Direct observation of quantum coherence in single-molecule magnets

Direct evidence of quantum coherence in a single-molecule magnet in a frozen solution is reported with coherence times as long as T{2}=630+/-30 ns. We can strongly increase the coherence time by modifying the matrix in which the single-molecule magnets are embedded. The electron spins are coupled to the proton nuclear spins of both the molecule itself and, interestingly, also to those of the solvent. The clear observation of Rabi oscillations indicates that we can manipulate the spin coherently, an essential prerequisite for performing quantum computations.     

Macroscopic quantum tunneling in molecular magnets

Our present understanding of the phenomenon of quantum tunneling of magnetization (QTM), is reviewed in the light of the experiments performed on the molecular complex Mn₁₂-ac. This system, in which QTM was clearly shown for the first time, consists of molecules with mesoscopic spins in dipolar interactions. Both single and many-molecule effects are essential for the observation of QTM (crystal field, hyperfine and dipolar interactions), which allows one to make a link between mesoscopic physics and magnetism.     

Impurity spin dynamics and quantum coherence in mesoscopic rings

We investigate the effects of impurity spin dynamics on quantum coherence in mesoscopic metallic rings. Spin relaxation induces temporal current fluctuations which are closely related to persistent currents in such systems. The persistent current is suppressed in the presence of magnetic impurities. We discuss spin-polarisation effects, spin-glass ordering, and the Kondo effect which are shown to restore the current even in the presence of magnetic scattering.     

Observation of a bi-domain state and nucleation free switching in mesoscopic ring magnets

We present the results of a study of the magnetic properties of an array of 34-nm thick Co(100) epitaxial ring magnets, with inner and outer diameters of d(in) = 1.3 microm and d(out) = 1.6 microm, respectively. Magnetic measurements and micromagnetic simulations show that a two step switching process occurs at high fields, indicating the existence of two different stable states. In addition to the vortex state, which occurs at intermediate fields, we have identified a new bi-domain state, which we term the onion state, corresponding to opposite circulation of the magnetization in each half of the ring. The onion state is stable at remanence and undergoes a simple and well characterized nucleation free switching.     

分子磁体中的量子隧穿及宏观量子效应

文章介绍了分子磁体中的量子隧穿和宏观量子效应理论和实验研究的新进展．分子磁体既有宏观磁体特性也呈现纯量子行为，例如磁化矢量的量子隧穿．文章作者解释了如何通过量子隧穿实现宏观量子相干(即薛定谔猫态的相干叠加)和量子态位相干涉．对隧穿率计算的瞬子方法，特别是有限温度隧穿理论及其在分子磁体量子隧穿中的应用也做了简要的阐述．     

Rabi oscillations revival induced by time reversal: a test of mesoscopic quantum coherence

Using an echo technique proposed by Morigi et al., we have time-reversed the atom-field interaction in a cavity quantum electrodynamics experiment. The collapse of the atomic Rabi oscillation in a coherent field is reversed, resulting in an induced revival signal. The amplitude of this "echo" is sensitive to nonunitary decoherence processes. Its observation demonstrates the existence of a mesoscopic quantum superposition of field states in the cavity between the collapse and the revival times.     

Signature of phase coherence in isolated mesoscopic systems

At low temperature, electronic wave functions in a metal keep their phase coherence on a length L_φ which can be of the order of few microns. Transport and thermodynamic properties of mesoscopic systems whose size are smaller than L_φ exhibit spectacular signatures of this coherence which can be revealed by instance through the sensitivity of the phase of the electrons to an applied vector potential. These quantum effects crucially depend on the way measurements are performed, in this paper we emphasize the difference between:• connected open systems, characterized by their transmission properties accessible through conductance measurements;• electrically isolated, closed systems caracterized by their energy level spectra and investigated through thermodynamic (mostly magnetization) and ac conductance (response to an electromagnetic wave) measurements.They correspond to different types of coupling to the measuring apparatus, and present different sensitivities to phase coherence. The amplitude of quantum oscillations of the magnetoconductance on a connected system are indeed only a small fraction of the classical conductance and can be much larger on an isolated system.     

Coherence and destruction of coherence in mesoscopic rings

Recent investigations have shown that an important contribution to the magnetic response of an ensemble of mesoscopic normal metal rings at low temperatures is given by the coherent backscattering familiar from the theory of weak localization, here initiated by the electron-electron interaction. It is studied how this collective effect is weakened by the orbital effect of the magnetic field, by spin-orbit scattering, spin-flip scattering, and the Zeeman splitting. The renormalization of the interaction constant due to higher order contributions in the Cooper channel, is discussed.     

Novel quantum phases and mesoscopic physics in quantum gases

Among many notable jubilees brought by the year 2012, the one of a special importance for the community of statistical physicists was the 140th birth anniversary of Marian Smoluchowski (Maryan Ritter von Smolan Smoluchowski, 28.05.1872 - 5.09.1917), who was one of the pioneers of statistical physics and, on a larger scale, one of those who shaped modern physical science as a whole. The present issue of EPJ ST entitled From Brownian motion to self-avoiding walks and Lévy flights aims to reflect the evolution of Smoluchowski’s ideas in the field of statistics of interacting random and self-avoiding walks, stochastic equations for many-particle systems, physics of glass-forming and noise driven systems. Majority of papers in this issue were presented at the international conference in statistical physics that took place in Lviv (Ukraine) on July 3-6, 2012.     

