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1.
Hyperfine structure and isotope shifts in five optical
transitions: 424.5 nm (
–
), 537.2 nm (
–
), 554.5 nm
(
–
), 560.9 nm
(
–
) and 666.0 nm
(
–
)
of Pb II have been measured. As a light source the discharge tube was used.
The hyperfine structure measurements were
performed using metallic isotope 207Pb. For isotope shifts
measurements natural lead was used. The high resolution spectral apparatus consisted of a silver
coated Fabry-Perot etalon and a grating spectrograph combined
with a CCD camera used as a detector. In the analysis of the
spectra a computer simulation technique was used. The hyperfine
structure observations yielded the splitting constants A for
seven levels of Pb II. The isotope shift studies enabled to
separate the mass and the field shifts and to determine values of
changes of the mean square nuclear charge radii. 相似文献
2.
A. Ehresmann W. Kielich L. Werner Ph. V. Demekhin D. V. Omel''yanenko V. L. Sukhorukov K.-H. Schartner H. Schmoranzer 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,45(2):235-246
Dispersed fluorescence from fragments formed after the de-excitation of the
1s-1π* resonances of N*O and NO* has been
measured in the spectral range of 118–142 nm. This range is dominated by
lines of atomic nitrogen and oxygen fragments and by the
bands in the NO+ ion which result from the participator Auger decay of the 1s-1π* resonances.
Ab-initio calculations of the transition probabilities between vibrational
levels during the reaction NO
N*O
⇒ NO
were used to explain the observed intensity dependence for the
fluorescence bands on the exciting-photon energy across
the resonances and on both v′ and v′′
vibrational quantum numbers. The multiplet structure of the 1s-1π* resonance and lifetime vibrational interference explain the observed exciting-photon energy dependence of the
fluorescence
intensity. A strong spin-orbit coupling between singlet and triplet states
of NO+ is proposed to reduce additional cascade population of the
state via radiative transitions from the
and
states and to explain
remaining differences between measured and calculated integral fluorescence
intensities. 相似文献
3.
A. Nadeem M. Nawaz S. U. Haq S. Shahzada M. A. Baig 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2009,53(2):147-151
We report term energies and quantum defects of highly excited even-parity states of mercury in the 83 876–84 140 cm-1 energy range, employing a two-step laser excitation scheme via the S0↦6s6p3P1 inter-combination transition. Two dye lasers, pumped by a common Nd:YAG laser, were frequency doubled by BBO crystals and
used to record the spectra in conjunction with a thermionic diode ion detector. Our new observations include the much extended
D2 (22 ≤n ≤52) series and a few members of the S1 (24 ≤n ≤30) Rydberg series. Members of the D2 Rydberg series with such a high n value are reported for the first time. The relative intensities of the D2 and S1 transitions (m = 4, 5 and 6) of group II-B elements excited from the P1 inter-combination states are also discussed. 相似文献
4.
B. F. Parsons K. E. Strecker D. W. Chandler 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,38(1):15-20
In our previous work we investigated electronically non-adiabatic effects in
using crossed molecular beam scattering
coupled with velocity mapped ion imaging. The prior experiments placed
limits on the cross-section for electronically non-adiabatic spin-orbit
excitation
and electronically non-adiabatic spin-orbit
quenching
.
In the present work, we investigate
electronically non-adiabatic spin-orbit quenching for
which is the required first step for the
reaction of Cl* to produce ground state HCl+H products. In these
experiments we collide Cl (2P) with H2 at a series of fixed
collision energies using a crossed molecular beam machine with velocity
mapped ion imaging detection. Through an analysis of our ion images, we
determine the fraction of electronically adiabatic scattering in
Cl* +H2, which allows us to place limits on the cross-section for
electronically non-adiabatic scattering or quenching. We determine the following
quenching cross-sections σ quench(2.1 kcal/mol) = 26 ±
21 ?2, σ quench(4.0 kcal/mol) = 21 ±
49 ?2, and σ quench(5.6 kcal/mol) = 14 ±
41 ?2. 相似文献
5.
We present new experimental data on the highly excited levels in mercury using the two-step laser excitation and optogalvanic detection technique in conjunction with a RF discharge cell. The 6s7s 3S1 intermediate level has been accessed from the 6s6p 3P2 metastable level that is collisionally populated in the mercury discharge in the presence of a buffer gas at a pressure of about 1 Torr. Two beams fromtwo different dye lasers pumped with a common excimer laser were passed through the discharge cell containing mercury vapors. The first laser was tuned to 6s7s 3S1 level whereas the second laser was scanned covering the wavelength region between 544-458 nm. We have observed the 6snp 3P0 (
), 6snp
(
), 6snp
(
) and 6snp
) Rydberg series. The 6snp
Rydberg series to such high n-value has been reported for the first time. The first ionization potential of mercury is determined from the 6snp
Rydberg series as 84184.15
0.05 cm-1. Some collisionally induced parity forbidden transitions have also been located that are identified as 6sns
(
) series.Received: 5 November 2003, Published online: 20 January 2004PACS:
31.50.-x Potential energy surfaces - 32.30.Jc Visible and ultraviolet spectra - 32.80.Rm Multiphoton ionization and excitation to highly excited states (e.g., Rydberg states) 相似文献
6.
