ЛЮМИНЕСЦЕНЦИЯ КРИСТ АЛЛОВ AgCl

AgCl –180°. . , ( : =4640 Å, =5080 Å). , , . . - . –183°, =1,6. 10^–8%±10%.

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Luminescence of AgCl crystals

The luminescence of normal and deformed single crystals of AgCl of different thickness was measured at a temperature of –180°C. With deformed samples the decrease in intensity of the luminescence was measured. On the luminescence band of the above crystals we observed a fine structure for which the series rule could be used (edge of series =4640 Å, =5080 Å).The observed luminescence was explained by means of the exciton mechanism proposed by Matyá, i.e. annihilation of a localized exciton either on a cation vacancy or on a cation vacancy on a dislocation jog. The luminescence yield at –183°C, =1.6×10^–3%±10%, was measured by a photographic method.

     

Electrical properties of films of TeO2-Sb2O3 glasses

It is shown that TeO₂-Sb₂O₃ films may be producted by vacuum evaporation. Stable properties are produced if the films are given an additional treatment in an oxidizing medium. Results are given for , tan , and as functions of temperature and other parameters.     

On Shirokov's “One New Effect of the Einsteinian theory of Gravitation”

In this note we study M.F. Shirokov's One New Effect of Einstein's theory of Gravitation in the Kerr field. We confine ourselves to a circular trajectory (r=const) in the plane=/2. In the limit that terms of the second order and higher ina/r (a is the angular momentum per unit mass) are negligible we find an additional shift betweenT andT _r (orT ) of amount –(8a/r)(m/r) ^3/2. Thus vibrations lie further behindr(or) vibrations in this case than in the Schwarzschild field.     

Calculation of Out‐of‐Plane Vibrations of a Porphin Molecule

Using the DFT/B3LYP method with the base set 631G^**, we carried out calculation of the frequencies of the normal vibrations of porphin and of its five isotopic types. Scaling of force constants for outofplane vibrations has been performed in independent natural coordinates. The symmetry coordinates are introduced and a force field for outof plane vibrations of a porphin molecule in independent coordinates of symmetry is obtained. A new correlation of the frequencies of vibrations in the type of the symmetry B _1u for the isotopic type of the d ₂ porphin molecule is suggested on the basis of discrete analysis of the distribution of a potential energy.     

The use of the repulsive potential in the quantum theory of solids

A new method is proposed for calculating the energy in certain special points of the Brillouin zone. The wave functions of valence and conduction electrons are given in the form of the linear combination of plane waves and the orthogonality condition of these functions to the wave functions of lower states is replaced by the repulsive potential. The practical application of this very simple method is illustrated on the energy spectrum of silicon in the centre of the Brillouin zone. It is proved that the results are comparable with some other methods, e. g. the orthogonalized plane-wave method.

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The basic thesis of this paper, together with concrete calculation of the energy spectrum of diamond, was delivered at the Czechoslovak-Polish conference in Sopoty in November 1956.

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In conclusion the autor would like to thank K. Trnková for carrying out the numerical calculations.     

Implementation of comparative probability by normal states. Infinite dimensional case

Let be an infinite dimensional Hilbert space and () the set of all (orthogonal) projections on . A comparative probability on () is a linear preorder on () such thatOP1,1O and such that ifP┴R,Q┴R, thenPQP+RQ+R for allP, Q, R in (). We give a sufficient and necessary condition for to be implemented in a canonical way by a normal state onB(), the bounded linear operators on .     

A natural scalar field in the einstein gravitational theory

In a Riemannian space-time, the difference between the third-order tensor potentialH of the Riemann tensor (presented in a precedent paper) and the Lanczos generating function of the Weyl tensor is here shown to be characterized by a vectorV , obtained by contractionH . The significant role of such a vector, in the context of general relativity, is then discussed. Particular attention is paid to the scalar potential which characterizes the irrotational part ofV : such a scalar field satisfies a space-time wave equation of the Poisson type. Weak fields are also considered: in the particular case of a static metric, the scalar is found to be proportional to the classic Newtonian potential.This work was done in the sphere of activity of the C.N.R. Groups for mathematical research.     

