Preparation and application of alginate-Ca/attapulgite clay core/shell particle for the removal of uranium from aqueous solution

The radioactivity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in 42 samples from different types of cements produced in Turkey were measured using gamma-ray spectrometer. The determined values were 18–143 Bq kg⁻¹ (²²⁶Ra), 5–66 Bq kg⁻¹ (²³²Th) and 142–540 Bq kg⁻¹ (⁴⁰K). Additionally, the calculated radiological hazard parameters such as absorbed dose rate, annual effective dose, radium equivalent activity, the external hazard, activity and alpha indices were found to be in the range of 38–158 nGy h⁻¹, 188–776 µSv year⁻¹, 41–182 Bq kg⁻¹, 0.11–0.49, 0.15–0.65 and 0.09–0.71, respectively. Finally, the results were statistically evaluated and compared with the reported data in other countries and the international standard values given by European Commission and UNSCEAR.

     

Statistical assessment of radiological data of tiles collected from Jordan

ABSTRACT

In this present study, activity concentration of natural radionuclides such as ²²⁶Ra, ²³²Th and ⁴⁰K were determined using gamma ray spectrometer based on High Purity Germanium (HPGe) detector in ceramic tiles collected from Jordan. The average activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K were found to be 63.75 ± 24.12, 93.65 ± 13.89 and 180.9 ± 45.69 Bq.kg^?1. respectively. Using activity concentration of ²²⁶R, ²³²Th and ⁴⁰K, the radiological parameters such as radium equivalent activity (Ra_eq), Criteria formula (CF), absorbed dose rate (D_R), annual effective dose rate (H_R), activity utilisation index (AUI), external hazard index (H_ex), international hazard index (H_in), alpha index and gamma index (I_γ) has been calculated to assess the radiation hazards in the Tiles. The calculated average value of all radiological parameters is less than the recommended limit. The calculated values of annual effective dose rate (H_R), show that about 30% of the samples exceeded the recommended limit of 1 mSv.y^?1. Moreover, multivariate statistical techniques such as Pearson correlation, factor and cluster analysis were performed between the radioactive variables to know the existing relation between them.     

Radiometric analysis of Chinese commercial granites

Summary Due to the widespread use of granites as building and ornamental materials, measurements of ²²⁶Ra, ²³²Th and ⁴⁰K activities in commercial granites have been carried out using a NaI(Tl)g-ray spectrometer with a matrix-inversion-based spectral stripping technique. The concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in Chinese commercial granite range from 14.5 to 204.7 Bq^. kg^-1, 16.7 to 186.7 Bq^. kg^-1and 185.7 to 1745.6 Bq^. kg^-1, respectively. The mean values of the activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in red and pink commercial granites are all higher than those in black and gray commercial ones. The radium equivalent activity (Ra_eq), the external hazard index (H_ex), the internal hazard index (H_in ) and the annual gonadal dose equivalent (AGDE) were also calculated and compared to the international recommended values. Six types of red commercial granites (CBR, MLR, QXR, PBR, JXR, LQR, YDR and TSR) of China do not satisfy the universal standards.     

Natural radioactivity studies of Bidar soil samples using gamma spectrometry

The activity of the terrestrial primordial radionuclides ²²⁶Ra, ²³²Th and ⁴⁰K are measured for Bidar soil samples. The collected soil samples are analyzed using HPGe detector based on high resolution gamma spectrometric system. The activity of the three radionuclides ²²⁶Ra, ²³²Th and ⁴⁰K were found to be in the range of BDL–47.68, 7.65–59.08 and BDL–260.65 Bq kg^?1 respectively. The mean gamma absorbed dose rate in air above 1 m from ground is estimated to be 34.47 nGy h^?1. Annual effective dose equivalent and the radium equivalent activity were within the limits in the present study and it is found that the activity of the radionuclides are comparable with the worldwide literature values. Also the external hazard indices for the soil samples of Bidar district were within the limit of unity.     

