环面黑洞背景下量子场的熵

利用薄层（改进的brick-wall模型），通过分别求解标量场方程和Dirac场方程，计算了环面黑洞事件视界附近的标量场和Dirac场的量子统计熵.按薄层模型的观点，在视界面附近薄层上的量子场的熵就是黑洞的熵.结果表明，黑洞熵正比于事件视界的面积，遵循Beken-stein-Hawking面积熵公式. 关键词： 熵 环面黑洞 薄层模型 量子场     

钩藤中异钩藤碱在TLC原位的FT-SERS研究

本文报道了将薄层色谱（TLC）与傅里叶变换表面增强拉曼散射（FT－SERS）联用，获得了中草药钩藤中的异钩藤碱光谱研究的新方法。研究表明，在薄层原位，2.5μg钩藤总碱可将异钩藤碱等8种生物碱完全分离。应用薄层原位的薄层色谱傅里叶变换表面增强拉曼散射（TLC－FT－SERS）技术，获得异钩藤碱分子的特征振动谱带，进而阐述了样品分子在银胶表面的吸附模式，异钩藤碱以分子中氧化吲哚基团上N原子的孤子电子对和吲哚环π电子共同吸附于银晶体微粒表面,1.615cm^-1与芳环骨架振动和氧化吲哚N－H变形振动相关的峰获得最大增强。说明TLC－FT－SERS对中草药化学成分进行高灵敏度示踪指纹检测的可靠性和优越性。     

板底薄层的超声谐振检测分析

理论上研究了带有薄层的板的超声谐振频率随薄层的厚度或物性改变而发生变化的规律,研究结果表明,在0≤ω相似文献   

基于热力学极值原理优化污泥干燥过程

本文在热风对流干燥实验台上进行污泥薄层等温干燥特性的实验研究,获得了一定风速下温度对薄层含水率影响规律。基于多元系热力学原理,构建了薄层含水率的双结构预测模型。基于热力学极值原理,分析污泥水分迁移过程中吉布斯函数的变化规律,以对薄层干燥工况方案进行优化。结果表明:双结构模型可用于预测薄层含水率的变化情况;在2 m/s风速下,薄层含水率从80%降低到60%时,控制干燥温度为100℃左右;含水率从60%降低到10%,应保持干燥温度在150℃左右。     

多孔薄层强化竖管外壁凝结换热的理论研究

1前言在壁上涂以极薄多孔层以强化凝结换热的问题很少研究过。目前，只有几位学者对恒壁温的短平壁进行了初步的研究［‘－‘l，而对坚圆管尚未见有人研究。为密切与实际应用相结合，我们对具有涂层的变壁温的长竖管进行了理论和实验研究，本文就理论问题进行了探讨。2理论模型及数值计算多孔薄层很薄，故凝液膜边界层被分成两层：内层（多孔薄层液膜层）和外层（纯液膜层）。系统简图如图1。坚管外壁上喷涂上一层导热率较高的多孔介质薄层。厚度为h，热导率为k。，孔隙率为。，渗透率为Kp，管长为L，壁温为几，蒸汽饱和温度为Ts，凝液膜…     

颗粒多孔层在真空状态下的沸腾两相流与传热

在前文［１］实验研究的基础上，利用带液池的多孔壁微热虹吸蒸发段模型，对颗粒多孔薄层在真空状态下的沸腾两相流与传热进行了分析，综合实验数据，建立了传热关联式。     

基于JASMIN平台的复合材料方舱SE快速评估

在时域有限差分（FDTD）法中采用亚网格边界条件（SGBC）法对复合材料薄层结构进行建模,可以突破复合材料薄层对空间步长的限制从而大大降低计算成本。基于大规模并行化平台JASMIN实现了SGBC-FDTD算法,通过对复合材料薄层结构的自动建模和适配,实现对复合材料薄层的快速并行化处理。利用所开发的并行SGBC-FDTD算法计算分析了含不同电磁特性复合材料薄层方舱在0.1～1.0 GHz内的电磁屏蔽效能,结果表明采用并行SGBC-FDTD算法的计算结果与全波分析软件计算结果吻合完好,且计算效率显著提升。     

