Solvent extraction separation of In/III/-Tl/III/ and Hg/II/-Cd/II/-Co/II/ with sulphoxides

Solvent extraction studies have been made on some metals: In/III/-Tl/III/ and Hg/II/-Cd/II/-Co/II/, from ammonium thiocyanate solutions by dialkyl sulphoxides. Separation of these metals from one another can be achieved by suitable choice of the extracted conditions. The nature of the extractable metal species has been elucidated.     

Synthesis of chlorobis/β-diketonato/oxotechnetium/V/ and tris/β-diketonato/technetium/III/ complexes

Chlorobis/-diketonato/ oxotechnetium/V/ complexes [TcOCl/-dik/₂, -diketone=acetylacetone, benzoylacetone and dibenzoylmethane] were newly synthesized using macroamount of⁹⁹Tc. These complexes were further separated into geometrical isomers. Furthermore, an improvement of the yields for the syntheses of tris/-dike-tonato/technetium/III/ complexes [Tc/-dik/₃, -diketone=acetylacetone, benzoylacetone and 2-thenoyltrifluoroacetone] was examined using Tc/III/-thiourea complexes as a starting material.     

Separation of Tl/III/ from Tl/I/

A method for the separation of Tl/III/from Tl/I/ is reported employing 1-/2-pyridylazo/-2-naphthol /PAN/ and Rhodamine-B as extracting agents.     

Base hydrolysis of halobis/8-quinolinolato/ oxotechnetium/V/ complexes

Reaction mechanism of base hydrolysis of halobis/8-quinolinolato/oxotechnetium (V) /TcOX (ox)₂ X=Cl and Br/ was investigated by means of solvent extraction and spectrophotometric methods. Furthermore, distribution coefficients of tris/acetylacetonato/technetium/III/, dichlorobis/8-quinolinolato/technetium/IV/ and TcOX/ox/₂ between chloroform and aqueous solutions were determined. In an alkaline solution, TcOX/ox/₂ decomposed to pertechnetate as a final product. On the basis of the established base hydrolysis, the respective rate constants were determined.     

Separation of Th/IV/ and U/VI/ by extraction chromatography

Application of extraction chromatographic technique to the analytical separation of Th/IV/ and U/VI/ has been investigated. The stationary phase was a macroporous resin Amberlite XE-270 impregnated with undiluted trin-n-butylphosphate /TBP/ and the mobile phase was either 5.OM HNO₃ or 6M HCl. Separation of traces of Th/IV/ from large quantities of U/VI/ was achieved on a laboratory column by elution of the absorbed Th/IV/ with 6M HCl.     

Recoil implantation reaction in geometrical isomers of tris/benzoylacetonato/chromium/III/

Hot atom chemical reaction by⁵⁰Cr/n, /⁵¹Cr and⁵²Cr/, n/⁵¹Cr reactions, and recoil implantation reaction by⁵¹V/p, n/⁵¹Cr reaction were investigated using geometrical isomers /mer and fac/ of tris/benzoylacetonato/ chromium/III/ /Cr/ba/₃/. The production of counter isomer was observed for both mer- and fac-targets, although the yield of labelled parent isomer was larger. The observed mer/fac yield ratio suggests that the main formation mechanism of⁵¹Cr/ba/₃ is the reaction of ba^– and Cr/ba/ ₂ ⁺ which has the same geometrical configuration of target complex, and the substitution reaction of central metal atom by recoil⁵¹Cr. Furthermore, implantation gave rise to a much higher yield of labelled Cr/ba/₃ compared to the case of in situ nuclear recoils.     

Exploiting the complementary nature of LC/MALDI/MS/MS and LC/ESI/MS/MS for increased proteome coverage

The goal of this work was to evaluate the improvement in proteome coverage of complex protein mixtures gained by analyzing samples using both LC/ESI/MS/MS and LC/MALDI/MS/MS. Parallel analyses of a single sample were accomplished by interfacing a Probot fractionation system with a nanoscale LC system. The Probot was configured to perform a post-column split such that a fraction (20%) of the column effluent was sent for on-line LC/ESI/MS/MS data acquisition, and the majority of the sample (80%) was mixed with a matrix solution and deposited onto the MALDI target plate. The split-flow approach takes advantage of the concentration sensitive nature of ESI and provides sufficient quantity of sample for MALDI/MS/MS. Hybrid quadrupole time-of-flight mass spectrometers were used to acquire LC/ESI/MS/MS data and LC/MALDI/MS/MS data from a tryptic digest of a preparation of mammalian mitochondrial ribosomes. The mass spectrometers were configured to operate in a data dependent acquisition mode in which precursor ions observed in MS survey scans are automatically selected for interrogation by MS/MS. This type of acquisition scheme maximizes the number of peptide fragmentation spectra obtained and is commonly referred to as shotgun analysis. While a significant degree of overlap (63%) was observed between the proteins identified in the LC/ESI/MS/MS and LC/MALDI/MS/MS data sets, both unique peptides and unique proteins were observed by each method. These results demonstrate that improved proteome coverage can be obtained using a combination of these ionization techniques.     