Concentration of natural radionuclides in and around Padubidri on the coastal Karnataka,India

The activity concentrations of natural radionuclides viz. ²³²Th, ²²⁶Ra and ⁴⁰K were measured in soil samples of Padubidri on the coastal Karnataka, the site for the proposed coal based thermal power station, using gamma-ray spectrometry to establish a baseline data on radioactivity levels in the environment of the region. The activity concentration of ²³²Th varies in the range of 38.5–115.5 Bq·kg⁻¹ with a mean value of 66.0 Bq·kg⁻¹, the activity concentration of ²²⁶Ra varies in the range 35.3–72.5 Bq·kg⁻¹ with a mean value of 53.5 Bq·kg⁻¹ and that of ⁴⁰K varies in the range of 307.5–550.9 Bq·kg⁻¹ with a mean value of 419.3 Bq·kg⁻¹. The radium equivalent activity varies in the range of 140.0–242.9 Bq·kg⁻¹ with a mean value of 180.2 Bq·kg⁻¹. The correlation between ²²⁶Ra and ⁴⁰K, ²³²Th and ⁴⁰K and ²²⁶Ra and ²³²Th was studied from the results of the concentration of these naturally occurring radionuclides. The calculated dose rates in air due to these naturally occurring radionuclides varies in the range of 66.0–110.0 nGy·h⁻¹ with a mean dose rate of 83.1 nGy·h⁻¹.     

Radiological hazard analysis of Malaysia’s ceramic materials using generic and RESRAD-BUILD computer code approach

In this study, 52 samples of ceramic materials were studied for ²²⁶Ra, ²²²Rn, ²³²Th and ⁴⁰K natural radionuclides using high-purity germanium detector and relevant radiological hazards parameters were also appraised. Furthermore, the long-term variations of the total effective dose equivalent (TEDE) and effects of wall thickness on TEDE were established and analyzed using RESRAD-BUILD computer code. The observed percentage variations of TEDE are 2% and 8% for ²²⁶Ra and ²³²Th, respectively, while no variation observed for external dose due to ⁴⁰K. The estimated indoor doses from the studied ceramic materials are all below the recommended maximum limit.

     

Measurement of natural radioactivity and radiation hazard assessment in the soil samples of Visakhapatnam,Andhra Pradesh,India

The present work aims to measure and estimate radioactivity and hazardous radiation indices of the soil. Soil samples were collected from various locations in the Visakhapatnam district in Andhra Pradesh, India. The measurement of specific activity of ²²⁶Ra, ²³²Th, and ⁴⁰K radionuclides is carried out with the help of HP-Ge based gamma spectrometer system. Activity concentration of radionuclides in the samples ²²⁶Ra, ²³²Th and ⁴⁰K ranged from 20 ± 2 to 91 ± 2 Bq.kg^-1, 45 ± 3 to 365 ± 3 Bq.kg^-1, and 400 ± 9 to 607 ± 8 Bq.kg^-1, and the respective mean values are 53.36 Bq.kg^-1, 203.74 Bq.kg^-1 and 479.19 Bq.kg^-1. The measured mean value of the absorbed dose rate is 171.41 nGy.h^-1, which was beyond the worldwide mean outdoor value of 60 nGy.h^-1. Thus, the annual effective dose estimated from the above value is 1.04 mSv.y^-1. The correlation was done among the measured ²²⁶Ra, ²³²Th, and ⁴⁰K activity concentrations. The estimated radium equivalent dose is 381.60Bq.kg^-1. The estimated health hazard index and annual effective dose rates of dwellers of Visakhapatnam were studied and compared to Indian average values. The study will help to generate the baseline data for assessing hazard indices to the public and geological mapping of natural radiation in India.     

Terrestrial gamma exposure in the granodiorite area of Bergama (Pergamon)�CKozak, Turkey

As higher radiation levels are associated with granite and Bergama (Pergamon) has increasingly become a large market for granite use over the last years, an extensive investigation was started in 2009. Samples from the granites and soils underlying this area were collected and analyzed by HPGe gamma spectrometry system. The specific activities of the naturally occurring radionuclides ²²⁶Ra, ²³²Th, and ⁴⁰K were found to be in the range of 29?C111 Bq kg^?1 for ²²⁶Ra, 35?C87 Bq kg^?1 for ²³²Th and 698?C1100 Bq kg^?1 for ⁴⁰K in granite samples. The ranges of ²²⁶Ra, ²³²Th, and ⁴⁰K activity concentrations for soils were 32?C82, 42?C88 and 667?C1127 Bq kg^?1, respectively. From these data radiological parameters were calculated and compared with respective data from the UNSCEAR reports.     

