Size dependence of multipolar plasmon resonance frequencies and damping rates in simple metal spherical nanoparticles

We have simulated the non-equilibrium dynamics of methanol adsorbed in FAU zeolite driven by external microwave (MW) radiation. We have modelled steady states produced by augmenting this MW-driven system with a thermostat that acts as a balancing heat sink. We have compared results from an implicit thermostat (Andersen velocity replacement) and an explicit thermostat (helium atoms subjected to Andersen velocity replacement). We find very good agreement between the implicit and explicit thermostats for energy distributions and diffusion coefficients produced under MW-heated steady-state conditions. This augurs well for the continued use of implicit thermostats, which are computationally more efficient.     

Lighting up multipolar surface plasmon polaritons by collective resonances in arrays of nanoantennas

We demonstrate the coupling of multipolar surface plasmons with photonic modes in periodic arrays of metallic nanoantennas. This coupling leads to sharp resonances known as lattice surface modes. In spite of the weak interaction of multipolar surface plasmons with light, lattice surface modes provide an efficient radiative decay channel for emitters in the proximity of the array. We observe a tenfold emission enhancement of dyes coupled to lattice resonances. Lattice surface modes light up multipolar plasmonic resonances, opening new possibilities for fluorescence spectroscopies.     

Calculation of curvature dependent surface plasmon resonance in gold nanospheroid and nanoshell

In this paper, theoretical calculations based on dipole-limit are performed to investigate the effects of curvature on the surface plasmon resonance (SPR) properties of nanometer size gold spheroid and shell. By comparing the aspect ratio with the shell thickness, we demonstrated that the curvature radius is a common better factor that can be used to predict the SPR wavelength and shift fashion. For nanospheroid, increasing the ratio of curvature radius corresponding to the climaxes leads to an increase in the ratio of SPR wavelength, whereas increasing the ratio of curvature radius of outer and inner surface in nanoshell leads to an decrease in the ratio of SPR wavelength. As a morphologic factor, curvature radius plays an important role in affecting the distribution of electron density, and consequently controlling the SPR frequency.     

利用表面等离子体共振效应确定金纳米棒的尺寸

金属纳米粒子的尺寸和形状对其物理和化学性质有很大影响,通常利用昂贵的透射电子显微镜和扫描电子显微镜进行其尺寸测量。为了节约测量成本,利用时域有限差分法研究了金纳米棒的尺寸与吸收峰的对应关系得到间接的测量方法。即当金纳米棒的纵横比增大时,横向等离子峰几乎没有变化,纵向等离子峰出现明显的红移,且红移速度随着金纳米棒半径的增大而增大。实际制备了两种不同尺寸的金纳米棒样品,通过理论模拟确定的金纳米棒的尺寸与利用透射电子显微镜测量的金纳米棒的尺寸符合的很好。     

Drastic reduction of plasmon damping in gold nanorods

The dephasing of particle plasmons is investigated using light-scattering spectroscopy on individual gold nanoparticles. We find a drastic reduction of the plasmon dephasing rate in nanorods as compared to small nanospheres due to a suppression of interband damping. The rods studied here also show very little radiation damping, due to their small volumes. These findings imply large local-field enhancement factors and relatively high light-scattering efficiencies, making metal nanorods extremely interesting for optical applications. Comparison with theory shows that pure dephasing and interface damping give negligible contributions to the total plasmon dephasing rate.     

金银三层纳米管局域表面等离激元共振特性研究

相对于单一金属纳米材料,二金属复合纳米材料具有更大的潜在应用价值.基于时域有限差分方法,研究了SiO₂-Ag-Au和SiO₂-Au-Ag二金属三层纳米管的消光光谱,并对其局域表面等离激元共振(Localized Surface Plasmon Resonance,LSPR)特性进行了分析.研究发现,内核尺寸变大将导致上述两种金属纳米管LSPR峰红移;内层金属及外层金属壳层厚度增大均会导致其LSPR峰蓝移.银壳厚度变化对纳米管LSPR的调制作用大于金壳厚度变化造成的影响.上述现象可以利用等离激元杂化理论及自由电子和振荡电子变化的竞争机制进行分析.     

