{lm} (\theta ,\varphi )}$ are the complex or real spherical harmonics. The origin of the ${\psi ^{(\alpha ^{\ast})} }$ -ETOs, therefore, of the one-range addition theorems obtained in this work for ${\chi}$ -NISTOs is the self-frictional potential of the field produced by the particle itself. The obtained formulas can be useful especially in the electronic structure calculations of atoms, molecules and solids when Hartree–Fock–Roothan approximation is employed.     

Mössbauer study of magnetism in FeII − III (oxy-)hydroxycarbonate green rusts; ferrimagnetism of FeII − III hydroxycarbonate

Fe^II???III hydroxycarbonate Fe $^{\rm II}_{4}$ Fe $^{\rm III}_{2}$ (OH)₁₂CO₃, green rust GR(CO $_{3}^{2-})$ , reveals a ferrimagnetic behaviour. Moments that lie within two-dimensional cation layers are parallel for same species and antiparallel between Fe^II and Fe^III. Respective ordering temperatures are 5.2 and 7 K. A sextet with distribution from 350 to 580 kOe for Fe^III and an octet reflecting a mixture of states with field of 130 kOe and quadrupole splitting of ?3.0 mm s^???1 for Fe^II are observed at 1.4 K. Ferric oxyhydroxycarbonate Fe $^{\rm III}_{6}$ O₁₂H₈CO₃ is ferromagnetic and displays at 4 K a sextet with field between 400 and 500 kOe (maximum at 480 kOe) and transition at 80 K. GR(CO $_{3}^{2-})$ deprotonation gives magnetic domains with compositions at x?=?1/3, 2/3 and 1 due to long range order.     

Courant–Dorfman Algebras and their Cohomology

We introduce a new type of algebra, the Courant–Dorfman algebra. These are to Courant algebroids what Lie–Rinehart algebras are to Lie algebroids, or Poisson algebras to Poisson manifolds. We work with arbitrary rings and modules, without any regularity, finiteness or non-degeneracy assumptions. To each Courant–Dorfman algebra ${(\mathcal{R}, \mathcal{E})}$ we associate a differential graded algebra ${\mathcal{C}(\mathcal{E}, \mathcal{R})}$ in a functorial way by means of explicit formulas. We describe two canonical filtrations on ${\mathcal{C}(\mathcal{E}, \mathcal{R})}$ , and derive an analogue of the Cartan relations for derivations of ${\mathcal{C}(\mathcal{E}, \mathcal{R})}$ ; we classify central extensions of ${\mathcal{E}}$ in terms of ${H^2(\mathcal{E}, \mathcal{R})}$ and study the canonical cocycle ${\Theta \in \mathcal{C}^3(\mathcal{E}, \mathcal{R})}$ whose class ${[\Theta]}$ obstructs re-scalings of the Courant–Dorfman structure. In the nondegenerate case, we also explicitly describe the Poisson bracket on ${\mathcal{C}(\mathcal{E}, \mathcal{R})}$ ; for Courant–Dorfman algebras associated to Courant algebroids over finite-dimensional smooth manifolds, we prove that the Poisson dg algebra ${\mathcal{C}(\mathcal{E}, \mathcal{R})}$ is isomorphic to the one constructed in Roytenberg (On the structure of graded symplectic supermanifolds and Courant algebroids. American Mathematical Society, Providence, 2002) using graded manifolds.     