R. M. Jennerich A. N. Keiser D. A. Tate 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,40(1):81-89
We have obtained Doppler-free spectra of transitions in the
→ 2p2(3P)
and
→
multiplets of atomic nitrogen using saturated absorption spectroscopy. These multiplets consist of
respectively of seven and eight transitions, and have center of gravity wavelengths of 821 nm and 869 nm. Values for the hyperfine
structure coupling constants of all the upper and lower states for these multiplets were obtained for both 14N and 15N. Isotope shifts of three transitions in each multiplet were also measured, and a significant J-dependence to the shifts
was observed. 相似文献
7.
The three-photon ionization in Ca from
S0 ground state is studied. The two-photon process is a near -- resonance process with one of the following bound states: 4s4d
1D2, 4p
P2, 4s6s
1S0, 4
D2 and 4
S0 while the third photon reach either directly the continuum or one of the autoionizing states. The succession of bound states as well as the transitions above the ionization limit are discussed. The dynamics of the multiphoton excitation processes is also discussed and radiative decay of 4
S0 Ca state with two-photon excitation as well as (the measured) decay times of the Ca autoionizing states using the proper line profiles for different quantum numbers has been determined.Received: 29 September 2003, Published online: 18 May 2004PACS:
32.70.-n Intensities and shapes of atomic spectral lines - 32.70.Cs Oscillator strengths, lifetimes, transition moments - 32.80.Fb Photoionization of atoms and ions - 32.80.Rm Multiphoton ionization and excitation to highly excited states (e.g., Rydberg states) 相似文献
8.
We have performed a series of experiments to observe 11 Stark-induced E1 transitions from the 15650.55 cm-1 level to higher levels with odd parity in samarium (Sm) with optical double-resonance technique. Five Stark-induced E1 transition to the 28233.08, 28613.22, 28913.97, 29041.31 and 29130.03 cm-1 levels have been observed. In order to investigate the contributors to the Stark-induced E1 transition, we have measured scalar and tensor polarizabilities for the observed Stark-induced E1 transitions. Clear Stark splittings were observed for the levels 28233.08 and 28613.22 cm-1, and their tensor polarizabilities were determined for each isotope. Scalar polarizabilities were determined for the 28233.08, 28613.22, 28913.97 and 29130.03 cm-1 levels for the first time. Among them, scalar polarizability for the 28233.08 cm-1 level was the largest in magnitude and was 3.60(10) x 103 kHz/(kV/cm)2 for
Sm. We noticed that both scalar and tensor polarizabilities of the 28233.08 cm-1 level depend on the isotope; the difference of magnitude of the scalar and tensor polarizabilities between
Sm and
Sm were remarkably large and were about 10 and 6 percent, respectively.Received: 10 February 2003, Published online: 30 July 2003PACS:
32.60.+i Zeeman and Stark effects - 32.10.Dk Electric and magnetic moments, polarizabilityD. Angom: Present address: Physical Research Laboratory, Navarangpura, Ahmedabad 380 009, India. 相似文献
9.
M. Z.M. Kamali K. Ratnavelu Y. Zhou 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,46(2):267-279
The recent theoretical work by Bartlett et al. [J. Phys. B 38, L95 (2005)] and the latest measurements on the reduced Stokes parameters
,
and
for 54.4 eV electron impact excitation of the 2p state atomic hydrogen by Williams and Mikosza [J. Phys. B 39, 4113 (2006)] has motivated the present work. A coupled-channel-optical calculation with 9 and 12 atomic states supplemented
with the continuum optical potentials for the stronger coupling channels has been performed. The calculated n = 2 and n =
3 differential cross sections and the reduced Stokes parameters are comparable with the state-of-the art calculations. There is closer agreement between the present calculations and the experimental measurements for the reduced
Stokes parameters
and
in the n = 2p excitation at 54.4 eV. The present CCO calculations also display good accord with the limited experimental
data for the reduced Stokes parameters in the n=3p excitation. 相似文献
10.
