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提出采用三组份改性酚醛树脂和混杂纤维冷压工艺制备离合器摩擦材料.三组份酚醛树脂为硼改性腰果壳油液体树脂、三聚氰胺改性酚醛液体树脂和芳烷基改性酚醛固体树脂.混杂纤维由玻璃纤维和复合包芯纱混杂构成.结果表明,采用三组份酚醛树脂和混杂纤维可以制备出摩擦性能良好,350℃不发生热衰退的离合器摩擦材料,且材料具有合适的孔隙率. 相似文献
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陈炯材蔡铭威吴嘉豪王知张诗洋闵永刚 《高分子通报》2023,(9):1174-1181
在集成电路领域中,线性酚醛树脂作为基础树脂,是关键的功能材料。然而,传统的酚醛树脂存在稳定性差、感光速度慢、透明度、分辨率和机械强度低等问题,增加了应用成本和技术难度,降低了酚醛树脂在集成电路领域的经济效益。因此,需要对传统线性酚醛树脂进行改性以更好地应用于集成电路领域。本文综述了近年来线性酚醛树脂在芯片光刻胶、电子封装及覆铜板应用的研究现状,总结了目前改性线性酚醛树脂的主要方法,并展望了线性酚醛树脂的发展趋势,为未来高性能集成电路应用材料的研发提供参考。 相似文献
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酚醛树脂因其材料成本低、工艺简单、原料易得等优点,在工业上得到了广泛应用。但由于其耐热性不足以及游离酚含量较高等因素,限制了其应用范围。本文利用硼酸对酚醛树脂进行改性,利用红外和质谱对其结构进行表征,改性后酚醛树脂的耐热性能、游离酚等指标得到明显改善。当失重20%时酚醛树脂改性前后耐热性能提高了56℃,可能是由于硼酚醛树脂中含有硼的三维交联网状结构,提高了树脂的交联密度;游离酚含量从改性前的4.12%降低到了2.21%,说明硼元素的引入改变了苯酚的活性,提高了树脂聚合度。 相似文献
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纤维级氢氧化镁阻燃体系研究 总被引:19,自引:0,他引:19
采用一种天然矿物纤维,经特殊加工改性,制成纤维级氢氧化镁,探讨了其与高分子材料的复合性,阻然,消烟,增强等作用,并以硼酸,硬脂酸和有机硅化物为阻然增效剂,LDPE为基体树脂制作作了低烟阻燃材料,产品性能接近于EWCZ-6287-1产品指标。 相似文献
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含氧化叔胺侧基的水溶性酚醛树脂的合成与成像性能 总被引:1,自引:0,他引:1
本实验通过一锅、两步法制备改性酚醛树脂.首先利用环氧酚醛树脂F-44与二甲胺反应,得到叔胺化酚醛树脂,叔胺化树脂被双氧水氧化后得到最终目标产物,即含强极性氧化叔胺基团的酚醛树脂.实验表明,该新型树脂易溶于水和一些强极性溶剂,如四氢呋喃、乙二醇独甲醚和N,N-二甲基甲酰胺等.在热的作用下,树脂能够分解并失去水溶性,但仍可溶于一些有机溶剂.由该树脂与830 nm激光增感染料匹配使用,树脂体系对红外光敏感,并能够通过中性水显影得到较为清晰的阴图型图像,表明该树脂有望用于免化学处理热敏激光成像领域. 相似文献
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对于通用型酚醛树脂和专用型酚醛树脂,其游离酚的分析方法通常采用容量法。但对碳素材料专用酚醛树脂,由于在生产时添加氯化苄对酚醛树脂进行改性,使树脂能浸润碳素材料的中心。这种树脂的生产过程控制和产品质量检验时,涉及游离酚、氯化苄和苄醇的分析测定,如果采用分别测定,其操作相当繁琐,准确性也不高。在常规方法蒸馏苯酚的过程中,氯化苄和苄醇也会被蒸馏出来,蒸馏出来的氯化苄和苄醇对苯酚的容量分析有干扰。在此基础之上,对氯化苄、苄醇和苯酚的蒸馏进行回收率测定,结果表明回收率满足要求。因此,本文建立了气相色谱法同时测定碳素材料专用树脂中的氯化苄、苄醇和苯酚的分析方法。即采用与容量分析方法一样的样品前期处理(酒精溶解样品、水浴蒸馏),使游离酚、氯化苄和苄醇同时与树脂分离后,采用气相色谱法测定。本方法使测定步骤简化,可用于氯化苄改性的专用酚醛树脂的科研和生产控制。 相似文献
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《中国科学:化学》2018,(12)
本文展示了一种新的材料表面改性方法:原子转移自由基聚合(sSI-ATRP)的亚表面修饰,即通过ATRP反应在聚合物材料界面嵌入聚合物刷,构筑稳定的、厚的聚合物亚表面层.首先,将ATRP引发剂分子通过共价键引入到丙烯酸树脂、聚氨酯、聚酯、环氧树脂等聚合物材料中,然后该基底材料在含有催化剂的单体溶液中引发表面原子转移自由基聚合.表面接枝的亲水聚合物刷使材料的表面变得亲水并发生溶胀,使得单体溶液可以进一步接触到材料内部的引发剂而引发新的ATRP反应,该过程不断重复,最后在基材表面上形成几十微米厚的聚合物刷改性的亚表面层.与传统的表面接枝的聚合物刷相比,这种嵌入式的聚合物刷赋予材料表面改性层更好的机械性能,可承受高载摩擦和更好的抗海生物附着特性,且在改性亚表面层破坏后,不需要引发剂修饰组装而再次重复引发聚合改性. 相似文献
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一种加成固化型热固性树脂PN-PAA固化过程和热稳定性研究 总被引:1,自引:0,他引:1
研究了炔丙基醚化酚醛树脂(PN)与聚芳基乙炔树脂(PAA)的反应性共混物(以下简称PN-PAA共混树脂)的相容性,并对共混树脂的固化过程和固化物的耐热性进行了表征.相态、DSC、SEM、TEM等测试结果均表明共混树脂及其固化物是完全相容的均相体系.凝胶时间、粘度、DSC等结果表明共混树脂固化工艺性优良,适合多种成型工艺(如RTM),显著改善了PAA树脂的固化工艺缺陷.DMA、TGA等分析表明共混树脂固化物具有很高的耐热性,可作为新型的防热复合材料和高温结构材料的基体. 相似文献
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Niloufar Ghasemi Rad Zeinab Karami Mohammad Jalal Zohuriaan‐Mehr Ali Salimi Kourosh Kabiri 《先进技术聚合物》2019,30(9):2361-2369
