共查询到20条相似文献,搜索用时 15 毫秒
1.
Ali Ramazani Abolfazl Momeni-Movahhed Farideh Gouranlou 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):903-907
Protonation of the highly reactive 1:1 intermediates, produced in the reaction between triphenylphosphine and dialkyl acetylenedicarboxylates, by 1-hydroxy-2-acetonaphthone leads to vinyltriphenylphosphonium salts, which undergo aromatic electrophilic substitution reaction with conjugate base to produce dialkyl 2-(3-acetyl-4-hydroxy-1-naphthyl)-3-(triphenylphosphoranylidene) butanedioates. Silica gel was found to catalyze conversion of dialkyl 2-(3-acetyl-4-hydroxy-1-naphthyl)-3-(triphenylphosphoranylidene) butanedioates to dialkyl 2-(3-acetyl-4-hydroxy-1-naphthyl)-2-butenedioates in solvent-free conditions at 90°;C in fairly good yields. 相似文献
2.
Ali Ramazani 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):1839-1844
Microwave catalyzed one-pot stereoselective synthesis of dialkyl 1,1-diacetyl-8 a -hydroxy-8-oxo-1,2,8,8 a -tetrahydrocyclopenta[ a ]indene-2,3-carboxylates in fairly high yields by the reaction of dialkyl 2-(1-acetyl-2-oxopropyl)-3-(triphenylphosphoranylidene) succinates and ninhydrin in the presence of MgSO 4 in solvent-free conditions. 相似文献
3.
《Phosphorus, sulfur, and silicon and the related elements》2013,188(10):2293-2295
Silica gel was found to catalyze the stereoselective conversion of dialkyl 2-(imido- N -yl)-3-(triphenylphosphoranylidene)butanedioates to electron-poor ( Z )- N -vinylimides in solvent-free conditions at 95°;C in high coversions. 相似文献
4.
Ali Ramazani Ali Souldozi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6):1325-1328
Protonation of the highly reactive 1:1 intermediates, produced in the reaction between triphenylphosphine and dialkyl acetylenedicarboxylates, by 1-hydroxynaphthalene leads to vinyltriphenylphosphonium salts, which undergo aromatic electrophilic substitution reaction with conjugate base to produce dialkyl 2-(1-hydroxy-2-naphthyl)-3-(triphenylphosphanylidene)butanedioates. Silica gel was found to catalyze conversion of dialkyl 2-(1-hydroxy-2-naphthyl)-3-(triphenylphosphanylidene)butanedioates to alkyl 2-oxo-2 H -benzo[ h ]chromene-4-carboxylates in solvent-free conditions at 80°;C in fairly good yields. 相似文献
5.
Ali Ramazani Nader Noshiranzadeh 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6):1321-1324
A facial one-pot stereoselective synthesis of dialkyl 3,3-diacetyl-3 a -hydroxy-8-oxo-2,3,3 a ,8-tetrahydrocyclopenta[ a ]indene-1,2-dicarboxylates in fairly high yields by the intermolecular Wittig reaction of dialkyl 2-(1-acetyl-2-oxopropyl)-3-(triphenylphosphoranylidene) succinates and ninhydrin in the presence of MgSO 4 in solvent-free conditions at 100°;C is reported. 相似文献
6.
Ali Ramazani Ali Reza Kazemizadeh Farzin Marandi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1537-1540
Abstract Potassium dihydrogen phosphate powder and sodium dihydrogen phosphate powder were found to catalyze stereoselective conversion of dialkyl 2-(imido-N-yl)- 3-(triphenylphosphoranylidene)butanedioates to electron-poor (Z)-N-vinylimides in solvent-free conditions under microwave irradiation in 5-6 minutes in high conversions. 相似文献
7.
《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):2663-2666
Protonation of the highly reactive 1:1 intermediates, produced in the reaction between triphenylphosphine and dimethyl acetylenedicarboxylate, by 4-bromophenol leads to vinyltriphenylphosphonium salt, which undergoes aromatic electrophilic substitution reaction with conjugate base to produce dimethyl 2-(5-bromo-2-hydroxyphenyl)-3-(triphenylphosphoranylidene)butanedioate. Silica gel was found to catalyze conversion of dimethyl 2-(5-bromo-2-hydroxyphenyl)-3-(triphenylphosphoranylidene)butanedioate to methyl 6-bromo-2-oxo-2H-chromene-4-carboxylate in solvent-free conditions at 80°C in fairly high yield. 相似文献
8.
Ali Ramazani Bagher Mohammadi Nader Noshiranzadeh 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):767-771
Protonation of the highly reactive 1:1 intermediates produced in the reaction between triphenylphosphine and dialkyl acetylenedicarboxylates by 2-hydroxy-3-methyl-2-cyclopenten-1-one leads to vinyltriphenylphosphonium salts, which undergo an intramolecular Wittig reaction to produce the corresponding cyclobutene derivatives. The cyclobutene derivatives are not isolable and undergo electrocyclic ring-opening reactions in CH 2 Cl 2 at room temperature to produce dialkyl ( E )-2-(2-methyl-5-oxo-1-cyclopentenyl)-2-butenedioates in moderate yields. 相似文献
9.