薄层扫描法测定黑皮秦艽中龙胆苦甙的含量

用薄层扫描法对黑皮秦艽中龙胆苦甙的含量进行测定，结果表明黑皮秦艽中龙胆苦甙的含量为0.467%，RSD＝1.95%。     

Gibbons-Maeda dilaton 黑洞的纠缠熵

按纠缠熵方法，计算了Gibbons-Maeda(G-M)dilaton黑洞视界外部与黑洞内量子态纠缠的一薄层内量子场的统计熵，得到了G-M dilaton黑洞的Bekenstein-Hawking熵.用广义不确定原理对量子态密度进行修正，克服了brick-wall模型中视界附近态密度的发散困难，该薄层可以紧贴在事件视界上.对brick-wall外部量子场中与黑洞内自由度有关联的自由度统计熵进行了计算，并把结果与brick-wall内量子场的熵进行比较分析，显示两结果具有与视界面积成正比的一致性，但后者能更 关键词： 纠缠熵 黑洞 广义不确定原理 截断     

经典瑞利-泰勒不稳定性界面变形演化的改进型薄层模型

激光惯性约束聚变(ICF)内爆靶丸通常采用多壳层组合结构设计,各壳层界面的流体力学不稳定性影响内爆加速和聚变点火,是ICF十分关心的问题.本文建立了描述任意Atwood数、任意初始界面分布Rayleigh-Taylor(RT)不稳定性界面变形及非线性演化的薄层模型.通过分析薄层中流体微团的受力,得到了运动微分方程组,并在二维情况进行数值求解.在线性阶段,薄层模型描述的界面演变规律与模拟结果符合很好;在非线性阶段,薄层模型可以描述至"蘑菇"形结构,与数值模拟的结果很接近.目前薄层的RT不稳定性非线性解析理论研究仅限于弱非线性阶段,本工作发展的薄层解析理论能很好地研究薄层非线性"气泡-尖钉"发展过程.     

Effect of ausforming temperature and strain on the bainitic transformation kinetics of a low carbon boron steel

The effect of ausforming temperature and strain on the bainitic transformation kinetics was investigated in a low carbon boron steel. A new mechanism, which is based on the competition between the increase in nucleation rate and the decrease in average volume of bainite sheaf after deformation, is proposed. The increase in nucleation rate is due to the decrease in boron concentration at the grain boundaries after small deformation and the formation of sub-grain boundaries at the grain interior after large deformation. The decrease in average volume of bainite sheaf is ascribed to the frequent impingement of bainite sub-units after deformation. The increase in nucleation rate after deformation results in the decrease in incubation time, which is confirmed from the experiment. The increase in nucleation rate overcomes the decrease in average volume of bainite sheaf, resulting in the increase in transformation velocity and volume fraction after small deformation. On the contrary, the decrease in the average volume of bainite sheaf overcomes the increase in nucleation rate after large deformation, leading to the decrease in transformation velocity and volume fraction of bainite.     

微波消解-ICP-AES测定鄱阳湖流域沉积物中微量元素

为了研究鄱阳湖沉积物中微量元素近几年来随季节、年度及沿程的变化情况,对2003年和2005年不同季节采集的鄱阳湖流域各采样点底泥进行了ICP-AES测定.结果表明,鄱阳湖沉积物中各元素的含量随着季节和年度变化而发生一定改变,枯水期普遍大于丰水期;南矶山2005年Cu和Pb含量较2003年有所降低;蔡家湾则与南矶山相反;姚公渡2005年Cu含量也较2003年低,Pb含量则高于2003年;与鄱阳湖流域底泥背景值相比,所测几个样点的Cu,Pb,Cr和Zn含量均在一定程度上超标;除大坞河外,其余各样点As含量均在背景值范围内;从饶河到鄱阳湖入湖口处,各元素含量呈逐渐降低趋势.文章提出的研究方法操作简便,效率高,劳动强度低.     

XPS and SIMS investigation on the role of nitrogen in Si nanocrystals formation

Since the demonstration of optical gain in silicon nanocrystals, in the last few years several papers appeared in the literature reporting gain measurements in silicon nanocrystals embedded in a silica matrix produced by different techniques. However, it is still unclear which are the structural, physical and chemical factors that contribute to enhance photoluminescence and gain in this type of samples. In particular, the presence and the role of nitrogen in the SiO₂ matrix are in fact supposed to be essential factors in understanding the gain mechanism.In fact it is possible to obtain similar samples with very different nitrogen content in the silica matrix changing one of the precursor gases used in the deposition process, thus evidencing the structural and chemical differences introduced by the presence of nitrogen. In this paper SIMS and XPS analysis of two series of similar samples, but with a very different nitrogen content, will be presented and compared. The data collected at different annealing temperatures, together with ellipsometric measurements, give important information on the role played by the nitrogen present in the matrix in the process of silicon nanocrystal formation. Moreover, we demonstrate that the annealing process causes always some oxidation of the sample surface and that nitrogen is incorporated in the material from the annealing atmosphere in nitrogen free samples.     

