Li2O-Al2O3-SiO2微晶玻璃表面粗糙度对纳米硬度测试的影响

 介绍了纳米压痕测试技术的基础理论及纳米压痕法常用的Oliver -Pharr方法的计算原理。采用纳米压痕试验测得不同表面粗糙度的Li2O-Al2O3-SiO2微晶玻璃样品的纳米硬度、弹性模量和载荷-位移曲线。结果表明样品表面粗糙度会降低纳米压痕测试结果的稳定性、准确性和可靠性：样品表面粗糙度越小,测得的纳米硬度和弹性模量值波动越小,载荷-位移曲线重合性越高。随着最大载荷的增大,测得的弹性模量逐渐减小,其原因是压痕边缘材料发生了塑形变形。在超光滑表面样品（Ra=0.9 nm）上测得较为准确的Li2O-Al2O3-SiO2微晶玻璃纳米硬度和弹性模量值分别为8.8 GPa和7.79 GPa。纳米压痕测试结果的重合度对于评价超光滑表面完整性研究具有指导意义。     

Effect of material stiffness on hardness: A computational study based on model potentials

We investigate the dependence of the hardness of materials on their elastic stiffness. This is possible by constructing a series of model potentials of Morse type; starting with modelling natural Cu, the model potentials exhibit an increased elastic modulus, while keeping all other potential parameters (lattice constant, bond energy) unchanged. Using molecular-dynamics simulation, we perform nanoindentation experiments on these model crystals. We find that the crystal hardness scales with the elastic stiffness. Also the load drop, which is experienced when plasticity sets in, increases in proportion to the elastic stiffness, while the yield point, i.e. the indentation at which plasticity sets in, is independent of the elastic stiffness.     

Experimental and numerical investigation of laser shock synchronous welding and forming of Copper/Aluminum

A novel laser shock synchronous welding and forming method is introduced, which utilizes laser-induced shock waves to accelerate the flyer plate towards the base plate to achieve the joining of dissimilar metals and forming in a specific shape of mold. The samples were obtained with different laser energies and standoff distances. The surface morphology and roughness of the samples were greatly affected by the laser energy and standoff distances. Fittability was investigated to examine the forming accuracy. The results showed that the samples replicate the mold features well. Straight and wavy interfaces with un-bonded regions in the center were observed through metallographic analysis. Moreover, Energy Disperse Spectroscopy analysis was conducted on the welding interface, and the results indicated that a short-distance elemental diffusion emerged in the welding interface. The nanoindentation hardness of the welding regions was measured to evaluate the welding interface. In addition, the Smoothed Particle Hydrodynamics method was employed to simulate the welding and forming process. It was shown that different standoff distances significantly affected the size of the welding regions and interface waveform characteristics. The numerical analysis results indicated that the opposite shear stress direction and effective plastic strain above a certain threshold are essential to successfully obtain welding and forming workpiece.     

Effect of temperature on residual stress and mechanical properties of Ti films prepared by both ion implantation and ion beam assisted deposition

Ti films with a thickness of 1.6 μm (group A) and 4.6 μm (group B) were prepared on surface of silicon crystal by metal vapor vacuum arc (MEVVA) ion implantation combined with ion beam assisted deposition (IBAD). Different anneal temperatures ranging from 100 to 500 °C were used to investigate effect of temperature on residual stress and mechanical properties of the Ti films. X-ray diffraction (XRD) was used to measure residual stress of the Ti films. The morphology, depth profile, roughness, nanohardness, and modulus of the Ti films were measured by scanning electron microscopy (SEM), scanning Auger nanoprobe (SAN), atomic force microscopy (AFM), and nanoindentation, respectively. The experimental results suggest that residual stress was sensitive to film thickness and anneal temperature. The critical temperatures of the sample groups A and B that residual stress changed from compressive to tensile were 404 and 428 °C, respectively. The mean surface roughness and grain size of the annealed Ti films increased with increasing anneal temperature. The values of nanohardness and modulus of the Ti films reached their maximum values near the surface, then, reached corresponding values with increasing depth of the indentation. The mechanism of stress relaxation of the Ti films is discussed in terms of re-crystallization and difference of coefficient of thermal expansion between Ti film and Si substrate.     

