8-mJ TEM(00) diode-end-pumped frequency-quadrupled Nd:YAG laser

A frequency-quadrupled Nd:YAG laser pumped by a commercially available high-brightness stack is described. A master oscillator power amplifier configuration was implanted, and the laser delivered energy of 8 mJ at 0.266microm . The laser was air cooled for easy use.     

208-W TEM00 operation of a diode-pumped Nd:YAG rod laser

208-W average-power TEM(00) -mode operation from a diode-pumped Nd:YAG rod laser was demonstrated. The side-pumping method of generating a high-gain aberration-free rod, the bifocusing-compensation technique with two identically pumped rods, and a suitable choice of beam spot size were employed in the design of this laser. At the maximum pump power of 1.1 kW the fundamental transverse-mode operation (M(2)<1.1) was characterized by 7.6% electrical efficiency. The extraction efficiency was almost 60% of full multimode operation. Stable operation was obtained within a pump-power range of 15% of the maximum pump power.     

A birefringence-compensated two-rod Nd:YAG laser operating in TEM00 mode with a CW 61W output power

Two identically pumped Nd:YAG rods with a imaging system and a polarization rotator are used in experiments to achieve a complete birefringence compensation. The measured depolarization ratio is from 1.0 to 2.5%, which increases with the increasing of pump power. With a TEM₀₀-mode operation, the depolarization ratio achieved is less than 1%. A dynamically stable resonator is performed using two flat mirrors and an intra-cavity lens. 61 W linearly polarized output was achieved with a M ² factor of 1.6, which is the state of the art for a lamp pumped laser.     

355 nm nanosecond pulsed Nd:YAG laser profile measurement, metal thin film ablation and thermal simulation

Laser ablation of nickel, gold and copper thin film on glass substrates has been investigated using a nanosecond pulsed Nd:YAG laser operating at 355 nm in air with a Gaussian intensity profile. The exact beam profile was measured through mechanical scanning with a photodiode. A small beam defect was observed, which can affect the machining performance at higher pulse energies. The ablation thresholds of the films were calculated from the crater diameter values. The effect of the pulse repetition rate and the film thickness was also studied. At high pulse repetition rates heat accumulation was observed and the ablation threshold decreased with the film thickness. Both cases resulted in higher diameters.     

Analysis of TEM00 laser beam quality degradation caused by a birefringent Nd: YAG rod

The effects produced by a birefringent rod on the beam quality factor,M _infr ^sup2 , of a Gaussian TEM₀₀ laser beam are studied. Analytical expressions for the beam parameters at the output plane of a rod amplifier are derived. The theory predicts that the beam quality degrades rapidly with the heat power dissipated in the rod.     

Efficient high-power diode-end-pumped TEM(00) Nd:YVO(4) laser with a planar cavity

We demonstrate a compact and efficient diode-end-pumped TEM>(00) laser with output power of 30 W for 48 W of incident pump power by use of two coated Nd:YVO> (4) crystals to form a thermally stabilized flat-flat cavity. In Q -switched operation 25 W of average power at a pulse-repetition rate of 100 kHz and ~0.9-mJ pulse energy at a pulse-repetition rate of 10 kHz were produced.     

Nd:YAG laser ablation characteristics of thin CIGS solar cell films

This work reports that the ablation characteristics of thin CuIn_1?x Ga _x Se₂ (CIGS) solar cell film differ significantly with elemental composition and laser pulse energy. From in situ shadowgraphs measured during Nd:YAG laser (1,064 nm) irradiation of CIGS films and crater morphologies, it was found that strong surface evaporation is dominant for low Ga concentration films of which band gap is well below the photon energy. As the band gap of CIGS film becomes close to or over the laser photon energy due to increased Ga content, surface absorption diminishes and at low laser energy, laser heating of the film plays an important role. It is demonstrated that for the CIGS films with Ga/(Ga + In) ratio being approximately over 0.2, the laser irradiation leads to solid phase removal of the film due to thermomechanical fracture at low laser energy but to ablative evaporation at elevated energy.     

Thin films of silver nanoparticles deposited in vacuum by pulsed laser ablation using a YAG:Nd laser

We report the deposition of thin films of silver (Ag) nanoparticles by pulsed laser ablation in vacuum using the third line (355 nm) of a YAG:Nd laser. The nanostructure and/or morphology of the films was investigated as a function of the number of ablation pulses, by means of transmission electron microscopy and atomic force microscopy. Our results show that films deposited with a small number of ablation pulses (500 or less), are not continuous, but formed of isolated nearly spherical Ag nanoparticles with diameters in the range from 1 nm to 8 nm. The effect of increasing the number of pulses by one order of magnitude (5000) is to increase the mean diameter of the globular nanoparticles and also the Ag areal density. Further increase of the number of pulses, up to 10,000, produces the formation of larger and anisotropic nanoparticles, and for 15,000 pulses, quasi-percolated Ag films are obtained. The presence of Ag nanoparticles in the films was also evidenced from the appearance of a strong optical absorption band associated with surface plasmon resonance. This band was widened and its peak shifted from 425 nm to 700 nm as the number of laser pulses was increased from 500 to 15,000.     

