Electron-impact ionization and dissociation of C<Subscript>2</Subscript>D<Superscript>+</Superscript>

Absolute cross sections for electron-impact single ionization, dissociative excitation and dissociative ionization of the ethynyl radical ion (C₂D⁺)^+) have been measured for electron energies ranging from the corresponding reaction thresholds to 2.5 keV. The animated crossed electron-ion beam experiment is used and results have been obtained for the production of C₂D²⁺, C²⁺, C₂⁺_2^+ , CD⁺, C⁺ and D⁺. The maximum of the cross section for single ionization is found to be (2.01 ± 0.02) × 10^-17 cm², at the incident electron energy of 105 eV. Absolute total cross sections for the various singly charged fragments production are observed to decrease by a factor of almost three, from the largest cross-section measured for C⁺, over C₂⁺_2^+ and CD⁺ down to that of D⁺. The maxima of the cross sections are obtained to be (14.5 ± 0.5) × 10^-17 cm² for C₂⁺_2^+, (12.1 ± 0.1) × 10^-17 cm² for CD⁺, (27.7 ± 0.2) × 10^-17 cm² for C⁺ and (11.1 ± 0.8) × 10^-17 cm² for D⁺. The smallest cross section is measured to be (1.50 ± 0.04) × 10^-18 cm² for the production of the doubly charged ion C²⁺. Individual contributions for dissociative excitation and dissociative ionization are determined for each singly-charged product. The cross sections are presented in closed analytic forms convenient for implementation in plasma simulation codes. Kinetic energy release distributions of dissociation fragments are seen to extend from 0 to 6 eV for the heaviest fragment C₂⁺_2^+, up to 11.0 eV for CD⁺, 14.2 eV for C⁺ and 11.2 eV for D⁺ products.     

Charge exchange collisions of H<Superscript>+</Superscript>/D<Superscript>+</Superscript> ions with alkaline Earth atoms (Ca,Mg)

The Classical Trajectory Monte Carlo (CTMC) Method has been used to calculate the differential, partial and total single electron capture cross sections for the collision of H⁺/D⁺ with Ca and Mg atoms in the energy range of 1–100 keV. The differential cross sections at angles near the diffraction limit (<0.1^○) in both systems show a forward peak followed by an asymptotic fall at higher angles. Total and partial capture cross sections are found to be in good agreement with the experimental observations. Oscillations in the partial capture cross sections have been explained due to the swapping of the field electron. Isotope effect in the electron transfer is reported to be negligible.     

Na<Superscript>+</Superscript>/K<Superscript>+</Superscript> selectivity in the formation of ion pairs in aqueous solutions

The integral equations of liquids (RISM) and molecular dynamics method were used to calculate the mean force potential for the SO₃ and COO hydrophilic groups and the CH₃ hydrophobic group in the acetate, methyl sulfonate, and hydrosulfate anions, which form ion pairs with sodium and potassium cations in water. The carboxyl group selectively binds sodium ions from solutions containing Na⁺ and K⁺ ions, in spite of their equal charges, because the potassium ion experiences stronger steric hindrances near this group compared with sodium. The biophysical consequences of the revealed selectivity are discussed.     

Effect of high doses of N<Superscript>+</Superscript>, N<Superscript>+</Superscript> + Ni<Superscript>+</Superscript>, and Mo<Superscript>+</Superscript> + W<Superscript>+</Superscript> ions on the physicomechanical properties of TiNi