H. Prakash P. Kumar 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,46(2):359-363
We study amplitude-squared squeezing of the Hermitian operator Zθ=Z1
cosθ+Z2 sin θ, in the most general superposition state
, of two coherent states
and
. Here operators Z1,2 are defined by
, a is annihilation operator, θ is angle, and
complex numbers C1,2 , α, β are arbitrary and only
restriction on these is the normalization condition of the state
. We define the condition for a state
to be amplitude-squared squeezed for the operator Zθ
if squeezing parameter
, where N=a+a and
. We find
maximum amplitude-squared squeezing of Zθ in the superposed
coherent state
with minimum value 0.3268 of the
parameter S for an infinite combinations with α- β= 2.16
exp [±i(π/4) + iθ/2],
and with
arbitrary values of (α+β) and θ. For this minimum
value of squeezing parameter S, the expectation value of photon number can
vary from the minimum value 1.0481 to infinity. Variations of the parameter
S with different variables at maximum amplitude-squared squeezing are also
discussed. 相似文献
11.
P.?Mas?owski K.?Bielska A.?Cygan J.?Domys?awska D.?Lisak R.?Ciury?o A.?Bielski R. S.?Trawiński 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2009,51(3):295-302
Careful analysis of the intercombination 51S0–53P1 line of the 113Cd isotope with two hfs components
and was carried out.
The hyperfine splitting of this line was determined to uncertainty less than
10-3 cm-1 using neon-perturbed Doppler limited spectra. 相似文献
12.
A. E. Kramida G. Nave 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,37(1):1-21
All observed spectral lines of Ne III in the
range 204 ? to 36 μm (277 cm-1 to 490000 cm-1) have been
compiled and critically evaluated. 57 visible and ultraviolet lines of Ne
III have been precisely measured using Fourier transform spectroscopy. An
optimized level scheme has been derived from the total list of observed
lines. Relative positions of about 180 out of a total of 226 previously
known energy levels of Ne III have been determined with improved accuracy
compared to previous studies. Excitation energies of almost all excited
levels have been revised by (1.5–2.0) cm-1. 127 precise wavelength
standards in the region 210 ? to 2900 ? have been derived. Concepts
of error current and covariance matrix have been implemented in a computational algorithm that permits one
to derive the uncertainties of Ritz wavelength standards obtained from a set
of least-squares-optimized energy levels. Nine new energy levels have been
found, and 16 new transitions have been identified in the extreme
ultraviolet region. The ionization potential has been increased by
4.5 cm-1. The new value is
(
(
). 相似文献
13.
J. P. Marques F. Parente P. Indelicato 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,41(3):457-465
In this paper, we used the multiconfiguration Dirac-Fock method to compute with high precision the influence of the hyperfine
interaction on the [Ar]
P0 level lifetime in Zn-like ions for stable and some quasi-stable isotopes of nonzero nuclear spin between Z=30 and Z=92. The
influence of this interaction on the
[Ar]
P
P0 separation energy is also calculated for the same ions. 相似文献
14.
The adiabatic interaction potentials were obtained for the paradigm transition metal-rare gas interactions: Sc(2D)-He and Ti(3F)-He and their di-cations. The ab initio approach included the coupled cluster and multireference configuration interaction methods. He atoms form very weak van der Waals complexes with Sc and Ti with well-depths of ca. 4-5 cm-1. The interactions are characterized by the nearly-degenerate manifolds of adiabatic states with splittings of the order of 0.1 cm-1 or less. The anisotropy of the Ti-He interaction is smaller than that for the Sc-He interaction. The origin of the weak anisotropy of these interactions was analyzed. The exchange repulsion was found to be nearly the same in the
,
and
states due to the valence d-electrons being submerged under the doubly filled 4s electron sub-shell. The anisotropy of the total potential is controlled by the weakly-anisotropic dispersion interaction.Received: 24 September 2004, Published online: 23 November 2004PACS:
34.20.-b Interatomic and intermolecular potentials and forces, potential energy surfaces for collisions - 31.50.Df Potential energy surfaces for excited electronic states - 31.15.Ar Ab initio calculations 相似文献
15.
G.?J.?Naga Raju G.?A.?V.?Ramana Murty B.?Seetharami Reddy T.?Seshi Reddy S.?Lakshminarayana S.?Bhuloka Reddy
The L X-ray intensity ratios in the elements Hf, Ta, Re, Ir, Pt, Au and Pb due to proton bombardment at energies from 1 to 5 MeV are measured and compared with the ECPSSR theoretical intensity ratios. The L
/L
l
intensity ratios obtained in the present work are in good agreement with theoretical values while the L
/L
and L
/L
intensity ratios are consistently lower than the theoretical values. This deviation may be explained in terms of multiple ionization effects in M, N and O shells.Received: 27 March 2004, Published online: 6 July 2004PACS:
32.80.Hd Auger effect and inner-shell excitation or ionization - 32.30.Rj X-ray spectra - 41.75.-i Charged-particle beams - 41.75.Ak Positive-ion beams 相似文献
16.
