CW DFB RT diode laser-based sensor for trace-gas detection of ethane using a novel compact multipass gas absorption cell

The development of a continuous wave, thermoelectrically cooled (TEC), distributed feedback diode laser-based spectroscopic trace-gas sensor for ultra-sensitive and selective ethane (C₂H₆) concentration measurements is reported. The sensor platform used tunable diode laser absorption spectroscopy (TDLAS) and wavelength modulation spectroscopy as the detection technique. TDLAS was performed using an ultra-compact 57.6 m effective optical path length innovative spherical multipass cell capable of 459 passes between two mirrors separated by 12.5 cm and optimized for the 2.5–4 μm range TEC mercury–cadmium–telluride detector. For an interference-free C₂H₆ absorption line located at 2,976.8 cm^?1, a 1σ minimum detection limit of 740 pptv with a 1 s lock-in amplifier time constant was achieved.     

Performance evaluation of a near infrared QEPAS based ethylene sensor

A sensor based on quartz-enhanced photoacoustic spectroscopy (QEPAS) was evaluated for the detection of trace levels of ethylene at atmospheric pressure using a fiber coupled DFB diode laser emitting in the 1.62 μm spectral range. A noise-equivalent QEPAS signal of ∼4 ppm C₂H₄ was achieved for a 0.7 s data acquisition time using wavelength-modulation with a second-harmonic detection scheme on the strongest C₂H₄ absorption peak at 6177.14 cm⁻¹ with an average optical power of ∼15 mW. Improved detection sensitivity of 0.5 and 0.3 ppm C₂H₄ (1σ) was demonstrated using longer averaging time of 70 and 700 s, respectively. Important characteristics for the QEPAS based sensor operation in real-world conditions are presented, particularly the influence of external temperature variations. Furthermore, the response time of the ethylene sensor was measured in different configurations and it is shown that the QEPAS technique can provide a response time in a few seconds range even without active gas flow.     

Cavity-enhanced absorption sensor for carbon monoxide in a rapid compression machine

A sensor based on cavity-enhanced absorption spectroscopy (CEAS) was implemented for the first time in a rapid compression machine (RCM) for carbon monoxide concentration measurements. The sensor consisted of a pulsed quantum cascade laser (QCL) coupled to a low-finesse cavity in the RCM using an off-axis alignment. The QCL was tuned near 4.89 µm to probe the P(23) ro-vibrational line of CO. The pulsed mode operation resulted in rapid frequency down-chirp (6.52 cm⁻¹/µs) within the pulse as well as a high time resolution (10 µs). The combination of rapid frequency down-chirp and off-axis cavity alignment enabled a near complete suppression of the cavity coupling noise. A CEAS gain factor of 133 was demonstrated in experiments, resulting in a much lower noise-equivalent detection limit than a single-pass arrangement. The sensor thus presents many opportunities for measuring CO formation at low temperatures and for studying kinetics using dilute reactive environments; one such application is demonstrated in this work using dilute n-heptane/air mixtures in the RCM. The formation of CO during first-stage ignition of n-heptane was measured over 802–899 K at a nominal pressure of 10 bar. These conditions correspond to the NTC region of n-heptane and such results provide useful metrics to test and compare the predictions of low-temperature heat release by different kinetic models.     

A mid-infrared carbon monoxide sensor system using wideband absorption spectroscopy and a single-reflection spherical optical chamber

A mid-infrared carbon monoxide (CO) sensor system based on a dual-channel differential detection method was developed using a broadband light source in the 4.60 µm wavelength region and a single-reflection spherical optical chamber with ∼0.373 m absorption path length. CO detection was realized by targeting the wideband strong absorption lines within 4.55–4.65 µm. A dual-channel pyroelectric detector as well as a self-developed digital signal processor (DSP) based orthogonal lock-in amplifier was employed to process CO sensing signal. A minimum detection limit of ∼0.5 ppm in volume (ppmv) was achieved with a measurement time of 6 s, based on an Allan deviation analysis of the sensor system. The response time (1000 → 0 ppmv) was determined to be ∼7 s for the CO sensor operation. Due to the characteristics of low detection limit, fast response time and high cost performance, the proposed sensor has relatively good prospect in coal-mining operation.     

Disposable and compact integrated plasmonic sensor using a long-period grating

This Letter theoretically proposes and investigates an integrated plasmonic sensor that is based on a grating-assisted coupling between a surface plasmon polariton (SPP) and a dielectric waveguide (DW) mode. It consists of a glass slide with a gold film for the propagation of an SPP and a separate DW with a long-period grating. For sensing, the two parts are temporarily combined. After sensing, the former is replaceable, and so the sensor has disposability. The design procedure and analysis method for the sensor are explained. The designed sensor is shown to be very compact. Its characteristics of sensing a change of the refractive index of liquid are analyzed and discussed.     