Investigation of Cr:YAG passive mode-locking in a pulsed Nd:YAG laser

Passive mode-locking of a pulsed Nd:YAG laser using a Cr⁴⁺:YAG saturable absorber was realized for the first time in a nearly critical stable resonator containing an antiresonant ring structure. The output energy and pulse duration are 13.5 mJ and 180 ps, respectively. The recovery time and saturable intensity for excited-state absorption of Cr⁴⁺:YAG under the action of strong laser pulses were calculated from rate equations.     

Generation and characterization of Nd-Fe-B-C nanoparticles by pulsed Nd:YAG laser ablation in liquid

We have generated Nd-Fe-B-C nanoparticles by Nd:YAG (1064 nm) laser irradiation in distilled water. Exposure times were 1, 5, and 10 min. Characterization of such nanoparticles in terms of their size distribution, shape, and chemical composition was carried out by transmission electron microscopy, energy-dispersive X-rays, and Fourier transform infrared spectroscopy. To investigate the nanoparticle stability, the size distribution of nanoparticles was measured two weeks after the nanoparticle generation, using dynamic light scattering. Investigations with the help of the atomic force microscope and magnetic force microscope showed other aspects of the generated nanoparticles.     

Quality of the beam produced a pulsed Nd:YAG laser

The quality of the beam produced by a Nd:YAG laser was investigated. A hemispherical Nd:YAG laser resonator was developed. A flashlamp driver was designed to pump a Nd:YAG laser crystal. The output of the laser was characterized via the variation of the capacitor voltage. A phosphor card was used to detect the invisible of the infrared beam. Exposed photographic paper was utilized to examine the energetic beam after interaction. The brightness and strength of the beams were analyzed using the Matrox Inspector and VideoTest 5 software packages. The intensity of the beam produced and the volume loss after interaction were found to linearly increase with respect to the input energy.     

Passive mode locking of a Nd：YAG laser with co－doped Nd, Cr：YAG as saturable absorber

We demonstrate the characteristics of relatively low saturation intensity using co-doped Nd, Cr:YAG as saturable absorber for passively mode locking the Nd:YAG laser. The difference of the saturation intensity between Q-switched and mode-locked operation in co-doped Nd, Cr:YAG was only one to two orders of magnitude, while Cr:YAG was generally reported at a difference of five orders of magnitude. More than 80% mode locking modulation depth was achieved at an incident pump power of 4.4W, corresponding to an intracavity intensity of 6×10^4W/cm^2, using a 68cm long plano-concave cavity.     

UV laser micromachining of piezoelectric ceramic using a pulsed Nd:YAG laser

UV laser (=355 nm) ablation of piezoelectric lead zirconate titanate (PZT) ceramics in air has been investigated under different laser parameters. It has been found that there is a critical pulse number (N=750). When the pulse number is smaller than the critical value, the ablation rate decreases with increasing pulse number. Beyond the critical value, the ablation rate becomes constant. The ablation rate and concentrations of O, Zr and Ti on the ablated surface increase with the laser fluence, while the Pb concentration decreases due to the selective evaporation of PbO. The loss of the Pb results in the formation of a metastable pyrochlore phase. ZrO₂ was detected by XPS in the ablated zone. Also, the concentrations of the pyrochlore phase and ZrO₂ increase with increasing laser fluence. These results clearly indicate that the chemical composition and phase structure in the ablated zone strongly depend on the laser fluence. The piezoelectric properties of the cut PZT ceramic samples completely disappear due to the loss of the Pb and the existence of the pyrochlore phase. After these samples were annealed at 1150 °C for 1 h in a PbO-controlled atmosphere, their phase structure and piezoelectric properties were recovered again. Finally, 1–3 and concentric-ring 2–2 PZT/epoxy composites were fabricated by UV laser micromachining and their thickness modes were measured by impedance spectrum analysis and a d₃₃ meter. Both composites show high piezoelectric properties. PACS 81.40.Gh; 77.84.-s     

Ambient gas effects on high-power Nd:YAG laser ablation of SnO2:Sb transparent conducting thin film

Optical emission spectra of the plasma produced by 1.06 μm Nd:YAG laser ablation of SnO₂:Sb transparent conducting thin film were recorded and analyzed as functions of distance from the target surface and incident laser power density in air and in vacuum. Ambient gas effects on pulsed laser ablation of target were analyzed in detail. We also discussed how the air takes part in the plasma evolution process and confirmed that the ignition of the air plasma is by the collisions between the energetic electrons and the nitrogen atoms through a cascade avalanche process.     

Indium tin oxide sol-gel precursor conversion process using the third harmonics of Nd:YAG laser

We use the third harmonics of Nd:YAG laser (λ = 355 nm) for simultaneous precursor conversion and dopant activation on sol-gel ITO thin films at a laser fluence range of 700-1000 mJ/cm². A minimum resistivity of 5.37 × 10⁻² Ω-cm with a corresponding carrier concentration of 6 × 10¹⁹ cm⁻³ is achieved at laser irradiation fluence of 900 mJ/cm². X-ray photoelectron analysis reveals that extremely high tin concentration of 19.4 at.% and above is presented in the laser-cured ITO thin films compared with 8.7 at.% in the 500 °C thermally cured counterpart. These excess tin-ions form complex defects, which contribute no free carriers but act as scattering centers, causing inferior electrical properties of the laser-cured films in comparison with the thermally cured ones.     