The radiolysis of aqueous solution of bis/1,2-dicarbollyl/cobalt/III/ acid

The radiation-induced oxidation of bis/1,2-dicarbollyl/cobalt/III/ acid by OH radicals in deaerated/aerated aqueous solutions has been investigated. 8-Monohydroxy-, and 8,8-dihydroxy-derivatives have been identified as products of the -radiolysis. For the different conditions the following radiationchemical yields were observed: in the presence of N₂ atmosphere G/_OHDCC/=1.58, in aerated solution 2.11 and 3.04 in a solution saturated with CCl₃.     

Isotope exchange behaviour of bis/diethyldithiocarbamate/mercury/II/ complex

Isotope exchange behaviour of bis/diethyldithiocarbamate/mercury/II/ complex has been studied at 25°C and 45°C varying the concentrations of both metal ion and the complex. The results show that the complex is kinetically labile. Temperature has a significant effect on the rate of the reaction. Increase in concentration increases the reaction rate.     

Storage-Reduction of NOx over Combined Catalysts of Pt/Ba/Al2O3-Mn/Ba/Al2O3： Carbon Monoxide as Reductant

Storage-reduction of NOx by carbon monoxide was investigated over combined catalysts of Mn/Ba/Al2O3-Pt/Ba/Al2O3. Combination of Mn/Ba/Al2O3 and Pt/Ba/Al2O3 catalysts in different ways showed excellent NOx storage-reduction performance and the content of Pt could be reduced by 50%. Not only the addition of 5Mn/15Ba/Al2O3 to lPt/15Ba/Al2O3 could improve its storage ability, but also enhance the NOx conversion consequently. NOx conversion over the combined catalysts (the combined catalysts I and II) was increased under dynamic lean-rich burn conditions, the maximum NOx conversion increased from 69.4% to respectively 78.8% and 75.7% over two combined catalysts.     

Physico-chemical studies on thermal analyses of sodium hexa/carboxylato/ferrates/III/

Journal of Radioanalytical and Nuclear Chemistry - The thermal decomposition of sodium hexa-carboxylato/ferrates/III/ i.e. Na3[Fe/RCOO/6].xH2O /R=H, CH3, C2H5/ has been studied at various...     

Photocatalytic conversion of NOx on AgCl/Al2O3 catalyst

The rate of NO conversion under UV illumination was evaluated over Ag/Al₂O₃ and AgCl/Al₂O₃ catalysts at room temperature. The AgCl/Al₂O₃ catalyst is highly active for the conversion of NO_x. The conversion is enhanced in the presence of O₂ and further enhanced when oxygen coexists with hydrocarbons. Diffuse reflectance spectra of AgCl/Al₂O₃ and Ag/Al₂O₃ show an absorption band at 250 nm, and a weak and broad band at 230 nm, respectively. The high photocatalytic NO_x conversion is achieved over the AgCl/Al₂O₃ catalyst. The conversion level of NO_x is maintained above 60% over 5 h in the presence of O₂ and hydrocarbons under UV-irradiation. The absorption band at 250 nm is ascribed to the band gap energy of crystallized AgCl particles on Al₂O₃. These results suggest that high photocatalytic NO_x conversion proceeds on crystallized AgCl particles formed on Al₂O₃.     

Au/PATP/PANI膜电极和Au/PATP/PANI/TiO2膜电极的光电化学

聚苯胺（PANI）是一种结构、 性质不同于聚乙炔和聚吡咯的新型导电高聚物,有着十分广泛的应用[1,2].近年来利用光电化学研究聚苯胺的电子结构、 掺杂情况引起人们的重视[3～5].在酸性溶液中电聚合制备聚苯胺的循环伏安曲线上出现两对氧化还原峰,其峰值电位分别为E11/2=0.13 V和E21/2=0.7 V(对饱和甘汞电极).通过改变电极电位,可获得部分氧化态、还原态、氧化态等3种状态的聚苯胺.部分氧化态具有金属导电性,还原态和氧化态均为绝缘体.本文测量3种状态聚苯胺膜电极的光电响应,首次得到其光电流谱,发现聚苯胺一些新的光电化学实验结果.提出了覆盖绝缘体的金属内发射的光电化学模型.同时,在聚苯胺膜上电沉积纳米TiO2微粒膜,得到广谱区的复合光电材料.     