Radioactivity levels and radiation hazard of healing mud from San Diego River, Cuba

Healing mud core samples were collected in the San Diego River (Southwest Cuba), in order to determine the behaviour of the radioactivity levels of ²²⁶Ra, ¹³⁷Cs, ²³²Th and ⁴⁰K and to evaluate their possible radiological impact on peloide therapeutic uses. The radionuclide concentration ranges in healing mud profiles on Bq kg^?1 dry weight varied as follows: ²²⁶Ra = 22–26, ¹³⁷Cs = 4.6–33.0, ²³²Th = 18–31 and ⁴⁰K = 208–433. The calculated average radium equivalent activity (82 Bq kg^?1), total absorbed dose rate (40 nGy h^?1), external hazard index (0.23), annual gonadal dose equivalent (280 μSv h^?1) and annual effective dose equivalent (48.5 μSv y^?1) are less than international recommended values. Hence, the levels of radioactivity in healing muds from San Diego River are not an impediment for its use for medical proposes.     

Concentration of radionuclides in building and ceramic materials of Bangladesh and evaluation of radiation hazard

The concentration of radioactive²²⁶Ra,²³²Th and⁴⁰K in building and ceramic materials of Bangladesh was investigated by γ-spectrometry with two HPGe detectors. Radium equivalent activities, representative level index values, criterion formula, emanation coefficients and²²²Rn mass exhalation rates were estimated for the radiation hazard of the natural radioactivity in the materials. The activity concentrations of the natural radionuclides, radium equivalent activities, emanation coefficients and²²²Rn mass exhalation rates are compared with the corresponding values for building and ceramic materials of different countries. The radium equivalent activities in the samples varied between 30.9 (mosaic stone) and 328.0 Bq·kg⁻¹ (gypsum). The emanation coefficient of the materials ranged from 7.83 (cement) to 33.0% (soil) and the²²²Rn mass exhalation rate ranged from 2.31 (stone chips) to 118.0 μBq·kg⁻¹·s⁻¹ (gypsum).     

Radiological hazard and radiogenic heat production in some building materials in upper Egypt</p> </p>

Summary Samples of limestone, sand, marble, clay brick, red brick, gypsum, Portland cement and white cement collected from upper Egypt used in building manufacturing have been analyzed for the natural radionuclides ²²⁶Ra, ²³²Th and ⁴⁰K usingg-ray spectrometry. The specific concentrations for ²²⁶Ra, ²³²Th and ⁴⁰K, ranged from 20-88, 13-115 and 54-304 Bq/kg, respectively. The average specific activities of these radionuclides were compared. Higher values of ²²⁶Ra and ²³²Th could be noticed in marble while that of ⁴⁰K was in red bricks. Radium equivalent activities, dose rate and the annual gonadal dose equivalents AGDE were calculated for the measured samples to assess the radiation hazard arising from using those materials in the construction of dwellings. The radioactive heat production values of the selected materials have also been determined. They vary from a minimum of 0.41 for white cement to a maximum of 5.52mW/m³ for marble samples. The calculated heat-production values are quite similar to those estimated in Corsica.</p> </p>     

The role of phosphate released from Na–Al–P glass under repository conditions in speciation and transport of americium

The uptake of natural radioactivity by pasture-grass collected from seven different grasslands of Digor was calculated. The activities of ²²⁶Ra, ²³²Th and ⁴⁰K in pasture-grass were in the range of 21.8 ± 6.3–49.6 ± 13.4, 51.9 ± 13.2–127.7 ± 23.8 and 309.5 ± 33.5–807.3 ± 64.4 Bq kg⁻¹, respectively. The soil to pasture-grass transfer factors were evaluated and determined to be in the range from 0.26 ± 0.13 to 0.69 ± 0.34, 0.64 ± 0.27 to 1.99 ± 0.40 and 0.64 ± 0.014 to 1.40 ± 0.032 for ²²⁶Ra, ²³²Th and ⁴⁰K, respectively. The distribution of ²²⁶Ra and ²³²Th in different parts of pasture-grass indicated a decreasing tendency in order of root > stem > leaf. ⁴⁰K mainly accumulated in stem of pasture-grass and is followed by declining trend stem > leaf > root.