CO2-laser annealing of Al/a-Si:H contact

The paper concerns the possibility of using CW (continuous wave) CO₂-laser annealing (=10.6 m,P 100 W/cm²) for formation of a barrier in the Al/a-Si:H/SS (SS-stainless steel) structures with good rectifyingI–V characteristics. The infrared absorption spectra, photoelectric properties, temperature effect on the conductivity and saturation current were analyzed and various contact models are discussed.We thank P. imanec for useful and stimulating discussion, J. Stuchlík for kindly manufacturing the a-Si:H films for us and D. N. Goncharov for the aid with the measurement of the conductivity temperature dependences.     

Kinetic limits of the HPP cellular automaton

We study the Boltzmann-Grad limit in various versions of the two-dimensional HPP cellular automaton. In the completely deterministic case we prove convergence to an evolution that is not of kinetic type, a well-known phenomenon after Uchyiama's paper on the Broadwell gas, whereas the limiting equation becomes of kinetic type in the model with random collisions. The main part of the paper concerns the case where the collisions are deterministic and the randomness comes from inserting, between any two successive HPP updatings, ^- stirring updatings, <1 being any fixed positive number and a parameter which tends to 0. The initial measure is a product measure with average occupation numbers of the order of (low-density limit) and varying on distances of the order of ^–1. The limit as 0 of the system evolved for times of the order of ^-1- corresponds to the Boltzmann-Grad limit. We prove propagation of chaos and that the renormalized average occupation numbers (i.e., divided by) converge to the solution of the Broadwell equation. Convergence is proven at all times for which the solution of the Broadwell equation is bounded.     

Rate equations in the hopping transport

The usual kinetic equations for the site occupation probabilities in an external field are solved exactly in a simple one-dimensional periodic model with two kinds of atoms using a) free boundary conditions and order of limitsN, 0 needed for a proper treatment of the dc conductivity here b) boundary conditions with metallic contacts and order of limitsN, 0 and c) the same boundary conditions but reversed order of limiting processes 0,N typical of e.g. numerical and percolation treatments. (N and are the number of sites and frequency.) It is demonstrated that though the bulk dc conductivity is the same in all three cases, local bulk properties of the material are strongly dependent on the régime used. The role of the order of all three limiting processes 0,N+ andn+ (N–n+) for local shifts of the chemical potential _n in the dc limit is examined (n is the number of the relevant site calculated from a boundary of the chain). It is shown especially that the rate equation treatment (régime a) on the one hand and numerical or percolation treatments (régime c) on the other hand never yield the same bulk values of _r.     