Two kinds of bio‐resourced reactive diluents have been synthesized from linseed oil. The prepared epoxidized linseed oil (ELO) and the cyclocarbonated linseed oil (CLO) were separately blended with a petroleum‐based tetra‐functional epoxy resin (TGDDM) to improve its processability and to overcome the brittleness of the thermoset network therefrom. The linseed oil modifications were spectrally established, and processability improvement of the resin blends was rheologically confirmed. The curing of samples was studied by differential scanning calorimetry, and their mechanical properties (ie, tensile, flexural, fracture toughness, and adhesion) were investigated as well. Scanning electron microscopy images were obtained to reconfirm the toughness improvement of the modified thermosets. In contrast of the epoxidized soybean oil (ie, the most conventionally studied bio‐based reactive diluent), ELO and CLO had no negative effects on the thermoset material characteristics. They improved properties such as tensile strength (up to 43.2 MPa), fracture toughness (1.1 MPa m1/2), and peel‐adhesion strength (4.5 N/25 mm). It was concluded that ELO and CLO were efficient reactive diluents to be used in formulations of polymer composites, surface coatings, and structural adhesives based on epoxy resins. 相似文献
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Yue Situ Jianfeng Hu Hong Huang Heqing Fu Hanwei Zeng Huanqin Chen 《Frontiers of Chemistry in China》2008,3(2):235-241
A novel epoxidized soybean oil (ESO) internally toughened phenolic resin(ESO-IT-PR) with both good toughness and excellent
thermal stability was prepared as the matrix resin of copper clad laminate (CCL). FTIR was adopted to investigate the molecular
structure of modified phenolic resins and SEM was used to observe the micro morphology of their impacted intersections. The
properties of CCLs prepared with these modified phenolic resins were studied to determine the optimal process and investigate
the toughening mechanism. The main modifying mechanism is the etherification reaction between phenol hydroxyl and ESO catalyzed
by triethanolamine and the chain extension polymerization between ESO and multi-amine gives the long-chain ESO epoxy grafting
on the phenolic resin prepolymer. when the ESO content is 30% and the curing agent content is 7%, the ESO toughened phenolic
resin possesses optimal performance. The flexible ESO epoxy shows significant toughening effect and it crosslinks with the
phenolic resin to form an internally toughened network, which is the key factor for improving the solderleaching resistance
of CCL prepared with this modified phenolic resin.