Physics design of a CW high-power proton Linac for accelerator-driven system

Accelerator-driven systems (ADS) have evoked lot of interest the world over because of their capability to incinerate the MA (minor actinides) and LLFP (long-lived fission products) radiotoxic waste and their ability to utilize thorium as an alternative nuclear fuel. One of the main subsystems of ADS is a high energy (∼1 GeV) and high current (∼30 mA) CW proton Linac. The accelerator for ADS should have high efficiency and reliability and very low beam losses to allow hands-on maintenance. With these criteria, the beam dynamics simulations for a 1 GeV, 30 mA proton Linac has been done. The Linac consists of normal-conducting radio-frequency quadrupole (RFQ), drift tube linac (DTL) and coupled cavity drift tube Linac (CCDTL) structures that accelerate the beam to about 100 MeV followed by superconducting (SC) elliptical cavities, which accelerate the beam from 100 MeV to 1 GeV. The details of the design are presented in this paper.     

New advanced in situ carbon monoxide sensor for the process application

Mixed potential solid electrolyte CO sensors with sensing electrodes based on composite with various semiconducting oxides were extensively studied in the temperature range 500–650 °C for sensitivity, stability and cross-sensitivity besides CO to other combustion components like CO₂, H₂O, O₂, and SO₂. The highest CO sensitivity was found for the CO sensor with composite electrode based on Au/Ga₂O₃ showing also good reproducibility and stability in hazardous combustion environment. CO sensor response behavior in non equilibrated oxygen containing gas mixtures is mainly determined by the catalytic activity of the measuring electrode and depends strongly on preparation and measuring conditions. Mixed oxides based on doped chromites show only a little sensitivity to CO. CO sensor based on Au/Ga₂O₃ composite electrodes was showing good CO selectivity in the presence of other combustion gas species and finally was tested in combustion environment at power plant. Paper presented at the 11th EuroConference on the Science and Technology of Ionics, Batz-sur-Mer, Sept. 9–15, 2007.     

S波段宽带大功率连续波耦合腔行波管3维模拟设计

 使用3维PIC粒子模拟软件定量分析了耦合腔行波管的大信号注波互作用行为。使用完整的仿真模型完成了S波段连续波管型的设计,达到如下设计指标：工作频率2.0~2.3 GHz,输出功率4.3 kW,频带内增益波动±0.7 dB。提出了使用大介电常数微扰介质棒减小耦合阻抗计算误差的方法,研究了行波管的冷腔特性,给出了色散、耦合阻抗等参数。     

S波段宽带大功率连续波耦合腔行波管3维模拟设计

使用3维PIC粒子模拟软件定量分析了耦合腔行波管的大信号注波互作用行为。使用完整的仿真模型完成了S波段连续波管型的设计,达到如下设计指标：工作频率2.0~2.3 GHz,输出功率4.3 kW,频带内增益波动±0.7 dB。提出了使用大介电常数微扰介质棒减小耦合阻抗计算误差的方法,研究了行波管的冷腔特性,给出了色散、耦合阻抗等参数。     

Experimental study of a high-power CW side-pumped Nd:YAG laser

The paper reports on the characterization of a side-pumped 40 W CW Nd:YAG laser. A side-pumping configuration with six laser diodes is used for the laser. We show the comparison between the calculated and measured pump energy distributions in the laser crystal. The birefringence and the thermal lens effect of the Nd:YAG crystal have been experimentally investigated, and their influence on the performance of the laser are discussed. Output power and beam quality of the laser under different output couplings, cavity lengths, types of cavity and different temperatures of the cooling water have been experimentally studied.     

Quartz-enhanced photoacoustic spectroscopy-based sensor system for sulfur dioxide detection using a CW DFB-QCL

Sulfur dioxide (SO₂) trace gas detection based on quartz-enhanced photoacoustic spectroscopy (QEPAS) using a continuous wave, distributed feedback quantum cascade laser operating at 7.24 μm was performed. Influence of water vapor addition on monitored QEPAS SO₂ signal was also investigated. A normalized noise equivalent absorption coefficient of NNEA (1σ) = 1.21 × 10^?8 cm^?1 W Hz^?1/2 was obtained for the ν ₃ SO₂ line centered at 1,380.93 cm^?1 when the gas sample was moisturized with 2.3 % H₂O. This corresponds to a minimum detection limit (1σ) of 63 parts per billion by volume for a 1 s lock-in time constant.     