Stability constants of complexes of uranium/VI/ and plutonium/VI/ with succinate ions

The stability constants of the complexes formed by U/VI/ and Pu/VI/ with succinate ions were determined in 0.5M NaClO₄ medium at 30°C following the Bjerrum-Calvin pH titration technique. The stability constants obtained agreed with values reported in literature following the same technique. The values for the second complexes were reported for the first time. U/VI/ complexes were found to have stabilities higher than the corresponding Pu/VI/ complexes in accordance with the acidities of the cations.     

Studies on licand displacement of thiourea in technetium/III/-coordination compounds by chlorine and 1,2 bis/diphenylphosphino/-ethane /dppe/

Ligand displacement reaction between Tc/III/-thiourea complexes and the model ligand 1,2 bis/diphenylphosphino/ ethane /dppe/ were investigated. The results appear unfavourable to the purpose of synthesizing Tc/III/ dppe complexes.     

The recoil reaction of technetium in mer- and fac-tris/benzoylacetonato/ruthenium/III/

The recoil reactions of technetium produced by¹⁰⁰Ru/γ, p/^99mTc reaction were studied in γ-irradiated mer- and fac-Ru/ba/₃ targets. Yields of mer- and fac-Tc/ba/₃ were determined by column chromatographic separation developed in our previous work. In the initial recoil reaction yields mer-form of Tc/ba/₃ was much more abundant than fac-form in the mer-Ru/ba/₃, but the reverse held good in the fac-Ru/ba/₃ showing selectivity in recoil replacement reactions in geometrical isomers. In the annealing reactions, however, such selectivity disappeared and the fac/mer ratio for the annealed portions could be explained by the following mixed mechanisms of ligand incorporation. $$\begin{gathered} Tc/ba/_2^ + + ba^ - \to Tc/ba/_3 \hfill \\ Tc/ba/^{2 + } orTc^{3 + } + xba \to Tc/ba/_3 \hfill \\ /x = 2or3/. \hfill \\ \end{gathered} $$      

Separation of iron/III/ from manganese/II/ in basalts by solvent extraction

The separation of iron/III/ from manganese/II/ by solvent extraction from hydrochloric acid to the chloroform solution of acetylacetone was applied to the analysis of basalts. The results after single and double separation of iron/III/ from manganese/II/ in basalts are presented.     

Isotope exchange study of tris/diethyl dithiocarbamate/chromium/III/ complex

Metal exchange behaviour of tris/diethyl dithiocarbamate/ chromium/III/ complex has been studied at 25°C and 35°C varying the concentration of the metal ion and the complex. Experimental observation showed that the complex is kinetically labile. Temperature and concentration increase, increases the rate of reaction.     

荧光粉Ba5-3x/2B4O11∶xEu3+的制备及发光性能

采用高温固相烧结法成功制备了Ba_5-3x/2B₄O₁₁∶xEu³⁺(x=0.02~0.22)荧光粉,利用XRD和SEM等对荧光粉进行了结构和形貌表征。 在激发波长为393 nm的条件下,发射峰(596、621、657和706 nm)与Eu³⁺的⁵D₀-⁷F_J(J=1,2,3,4)电子跃迁相对应,其中621 nm最强发射峰由Eu³⁺离子⁵D₀→⁷F₂电偶极跃迁造成。 文章还研究了Eu³⁺掺杂浓度对Ba_5-3x/2B₄O₁₁∶xEu³⁺发光性能的影响,结果表明,荧光粉的发光强度随着Eu³⁺掺杂量的增加呈现先增大后减小的趋势,Eu³⁺最佳掺杂量为0.16。     

TiO2包覆对LiCo1/3Ni1/3Mn1/3O2材料的表面改性

为了提高材料LiCo1/3Ni1/3Mn1/3O2的循环性能, 采用浸渍-水解法对其进行TiO2包覆. 用X射线衍射(XRD)、电化学交流阻抗谱(EIS)、电感耦合等离子体发射光谱(ICP-OES)和恒流充放电测试研究包覆材料的结构和电化学性能. TiO2仅在材料表面形成包覆层, 并未改变材料的结构. TiO2包覆能提高材料LiCo1/3Ni1/3Mn1/3O2的倍率性能和循环性能, TiO2包覆后的材料在5.0C(1.0C=160 mA·g-1)下的放电容量达到0.2C下的66.0%, 而包覆前的材料在5.0C下的放电容量仅为其0.2C下的31.5%. 包覆后的材料在2.0C下循环12周后的容量没有衰减, 而未包覆的材料容量保持率仅为94.4%. EIS测试表明包覆材料性能的提高是由于循环过程中材料的界面稳定性得到了提高. 循环后材料的XRD和ICP-OES测试表明, 包覆层能提高材料LiCo1/3Ni1/3Mn1/3O2的结构稳定性.