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Translated from Journal of South China University of Technology (Natural Science Edition), 2007, 35(7): 99–104 [译自: 华南理工大学学报(自然科学版)] 相似文献
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Arunjunai Raj Mahendran Nicolai Aust Günter Wuzella Andreas Kandelbauer 《Macromolecular Symposia》2012,311(1):18-27
Summary: The use of renewable raw materials in the polymer industries is becoming increasingly popular because of environmental concerns and the need to substitute fossil resources. Plant oils with triglyceride backbones can be chemically modified and used to synthesize polymers from renewable resources (biopolymers). In the present study, linseed oil was epoxidized using a chemo-enzymatic method based on Candida Antarctica lipase B (CALB) as a biocatalyst and the modified linseed oil was cured using maleinated linseed oil and a commercial polyamide resin. The amount of epoxidation achieved depended on the amount of lipase used and was determined by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopies. With 20% (weight per weight) catalyst concentration based on the wt % of oil a degree of epoxidation of > 90% was achieved. The cross-linking reaction of epoxidized linseed oil with the maleinated linseed oil and the polyamide resin was studied using differential scanning calorimetry (DSC). DSC traces showed that an increase in epoxidation degree lead to larger values for the exothermic enthalpy integrals of the curing reactions and hence to a higher reactivity of the linseed oil towards the cross-linking agents. 相似文献
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In this paper, five different structural urethane acrylates modified by linseed oil were synthesized and then properties of their electron beam cured (EBC) coatings, i.e., adhesion, gloss, flexibility, impact resistance, hardness, tensile strength and elongation were studied. It was shown that these synthesizing conditions of urethane acrylates modified by linseed oil were temperate. Effect of structure of urethane acrylates modified by linseed oil on these properties of their EBC coatings was obvious, except gloss. According to synthetical properties of EBC coatings, the optimum oligomer among these was No. A, whose main chains were formed by hexane diacid, average functionality was 2, and oil content was 25.5%. With increasing of absorbed doses, these properties of EBC coatings, except gloss, changed correspondingly. It was advisable that absorbed dose wasn’t greater than 180 kGy. At higher absorbed doses, cobaltous naphthenate had obvious effect on these properties of EBC coatings, whose oil content of linseed oil was rather high. 相似文献
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《高分子科学杂志,A辑:纯化学与应用化学》2013,50(1-2):65-79
Castor oil was initially subjected to an interesterification reaction with linseed and tung oils and the resulting intermediate was used for the preparation of polyurethanes and their IPNs with poly(methyl methacrylate). They were characterized for their physico-mechanical, swelling, and thermal properties. The morphologies of IPNs were studied with the aid of scanning electron microscopy and differential scanning calorimetry. On comparing the mechanical properties of castor oil polyurethane (CU) and their IPNs (C-IPNs) with those of the castor oil modified with linseed and tung oil (L-IPN and T-IPN, respectively) it was found that L-IPNs showed higher tensile strength, hardness, and better compatibility than C-IPNs. All IPNs showed synergistic effect in elongation and exhibited similar thermal behavior with no significant change with respect to their composition. However, the castor oil polyurethane and their IPNs showed relatively higher elongation and better resistance to solvents. 相似文献
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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(6):1641-1645
British 19th century painters such as J. M. W. Turner, commonly modified the properties of their paint by using gels called “gumtions”. These gels allowed them to easily tune the paint handling and drying properties. The fascinating properties of these “gumtions” were obtained by adding lead acetate to a ternary system based on mastic resin, linseed oil and turpentine. Herein, we report and investigate in depth the rheological properties of these gels as well as their structure at a molecular and supra‐molecular scale. 相似文献
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以自乳化型聚氨酯和甲阶酚醛制备了聚氨酯 酚醛复合水分散液 .pH值与酚醛溶解度的关系表明甲阶酚醛的溶解是酚羟基电离的结果 .聚氨酯 甲阶酚醛水分散液粒子的形态有核壳结构、不完善的核壳结构及纯聚氨酯颗粒三种 ,后者粒径最小 .随着酚醛用量的增大 ,粒子平均粒径增大 .酚醛含量增加使体系热稳定性、机械稳定性、冻融稳定性及临界聚沉值下降 ,pH值稳定范围变窄 .分散液稳定性和电性能考察证明 ,本复合分散液的稳定性主要由分散液的电性能所决定 ,属真溶胶 ,但在一定程度上也具有大分子溶液的特性 .复合液涂膜的性能较纯聚氨酯有所改善 ,尤其在添加了硅溶胶之后 相似文献
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Chen‐Chi M. Ma Shang‐Chin Sung Feng‐Yih Wang Long Y. Chiang Lee Y. Wang Chin‐Lung Chiang 《Journal of Polymer Science.Polymer Physics》2001,39(20):2436-2443
Fullerenol polyurethane (C60‐PU) and linear polyurethane (linear‐PU) modified phenolic resins were prepared in this study. Phenolic resin/C60‐PU and phenolic resin/linear‐PU blends show good miscibility as a result of the intermolecular hydrogen bonding existing between phenolic resin and PU modifiers. DSC and thermogravimetric analysis methods were used to study the thermal properties of phenolic resin blended with different types of PUs. The intermolecular hydrogen bonding that existed between phenolic resin and C60‐PU was investigated by Fourier transform infrared spectroscopy. The morphology and mechanical properties of phenolic resin/C60‐PU and phenolic resin/linear‐PU blends were also investigated. The char yield of the modified phenolic resins decreased with increasing PU modifier content. Significant improvement in the toughness of the modified phenolic resins was observed. The improvements of impact strength were 27.4% for the phenolic resin/linear‐PU system and 54.3% for the phenolic resin/C60‐PU system, respectively, both with 3 phr linear‐PU and C60‐PU content. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 2436–2443, 2001 相似文献