Review of scattering and extinction cross-sections, damping factors, and resonance frequencies of a spherical gas bubble

Perhaps the most familiar concepts when discussing acoustic scattering by bubbles are the resonance frequency for bubble pulsation, the bubbles' damping, and their scattering and extinction cross-sections, all of which are used routinely in oceanography, sonochemistry, and biomedicine. The apparent simplicity of these concepts is illusory: there exist multiple, sometimes contradictory definitions for their components. This paper reviews expressions and definitions in the literature for acoustical cross-sections, resonance frequencies, and damping factors of a spherically pulsating gas bubble in an infinite liquid medium, deriving two expressions for "resonance frequency" that are compared and reconciled with two others from the reviewed literature. In order to prevent errors, care is needed by researchers when combining results from different publications that might have used internally correct but mutually inconsistent definitions. Expressions are presented for acoustical cross-sections associated with forced pulsations damped by liquid shear and (oft-neglected) bulk or dilatational viscosities, gas thermal diffusivity, and acoustic re-radiation. The concept of a dimensionless "damping coefficient" is unsuitable for radiation damping because different cross-sections would require different functional forms for this parameter. Instead, terms based on the ratio of bubble radius to acoustic wavelength are included explicitly in the cross-sections where needed.     

Shape and size dependence of the surface plasmon resonance of gold nanoparticles studied by Photoacoustic technique

We report on the optical absorption properties of as prepared gold naoparticles of different shapes and sizes measured by photoacoustic (PA) method. The gold nanoparticles of two different shapes (dots, rods) have been prepared using the seed mediated growth method. The shape and the size of these different nanoparticles were determined by STM measurements. PA spectra show the splitting of the surface plasmon resonance (SPR) into two modes (transverse and longitudinal) in case of gold nanorods. The increase in the aspect ratio of the nanorods leads to clear redshifts of the longitudinal SPR. These shifts were used to determine the dielectric constant of the surrounding medium and its variation with the aspect ratios.     

Surface plasma resonances in small spherical silver and gold particles

With 51 keV electrons surface plasma losses have been investigated on small spherical Ag and Au particles embedded in a medium with dielectric constant? _a=2.37. The surface loss of particles with radii of about 50 Å is found at 2.99 ±0.03 eV for silver and 2.34±0.03 eV for gold being in good agreement with calculated values. For larger radii the loss shifts to higher energy values which agrees qualitatively with the theory of Fujimoto and Komaki for the free electron gas. The optical extinction bands of the particles have been measured, too. Their maxima are shifted to lower energies, in accordance with Mie's theory, if the particle size increases sufficiently. Comparison of the energy values of the “electric” extinction bands with those of the surface plasmons shows, that they correspond in theory and experiment, if the particles are small. This confirms, that the optical colloid extinction of Ag and Au may be interpreted as plasma resonance absorption and emission of the particles.     

Concentration of energy inside laser-irradiated gold and silver plasmon nanoparticles in air

We simulated laser-intensity distribution inside spherical gold and silver nanoparticles with radii between 10 and 100 nm, which are exposed to laser radiation at 400, 532, and 800 nm in air, and analyzed the results. The effect of high energy concentration inside illuminated (front) and shadowed (back) hemispheres of gold and silver nanoparticles is established for several nanoparticle sizes and laser wavelengths. The results can be used in nanophotonics of new plasmon devices (concentrators, antennas, etc.) and photon components.     

Femtosecond surface plasmon resonance dynamics and electron-electron interactions in silver nanoparticles

Femtosecond excitation and relaxation of nonequilibrium electrons are investigated in silver clusters using a two color pump-probe technique with resonant excitation of the surface plasmon resonance and off resonant probing. The excitation process is shown to be identical to that in metal films, and permits creation of a strongly athermal single electron excitation in a time scale shorter than the duration of the pulses (25-30 fs), in agreement with the free-electron absorption model. Following the time evolution of the nonequilibrium distribution yields information on the internal energy redistribution dynamics of the conduction electrons and of its modification by confinement in metal clusters. Received 1st December 2000     

Quantifying plasmon resonance and interband transition contributions in photocatalysis of gold nanoparticle

Localized surface plasmon has been extensively studied and used for the photocatalysis of various chemical reactions.However, the different contributions between plasmon resonance and interband transition in photocatalysis has not been well understood. Here, we study the photothermal and hot electrons effects for crystal transformation by combining controlled experiments with numerical simulations. By photo-excitation of Na YF4:Eu~(3+)@Au composite structure, it is found that the plasmonic catalysis is much superior to that of interband transition in the experiments, owing to the hot electrons generated by plasmon decay more energetic to facilitate the reaction. We emphasize that the energy level of hot electrons plays an essential role for improving the photocatalytic activity. The results provide guidelines for improving the efficiency of plasmonic catalysis in future experimental design.     

柱状磁光颗粒的局域表面等离激元共振及尺寸效应

柱状磁光颗粒的局域表面等离激元共振为二维磁光光子晶体的手征性边缘模的生成提供了重要的机制. 但目前对此类颗粒的局域表面等离激元共振效应的研究局限于长波长近似下的结果, 且缺乏对发生共振时的远场与近场特征的深入了解. 本文从散射理论出发, 计算并分析了柱状磁光颗粒发生局域表面等离激元共振的条件与特殊的场特征, 并讨论了颗粒尺寸对共振峰的影响. 计算结果解释了实验中观察到的二维磁光光子晶体的共振带隙与在长波长近似下得到的局域表面等离激元共振频率的明显偏移, 并展示了颗粒在较大尺寸下形成的高阶共振峰, 这可能有助于利用共振效应在磁光光子晶体中实现多模的手征边缘态.     