Direct laser sintered WC-10Co/Cu nanocomposites

In the present work, the direct metal laser sintering (DMLS) process was used to prepare the WC-Co/Cu nanocomposites in bulk form. The WC reinforcing nanoparticles were added in the form of WC-10 wt.% Co composite powder. The microstructural features and mechanical properties of the laser-sintered sample were characterized by X-ray diffraction (XRD), atomic force microscope (AFM), scanning electron microscope (SEM), energy dispersive X-ray spectroscope (EDX), and nanoindentation tester. It showed that the original nanometric nature of the WC reinforcing particulates was well retained without appreciable grain growth after laser processing. A homogeneous distribution of the WC reinforcing nanoparticles with a coherent particulate/matrix interfacial bonding was obtained in the laser-sintered structure. The 94.3% dense nanocomposites have a dynamic nanohardness of 3.47 GPa and a reduced elastic modulus of 613.42 GPa.     

Evaluation of elastic modulus of cantilever beam by TA-ESPI

The paper proposes an evaluation technique for the elastic modulus of a cantilever beam by vibration analysis based on time average electronic speckle pattern interferometry (TA-ESPI) and Euler-Bernoulli equation. General approaches for the measurement of elastic modulus of a thin film are the Nano indentation test, Buldge test, Micro-tensile test, and so on. They each have strength and weakness in the preparation of the test specimen and the analysis of experimental results. ESPI is a type of laser speckle interferometry technique offering non-contact, high-resolution and whole-field measurement. The technique is a common measurement method for vibration mode visualization and surface displacement. Whole-field vibration mode shape (surface displacement distribution) at resonance frequency can be visualized by ESPI. And the maximum surface displacement distribution from ESPI can be used to find the resonance frequency for each vibration mode shape. And the elastic modules of a test material can be easily estimated from the measured resonance frequency and Euler-Bernoulli equation. The TA-ESPI vibration analysis technique can be used to find the elastic modulus of a material requiring simple preparation process and analysis.     

Effects of post-annealing on the structural and nanomechanical properties of Ga-doped ZnO thin films deposited on glass substrate by rf-magnetron sputtering

In this study, the effects of post-annealing on the structure, surface morphology and nanomechanical properties of ZnO thin films doped with a nominal concentration of 3 at.% Ga (ZnO:Ga) are investigated using X-ray diffraction (XRD), atomic force microscopy (AFM) and scanning electron microscopy (SEM) and nanoindentation techniques. The ZnO:Ga thin films were deposited on the glass substrates at room temperature by radio frequency magnetron sputtering. Results revealed that the as-deposited ZnO:Ga thin films were polycrystalline albeit the low deposition temperature. Post-annealing carried out at 300, 400 and 500 °C, respectively, has resulted in progressive increase in both the average grain size and the surface roughness of the ZnO:Ga thin film, in addition to the improved thin films crystallinity. Moreover, the hardness and Young's modulus of ZnO:Ga thin films are measured by a Berkovich nanoindenter operated with the continuous contact stiffness measurements (CSM) option. The hardness and Young's modulus of ZnO:Ga thin films increased as the annealing temperature increased from 300 to 500 °C, with the best results being obtained at 500 °C.     

板料激光成型技术的实验研究

激光成型是一种利用激光作为热源的热应力无模成型新技术。介绍了板料激光成型技术的工艺过程及影响激光成型的主要因素 ,通过实验研究了激光能量因素、板料的材料性能及几何参数对板料弯曲角度的影响     

Study of the buckling mechanism in laser tube forming

The buckling mechanism of a thin metal tube during laser forming was investigated numerically and experimentally in this study. Metal tubes made of 304 stainless steel were heated by a CO₂ Gaussian laser beam, which induced the buckling phenomenon on the tube surface due to elastic–plastic deformation. This uncoupled thermal–mechanical problem was solved using a three-dimensional finite element method and was subsequently satisfactorily verified with displacement measurements. The transient bending angle and residual stress of the thin metal tube under specific operation conditions were also studied.     

Laser-induced vibration during pulsed laser forming

In this study, the vibration phenomenon during pulsed laser forming of thin metal plates was investigated numerically and experimentally. The metal plates were made of 304 stainless steel and were heated by a CO₂ Gaussian laser beam with a long pulse duration of 0.1 s, which incited vibration due to the elastic–plastic deformation of the specimen. This uncoupled thermal–mechanical problem was solved using a three-dimensional finite element method and was subsequently satisfactorily verified with experiments. Using the superposition method with multiple laser pulses, the non-linear vibration phenomenon during pulsed laser forming has also been observed experimentally for thin plates.     

