Doping-induced changes in the saturable absorption of monolayer graphene

Graphene is a broadband, fast saturable absorber well suited for passive mode-locking of lasers. The broadband absorption, ultra-short recovery time, and low cost of graphene absorbers compare favorably with traditional semiconductor saturable absorber mirrors (SESAMs). However, it remains difficult to tailor the parameters of a monolayer graphene absorber such as the modulation depth and the insertion loss; this limits the absorber??s design freedom, which is often required for mode-locking without Q-switching instability. We demonstrate in this work that, by hole-doping graphene chemically to various Fermi levels, the modulation depth and insertion loss are modified. Further control of graphene??s saturable absorption by electric-field gating and its application to active suppression of Q-switching in lasers is discussed.     

Two-photon absorption and self-phase modulation measurements with shaped femtosecond laser pulses

We show that phase-sensitive detection of spectral hole refilling can yield information about self-phase modulation and two-photon absorption coefficients. We expect that, when applied to tissue microscopy, this technique will allow the study of endogenous molecular markers beneath the surface, even if those markers are nonfluorescent.     

Two-photon absorption towards pulse modulation in mechanically exfoliated and CVD monolayer cascaded MoS_2 structures

Mechanical exfoliation(ME) and chemical vapor deposition(CVD) MoS_2 monolayers have been extensively studied, but the large differences of nonlinear optical performance between them have never been clarified. Here,we prepared MoS_2 monolayers using ME and CVD methods and investigated the two-photon absorption(TPA)response and its saturation. We found that the TPA coefficient of the ME monolayer was about(1.88 ± 0.21) × 10~3 cm/GW, nearly two times that of the CVD one at(1.04 ± 0.15) × 10~3 cm/GW. Furthermore,we simulated and compared the TPA-induced optical pulse modulation in multilayer cascaded structures, which is instructive and meaningful for the design of optical devices such as a beam shaper and optical limiter.     

Two-photon absorption in hexagonal-CdS

The “composite sample technique” has been used to investigate the two-photon absorption coefficient (β) of CdS at 3.91 eV. The absolute value of β and its optical anisotropy have been studied for samples with different carrier densities. The present results may provide a new interpretation of experiments on CdS and other semiconductors reported in the literature.     

Two-photon absorption in CuCl

The two-photon absorption spectrum of CuCl at 4.2°K is studied in the energy range of the excitonic lines. The observed lines are suggested to be due to the creation of excitons in the 1S, 2P and 3P states and also to the simultaneous creation of 2P and 3P excitons and one or more longitudinal optical phonons.     

Enhancement of THz absorption in monolayer graphene for light at Brewster angle incidence

The enhancement of absorption in graphene for light at Brewster angle incidence is investigated. It is achieved by placing a graphene on a resonant Brewster filter that incorporating a spacer layer. The absorber presents above 50% absorption at resonance, which is attributed to the excitation of guided mode resonances. The electromagnetic field intensity distributions are illustrated to intuitively confirm the physical mechanism of such phenomenon. Moreover, the influence of geometric parameters on absorption is investigated to provide a useful guidance for practical fabrication. Besides, it is found that the absorption properties not only can be controlled by adjusting the incident angle but also can be dynamically tuned by changing the Fermi level. Last, the graphene absorption can be easily extended to multichannel by only an increase in the thickness of spacer. The results open new avenues for combining graphene with general guided mode resonance structure to enable novel optoelectronics device applications.     

Controlling theoretically total absorption in hybrid-cavity resonator with one graphene monolayer outside cavity

Total absorption is realized theoretically in a graphene-outside-cavity resonator. The structure is composed of the FP-Fano hybrid resonance cavity. Changing the thickness of grating exciting Fano resonance, the absorption-mode number can be tuned effectively. For the focused double-mode absorption, the resonances behave insensitively with the variation of chemical potential of graphene. Varying the geometry of grating can control the coupling extent of two modes. Also, by manipulating the period number of two-side multilayers around graphene, the absorption, shift and number of modes are governed.     