Fomenko–Mischenko Theory, Hessenberg Varieties, and Polarizations

The symmetric algebra ${S(\mathfrak{g})}$ over a Lie algebra ${\mathfrak{g}}$ has the structure of a Poisson algebra. Assume ${\mathfrak{g}}$ is complex semisimple. Then results of Fomenko–Mischenko (translation of invariants) and Tarasov construct a polynomial subalgebra ${{\mathcal {H}} = {\mathbb C}[q_1,\ldots,q_b]}$ of ${S(\mathfrak{g})}$ which is maximally Poisson commutative. Here b is the dimension of a Borel subalgebra of ${\mathfrak{g}}$ . Let G be the adjoint group of ${\mathfrak{g}}$ and let ? = rank ${\mathfrak{g}}$ . Using the Killing form, identify ${\mathfrak{g}}$ with its dual so that any G-orbit O in ${\mathfrak{g}}$ has the structure (KKS) of a symplectic manifold and ${S(\mathfrak{g})}$ can be identified with the affine algebra of ${\mathfrak{g}}$ . An element ${x\in \mathfrak{g}}$ will be called strongly regular if ${\{({\rm d}q_i)_x\},\,i=1,\ldots,b}$ , are linearly independent. Then the set ${\mathfrak{g}^{\rm{sreg}}}$ of all strongly regular elements is Zariski open and dense in ${\mathfrak{g}}$ and also ${\mathfrak{g}^{\rm{sreg}}\subset \mathfrak{g}^{\rm{ reg}}}$ where ${\mathfrak{g}^{\rm{reg}}}$ is the set of all regular elements in ${\mathfrak{g}}$ . A Hessenberg variety is the b-dimensional affine plane in ${\mathfrak{g}}$ , obtained by translating a Borel subalgebra by a suitable principal nilpotent element. Such a variety was introduced in Kostant (Am J Math 85:327–404, 1963). Defining Hess to be a particular Hessenberg variety, Tarasov has shown that ${{\rm{Hess}}\subset \mathfrak{g}^{\rm{sreg}}}$ . Let R be the set of all regular G-orbits in ${\mathfrak{g}}$ . Thus if ${O\in R}$ , then O is a symplectic manifold of dimension 2n where n = b ? ?. For any ${O\in R}$ let ${O^{\rm{sreg}} = \mathfrak{g}^{\rm{sreg}} \cap O}$ . One shows that O ^sreg is Zariski open and dense in O so that O ^sreg is again a symplectic manifold of dimension 2n. For any ${O\in R}$ let ${{\rm{Hess}}(O) = {\rm{Hess}}\cap O}$ . One proves that Hess(O) is a Lagrangian submanifold of O ^sreg and that $${\rm{Hess}} = \sqcup_{O\in R}{\rm{Hess}}(O).$$ The main result of this paper is to show that there exists simultaneously over all ${O\in R}$ , an explicit polarization (i.e., a “fibration” by Lagrangian submanifolds) of O ^sreg which makes O ^sreg simulate, in some sense, the cotangent bundle of Hess(O).     

Effect of isospin-dependent cross-section on fragment production in the collision of charge asymmetric nuclei

To understand the role of isospin effects on fragmentation due to the collisions of charge asymmetric nuclei, we have performed a complete systematical study using isospin-dependent quantum molecular dynamics model. Here simulations have been carried out for $^{124}{\rm X}_{n}+^{124}{\rm X}_{n}$ , where n varies from 47 to 59 and for $^{40}{\rm Y}_{m}+^{40}{\rm Y}_{m}$ , where m varies from 14 to 23. Our study shows that isospin-dependent cross-section shows its influence on fragmentation in the collision of neutron-rich nuclei.     