     

Radioactivity measurements and radiation dose assessments due to natural radiation in Karabük (Turkey)

In this work, the radionuclide activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in surface soils and radon levels in dwellings of Karabük, Turkey were determined in order to evaluate the environmental radioactivity. Concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K radionuclides were determined using gamma spectrometry with using HPGe detector. The etch track detectors (CR-39) were used to determine the distribution of radon concentrations. The average activity concentrations for ²²⁶Ra, ²³²Th and ⁴⁰K were found as 21.0, 23.5 and 363.5 Bq kg⁻¹, respectively. The calculated average annual effective dose equivalent from the outdoor terrestrial gamma radiation from ²²⁶Ra, ²³²Th and ⁴⁰K is 53.5 μSv y⁻¹. The average radon concentration and annual effective dose equivalent of ²²²Rn in Karabük dwellings were obtained 131.6 Bqm⁻³ and 3.32 mSv y⁻¹, respectively. The evaluated data were compared with the data obtained from different countries.     

Natural radioactivity and their radiological effects for different types of rocks from Egypt

The present work investigated the radioactivity level of the rocks samples collected from different sites in Egypt. Twenty one rocks samples were analyzed by gamma-ray spectrometry using NaI(Tl) detector with specially designed shield. The concentration of three natural radionuclides namely ²²⁶Ra, ²³²Th and ⁴⁰K has been determined and compared with chemical data obtained by XRF analysis. The results showed that these radionuclides were present in concentration ranges (3.4-99, 7.5-134 and 93-3382 Bq kg⁻¹), (54.9-211.6, 20.71-170.5 and 2068-2344 Bq kg⁻¹) and (13-106, 29.25-106.1 and 682-755 Bq kg⁻¹) for gneiss, granite and basalt rocks, respectively, while the values were (7.5, 12.5 and 263.9 Bq kg⁻¹) and (113, 148.5 and 1672 Bq kg⁻¹) for ²²⁶Ra, ²³²Th and ⁴⁰K in sandstone and siltstone rocks, respectively. Also radium equivalent activity, total dose rates and external hazard index of the rocks samples under consideration were calculated. The results showed that granite rocks contain a high proportion of natural radioactive elements, while sandstone rocks have lesser radioactivity concentration compared with other types of rocks.     

Radioactivity mapping of north western areas of Pakistan

Summary A systematic study of natural and fall-out radionuclides was carried out with the environmental samples of soil, vegetation and water from some regions of North West Frontier Province (NWFP) of Pakistan. The pretreatment of the samples was performed in the laboratory using IAEA recommended methods. The analysis of gamma-emitters such as ⁴⁰K, ²²⁶Ra, ²³² Th and ¹³⁷Cs was performed with a high purity germanium detector (HPGe). For the determination of ⁹⁰Sr, a liquid scintillation counting system was used. The average specific activities of ⁴⁰K, ²²⁶Ra, ²³² Th and ¹³⁷Cs have been found to be 307±101 Bq ^. kg^-1, 10.2±3 Bq ^. kg^-1, 24±6 Bq ^. kg^-1 and 2.8±1.3 Bq ^. kg^-1, respectively, in soil samples. Vegetation samples have smaller values of specific activities and even the analysis of water samples showed values less than LLD for earlier reported radionuclides. Other parameters like hazard indices, radium equivalent activities, absorbed dose rates and effective dose equivalents have also been determined. All these parameters have values less than their respective limiting values representing that the surveyed areas have no significant hazard from health point of view. Analysis of ⁹⁰Sr for all the samples showed results below LLD. The present study provides a general background of the detectable radionuclides for the surveyed areas that will be helpful in any radiological emergency.     

Natural radioactivity and radiological hazards of building materials in Xianyang,China

Common building materials collected from Xianyang, China were analyzed for the natural radioactivity of ²²⁶Ra, ²³²Th and ⁴⁰K using γ-ray spectroscopy. The average activity concentration of ²²⁶Ra, ²³²Th and ⁴⁰K in the studied building materials ranges from 13.4 to 69.9, 13.1–99.1 and 124.7–915.1 Bq kg^?1, respectively. The measured activity concentrations for these radionuclides were compared with the reported data of other countries and with the worldwide average activity of soil. To assess the radiation hazard of the natural radioactivity in all samples to the people, the radium equivalent activity, external hazard index, internal hazard index, indoor absorbed dose rate and total annual effective dose were estimated. The radium equivalent activities of the studied samples are below the internationally accepted values. The external hazard index and internal hazard index of all analyzed building materials are less than unity. The mean values of indoor absorbed dose rate for all building materials except for lime are higher than the world population-weighted average of 84 nGy h^?1 and the total annual effective dose values of building materials are lower than 1 mSv y^?1 except for some cyan brick samples. The study shows the measured building materials do not pose significant source of radiation hazard and are safe for use in the construction of dwellings.     