Effect of sample tilt on nanoindentation behaviour of materials

Analysis of nanoindentation is based on the elastic solution of a rigid indenter perpendicularly penetrating a flat contact surface. In reality, nanoindentation is often performed on a tilt sample surface due to sample tilt mounting or the existing roughness of a polished or raw surface. In this study, finite element simulations as well as nanoindentation experiments on a fused-quartz sample with different tilt angles were carried out to investigate the influence of sample tilt on nanoindentation behaviour of materials. It was found that sample tilt results in increases in the indentation load, contact area and contact stiffness at the same penetration depth. The contact area increase caused by sample tilt cannot be accounted for by Sneddon's equation, commonly used in nanoindentation analysis. This results in a significant underestimation of indentation projected contact area, which in turn leads to an overestimation of the mechanical properties measured by nanoindentation.     

Characteristic of energy input for laser forming sheet metal

Laser forming is a process in which laser-induced thermal deformation is used to form sheet metal without a hard forming tool or external forces. The energy input of laser beam is the key factor for the temperature and stress distribution of sheet metal. The purpose of this work is to investigate the influence of energy input condition on heat input and deformation angle for two-dimension laser forming. Variations in heat input resulting from material deformation was calculated and discussed in this paper at first. Furthermore, in laser forming under the condition of constant laser energy input, the effects of energy input mode on deformation angle and temperature field were investigated.     

Investigation of the photoplastic effect in vitreous semiconductors by cyclic nanoindentation

The dynamics of photoinduced changes in the internal friction and the Young’s modulus for films in the As-Se system is investigated by cyclic nanoindentation at infralow frequencies. It is revealed that the irradiation of the films leads to an increase in the Young’s modulus, a retardation of relaxation processes, and a decrease in the viscosity and nanohardness of the material. The results obtained are discussed in the framework of the concept of microheterogeneous glass structure.     

Laser forming of a bowl shaped surface with a stationary laser beam

Despite a lot of research done in the field of laser forming, generation of a symmetric bowl shaped surface by this process is still a challenge mainly because only a portion of the sheet is momentarily deformed in this process, unlike conventional sheet metal forming like deep drawing where the entire blank undergoes forming simultaneously reducing asymmetry to a minimum. The motion of laser beam also makes the process asymmetric. To counter these limitations this work proposes a new approach for laser forming of a bowl shaped surface by irradiating the centre of a flat circular blank with a stationary laser beam. With high power lasers, power density sufficient for laser forming, can be availed at reasonably large spot sizes. This advantage is exploited in this technique. Effects of duration of laser irradiation and beam spot diameter on the amount of bending and asymmetry in the formed surface were investigated. Laser power was kept constant while varying irradiation time. While varying laser spot diameter laser power was chosen so as to keep the surface temperature nearly constant at just below melting. Experimental conditions promoted almost uniform heating through sheet thickness. The amount of bending increased with irradiation time and spot diameter. It was interesting to observe that blanks bent towards the laser beam for smaller laser beam diameters and the reverse happened for larger spot diameters (~10 times of the sheet thickness). Effect of spot diameter variation has been explained with the help of coupled thermal-structural finite element simulations.     

TiCN thin films grown by reactive crossed beam pulsed laser deposition

In this work, we used a crossed plasma configuration where the ablation of two different targets in a reactive atmosphere was performed to prepare nanocrystalline thin films of ternary compounds. In order to assess this alternative deposition configuration, titanium carbonitride (TiCN) thin films were deposited. Two crossed plasmas were produced by simultaneously ablating titanium and graphite targets in an Ar/N₂ atmosphere. Films were deposited at room temperature onto Si (100) and AISI 4140 steel substrates whilst keeping the ablation conditions of the Ti target constant. By varying the laser fluence on the carbon target it was possible to study the effect of the carbon plasma on the characteristics of the deposited TiCN films. The structure and composition of the films were analyzed by X-ray Diffraction, Raman Spectroscopy and non-Rutherford Backscattering Spectroscopy. The hardness and elastic modulus of the films was also measured by nanoindentation. In general, the experimental results showed that the TiCN thin films were highly oriented in the (111) crystallographic direction with crystallite sizes as small as 6.0 nm. It was found that the hardness increased as the laser fluence was increased, reaching a maximum value of about 33 GPa and an elastic modulus of 244 GPa. With the proposed configuration, the carbon content could be easily varied from 42 to 5 at.% by changing the laser fluence on the carbon target.     

