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1.
The Vibrational Spectra of Trimethyl-s-triazine The vibrational spectra (IR and Raman) of trimethyl-s-triazine have been measured, discussed and assigned. For the (dissolved) compound the data point to a planar six membered ring of (pseudo-)D3h symmetry.  相似文献   

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The infrared and laser-Raman spectra of crystalline Ba2V2O7 are reported and discussed by means of a Site Symmetry analysis.
28. Mitt. der Reihe Orthovanadate und verwandte Verbindungen. 27. Mitt.:E. J. Baran undM. E. Escobar, J. Phys. Chem. Solids, im Druck; 26. Mitt.:E. J. Baran, I. L. Botto, J. F. Ramos undP. J. Aymonino, Mh. Chem.109, 1139 (1978); 25. Mitt.:E. J. Baran, J. Mol. Struct.48, 441 (1978); 24. Mitt.:E. J. Baran undI. L. Botto, J. inorg. nucl. Chem.40, 1603, (1978); 23. Mitt.:M. E. Escobar undE. J. Baran, Z. Anorg. allg. Chem.,441, 273 (1978).  相似文献   

3.
The infrared and laser-Raman spectra of crystalline Mg3(VO4)2 are reported and a factor group analysis for the full lattice is presented to support the discussion. The 1,000 to 600 cm?1 region of the spectrum is essentially related to internal (stretching) modes of the greatly distorted VO4 tetrahedra, whereas the bands in the low frequency region must be assigned to complex vibrations originating in the interaction of the bending vibrations of the tetrahedral groups with the external modes.  相似文献   

4.
The ether complex of the tribromomanganese(II) acid has the ionic structureEt 2OH+MnBr3 in the solid state. The vibrational spectra of the pyramidal anion MnBr3 are described and discussed.

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Zusammenfassung Die Infrarot- und Ramanspektren von Ti[N(CH3)2]4 werden mitgeteilt, zugeordnet und mit den Spektren der analogen Dimethylamino-Verbindungen von Si, Ge und Sn verglichen.
The IR and Raman spectra of Ti[N(CH3)2]4 are reported, assigned and compared with those of the Si, Ge and Sn analoga.
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8.
The infrared and laser-Raman spectra of Sr2V2O7 are reported and discussed by means of a Site Symmetry analysis. The principal force constants as well as the mean amplitudes of vibration for the V2O7 4– ion have been calculated using a simplified molecular model. Some aspects of the vibrational behaviour of the V–O–V bridge in this ion are also discussed.

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22. Mitt. der Reihe Orthovanadate und verwandte Verbindungen. 21. Mitt.:M. E. Escobar undE. J. Baran, Z. Naturforsch.B32, 349 (1977); 20. Mitt.:E. J. Baran undI. L. Botto, Mh. Chem.,108, 311 (1977); 19. Mitt.:E. J. Baran, Z. anorg. allgem. Chem.427, 131 (1976).  相似文献   

9.
The infrared and laser-Raman spectra of crystalline Li5ReO6 are reported and discussed and some comparisons with other lithium hexaoxometallates are made.  相似文献   

10.
The Vibrational Spectrum of Ba2ZnTeO6 The vibration modes of Ba2ZnTeO6 are assigned to TeO6 octahedra linked by apexes and sharing faces respectively. Both octahedra types show different force constants, bond order, and Te? O distances.  相似文献   

11.
The Raman and infrared spectra of cyclopentasilane, Si5H10 (and Si5D10), the first cyclic silicon hydrogen compound, have been measured and assigned. Analogous to cyclopentane, cyclopentasilane is not planar and undergoes rapid pseudorotation. A complete normal coordinate analysis has been performed using isotopic data. The SiSi stretching force constant is calculated to be 1.68 N/cm.  相似文献   

12.
The infrared and laser-Raman spectra of crystalline Pb2V2O7 are reported and discussed with the aid of a Site Symmetry-analysis.

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14. Mitteilung der Reihe Orthovanadate und verwandte Verbindungen 13. Mitt.:E. J. Baran, I. L. Botto undP. J. Aymonino, Z. anorg. allg. Chem., im Druck, 12. Mitt.:E. J. Baran, Mh. Chem.106, 1 (1975).  相似文献   

13.
The infrared and laser-Raman spectra of crystalline Ba5(ReO6)2 are reported and discussed. From the obtained spectroscopic data a calculation of force constants and mean amplitudes of vibration for the ReO6 5– ion has been carried out.

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