The surface layer of an equiatomic TiNi alloy, which exhibits the shape memory effect in the martensitic state, is modified with high-dose implantation of 65-keV N⁺ ions (the implantation dose is varied from 10¹⁷ to 10¹⁸ ions/cm²). TiNi samples are implanted by N⁺, Ni⁺-N⁺, and Mo⁺-W⁺ ions at a dose of 10¹⁷–10¹⁸ cm⁻² and studied by Rutherford backscattering, scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction (glancing geometry), and by measuring the nanohardness and the elastic modulus. A Ni⁺ concentration peak is detected between two maxima in the depth profile of the N⁺ ion concentration. X-ray diffraction (glancing geometry) of TiNi samples implanted by Ni⁺ and N⁺ ions shows the formation of the TiNi (B2), TiN, and Ni₃N phases. In the initial state, the elastic modulus of the samples is E = 56 GPa at a hardness of H = 2.13 ± 0.30 GPa (at a depth of 150 nm). After double implantation by Ni⁺-N⁺ and W⁺-Mo⁺ ions, the hardness of the TiNi samples is ∼2.78 ± 0.95 GPa at a depth of 150 nm and 4.95 ± 2.25 GPa at a depth of 50 nm; the elastic modulus is 59 GPa. Annealing of the samples at 550°C leads to an increase in the hardness to 4.44 ± 1.45 GPa and a sharp increase in the elastic modulus to 236 ± 39 GPa. A correlation between the elemental composition, microstructure, shape memory effect, and mechanical properties of the near-surface layer in TiNi is found.     

Kinetics of Rb<Stack><Subscript>2</Subscript><Superscript>+</Superscript></Stack> and Rb<Superscript>+</Superscript> formation in laser-excited rubidium vapor

We have studied the formation of the molecular ion Rb₂⁺ and the atomic ion Rb⁺. These are created in laser excited rubidium vapor at the first resonance, 5s–5p and 5p-nl transitions. A theoretical model is applied to this interaction to explain the time evolution and the laser-power dependence of the population density of Rb⁺ and Rb₂⁺. A set of rate equations which describe: the temporal variation of the population density of the excited states; the atomic ion density; and the electron density, were solved numerically under the experimental conditions of Barbier and Cheret. In their experiment the Rb concentration was 1×10¹³cm⁻³ and the laser power was taken to be 50–500 mW at vapor temperature = 450 K. The results showed that the main processes for producing Rb₂⁺ are associative ionization and Hornbeck-Molnar ionization. The calculations have also showed that, the atomic ions Rb⁺ are formed through the Penning Ionization (PI) and photoionization processes. Moreover, a reasonable agreement between the experimental results and our calculations for the ion currents of the Rb⁺ and Rb₂⁺ is obtained.      

Secondary Electron and Negative-Ion Emission from Metal Surface under the Bombardment by Positive Ions (H<Superscript>+</Superscript>, Cl<Superscript>+</Superscript>, HCl<Superscript>+</Superscript>)

A trap for positive ions (H⁺, Cl⁺, HCl⁺) is created within a time-of-flight mass spectrometer. The yields of secondary electrons and negative ions (HCl^?, H^?) formed due to forward and backward scattering of positive ions by steel wire at different kinetic energies (200–750 eV) are measured.     

1<Superscript>+</Superscript>(0<Superscript>+</Superscript>) state at 12.4 MeV in <Superscript>20</Superscript>Ne

Careful review of all the evidence makes it clear that at least three states are important at 12.4-MeV excitation in ²⁰Ne (four, if the broad (2⁺) at 12.5 MeV is included). The three states are 3 ^- , 0 ⁺ , and 1 ⁺ (0⁺). The latter, which is quite strong in ¹⁹F (³He, d) singles, is probably the state observed in coincidence with 6.13-MeV γ-rays in ¹⁹F(³He, dγ). Received: 19 August 2002 / Accepted: 28 October 2002 / Published online: 17 January 2003 RID="a" ID="a"e-mail: fortune@physics.upenn.edu Communicated by D. Guerreau     

D<Subscript>s0</Subscript><Superscript>+</Superscript>(2317) as an iso-triplet four-quark meson

Although assigning D _s0 ⁺(2317) to the I ₃ = 0 component of iso-triplet four-quark mesons is favored by experiments, its neutral and doubly charged partners have not yet been observed. It is discussed why they were not observed in inclusive e ⁺ e ^-→cˉ experiment and that they can be observed in B decays.     