Holes in the probability density of strongly colored noise driven systems

A qualitative change in the topology of the joint probability densityP(,x), which occurs for strongly colored noise in multistable systems, has recently been observed first by analog simulation (F. Moss and F. Marchesoni,Phys. Lett. A 131:322 (1988)) and confirmed by matrix continued fraction methods (Th. Leiber and H. Riskin, unpublished), and by analytic theory (P. Hänggi, P. Jung, and F. Marchesoni,J. Stat. Phys., this issue). Systems studied were of the classx=–U(x)/x+(t,), whereU(x) is a multistable potential and (t, ) is a colored, Gaussian noise of intensityD, for which =0, and (t) (s)=(D/)exp(–t–s/). When the noise correlation time is smaller than some critical value ₀, which depends onD, the two-dimensional densityP(,x) has the usual topology [P. Jung and H. Risken,Z. Phys. B 61:367 (1985); F. Moss and P. V. E. McClintock,Z. Phys. B 61:381 (1985)]: a pair of local maxima ofP(,x), which correspond to a pair of adjacent local minima ofU(x), are connected by a single saddle point which lies on thex axis. When >₀, however,the single saddle disappears and is replaced by a pair of off-axis saddles. A depression, or hole, which is bounded by the saddles and the local maxima thus appears. The most probable trajectory connecting the two potential wells therefore does not pass through the origin for >₀, but instead must detour around the local barrier. This observation implies that successful mean-first-passage-time theories of strongly colored noise driven systems must necessarily be two dimensional (Hänggiet al.). We have observed these holes for several potentialsU(x): (1)a soft, bistable potential by analog simulation (Moss and Marchesoni); (2) a periodic potential [Th. Leiber, F. Marchesoni, and H. Risken,Phys. Rev. Lett. 59:1381 (1987)] by matrix continued fractions; (3) the usual hard, bistable potential,U(x)=–ax ²/2+bx ⁴/4, by analog simulations only; and (4) a random potential for which the forcingf(x)=–U(x)/x is an approximate Gaussian with nonzero correlation length, i.e., colored spatiotemporal noise, by analog simulation. There is a critical curve ₀(D) in the versusD plane which divides the two topological behaviors. For a fixed value ofD, this curve is shifted toward larger values of ₀ for progressively weaker barriers between the wells. Therefore, strong barriers favor the observation of this topological transformation at smaller values of . Recently, an analytic expression for the critical curve, valid asymptotically in the small-D limit, has been obtained (Hänggiet al.).This paper will appear in a forthcoming issue of theJournal of Statistical Physics.     

Stochastic coupling and thermodynamic inequalities

Let ₁ and ₂ be thermodynamic Gibbs measures on ^m and ⁿ , respectively. Diffusions are constructed having ₁, and ₂ as invariant measures. These diffusions are then coupled; inequalities between expectations of certain random variables on the two spaces result.Partially supported by NSF-MCS 74-07313-A03     

Resistivity exponent of two-dimensional lattice animals

We calculate the average resistanceR(L) of lattice animals spanningL×L cells on the square lattice using exact and Monte Carlo methods. The dynamical resistivity exponent, defined asR(L) L , is found to be =1.36±0.07. This contradicts the Alexander-Orbach conjecture, which predicts 0.8. Our value for differs from earlier measurements of this quantity by other methods yielding =1.17±0.05 and 1.22±0.08 by Havlin et al.On leave from the Institute of Theoretical Physics, Chinese Academy of Sciences, Beijing, China.     

Direction-Dependent Free Energy Singularity of the Antiferroelectric Asymmetric Six-Vertex Model

The transition from the ordered commensurate phase to the incommensurate Gaussian phase of the antiferroelectric asymmetric six-vertex model is investigated by keeping the temperature constant below the roughening point and varying the external fields (h, v). In the (h, v) plane, the phase boundary is approached along straight lines v = k h, where (h, v) measures the displacement from the phase boundary. It is found that the free energy singularity displays the exponent 3/2 typical of the Pokrovski–Talapov transition f const(h)^3/2 for any direction other than the tangential one. In the latter case f shows a discontinuity in the third derivative.     

Antibound states for a class of one-dimensional Schrödinger operators

Let (x) be the Dirac's delta,q(x)L ¹ (R)L ² (R) be a real valued function, and , R; we will consider the following class of one-dimensional formal Schrödinger operators on . It is known that to the formal operator may be associated a selfadjoint operatorH(,) onL ²(R). Ifq is of finite range, for >0 and || is small enough, we prove thatH(,) has an antibound state; that is the resolvent ofH(,) has a pole on the negative real axis on the second Riemann sheet.Work done while the author was supported by an undergraduate fellowship of the (Italian) National Research Council (CNR).     

The modular group and super-KMS functionals

Every normal, faithful, self-adjoint functional on a von Neumann algebraA canonically determines a one-parameter-weakly continuous *-automorphism group (the analog of the modular group) and a canonical ₂ grading onA, commuting with . We show that the functional satisfies the weak super-KMS property with respect to and Furthermore, we prove that and are the unique pair of a-weakly continuous one-parameter *-automorphism group and a grading of the algebra, commuting with each other, with respect to which is weakly super-KMS. The above results thus provide a complete extension of the theory of Tomita and Takesaki to the nonpositive case.Supported in part by the National Science Foundation under Grant DMS-8922002.     