Two-photon Fourier spectroscopy with femtosecond light pulses

We demonstrate a Fourier spectrometer that uses intense ultrashort laser pulses. By exciting the 6S(1/2) - 8S(1/2) two-photon transition in atomic cesium vapor, we are able to measure the small hyperfine splitting of the 8S(1/2) excited state. This technique, combining a high spectral resolution with the high peak intensities available to femtosecond laser systems, may offer intriguing opportunities for the study of multiphoton transitions and for spectroscopy in the short-wavelength region.     

Two-photon interband magneto absorption in InSb

Two-photon interband magnetoabsorption in InSb has been studied by measuring the resulting changes in the photoconductivity and free-hole absorption as a function of magnetic field and incident photon energy. In both the photoconductivity and transmission measurements, resonant structure with the peaks occuring at the same values of magnetic field was observed with the incident light polarized both parallel and perpendicular to the magnetic field. The results thus are not in agreement with the existing theories of two-photon magnetoabsorption. A modification to a perturbation theory approach is suggested that appears to explain the experimental observations.     

Two-photon interference in the presence of absorption

Experiments on two-photon interference are discussed in the case when there is absorption of all the modes participating in the process of spontaneous parametric down-conversion (SPDC) of light. The objects of investigation are 10-to 80-Å-thick ultrathin gold films deposited on fused-silica substrates. Conditions are determined under which the effect of absorption of the signal and pump waves on the interference pattern is small. It is shown that, under these conditions, the visibility of the interference pattern and the shape of the frequency-angular spectrum at the signal frequency are determined by the optical parameters of the medium at the idler frequency, which belongs to the near-infrared region.     

Cavity plasmon polaritons in monolayer graphene

Plasmon polaritons in a new system, a monolayer doped graphene embedded in optical microcavity, are studied here. The dispersion law for lower and upper cavity plasmon polaritons is obtained. Peculiarities of Rabi splitting for the system are analyzed; particularly, role of Dirac-like spinor (envelope) wave functions in graphene and corresponding angle factors are considered. Typical Rabi frequencies for maximal (acceptable for Dirac-like electron spectra) Fermi energy and frequencies of polaritons near polariton gap are estimated. The plasmon polaritons in considered system can be used for high-speed information transfer in the THz region.     

Two-photon cross-section measurement of meso-tetra-hydroxyphenyl-chlorin using femtosecond laser pulses

Experiments were carried out using the femtosecond laser to compare the fluorescence amplitude produced by two-photon excitation at 800 nm and 400 nm (i.e. to the strong absorption band in mTHPC). Using an experimental arrangement where the fluorescence sampling geometry was kept unchanged between the two exposure wavelengths a value for the two-photon cross-section of mTHPC at 800 nm of ?1.8 × 10^?57 m⁴ s/molecule/photon was derived. This is larger than the value estimated using a simple theoretical model, probably because the calculation neglects ??resonant?? assistance provided by the real state at ??650 nm (S ₀). In terms of order of magnitude the values are in agreement with the two-photon cross-section for other organic species.     

Two-photon absorption of tetraphenylporphin free base

We study two-photon absorption (TPA) spectra for toluene solution of 5,10,15,20-tetraphenyl-21H,23H-porphin (H₂TPP) in B and Q bands regions and find the maximum TPA cross-section values of 25 and 1-6 GM in laser wavelength ranges, 730-790 and 1100-1400 nm, correspondingly. In the 730-790 nm range the spectrum is attributed to parity allowed two-photon transition into g parity state, positioned nearby B state. Much lower TPA cross-section of ∼1 GM is measured for the transition into pure electronic Q state and it is due to the contribution of only those low-symmetry H₂TPP confomers, where mutual orientation of the porphyrin plane and the four phenyl rings lifts the center of inversion. The intermediate values of TPA cross-section of ∼6 GM are observed for the transition into vibronic Q states and are explained by TPA-allowed transition into vibronic states, which can occur even for totally centrosymmetrical molecules. Measurement of two-photon polarization ratio, Ω=σ_circ/σ_lin, shows that for parity allowed g→g transition Ω =1.05±0.05 and for transitions into electronic and vibronic Q-states, Ω=0.62±0.06 and 0.79±0.1 (depending on wavelength), respectively. Quantum-chemical calculations of both u and g parity excited energy levels of H₂TPP molecule are performed by CNDO/S method and the results are in good agreement with the experimental data.