Kinetic energy release for the collision-induced dissociation of CO<Superscript>+</Superscript>

The kinetic energy release distributions (KERDs) of C⁺ and O⁺ fragments arising from 5 keV collision-induced dissociation (CID) of CO⁺ ions with helium have been measured. The KERDs of C⁺ and O⁺ exhibit different features corresponding to the states that participate in CID processes. We have identified groups of dissociative and predissociative states, and compare them with theoretical and experimental values.     

Description of the torsional motion in the isotopically asymmetric ionic complexes ArH<Subscript>2</Subscript>D<Superscript>+</Superscript> and ArD<Subscript>2</Subscript>H<Superscript>+</Superscript>

The internal dynamics of the isotopically asymmetric ionic complexes ArH₂D⁺ and ArD₂H⁺ is considered to be a distorted dynamics of the isotopically symmetric ArH₃⁺ complex. By using the group chain methods, a rigorous algebraic model is constructed to describe the spectrum of the asymmetric complexes with an allowance for the torsional motion of the structure of hydrogen nuclei. The model is based on the geometrical group of symmetry of internal dynamics of the isotopically symmetric ionic complex, which is used here as a noninvariant group.     

Low-spin states in <Superscript>182</Superscript>Os and K<Superscript>π</Superscript> = 0<Superscript>+</Superscript>, 2<Superscript>+</Superscript> excited bands

Excited states in ¹⁸²Os were populated by the β⁺/EC decay of ¹⁸²Ir following mass separation. Gamma-ray and conversion electron spectroscopy techniques were employed. Monopole (E0) contributions were determined in transitions populating the ground-state band. A systematic study of the low-spin structures in the Os isotopes is presented and a detailed analysis in the framework of a microscopic configuration mixing approach is performed.     

I. Electron-impact ionization and dissociation of C<Subscript>2</Subscript>H<Stack><Subscript>2</Subscript><Superscript>+</Superscript></Stack> and C<Subscript>2</Subscript>D<Stack><Subscript>2</Subscript><Superscript>+</Superscript></Stack>

Absolute cross-sections for electron-impact ionization and dissociation of C₂H₂⁺ and C₂D₂⁺ have been measured for electron energies ranging from the corresponding thresholds up to 2.5 keV. The animated crossed beams experiment has been used. Light as well as heavy fragment ions that are produced from the ionization and the dissociation of the target have been detected for the first time. The maximum of the cross-section for single ionization is found to be (5.56 ± 0.03)× 10^-17 cm² around 140 eV. Cross-sections for dissociation of C₂ H₂⁺ (C₂D₂⁺) to ionic products are seen to decrease for two orders of magnitude, from C₂D⁺ (12.6 ± 0.3) × 10^-17 cm² over CH⁺(9.55 ± 0.06) × 10^-17 cm², C⁺ (6.66 ± 0.05) × 10^-17 cm², C₂⁺ (5.36 ± 0.27) × 10^-17 cm², H⁺ (4.73 ± 0.29) × 10^-17 cm² and CH₂⁺ (4.56 ± 0.27) × 10^-18 cm² to H₂⁺ (5.68 ± 0.49) × 10^-19 cm². Absolute cross-sections and threshold energies have been compared with the scarce data available in the literature.     

Isotopomer selective optimization of <Superscript>39</Superscript>K<Superscript>85</Superscript>Rb<Superscript>+</Superscript> and <Superscript>41</Superscript>K<Superscript>87</Superscript>Rb<Superscript>+</Superscript> using optimal control

We report on isotope selective three-photon ionization of two isotopomers of KRb by applying evolution strategies. The particularity of this experiment is based on the high resolution phase and amplitude modulation of the fs-laser pulses provided by a 2 × 640 pixel pulse shaper. The optimization in a closed feedback loop performed with spectrally broad pulses centered at 840 nm shows high enhancements of one isotopomer at the expense of the other isotopomer and vice versa. From the optimal laser field we aim to gain details about the selective ionization sequence and the wavepacket evolution on the involved vibrational states.     