Importance of lattice contraction in surface plasmon resonance shift for free and embedded silver particles

The size evolution of the surface plasmon resonance was investigated for free and embedded silver particles between about 2 to 10 nm in size. The crystal lattice of such particles as analyzed by high resolution electron microscopy show linear contraction with reciprocal particle size. Based on this, a model was presented by combining the lattice contraction of particles and the free path effect of electrons to predict the size evolution of the resonance. The results reveal a contribution of the lattice contraction to the resonance shift according to a roughly linear relation that changes slightly with particle radius (> 1.0 nm) and surrounding media. This surface plasmon resonance shift proceeds linearly with reciprocal size for Ag particles in vacuum and argon, but for Ag particles embedded in glass it appears to be independent of the radius down to nearly 1 nm. All predictions are quantitatively compared to previously reported experimental data and a good agreement is obtained. An unusual red-shift observed for Ag particles in glass may be attributed to a thermal expansion mismatch induced lattice dilatation. Received 26 July 2000 and Received in final form 14 September 2000     

Comparison investigation of near- and far-field properties for plasmon resonance of silver nanosphere dimers

Near- and far-field plasmon resonance properties of silver nanospheres dimers are calculated and compared based on the Generalized Multiparticle Mie-solution method. Greater differences between near- and far-field plasmon resonances are found than those of silver single nanoparticle, while the dimer of strongest near-field electric field amplitude and the dimer of highest far-field extinction coefficient almost have the same geometry parameter value under the illumination with fixed wavelength and polarization.     

Stochastic resonance phenomenon in Monte Carlo simulations of silver adsorbed on gold

The possibility of observing the stochastic resonance phenomenon was analyzed by means ofMonte Carlo simulations of silver adsorbed on 100 gold surfaces. The coverage degree was studied as a function ofthe periodical variation of the chemical potential. The signal-noise relationship wasstudied as a function of the amplitude and frequency of chemical potential andtemperature. When this value is plotted as a function of temperature, a maximum is found,indicating the possible presence of stochastic resonance.     

Dipole and quadrupole surface plasmon resonance contributions in formation of near-field images of a gold nanosphere

Multipolar plasmon optical excitations at spherical gold nanoparticles and their manifestations in the particle images formatted in the particle surface proximity are studied. The multipolar plasmon size characteristic: plasmon resonance frequencies and plasmon damping rates were obtained within rigorous size dependent modelling. The realistic, frequency dependent dielectric function of a metal was used. The distribution of light intensity and of electric field radial component at the flat square scanning plane scattered by a gold sphere of radius 95 nm was acquired. The images resulted from the spatial distribution of the full mean Poynting vector including near-field radial components of the scattered electromagnetic field. Monochromatic images at frequencies close to and equal to the plasmon dipole and quadrupole resonance frequencies are discussed. The changes in images and radial components of the scattered electromagnetic field distribution at the scanning plane moved away from the particle surface from near-field to far-field region are discussed.     

Surface plasmon resonance in near-field coupled gold cylinder arrays fabricated by EUV-interference lithography and hot embossing

Arrays of metal nanoparticles with nanometer-scale gaps between the particles is highly interesting for plasmonic field enhancement applications. We report a simple method to fabricate arrays of closely spaced Au particles with inter-particle separation down to 20 nm. We used extreme ultraviolet interference lithography (EUV-IL) and a mechanical press to fabricate two-dimensional arrays of Au nanoparticles. Lithographically produced particle arrays were modified by hot pressing in a nanoimprint machine and the gap was varied in a range from 50 nm to below 20 nm. Optical measurement shows two resonances at 520 nm and 620 nm, with the latter gaining strength as the gap is reduced. The experimental and theoretical investigations using a FDTD algorithm demonstrate that the low-energy resonance can be assigned to a collective surface plasmon resonance arising from the strong near-field coupling between the nanoparticles. Surface Enhanced Raman Spectroscopy (SERS) experiments performed on a model molecule (BPE) show a large gain in signal intensity as a result of the reduced gaps between the particles.     

Sample size effects on the spin resonance of conduction electrons in silver

The CESR linewidths of evaporated films of silver, deposited on quartz substrates, have been measured at 9.27 GHz. An increase in low temperature linewidth with decrease in thickness over the range 1.1 μm to 0.5 μm is observed. Below 13 K, ?, the probability of an electron losing its spin memory on colliding with the surface, is found to be about 4.10^-4.