Few-Body Aspects of Hypernuclear Physics

Recent development in the study of the structure of light Λ and double Λ hypernuclei is reviewed from the view point of few-body problems and interactions between the constituent particles. In the study the present author and collaborators employed Gaussian expansion method for few-body calculations; the method has been applied to many kinds of few-body systems in the fields of nuclear physics and exotic atomic/molecular physics. We reviewed the following subjects studied using the method: (1) Precise three- and four-body calculations of ${^7_{\Lambda}{\rm He}}$ , ${^7_{\Lambda}{\rm Li}}$ , ${^7_{\Lambda}{\rm Be}}$ , ${^8_{\Lambda}{\rm Li}}$ , ${^8_{\Lambda}{\rm Be}}$ , ${^9_{\Lambda}{\rm Be}}$ , ${^{10}_{\Lambda}{\rm Be}}$ , ${^{10}_{\Lambda}{\rm B}}$ and ${^{13}_{\Lambda}{\rm C}}$ provide important information on the spin structure of the underlying Λ N interaction by comparing the calculated results with the recent experimental data by γ-ray hypernuclear spectroscopy. (2) The Λ-Σ coupling effect was investigated in ${^4_{\Lambda}{\rm H}}$ and ${^4_{\Lambda}{\rm He}}$ on the basis of the N?+?N?+?N?+?Λ (Σ) four-body model. (3) A systematic study of double-Λ hypernuclei and the Λ Λ interaction, based on the NAGARA event data ( ${^6_{\Lambda\Lambda}{\rm He}}$ ), was performed within the α +?x?+?Λ +?Λ cluster model (x = n, p, d, t,³He and α) and α +?α +?n?+?Λ +?Λ cluster model, (4) The Demachi-Yanagi event was interpreted as observation of the 2⁺ state of ${^{10}_{\Lambda \Lambda}{\rm Be}}$ , (5) The Hida event was interpreted as observation of the ground state of ${^{11}_{\Lambda \Lambda}{\rm Be}}$ .     

Recent results on antiproton annihilation in 4He

With experimental data of ${\bar p}$ annihilation at rest on nuclei of ⁴He, collected by the Obelix spectrometer (LEAR, CERN), we have studied a number of reactions with 4 and 5 charged particles in the final state, distinguishing the annihilations on more than one nucleon, and with strangeness production. The main results of our observations are: (a) a higher (up to 20 times) strangeness production in ⁴He than in H; (b) the evidence of a possible signature of a $\overline{K}pp$ ( $\overline{K} ppn$ ) bound state; (c) a measurement of a double strangeness production (2K ⁺) and a hint for some production yields of double-strange bound systems like 2K ^?2n; (d) a signal compatible with the baryonic $\Theta^+(1530)$ resonance, interpreted as a pentaquark system.     

Fougerite FeII − III oxyhydroxycarbonate in environmental chemistry and nitrate reduction

The identification of the fougerite mineral responsible for the bluish-green shade of gleysols in aquifers as being the Fe^II???III oxyhydroxycarbonate $\text{GR}(\text{CO}_{3}^{2-})^*$ of formula, $[\text{Fe}^{\rm II}_{6x}\text{Fe}^{\rm III}_{6(1 - x)}\text{O}_{12}\text{H}_{2(7-3x)}]^{2+}\bullet[\text{CO}_{3}^{2-}\bullet3\text{H}_{2}\text{O}]^{2-}$ where the ferric molar ratio x = [Fe^III/Fe_total] is restricted to the domain [1/3–2/3] induces to study the reactivity of the synthetic green rust for reducing some major pollutants. The oxidation within the solid compound $\text{GR}(\text{CO}_{3}^{2-})^*$ in the presence of nitrates is followed by miniaturized Mössbauer spectrometer (MIMOS). Ratio x = [Fe^III/Fe_total] increases up to 0.67 where $\text{GR}(\text{CO}_{3}^{2-})^*$ transforms gradually into magnetite. This could well explain the composition variability of fougerite occurrences.     

{^6_{\Lambda} \rm{H}} Modeled as {^4_{\Lambda} \rm{H}} + n + n

A three-body calculation for the \({^4_{\Lambda} \rm{He}}\) and \({^6_{\Lambda}{\rm H}}\) hypernuclei has been undertaken. The respective cores are \({^4_{\Lambda}{\rm H}}\) . The interactions in the \({^6_{\Lambda}{\rm He}}\) system, modeled as \({^4_{\Lambda} {\rm H+p+n}}\) , are reasonably well known. For example, the p n interaction is well determined by the p n scattering data, the \({^4_{\Lambda}{\rm H}}\) –p interaction can be fitted to the \({^5_{\Lambda}{\rm He}}\) binding energy. The \({^4_{\Lambda}{\rm He}}\) –n interaction can be fitted to α–n scattering data. For the ⁴He–n system the s-wave can be modeled alternatively as a repulsive potential or as an attractive potential with a forbidden bound state. We explore these alternatives in ⁶He, because the interaction comes into play in modeling \({^6_{\Lambda}{\rm He}}\) as well as in our \({^4_{\Lambda}{\rm H}}\) + n + n model of \({^6_{\Lambda}{\rm H}}\) , where the valence neutrons are Pauli blocked from the s-shell of the core nucleus.     