Double ionization of Sc<Superscript>+</Superscript>ions by electron impact

Electron impact double ionization cross-sections of Sc⁺ions have been calculated in the binary encounter approximation (BEA). Accurate expression of σ_ΔE(cross-section for energy transfer ΔE) and Hartree-Fock velocity distributions for the target electrons have been used throughout the calculations. Direct double ionization from ejection of 3d and 4s electrons has been investigated in the modified double binary encounter model incorporating the focusing action of the target ion on the incident electron. The identification of the 3p shell whose ionization provides a major contribution to double ionization through ionization-autoionization is an interesting aspect of the present investigation. The theoretical results show satisfactory agreement with the experimental observations.     

General analysis of the rare B<Subscript>c</Subscript>→D<Subscript>s</Subscript><Superscript>*</Superscript>ℓ<Superscript>+</Superscript>ℓ<Superscript>-</Superscript> decay beyond the standard model

The general analysis of the rare B_c→D_s ^*ℓ⁺ℓ^- decay is presented by using the most general, model independent effective Hamiltonian. The dependencies of the branching ratios and of the longitudinal, normal and transversal polarization asymmetries for ℓ^- and the combined asymmetries for ℓ^- and ℓ⁺ on the new Wilson coefficients are investigated. Our analysis shows that the lepton polarization asymmetries are very sensitive to the scalar and tensor type interactions, which will be very useful in looking for new physics beyond the standard model.     

H<Superscript>+</Superscript> and He<Superscript>2+</Superscript> impact charge transfer cross sections of magnesium

H⁺ impact single and He²⁺ impact single and double electron capture cross sections of magnesium atoms have been calculated in the modified binary encounter approximation (BEA). The accurate expressions of ion impact s_DE\sigma _{\Delta {E}} (cross section for energy transfer DE\Delta E) and Hartree-Fock momentum distributions of the target electrons have been used throughout the calculations. On the basis of the present work it is concluded that inner shell captures by H⁺ and He²⁺ ions incident on magnesium atoms contribute partly to single electron capture and partly to transfer ionization cross sections. The calculated He²⁺ impact double electron capture cross sections of magnesium are in reasonably good agreement with the experimental observations. This indicates the success of the present theoretical approach in study of charge transfer cross sections of atoms as indirect mechanisms do not interfere with double electron capture processes in this case.     

<Superscript>10</Superscript>B<Superscript>+</Superscript>-ion implantation into photoresist

100-keV ¹⁰B⁺ ions were implanted into photoresist in different directions at a fluence of 1×10¹⁴ cm^-2, and their depth distribution was determined by means of the neutron depth profiling technique. In no case were the projectile ions found to come to rest according to their predicted implantation profiles. Instead, they are always found to undergo considerable long-range migration. During the irradiation process this motion appears to be enhanced by the radiation damage, and during the subsequent annealing steps one deals with thermal diffusion. The implant redistribution is always found to be governed strongly by the self-created damage, insofar as both electronic and nuclear defects in the polymer act as trapping centers. The implant redistribution shows a pronounced directional dependence, essentially as a consequence of the spatial distribution of the electronic energy loss. The changes of the nuclear defect distribution during thermal annealing are studied by a specially developed tomographic method in three dimensions. PACS 61.72.Ww; 61.80.Jh; 61.41.+e; 66.30.-h; 66.30.Jt     

The influence of P<Superscript>+</Superscript>, B<Superscript>+</Superscript>, and N<Superscript>+</Superscript> ion implantation on the luminescence properties of the SiO<Subscript>2</Subscript>: nc-Si system

The possible mechanisms of the influence of implanted impurities of Group III and V elements on the luminescence properties of a system consisting of silicon nanocrystals in SiO₂ are considered and generalized. The effect of boron and nitrogen ion implantation on the photoluminescence intensity is investigated experimentally. The experimental results and previously reported data on the ion-implantation doping with phosphorus are discussed in terms of the mechanisms under consideration. The state of implanted phosphorus is determined using x-ray photoelectron spectroscopy. It is shown that the enhancement and degradation of the photoluminescence depend on the type of implanted impurities and the conditions of postimplantation heat treatment.