An fMRI study of magnitude comparison and exact addition in children

By contrast to the adult literature, in which a consistent parietofrontal network for number processing has been identified, the data from studies of number processing in children have been less consistent, probably due to differences in study design and control conditions. Number processing was examined using functional magnetic resonance imaging in 18 right-handed children (8–12 years) from the Cape Coloured community in Cape Town, South Africa, using Proximity Judgment and Exact Addition (EA) tasks. The findings were consistent with the hypothesis that, as in adults, the anterior horizontal intraparietal sulcus (HIPS) plays a major role in the representation and manipulation of quantity in children. The posterior medial frontal cortex, believed to be involved in performance monitoring in more complex arithmetic manipulations in adults, was extensively activated even for relatively simple symbolic number processing in the children. Other areas activated to a greater degree in the children included the left precentral sulcus, which may mediate number knowledge and, for EA, the head of the caudate nucleus, which is part of a fronto-subcortical circuit involved in the behavioral execution of sequences. Two regions that have been linked to number processing in adults — the angular gyrus and posterior superior parietal lobule — were not activated in the children. The data are consistent with the inference that although the functional specialization of the anterior HIPS may increase as symbolic number processing becomes increasingly automatic, this region and other elements of the parietofrontal network identified in adults are already reliably and robustly activated by middle childhood.     

Spectral Properties of Single BODIPY Dyes in Polystyrene Microspheres and in Solutions

The absorption, fluorescence, fluorescence quantum yield, and photostability of five BODIPY dyes are characterized and compared as single dyes in two environments, in 40-nm polystyrene spheres and in solution. The absorption and fluorescence spectra of the dyes in spheres are similar in profile but shifted to lower energies compared to those in solution. All the dyes are highly fluorescent, with three having fluorescence quantum yields of 1.0. For three of the five dyes, the yields were the same in spheres as in solution (1.00, 1.00, and 0.73). The high concentration of these dyes in spheres does not quench their fluorescence. For two other dyes the yields dropped, from 1.00 to 0.55 in one case and 0.83 to 0.50 in another, comparing the dyes in solution versus in spheres. The photodegradation of the dyes decreases in spheres compared to in solution in all but one case. For one dye, it decreases as much as 800-fold. Dyes overlooked because of low fluorescence or stability in solution could become useful fluorescent materials in the microsphere environment.     

ICP-AES测定云南楚雄糖尿病患者发样微量元素的研究

探讨微量元素与糖尿病间的关联性及临床意义。采用ICP-AES等离子体发射光谱仪测定了楚雄地区糖尿病患者人发中11种元素,采用2,3-二氨基萘荧光法测定发样中的硒元素。选取糖尿病患者120例,对照组35例。糖尿病组发样中常量元素Ca、Mg低于对照组,P高于对照组;除Cd、Cr、Fe外,微量元素Zn、Se、Ni、Mn、Cu等5种元素低于对照组,并有显著差异(P0.01)。糖尿病组间性别比较数据显示男性除发Ni、Mn、P外,其余元素含量均低于女性,其中发锌远低于女性。3个不同年龄段糖尿病人群的微量元素含量变化显示Fe、P2种元素随年龄增加含量增高;Mg、Cd2种元素随年龄增加含量减少;其余各元素变化情况为Fe、P元素在老年组中较高,Cu、Cd、Mg较低;Mn、Cr、Cu元素含量在中年组中较高,而Zn、Se略低;Zn、Se在青年组较高,而Mn、Cr低。城市人群发中Zn、Cd、Cu、Mg、Ca含量比农村人群高;Se元素含量二者间差别也不大,其余元素含量均低于农村人群。楚雄地区糖尿病患者发中Zn、Se、Mg、Mn4种元素水平低,楚雄地区糖尿病患者致病原因可能与地区属低Se水平和患者体内硒水平低有关。     