Properties of Cu film and Ti/Cu film on polyimide prepared by ion beam techniques

Cu film and Ti/Cu film on polyimide substrate were prepared by ion implantation and ion beam assisted deposition (IBAD) techniques. Three-dimension white-light interfering profilometer was used to measure thickness of each film. The thickness of the Cu film and Ti/Cu film ranged between 490 nm and 640 nm. The depth profile, surface morphology, roughness, adhesion, nanohardness, and modulus of the Cu and Ti/Cu films were measured by scanning Auger nanoprobe (SAN), atomic force microscopy (AFM), and nanoindenter, respectively. The polyimide substrates irradiated with argon ions were analyzed by scanning electron microscopy (SEM) and AFM. The results suggested that both the Cu film and Ti/Cu film were of good adhesion with polyimide substrate, and ion beam techniques were suitable to prepare thin metal film on polyimide.     

Effect of structural states in near-surface layers of commercial titanium on its fatigue life and fatigue fracture mechanisms

Changes of structural states in near-surface layers of α-titanium strongly affect its fatigue life and fatigue fracture mechanisms. In α-titanium subjected to alternate bending a sliding mode crack develops, resulting in slight delamination of the material. Hydrogenation of α-titanium surface layers preserves their sliding mode cracking but greatly enhances their delamination. Nanostructuring of α-titanium surface layers increases their nanohardness and elastic modulus and causes opening mode cracking. The fatigue life of the material after surface hydrogenation decreases three times, and after surface nanostructuring, it increases four times.     

Investigation into the direct laser forming process of steam turbine blade

In order to achieve high precision and unidirectional solidification microstructure of steam turbine blade fabricated by direct laser forming (DLF), this study is focused on the influence of the laser scanning speed, specific energy and powder feeding rate on the forming characteristics of single cladding pass, which is elementary units in DLF, and a new method of columnar crystal preparation is investigated. Results show that both the metal powder stream and the laser specific energy are the most important factors, that control the high temperature behavior of molten pool so as to determine the micro-morphology of laser scanning track. Based on the optimum processing conditions, high definition steam turbine blade of 316L is fabricated (surface roughness Ra of 10.08 to 26.51 μm or so). The microstructure is of fish scale type by natural cooling after DLF, but it is first found that columnar crystals can be formed on the non-columnar crystal substrate of 316L by intermittent cooling with liquid argon. Therefore, the above investigations will benefit the rapid development of steam turbine blade.     

An experimental investigation of underwater pulsed laser forming

Laser forming is a new forming technology, which deforms a metal sheet using laser-induced thermal stresses. This paper presents an experimental investigation of pulsed laser forming of stainless steel in water and air. The effects of cooling conditions on bending angle and morphology of the heat affected zone (HAZ) are studied. It is shown that the case of the top surface in air and the bottom surface immersed in water has the greatest bending angle based on the forming mechanism of TGM. The water layer above the sample decreases the coupling energy, leading to a small bending angle. For a thin water thickness (1 mm), the water effects on the HAZ are limited. As water layer thickness increases (5 mm), the concave shape of the HAZ is more remarkable and irregular because the shock waves by high laser energy heating water are fully developed. However, the area and the depth of the HAZ become less significant when water thickness is 10 mm due to the long pathway that laser undergoes.     

Chromium-doped diamond-like carbon films deposited by dual-pulsed laser deposition

Diamond-like carbon (DLC) and Cr-doped diamond-like carbon layers were studied. DLC and Cr-DLC were deposited on silicon and titanium substrates (Ti-6Al-4V) by dual-pulsed laser ablation using two KrF excimer lasers and two targets (graphite and chromium). The composition was analyzed using wavelength-dependent X-ray spectroscopy. The Cr content increased from 2.2 to 17.9 at%. The topology and surface properties as roughness of layers were studied using scanning electron microscopy and atomic force microscopy. With the chromium concentration increased the roughness and the number of droplets. Carbon and chromium bonds were determined by Raman spectroscopy. With an increase in chromium content the I _D/I _G ratio increased. Mechanical properties of DLC films with various chromium content were evaluated. Hardness (reduced Young’s modulus) was determined by nanoindentation and reached of 51 GPa (309 GPa). Films adhesion was studied using scratch test and with concentration of chromium increased up to 20 N.