Symmetries and half-sided modular inclusions of von Neumann algebras

LetN, be a von Neumann algebras on a Hilbert space , a common cyclic and separating vector. Assume to be cyclic and also separating forN . Denote by , _N , _N the modular operators to (, ), (N, ), resp (N , ). Assume now ^-it N ^it N for allt 0. (Such type of inclusions ((N U, ) , ) are called half-sided modular.) Then the modular groups ^it , _N ^ir , _N ^is ,t, r, s generate a unitary representation of the group S1(2, )/Z ₂ of positive energy.Another result is related to two half-sided modular inclusions (₁ , ) and (₂ , ). Under proper conditions the three modular groups ^it , ₁ ^ir , ₂ ^is ,t, r, s generate the three-dimensional subgroup of O(2, 1) of two commuting translations and the Lorentz transformation.Partly supported by the DFG, SFB 288 Differentialgeometrie und Quantenphysik.     

The Schrödinger equation and canonical perturbation theory

LetT ₀(, )+V be the Schrödinger operator corresponding to the classical HamiltonianH ₀()+V, whereH ₀() is thed-dimensional harmonic oscillator with non-resonant frequencies =(₁, ... , _d ) and the potentialV(q ₁, ... ,q _d) is an entire function of order (d+1)^–1. We prove that the algorithm of classical, canonical perturbation theory can be applied to the Schrödinger equation in the Bargmann representation. As a consequence, each term of the Rayleigh-Schrödinger series near any eigenvalue ofT ₀(, ) admits a convergent expansion in powers of of initial point the corresponding term of the classical Birkhoff expansion. Moreover ifV is an even polynomial, the above result and the KAM theorem show that all eigenvalues _n (, ) ofT ₀+V such thatn coincides with a KAM torus are given, up to order , by a quantization formula which reduces to the Bohr-Sommerfeld one up to first order terms in .     

Geometric localization of the threshold in two-dimensional Ising ±J spin glasses forT=0

Following an approach of Toulouse, ground states in random 2D Ising ±J spin glasses (without external magnetic field), on square lattices, and with concentrations 0p0.5 of antiferromagnetic bonds are studied by means of minimal matchings of frustrated plaquettes. Lete(p) be the ground-state energy per spin in the thermodynamic limit. Then the well-known equatione(p)=–2+(p)f(p) holds, wheref(p) is the concentration of frustrated plaquettes and(p) is the average connection length between paired frustrated plaquettes in minimal matchings. Introducing (p) as the probability that a frustrated plaquette is matched to another frustrated plaquette by a connection of length (in a minimal matching), the average length(p) can be rewritten asgl(p)=(p). The study of(p) and its components (p) leads to an intervalp ^*pp ₂ (p ^*0.121±0.008,p ₂0.161±0.008) where the threshold between ferromagnet and paramagnet forT=0 lies. Analyzing a similar so-called adjoined average lengthl(p) admits further insight.     

The positive muon as a tracer for the study of metal hydrogen systems

We present the first systematic study of dynamic muon H-correlations in a metal hydride (NbH _x ) over a large range of H concentrations. The following observations were made: (i) H loading shifts the motional narrowing range for muons in Nb from 60 K to above 170 K; (ii) in-NbH _x muon () and H correlation times are of the same order but the corresponding activation energies are distinctly different; (iii) the concentration dependence of ^–1 exhibits strong negative deviations from a (1-c) behavior; (iv) the H/D isotope effect in-NbH(D)_0.92 is distinctly non-classical; (v) the ordering of vacancies in the subhydrides suppresses long range muon motion. The experimental features are interpreted in the framework of tracer diffusion theory and bear clear evidence that repulsive muon-H interactions are an important feature of the dynamic muon hydrogen correlations.