Switchable molecular magnets

Various molecular magnetic compounds whose magnetic properties can be controlled by external stimuli have been developed, including electrochemically, photochemically, and chemically tunable bulk magnets as well as a phototunable antiferromagnetic phase of single chain magnet. In addition, we present tunable paramagnetic mononuclear complexes ranging from spin crossover complexes and valence tautomeric complexes to Co complexes in which orbital angular momentum can be switched. Furthermore, we recently developed several switchable clusters and one-dimensional coordination polymers. The switching of magnetic properties can be achieved by modulating metals, ligands, and molecules/ions in the second sphere of the complexes.     

Bose-glass phases in disordered quantum magnets

In disordered spin systems with antiferromagnetic Heisenberg exchange, transitions into and out of a magnetic-field-induced ordered phase pass through unique regimes. Using quantum Monte Carlo simulations to study the zero-temperature behavior, these intermediate regions are determined to be Bose-glass phases. The localization of field-induced triplons causes a finite compressibility and, hence, glassiness in the disordered phase.     

A mesoscopic quantum gravity effect

We explore the symmetry reduced form of a non-perturbative solution to the constraints of quantum gravity corresponding to quantum de Sitter space. The system has a remarkably precise analogy with the non-relativistic formulation of a particle falling in a constant gravitational field that we exploit in our analysis. We find that the solution reduces to de Sitter space in the semi-classical limit, but the uniquely quantum features of the solution have peculiar property. Namely, the unambiguous quantum structures are neither of Planck scale nor of cosmological scale. Instead, we find a periodicity in the volume of the universe whose period, using the observed value of the cosmological constant, is on the order of the volume of the proton.     

Heat conduction in low-dimensional quantum magnets

Transport properties provide important information about the mobility, elastic and inelastic of scattering of excitations in solids. Heat transport is well understood for phonons and electrons, but little is known about heat transport by magnetic excitations. Very recently, large and unusual magnetic heat conductivities were discovered in low-dimensional quantum magnets. This article summarizes experimental results for the magnetic thermal conductivity κ_mag of several compounds which are good representations of different low-dimensional quantum spin models, i.e. arrangements of S=1/2 spins in the form of two-dimensional (2D) square lattices and one-dimensional (1D) structures such as chains and two-leg ladders. Remarkable properties of κ_mag have been discovered: It often dwarfs the usual phonon thermal conductivity and allows the identification and analysis of different scattering mechanisms of the relevant magnetic excitations.     

Magnetization reversal measurements in mesoscopic amorphous magnets by magneto-optical Kerr effect

A magneto-optical setup based on the transverse Kerr effect has been designed to study the magnetization reversal processes by vector magnetometry in arrays of magnetic nanostructures with a reduced total volume. This system allows the measurement of both the parallel and perpendicular to the field components of the magnetization. It has been used to analyze the behavior of amorphous Co _x Si_1-x lines fabricated by electron beam lithography that present a very well defined shape induced uniaxial anisotropy. When the field is applied near to the hard direction, coherent rotation processes are found to occur with a collapse of this reversal mode at fields very close to the hard axis that allows to estimate the very low anisotropy dispersion of these samples. The analysis of the vector hysteresis loops reveals that the magnetization switches via an incoherent process that starts prior to the Stoner-Wohlfarth instability and that can be described in terms of a localized curling-like reversal mode.Received: 16 June 2004, Published online: 24 September 2004PACS: 75.75. + a Magnetic properties of nanostructures - 75.60.Jk Magnetization reversal mechanisms - 75.50.Kj Amorphous and quasicrystalline magnetic materials     

Transport through quantum dots in mesoscopic circuits

We study the transport through a quantum dot, in the Kondo Coulomb blockade valley, embedded in a mesoscopic device with finite wires. The quantization of states in the circuit that hosts the quantum dot gives rise to finite size effects. These effects make the conductance sensitive to the ratio of the Kondo screening length to the wires length and provide a way of measuring the Kondo cloud. We present results obtained with the numerical renormalization group for a wide range of physically accessible parameters.     

Spin quantum tunneling in single molecular magnets: fingerprints in transport spectroscopy of current and noise

We demonstrate that transport spectroscopy of single molecular magnets shows signatures of quantum tunneling at low temperatures. We find current and noise oscillations as a function of bias voltage due to a weak violation of spin-selection rules by quantum tunneling processes. The interplay with Boltzmann suppression factors leads to fake resonances with temperature-dependent position which do not correspond to any charge excitation energy. Furthermore, we find that quantum tunneling can completely suppress transport if the transverse anisotropy has a high symmetry.     

Spin tunneling properties in mesoscopic magnets: effects of a magnetic field

The tunneling of a giant spin at excited levels is studied theoretically in mesoscopic magnets with a magnetic field at an arbitrary angle in the easy plane. Different structures of the tunneling barriers can be generated by the magnetocrystalline anisotropy, the magnitude and the orientation of the field. By calculating the nonvacuum instanton solution explicitly, we obtain the tunnel splittings and the tunneling rates for different angle ranges of the external magnetic field ( θ _H = π/2 and π/2 < θ _H < π). The temperature dependences of the decay rates are clearly shown for each case. It is found that the tunneling rate and the crossover temperature depend on the orientation of the external magnetic field. This feature can be tested with the use of existing experimental techniques. Received 12 March 2001 and Received in final form 18 October 2001     

Long-lived memory for mesoscopic quantum bits

We describe a technique to create long-lived quantum memory for quantum bits in mesoscopic systems. Specifically we show that electronic spin coherence can be reversibly mapped onto the collective state of the surrounding nuclei. The coherent transfer can be efficient and fast and it can be used, when combined with standard resonance techniques, to reversibly store coherent superpositions on the time scale of seconds. This method can also allow for "engineering" entangled states of nuclear ensembles and efficiently manipulating the stored states. We investigate the feasibility of this method through a detailed analysis of the coherence properties of the system.