Sex differences in human cardiovascular responses to external excitation

Summary The purpose of this study was to investigate the sex particularities in human cardiovascular responses to different external influences using the traditional physiological approach and non-traditional methods of dynamical systems theory. Measurements were taken in 21 healthy women and 15 men exposed to noise stress, passive coping, and in 35 women and 25 men exposed to double mental arithmetic stress, active coping. Results showed that, firstly, cardiovascular reactivity in men and women was determined by the type of stress. Thus, in a majority of humans heart rate did not change during noise but increased during mental stress, blood pressure decreased during noise but increased during mental stress. Secondly, results demonstrated the significant sex differences in the basal and stress cardiovascular activity. So, the women showing the greater basal and stress heart rate displayed the hypotensive responses to passive coping more often and the hypertensive responses to active coping less often than men. Thirdly, the changes in normalized entropy of the electrocardiogram signal, reflecting the changes in heart physiological variability, also depended on the sex of subjects and the nature of stress. During noise normalized entropy increased in a majority of women but decreased in a majority of men. Mental stress caused both decreases and increases in normalized entropy in men and women. But the increases in normalized entropy during stress and especially during recovery were greater in women than in men. Normalized entropy was demonstrated to be a more sensitive marker of sex and individual differences in cardiovascular responses to stress than heart rate and blood pressure. Results suggest that the lower blood pressure reactions and the greater increases in normalized entropy,i.e. in physiological heart variability, may partly result in higher cardiovascular stress resistance in women relative to men. Paper presented at the International Workshop ?Fluctuations in Physics and Biology: Stochastic Resonance, Signal Processing and Related Phenomena?, Elba, 5–10 June 1994.     

胶磷矿中杂质赋存形式及酸解过程变化

我国中低品位胶磷矿量大、分布广,磷矿中杂质种类及含量对于磷石膏结晶及磷酸品质均有较大影响。以湖北某地区的典型低品位胶磷矿为原料,采用X射线光电子能谱仪、扫描电镜、能谱等方法,分析了磷矿及反应后磷石膏中的主要杂质种类及含量变化,并以此推测湿法磷酸过程中杂质的主要变化。结果表明磷矿中的主要成分是氟磷灰石和石英,杂质组分占比最高的分别是硅、铝、氟、镁,其中硅主要以石英和硅酸钙存在,氟主要存在于氟磷酸钙中,铝是以不同形式的铝硅酸盐存在的,而镁则是以MgF₂和部分硅酸盐存在。通过酸解反应,钙与硫酸根生成磷石膏,硅元素主要存在于固相石膏中,而铝、氟、镁则大部分进入到液相磷酸中,其中存在于固相中的硅则基本以石英形式存在,硅酸钙溶解于酸液中,铝主要以铝硅磷的化合物存在,氟则以氟硅化物形式存在,大部分的MgF₂溶解进入液相,磷石膏中镁主要以镁硅酸盐形式存在。通过磷矿中杂质存在形式及反应过程的变化研究,可以更好的明晰酸解过程中的体系变化,从而为磷石膏结晶过程的考察和控制提供理论基础。     

用原子吸收光谱法分析铁路运输对周边脐橙种植园土壤元素的影响

铁路运输在推动路域经济发展的同时,也会对路域生态环境带来某些不良影响。水果品质与种植园土壤元素含量有直接关系,研究铁路周边脐橙种植园土壤元素含量对于农产品安全以及铁路周边生态环境建设都具有十分重要的意义。脐橙是一种人们十分喜欢的优质水果,在铁路周边尤其是四川省、重庆市、湖北省、江西省、贵州省等南方地区的铁路周边的栽种面积很大。应用原子吸收光谱法检测了四川省金堂县境内1997年建成的成达铁路沿线脐橙种植园土壤与对照土壤中Pb,Cd,Mn,Cu,Zn等多种元素的含量。结果表明, 铁路周边脐橙种植园土壤中重金属元素Pb和中量元素Mn比对照土壤增加明显,但重金属元素Cd与微量元素Cu和Zn在铁路周边脐橙种植园土壤与对照土壤之间差别并不明显。     

污染土壤对脐橙叶片镉含量影响的光谱预测

近年来可见-近红外光谱技术在农业污染监测中应用越来越广泛,但在果树的重金属污染研究中应用较少。本文以纽荷尔脐橙(Citrus sinensis[L.]Osbeck cv. Newhall)为研究对象,采用盆栽方法,通过添加镉（Cd）形成不同污染程度的土壤,然后定期监测叶片中Cd含量及其光谱,分别建立了基于光谱指数的线性回归预测模型,以及基于偏最小二乘回归（PLSR）的Cd含量高光谱预测模型。结果表明：Cd更容易向新叶迁移和聚集,在高Cd污染的土壤中这种现象更加明显;新叶光谱在700～730 nm之间反射率升高,发生红边蓝移现象,老叶光谱没有显著变化;基于光谱指数建立的线性回归模型的R2达到0.8左右,而利用PLSR方法建立的预测模型精度普遍高于线性回归模型,其R2达到0.9左右,并且标准归一化（SNV）的光谱预处理方法可以显著提高PLSR模型的预测精度。研究显示,可见-近红外光谱技术在脐橙重金属污染监测上有很好的潜力。