Laser welding of glasses using a nanosecond pulsed Nd:YAG laser

This work reports on laser welding of two 1 mm thickness borosilicate glasses through the irradiation with a nanosecond pulsed laser, as a novel alternative to the use of ultrashort pulsed lasers for welding of transparent materials. Two different methodologies were investigated and compared in terms of interface quality. In a first approach, the glasses were joined without any absorbing intermediate layer. However, the bond interface possesses defects. To improve the resulting bond interface, the use of a titanium ultrathin intermediate layer was proposed to weld the glasses substrates, acting as a sealant between them. The laser parameters were optimized to achieve the best joining conditions of the Ti film. The use of the Ti layer gives rise to a bond interface more homogeneous and free of damages. As a further step, thin glasses of 86 µm thickness, of great technological value, were joined through the Ti film as well. The joined interfaces were inspected through optical microscopy and scanning electron microscopy (SEM) while the bond quality was evaluated by Scanning Acoustic Microscopy (SAM).     

Spectroscopic characterization of low-nickel copper welding with pulsed Nd:YAG laser

Effects of various operating parameters of 400 W pulsed Nd:YAG laser on welding of nickel-alloyed copper have been investigated. The induced plume spectra in case of using different assist gases and preheat temperatures have been analyzed and the effects of these key factors on melt features such as penetration depth, porosity and spattering have been attributed to the spectroscopic behavior of the plume. Moreover, the CuI electron temperature and its standard deviation as the spectroscopic responses of the plasma plume to various laser process parameters have been quantitatively evaluated at different average and peak powers and pulse energies. Also, the mentioned responses were utilized to justify the weld bead profile features, involving weld depth, width and their stabilities, at similar process parameters. The operating conditions of welding were optimized, regarding the results of spectroscopic observations and attributing them to the qualitative aspects of the melt pool.     

Laser ablation of dental materials using a microsecond Nd:YAG laser

The action of microsecond laser pulses with a wavelength of 1064 nm on dental tissues (enamel and dentin) and various dental materials used for tooth replacement and filling (ceramics, metal alloys, and composites) is studied. It is demonstrated that the ablation thresholds of all of the dental materials are significantly lower than the threshold laser fluences for the dental tissue (E _thr = 200–300 J/cm²). At the laser fluences that do not allow ablation and damage of the dental tissues, the dental materials are effectively removed at a rate of no greater than 40 μm per pulse. It is shown that the laser ablation of the materials under study involves two processes (evaporation and volume explosion) depending on the optical density. The results obtained indicate that the laser radiation with a wavelength of 1064 nm and the microsecond pulse duration is promising for dental applications, since it allows effective cleaning of the tooth surface from various dental materials in the absence of the damages of dental tissues.     

A 15.1 W continuous wave TEM00 mode laser using a YVO4/Nd:YVO4 composite crystal

A effective continuous-wave (CW), high power laser generated using a YVO₄/Nd:YVO₄ composite crystal is presented. 18.8 W output power in multi-mode has been achieved with a maximum absorbed pump power of 31.2 W, corresponding to an optical-to-optical efficiency of 60.26%. In TEM₀₀ mode operation, 15.1 W output power also has been achieved with the maximum absorbed pump power of 31.2 W, corresponding to an optical-to-optical efficiency of 47.69%. With a 200 mm focal-length positive lens and using the moving knife-edge method, the beam quality factor is measured to be M² = 1.2 for TEM₀₀ mode beam.     

Production and characterization of Nd,Cr:GSGG thin films on Si(001) grown by pulsed laser ablation

Nd,Cr:Gd₃Sc₂Ga₃O₁₂ (GSGG) thin films have been produced for the first time. They were grown on Si(001) substrates at 650 °C by pulsed laser ablation at 248 nm of a crystalline Nd,Cr:GSGG target rod. The laser plume was analyzed using time-of-flight quadrupole mass spectroscopy, and consisted of elemental and metal oxide fragments with kinetic energies typically in the range 10 to 40 eV, though extending up to 100 eV. Although films deposited in vacuum using laser fluences of 0.8±0.1 J cm⁻² reproduced the Nd,Cr:GSGG bulk stoichiometry, those deposited using fluences above ≈3 J cm⁻² resulted in noncongruent material transfer and were deficient in Ga and Cr. Attempts to grow films using synchronized oxygen or oxygen/argon pulses yielded mixed oxide phases. Under optimal growth conditions, the films were heteroepitaxial, with GSGG(001)[100]∥Si(001)[100], and exhibited Volmer–Weber-type growth. Room-temperature emission spectra of the films suggest efficient non-radiative energy transfer between Cr³⁺ and Nd³⁺ ions, similar to that of the bulk crystal. Received: 1 October 1999 / Accepted: 15 October 1999 / Published online: 23 February 2000