Muonic Anti-hydrogen {(\bar{\rm H}_{\mu}}) Formation in Low-energy Three-body Reactions

A few-body type computation is performed for a three-charge-particle collision with participation of a slow antiproton ${\bar{\rm{p}}}$ and a muonic muonium atom (true muonium), i.e. a bound state of two muons ${(\mu^{+}\mu^{-})}$ in its ground state. The total cross section of the following reaction ${\bar{\rm p}+(\mu^{+}\mu^{-}) \rightarrow \bar{\rm{H}}_{\mu} + \mu^{-}}$ , where muonic anti-hydrogen ${\bar{\rm{H}}_{\mu}=(\bar{\rm p}\mu^{+})}$ is a bound state of an antiproton and positive muon, is computed in the framework of a set of coupled two-component Faddeev-Hahn-type equation. A better known negative muon transfer low energy three-body reaction: ${{\rm t}^{+} + ({\rm d}^{+}\mu^{-})\rightarrow ({\rm t}^{+}\mu^{-}) + {\rm d}^{+}}$ is also computed as a test system. Here, t⁺ is triton and d⁺ is deuterium.     

Studies of the three-nucleon system dynamics: Cross sections of the deuteron-proton breakup at 130 MeV

The three-nucleon system is the simplest non-trivial testing ground in which the quality of modern nucleon-nucleon interaction models, as well as additional dynamical ingredients referred to as three-nucleon forces, can be probed quantitatively by means of a rigorous technique of solving the Faddeev equations. A large set of high precision, exclusive cross-section data for the $^1{\rm H}({\vec d},pp)n$ breakup reaction at 130?MeV was obtained at KVI, Groningen. It allowed to establish for the first time a clear evidence of the three-nucleon force contributions to the cross sections of the breakup process and to confirm recent predictions of sizable influences of the Coulomb force in this reaction.     

{{\psi(3S)}} and {{\Upsilon(5S)}} Originating in Heavy Meson Molecules: A Coupled Channel Analysis Based on an Effective Vector Quark–Quark Interaction

In our previous coupled channel analysis based on the Cornell effective quark–quark interaction, it was indicated that the ${\psi(3S)}$ solution corresponding to ${\psi(4040)}$ originates from a ${{\rm D}^{^{*}}\overline{{\rm D}}^{*}}$ channel state. In this article, we report on a simultaneous analysis of the ${\psi}$ - and ${\Upsilon}$ -family states. The most conspicuous outcome is a finding that the ${\Upsilon(5S)}$ solution corresponding to ${\Upsilon(10860)}$ originates from a ${{\rm B}^{*}\overline{{\rm B}}^{*}}$ channel state, very much like ${\psi(3S)}$ . Some other characteristics of the result, including the induced very large S–D mixing and relation of some of the solutions with newly observed heavy quarkonia-like states are discussed.     

Mössbauer spectroscopy in the investigation of new mineral–related materials

New materials based on the composition of the mineral schafarzikite, FeSb $_{2}\textit {O}_{4}$ , have been synthesised. $^{57}$ Fe- and $^{121}$ Sb- Mössbauer spectroscopy shows that iron is present as Fe $^{2+}$ and that antimony is present as Sb $^{3+}$ . The presence of Pb $^{2+}$ on the antimony sites in materials of composition FeSb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ induces partial oxidation of Fe $^{2+}_{}$ to Fe $^{3+}$ . The quasi-one-dimensional magnetic structure of schafarzikite is retained in FeSb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ and gives rise to weakly coupled non-magnetic Fe $^{2+}$ ions coexisting with Fe $^{3+}$ ions in a magnetically ordered state. A similar model can be applied to account for the spectra recorded from the compound Co $_{0.5}$ Fe $_{0.5}$ Sb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ .