稀土催化材料的应用及研究进展

介绍了稀土催化材料在石油化工，化石燃料催化燃烧、机动车尾气的催化净化，有毒有害废气的治理，Cl化工、固体氧化物燃料电池及移动制氢、稀土催化理论研究等方面的应用和研究现状，并就稀土催化材料研究中存在的问题和稀土催化材料的发展进行了思考和展望。     

生物质焦油的催化裂解研究

对稻壳热解过程中产生的焦油进行了催化裂解研究。实验装置主体由裂解炉和固定床催化裂解反应器组成。研究得出催化裂解条件（温度、停留时间等）对焦油脱除的影响规律，并分析了生物质焦油催化裂解过程中发生的反应和焦油催化裂解机理。研究表明，白云石对焦油的催化裂解有较好的效果，随着温度和停留时间的增加，其催化裂解率提高。     

金属离子负载修饰阳离子树脂在酯化反应中的研究

将催化精馏中常用作催化填料的强酸性阳离子交换树脂用金属离子负载修饰后，考察了树脂催化性能的改变及树脂结构对催化性能的影响。实验表明，经修饰后树脂的催化能力都高于原树脂，在不分水的情况下，合成乙酸乙酯时乙酸的转化率最高可达73％，具有很好的选择性，金属离子能与树脂的磺酸基团产生络合，提高了树指的催化性能，所形成的新酸中心不会被阳离子交换而失活。     

中国催化成就奖和中国催化青年奖简介

为奖励在催化科学和技术研究中做出原始创新性或创造性成果、对中国催化科学的发展和重大应用做出突出贡献的中国催化科学工作者，2005年中国化学会催化委员会设立了“中国催化成就奖”（冠名“张大煜奖”，National Catalysis Award）“中国催化青年奖”（National Catalysis Prize for Young Scientists）．     

中国化学会催化专业委员会扩大会议纪要

在中国化学会催化专业委员会杨元一主任领导下，经过秘书处的积极筹备，于2005年4月13日在北京召开了催化专业委员会扩大会议．催化专业委员会的上届委员和来自全国高校、中科院和工业界的42个单位共80余位专家学者参加了会议，魏可镁、何鸣元、万惠霖和李灿院士出席了会议．出席会议的还有部分前任的催化专业委员会主任和催化界的一些老前辈．     

催化动力学光度法测定痕量铜的研究进展

综述了近年来国内外催化动力学光度法测定痕量铜的进展情况。对催化氧化动力学光度法、催化还原动力学光度法、催化荧光光度法、阻抑动力学光度法等几个类别，从反应介质、灵敏度、线性范围等方面介绍了对不同反应体系的研究情况，并对催化动力学光度法测定痕量铜的发展趋势做出预测。     

金属担载量对CuO/AC干法催化氧化苯酚的影响

采用程序升温氧化（TPO）技术和吸附 催化氧化循环实验,研究了金属担载量对CuO/AC催化-吸附剂干法催化氧化苯酚的影响。结果表明，随着金属担载量的增加，CuO/AC催化-吸附剂的苯酚催化氧化活性升高，并且苯酚与催化-吸附剂之间的相互作用增强，使吸附的苯酚不易脱附/降解脱附。同时，CuO/AC催化 吸附剂自身的烧蚀活性也随金属担载量的增加而升高。对于吸附-干法催化氧化法而言，CuO/AC存在一个较佳的金属担载量范围，该范围以Cu的质量分数计为3%～5%。     

催化不对称Michalel加成反应的新进展

总结了近年催化不对称Michael加成反应的新方法，包括手性金属络合物催化 的反应，呈手性Lewis酸性的手性金属络合物促进的不对称加成，手性冠醚络合物 催化的反应及其它催化反应。     

中国化学会催化专业委员会奖励条例（讨论稿）

为奖励我国催化科学工作者的学术成就和突出贡献，促进我国催化学科的发展，中国化学会催化专业委员会设立“中国催化奖”，包括“中国催化成就奖”(可冠名为张大煜奖)、“中国催化青年奖”和“全国催化大会优秀论文奖”．     

新型含硅聚芳醚酮的合成与表征

对FeBr3／Me6TREN催化的反向原子转移自由基聚合进行了研究。在不同的催化剂、引发剂的配比、聚合温度和配体用量等条件下，该催化体系催化的MMA聚合反应动力学为一级反应。聚合物分子量可控，分子量分布很窄，说明该体系催化的聚合反应为活性可控聚合，通过实验计算了反应的活化能，并利用UV光谱对催化剂进行了研究。     

用IR法测定线型间甲酚-甲醛树脂中亚甲基桥的邻-对位比

线型间甲酚-甲醛树脂中亚甲基桥与羟基的相对位置不同,其性能有很大不同。我们用IR法测定785cm~(-1)和855cm~(-1)处的吸光度——A_(725)和A_(856),用其比值A_(785)/A_(855)测定线型间甲酚-甲醛-树脂中亚甲基桥的邻-对位比。     

Method of Separating the Sensitive Volume of Calorimetric Cells in a Differential Titration Calorimeter

A scientific and technical solution of capillary calorimetric unit design is described based on a method of separating the sensitive volume of calorimetric cells with a heat-conducting bridge in a differential titration calorimeter. The design of the calorimetric cells as thin capillary tubes allowed to minimize the dimension of the heat-conducting bridges and to separate with high accuracy the sensitive volume of the calorimetric cells which is of 78.5 μl. Due to high calorimeter power sensitivity (10 nW) a modern level of requirements for measuring minimum specific heat of processes is provided. The adopted design of the calorimetric cells permits to possess the cells located horizontally and to simplify the solution of the problem of equalizing components concentration along the volume of the calorimetric cells. This revised version was published online in July 2006 with corrections to the Cover Date.     

Structure and magnetic properties of a copper(II) compound with syn–anti carboxylato- and linear Cu–Cl–Cu chloro-bridges

The copper(II) polymer Cu(2-qic)Cl (2-qic = quinoline-2-carboxylate) was synthesized and then characterized by X-ray crystal structure determination, spectroscopic and magnetic studies. The crystal structure consists of copper(II) ions with two different chromophores: four-coordinated in a square-planar geometry and five-coordinated in an environment between square-pyramidal and trigonal-bipyramidal. The copper ions are bridged sequentially through the carboxylate groups in a syn–anti conformation, forming an infinite one-dimensional zigzag chain with two alternating non-equivalent copper(II) chromophores. The chloride atom acts as a single chloro-bridge link to adjacent chains, forming a ribbon type structure (1D). The variable-temperature (1.8–300 K) magnetic susceptibility data of the complex were interpreted with the dimer law using the molecular field approximation. The results obtained indicate a very weak ferromagnetic (J₂ = 0.37 cm⁻¹) interchain interaction through the syn–anti carboxylate bridge. A relatively strong antiferromagnetic interaction, transmitted through the chloro-bridge with an exchange coupling of J₁ = −57.0 cm⁻¹, dominates the magnetic properties of this complex. The magnitude and the nature of the exchange coupling are explained on the basis of the structural results.     

氮桥双共轭体系共轭阻断效应AM1研究

利用AM1方法研究了氮桥双共轭体系共轭阻断效应，在蒋明谦先生等的研究基础上，用HOMO中烯醛或芳环成分能形象地说明芳环与烯醛共轭竞争。在氮桥的二边，一个双键及一个烯醛基共轭程度大致与二个芳稠环相当。     

Synthesis and Crystal Structure of μ1,1,3 Formic Bridging 3D Microporous Ni(Ⅱ) Complex

A μ1,1,3 formic bridging Ni2 complex [Ni3(HCOO)6·H2O]]n 1 has been synthesi-zed under hydrothermal conditions. The single-crystal X-ray diffraction analysis shows that 1 exhibits a 3D open microporous tube formed by covalent and coordination bonds. Complex 1 crystallizes in the monoclinic system, space group P21/c with a = 11.1487(13), b = 9.7763(11), c =17.9685(17) A, β= 126.948(6)°, C6H6Ni3O13, Mr = 462.02, V = 1565.2(3) A3 Z = 4, Dc= 1.961 g/cm3, μ = 3.630 mm-1, F(000) = 917.7, Rint = 0.0234, the final R = 0.0234 and wR = 0.0734 for 3469 observed reflections (Ⅰ>2σ(Ⅰ)).     

Synthesis of Heterobimetallic Phosphido-Bridged W-Mo Complexes with Chelating dppe and dppm Ligands

Reactions between and bidentate phosphines (dppm and dppe) produced complexes and with chelating dppm and dppe ligands as only products. No bridging bidentate phosphine complex was observed. Both complexes were spectroscopically characterized.     

色谱法测定催化剂中碳含量操作条件研究

根据燃烧-色谱法的原理建立了催化剂碳含量的测定方法并开发了催化剂高温定碳仪,通过考察燃烧温度、载气流速、桥流等对催化剂碳含量测定的影响,确定了测定催化剂碳含量的最佳操作条件。实验结果表明,在确定的最佳操作条件下,测定的催化剂碳含量与化学法基本相同。     

含线性碳桥金属有机"分子导线"的研究进展

由过渡金属与线性有机共轭桥组成的“分子导线”以其在一维分子导体、液晶材料和非线性光学材料等方面的潜在应用价值引起学术界和产业界的关注 .结合自己在此方面所做的工作 ,从合成、性质等方面对近年来含线性碳桥金属有机“分子导线”的研究进展作一综述     

JONES型电导池测量的LCR电桥等效电路选择

JONES电导池系统的交流阻抗由电极过程的相关阻抗和电极间溶液的电阻两部分组成,可用适当的等效电路模拟。采用LCR电桥测量JONES电导池中溶液的电阻时需要选择合适的等效电路为模型解析测量的交流阻抗。通过等效电路的分析发现,选择串联电路作为LCR电桥的解析等效电路测量JONES型电导池中溶液的电阻时引入的误差比并联电路小。     

Ferromagnetic copper(II)–copper(II) interaction in a single chlorido and dicyanamido bridged mixed–valence copper(I/II) 2-D polymer generated by in situ partial reduction of copper(II)

A mixed-valence 2-D Cu(I/II) complex, [{Cu(II)(dmen)(μ-Cl)(μ_1,5-dca)}{Cu(I)(μ_1,5-dca)}]_n (1) (dmen = N,N-dimethylethylenediamine, dca = dicyanamide = [N(CN)₂]^?), has been synthesized by in situ partial reduction of Cu(II) to Cu(I) using benzoin (2-hydroxy-1,2-di(phenyl)ethanone) as reductant. Complex 1 was characterized by spectroscopic techniques, single crystal X-ray diffraction, and low temperature magnetic measurements. Structural investigation reveals that 1 represents a mixed-valence 2-D coordination polymer formed by parallel 1-D [Cu(II)(dmen)(Cl)Cu(I)(μ_1,5-dca)₂]_n chains running along the b axis, where chloride bridges Cu(II) ions of adjacent polymers through long connections (2.8401(1) Å) to form a 2-D network. The metal centers have two different geometrical environments (distorted square pyramidal and distorted trigonal planar geometries for Cu(II) and Cu(I), respectively). The Cu(II) ions in [Cu(II)(dmen)(μ-Cl)(dca)]_n are interconnected through single chloride bridges while within the [Cu(I)(μ_1,5-dca)]_n units, the dca connects adjacent Cu(I) ions through μ_1,5-dca bridges. Magnetic susceptibility measurements reveal weak ferromagnetic interactions (J = +0.3 cm^?1) within the chlorido-bridged Cu(II) regular chain present in 1. Simultaneous presence of μ_1,5-dca and single chlorido bridges with ferromagnetic coupling is believed to be unique in mixed-valence Cu(I)/Cu(II) complexes.