Saeed Balalaie Elahe Kowsari Mehri S. Hashtroudi 《Monatshefte für Chemie / Chemical Monthly》2003,134(3):453-456
Summary. Three component condensation of alkylacetoacetates, primary amines, and alkyl cyanoacetates catalyzed by solid supports under
microwave irradiation gave N-alkyl 3-cyano-6-hydroxy-2(1H)-pyridinones with high yields. Upon carrying out the reaction under the same condition on acidic alumina, zeolite HY, silica
gel, and montmorillonite K-10, the best yields were achieved by silica gel.
Corresponding author. E-mail: balalaie@yahoo.com
Received August 28, 2002; accepted September 3, 2002 相似文献
10.
Ali Souldozi Ali Ramazani Nader Noshiranzadeh 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6):1271-1275
Protonation of the highly reactive 1:1 intermediates, produced in the reaction between triphenylphosphine and dialkyl acetylenedicarboxylates, by 1-(2-hydroxy-1-naphtyl)-1-ethanone leads to vinyltriphenylphosphonium salts, which undergo a Michael addition reaction with a conjugate base to produce corresponding stabilized phosphorus ylides. Dipotassium hydrogen phosphate powder was found to catalyze the conversion of stabilized phosphorus ylides to dialkyl (E, Z)-2-(1-acetyl-2-naphthyl)-2-butenedioates under thermal and microwave conditions in a solventless system. 相似文献
11.
《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):2659-2661
Manganese dioxide was found to catalyze stereoselective conversion of dialkyl 2-(imido-N-yl)-3-(triphenylphosphoranylidene)butanedioates to electron-poor (Z)-N-vinylimides in solvent-free conditions at 95°C in high coversions. 相似文献
12.
M. V. Vovk N. V. Mel'nichenko V. A. Chornous M. K. Bratenko 《Chemistry of Heterocyclic Compounds》2002,38(9):1096-1097
4-Isocyanato-3-(2-naphthyl)-1-phenylpyrazole cyclized under the influence of AlCl3 to give 2H-benzo[h]pyrazolo[4,3-c]isoquinoline. 相似文献
13.
K. B. Bazhykova I. A. Poplavskaya K. D. Praliev 《Chemistry of Heterocyclic Compounds》2005,41(11):1386-1389
The reaction of 1-(2-ethoxyethyl)piperidin-4-one with ethynylcyclohexanol led to the synthesis of a glycol, the hydration
of which gave a mixture of spirocyclic compounds with a carbonyl group at various positions in the furan ring.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1649–1652, November, 2005. 相似文献
14.
The disclosure herein describes the rapid synthesis of 4-hydroxy-3-phenylquinolin-2(1H)-ones and variants via a solvent-free microwave cyclocondensation reaction using di-(2,4,6-trichlorophenyl)-2-phenylmalonate, which improves the general scope of this reaction. 相似文献
15.
Under microwave irradiation,2,2'-alkoxy-bridging or 4,4'-alkoxy-bridging dibenzaldehydes reacted with 4-hydroxycoumarin in DMF to give a series of 3,3',3″,3'″-o-and 3,3',3″,3'″-p-phenylenedimethylidinetetrakis-(4-hydroxy-2H-1-benzopyran-2-ones) in moderate yields.The structures of the synthetic coumarin derivatives were characterized with IR,1H NMR and MS spectroscopy as well as X-ray single crystallography. 相似文献
16.
Asghar Hosseinian Hamid Reza Shaterian 《Phosphorus, sulfur, and silicon and the related elements》2013,188(9):1056-1063
A one-pot, efficient three-component condensation of aldehydes, 2-naphthol, and 2-aminobenzothiazole in the presence of sodium hydrogen sulfate as an effective catalyst for the synthesis of 1-(benzothiazolylamino)methyl-2-naphthol derivatives under thermal and solvent-free conditions is described. These products involve two biologically active parts, Betti's base and benzothiazole. The present methodology offers several advantages, such as good yields, short reaction times, and easy work-up. 相似文献
17.
18.
A mild, efficient, and high-yielding method for the synthesis of 2-aryl-2,3-dihydroquinolin-4(1H)-ones from their corresponding 2-amino chalcones using silica chloride (SiO2Cl) under solvent-free conditions is described. A series of 2-aryl-2,3-dihydroquinolin-4(1H)-ones containing both electron-donating and electron-withdrawing substituents were synthesized. 相似文献
19.
A synthesis of methyl 2-hydroxy-4-oxo-4-(substituted phenyl)butanoates has been accomplished using Friedel-Crafts acylation of substituted benzenes with 2-acetoxybutanoyl chloride.The key feature of this strategy is that various 4-arylbutanoates can be obtained conveniently,which are important intermediates for the synthesis of biologically active compounds including ACE inhibitors. 相似文献
20.
The interaction of the sodium salts of 3-(1-adamantyl)-1-hydroxy-1-propen-3-one and 4-(1-adamantyl)-1-hydroxy-1-buten-3-one with hydroxylamine, hydrazine, and guanidine leads to the synthesis of 5-(1-adamantyl)-5-hydroxy- and 5-(1-adamantylmethyl)-5-hydroxy-2-isoxazolines, 3-(1-adamantyl)- and 3-(1-adamantylmethyl)pyrazoles, 3-(1-adamantyl)-2-phenylpyrazole, and 4-(1-adamantyl)-2-amino- and 4-(1-adamantylmethyl)-2-aminopyrimidines. 相似文献