Distribution and environmental impact of radionuclides in marine sediments along the Venezuelan coast

The activity concentrations of ¹³⁷Cs, ⁴⁰K, ²²⁶Ra and ²³²Th in Bq/kg from 42 marine sediment samples collected at nine sampling sites were determined in order to establish a radiological baseline along the Venezuelan coast. The radioactivity levels were determined by means of a gamma-ray spectroscopy system using a hyper-pure germanium detector in a low-background configuration. Particle size distribution and total organic matter content were also determined. Activity concentrations of ¹³⁷Cs were lower than the detection limit of the analytical technique (0.9 Bq/kg) in all studied sites. The results suggest that the variation of grain-size distribution is one of the most important factors influencing the spatial variations of ⁴⁰K, ²²⁶Ra and ²³²Th in sediments along the Venezuelan coasts. In all sampling sites, average concentrations of ⁴⁰K, ²²⁶Ra and ²³²Th were lower than the world average values. Activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in coastal marine sediments along the Venezuelan coast could be considered to be low when compared with global average values, indicating that they are not apparently above of the range that might be considered normal or background. These results suggest that the studied sites do not pose any significant radiological threat to the population. The results attained in this study should be of considerable value as baseline data and background reference levels for Venezuelan coastlines.     

Natural radioactivity in some building materials and by-products of Shaanxi, China

The concentration of ²²⁶Ra, ²³²Th and ⁴⁰K has been determined by -ray spectrometry. The measured activity in the selected building materials and by-products of coal fired power plants ranges from 21.5 to 91.3 Bq·kg^–1, 15.4 to 63.2 Bq·kg^–1 and 83.2 to 683.9 Bq·kg^–1 for ²²⁶Ra, ²³²Th and ⁴⁰K, respectively. The results were compared with the reported data of other countries and with the world average activity of soil. The radium equivalent activities values of all building materials are lower than the limit of 370 Bq·kg^–1, equivalent to a -dose of 1.5 mSv·y^–1. The values of the external hazard index and the internal radiation hazard index are less than unity.This work was supported by the Provincial Natural Sciences Foundation of Shaanxi through Grants 2003D04 and by the Science Foundation of Shaanxi Normal University. Gratitude is expressed to J. Xiaowei, W. Xiaolei, L. Zhendong for assisting in sampling.     

Studies on radionuclides around Hemavathi river basin of Karnataka,India

The activity concentration and total annual effective dose of the terrestrial naturally occurring radionuclides (²³²Th, ²²⁶Ra and ⁴⁰K) were measured in soil and rock samples collected from various locations of Hemavathi river basin in Karnataka, using HPGe detector. The results revealed that activity concentration of radionuclides ²²⁶Ra, ²³²Th and ⁴⁰K in the soil had geometrical mean values of 16.7 ± 0.6, 33.9 ± 1.2 and 359.9 ± 9.2 Bq kg^?1, respectively. In rock samples activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K had geometrical mean values of 20.2 ± 0.7, 18.0 ± 0.9 and 276 ± 9.6 Bq kg^?1, respectively. The external Hazard index and indoor hazard index were found to be within safety limits prescribed by European commission 1999 report.     

Natural radioactivity in some building materials and by-products of Shaanxi, China

The concentration of ²²⁶Ra, ²³²Th and ⁴⁰K has been determined by -ray spectrometry. The measured activity in the selected building materials and by-products of coal fired power plants ranges from 21.5 to 91.3 Bq·kg^–1, 15.4 to 63.2 Bq·kg^–1 and 83.2 to 683.9 Bq·kg^–1 for ²²⁶Ra, ²³²Th and ⁴⁰K, respectively. The results were compared with the reported data of other countries and with the world average activity of soil. The radium equivalent activities values of all building materials are lower than the limit of 370 Bq·kg^–1, equivalent to a -dose of 1.5 mSv·y^–1. The values of the external hazard index and the internal radiation hazard index are less than unity.This work was supported by the Provincial Natural Sciences Foundation of Shaanxi through Grants 2003D04 and by the Science Foundation of Shaanxi Normal University. Gratitude is expressed to J. Xiaowei, W. Xiaolei, L. Zhendong for assisting in sampling.