Testing a thermoacoustic sensor of high-power microwave pulses

We present the results of testing a new thermoacoustic sensor designed to detect microwave pulses having durations from 3 to 120 ns at wavelengths of 0.8 and 3 cm. Operation of the sensor is based on the effect of generation of acoustic signals during absorption of microwave pulses in a radiotransparent substrate–absorber–liquid layered structure . A thin nanometer-thick film deposited on a substrate is used as an absorber. Microwaves are converted to an acoustic pulse in the film and the adjacent liquid. The pulse is received by a wideband acoustic receiver and then recorded by a digital oscilloscope. It is shown that for a pulse duration of 120 ns, the shape of the signal recorded by the thermoacoustic sensor completely corresponds to the signal of a tube-diode detector of microwave pulses. The response of the thermoacoustic sensor to shorter pulses (3 and 5 ns long) is a pulse with a duration of 18 ns which is determined by a limited frequency band of the acoustic receiver.     

Self-pulsing characteristics of a high-power single transverse mode Yb-doped CW fiber laser

We present an experimental study of self-pulsing characteristics of a high-power single transverse mode Yb-doped double-clad continuous wave (CW) fiber laser. The self-pulsing features under high-power single-end pumping and double-end pumping configurations have been shown to be distinct. Our experimental observation indicates that in single-end pumping configuration, self-pulsing is predominant due to saturable absorption effect, caused by the weakly pumped portion of the fiber at the farther end. However, in double-end pumping configuration, uniform pumping and hence gain uniformity along the fiber length avoids the onset of saturable absorption of signal along the fiber length and thereby reduces self-pulsing, which finally results in a much more stable output.     

Design of a compact photonic crystal sensor

The development of technology in photonic crystal (PC) structures has seen rapid progress. Using PCs in biosensing area may open new venues to achieve single molecule detection, and high resolution scanning. A novel PC sensor with improved performances, in terms of size, compactness and sensitivity is presented in this paper. The sensing element consists of dielectric cylinders with varying radius introduced along <01> and <10> directions of the crystal. The results show that the peak wavelength shifts to the high frequency region when only six cylinders are filled with analytes. Also, the peaks show a larger shift compared to the structure obtained using the entire PC waveguide as sensing region. The proposed sensor shows a better sensitivity to water than other analytes, where the peak wavelength tends to shift towards the low frequency region.     

Effect of palladium oxide electrode on potentiometric sensor response to carbon monoxide

Ionics - This study aims to explore the potential merits of palladium oxide sensing electrode. PdO is applied on a solid-state potentiometric sensor on an yttria-stabilized zirconia (YSZ)...     

Generation of high-order rotational lines by four-wave Raman mixing using a high-power picosecond Ti:Sapphire laser

More than thirty rotational lines equally spaced by 587 cm^–1 are generated simultaneously in the vicinity of the fundamental line by four-wave Raman mixing using a high-power picosecond Ti:Sapphire laser as a pump source and hydrogen as a Raman medium. Since the wavelength of this multifrequency laser emission extends from the near-infrared to the near-ultraviolet, it can be utilized as a tunable light source for picosecond spectroscopy. Because of the wide spectral bandwidth available, this procedure has great potential for the generation of ultrashort laser pulses by mode-locking these emission lines.     

Multipole mixing ratios of transitions in Te

Gamma-gamma directional correlation measurements were made on nine transitions in ¹²⁴Te with a NaI(Tl)-Ge(Li) detector arrangement and multichannel analysis. The multipole mixing ratios obtained were δ(646) = 0.000±0.001, δ(714) = 1.5_−0.3^+0.6, δ(723) = −3.3±0.2, δ(1437) = 3.7_−2.0^+2.7, δ(1489) = −3.4_−1.5^+0.9, δ(968) = −0.03_−0.05^+0.06, δ(1368) = −0.045±0.090, δ(1045) = 0.041_−0.041^+0.047, δ(1691) = −0.02±0.01, and δ(2091) = 0.00_−0.03^+0.02. The first δ is M3/E2, the next three are E2/M1, and the last five are M2/E1. The retardation (a factor of approximately 50) of the crossover to cascade transitions from the 2039 keV, third 2⁺ level to the second and first 2⁺ levels is essentially the same for both the M1 and E2 components. In addition, spin and parity assignments of 2⁺ were made for the 2039 and 2092 keV levels.     

Nuclear pumping of a carbon monoxide laser

It is shown that plasma-chemical processes involving ionized and excited particles can make the main contribution to the pumping of energy into vibrations of carbon monoxide molecules. It is noted that the use of helium as a buffer gas in the active laser medium is not optimal. The employment of argon instead of helium permits a 1.5-fold increase in the efficiency of the pumping of energy into carbon monoxide molecules and an order-of-magnitude decrease in the threshold energy for pumping the active medium. Zh. Tekh. Fiz. 68, 80–85 (July 1998)     

Design of a low pressure CW carbon dioxide laser

The purpose of this paper is to describe the design and the construction of a continuous wave CO₂ laser for single line operation. This laser operates in a single axial mode with a frequency stabilization, at the maximum of the power profile, of better than 100 KHz. The output power is in the 0.1–5 W range. A variable coupling experiment is also described. This was used to obtain the gain of the amplifying medium and the optimum coupling for the maximum output power.