For a homogeneous quantum network of N subsystems with n levels each we consider separable generalized Werner states. A generalized Werner state is defined as a mixture of the totally mixed state and an arbitrary pure state
:
with a mixture coefficient
. For this density operator
to be separable,
will have an upper bound
. Below this bound one should alternatively be able to reproduce
by a mixture of entirely separable input-states. For this purpose we introduce a set of modules, each contributing elementary coherence properties with respect to a generalized coherence vector. Based on these there exists a general step-by-step mixing process for any
. For
being a cat-state it is possible to define an optimal process, which produces states right up to the separability boundary (
).Received: 3 December 2002, Published online: 29 July 2003PACS:
03.65.Ud Entanglement and quantum nonlocality (e.g. EPR paradox, Bells inequalities, GHZ states, etc.) - 03.67.-a Quantum information - 03.65.-w Quantum mechanics 相似文献
17.
G. Poletti F. Orsini D. Batani A. Bernardinello T. Desai J. Ullschmied J. Skala B. Kralikova E. Krousky L. Juha M. Pfeifer Ch. Kadlec T. Mocek A. Präg O. Renner F. Cotelli C. Lora Lamia A. Zullini 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2004,30(2):235-241
Soft X-ray Contact Microscopy (SXCM) of Caenorhabditis elegans nematodes with typical length
m and diameter
m has been performed using the PALS laser source of wavelength
m and pulse duration
ps. Pulsed soft X-rays were generated using molybdenum and gold targets with laser intensities
W/cm2. Images have been recorded on PMMA photo resists and analyzed using an atomic force microscope operating in contact mode. Cuticle features and several internal organs have been identified in the SXCM images including lateral field, cuticle annuli, pharynx, and hypodermal and neuronal cell nuclei.Received: 18 February 2004, Published online: 29 June 2004PACS:
42.62.Be Biological and medical applications - 07.85.Tt X-ray microscopes - 87.59.Bh X-ray radiographyA color version of the figures is available in electronic form at . 相似文献
18.
Measurements of multiphoton ionization and dissociation of acetone are reported in the wavelength range 582.60-585.80 nm at photon energy resolution of 0.3 cm-1. To our knowledge there are not available results of (3 + 2) REMPI on acetone at 0.01 nm in this region. The experiments were performed using an Nd: YAG-OPO (optical parametric oscillator) laser system coupled to time-of-flight mass spectrometer. The ion yield and the single ion channel are presented. The high-resolution three-photon resonance multiphoton spectrum of the acetone
Rydberg transition is also reported. The experimental results show three dissociation channels of the acetone ion, leading to the products: (CH3CO + ), (CH3
+ ) and (COH + ); the channel CH3COCH
3CO + + CH3 being the most favored. The acetone and acetyl ions are observed in all wavelength range investigated. In addition, we have measured the origin of the
and
transitions, and vibrational bands of the 3s state.Received: 21 March 2004, Published online: 11 May 2004PACS:
33.80.Rv Multiphoton ionization and excitation to highly excited states (e.g., Rydberg states) - 33.15.Ta Mass spectra - 33.80.Gj Diffuse spectra; predissociation, photodissociation 相似文献
19.
G. Spavieri 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,39(2):157-166
The wave equation for light propagation in slowly moving media, which is
analogous to that of quantum effects of the Aharonov-Bohm type, is
characterized by the interaction momentum
, related to the flow
. In effects of the Aharonov-Bohm type the interaction momentum
is related to the momentum of the electromagnetic (em) fields, that
characterizes an em flow
. It is shown that in both cases
has the same physical origin. Calculation of the interaction em momentum
for the light wave dragged by the flow yields exactly the
Fresnel-Fizeau momentum. These results corroborate the validity of the
magnetic model for light and highlight the role and relevance of the em
momentum in new effects of classical and quantum physics. A tentative test
of an astrophysical Fizeau-Aharonov-Bohm effect is discussed. 相似文献
20.
A pair
of interacting Kerr oscillators treated as a master coupler sending chaotic or hyperchaotic signals to its slave copy
is considered. We synchronize a with A and b with B through two communication channels
and
. The effect of synchronization is non-simultaneous, the pairs
and
have different times of synchronization. It is possible to synchronize an individual pair, for example,
when its communication channel
is turned off, provided that the second channel for the pair
is turned on. The resulted synchronization is termed induced. The efficiencies of the presented synchronization precesses are studied.Received: 20 February 2003, Published online: 29 April 2003PACS:
05.45.Xt Synchronizations; coupled oscillators - 05.45.Pq Numerical simulations of chaotic systems - 42.65.Sf Dynamics of nonlinear optical systems; optical instabilities, optical chaos and complexity, and optical spatio-temporal dynamics 相似文献