丙烯酰胺基光致聚合物全息光栅的动力学研究

研究了光致聚合物的光化学反应和单体扩散反应的理论模型及动力学参数. 合成了以聚乙烯醇为粘结剂,三乙醇胺为引发剂,藻红B敏化的丙烯酰胺基光致聚合物全息存储材料,通过对测定的透过率和衍射效率进行曲线拟合,分析了染料浓度对光致聚合物的摩尔吸收系数ε、量子产率Φ和光化漂白速率常数k等光化动力学参数的影响规律,以及曝光强度对聚合反应速率k₀、扩散时间常数τ_D和最大折射率调制度Δn等扩散动力 关键词： 光致聚合物 透过率 衍射效率 动力学参数     

番红花红T光敏感光致聚合物全息存储材料

制备了一种以番红花红T为光敏剂的新型全息存储材料,主要用Ar⁺激光器的514.5nm波长的绿光研究材料的全息特性.研究表明,该材料具有较高的衍射效率、曝光灵敏度和较大的折射率调制度,衍射效率近40%,灵敏度为7.22×10^-4cm²/mJ,折射率调制度为3.65×10^-4,同时,在读出时必须考虑布拉格偏移对全息存储的影响.在介质膜中存储了全息图像,再现图像较为清晰,说明该材料适合用作高密度全息存储介质. 关键词： 全息存储 光致聚合物 衍射效率 布拉格偏移     

掺杂TiO2纳米颗粒的抗缩皱光致聚合物全息特性的研究

报道了一种掺杂亲水性TiO₂纳米颗粒的丙烯酰胺基光致聚合物厚膜的全息特性.实验结果表明,掺杂TiO₂纳米颗粒后的聚合物材料不仅在曝光过程中厚度缩皱有了明显的降低,而且衍射效率和其他性能参数都有了一定的改善,同时存在一个最佳的掺杂浓度,使得材料的最大衍射效率可以达到92.3%,最大折射率调制度达到2.09×10^-3,体积缩皱降低至0.80%. 关键词： 全息 光致聚合物 衍射效率 布拉格偏移     

全息光致聚合物中光化学反应参数的理论拟合研究

结合光致聚合物中光化学反应的基本过程及其理论函数模型,对多种采用不同双染料敏化的光致聚合物的透射率曲线进行拟合,得到了光化学反应理论模型中的参数。依托于实验数据,分析了利用MATLAB实现曲线拟合并得到光致聚合物中各光化学参数的新方法。结果表明：当曝光波长为632.8nm,曝光强度为65mW/cm²时,3种光致聚合物的拟合统计指标R-Square值分别为0.9687,0.9958和0.9902,说明所使用的理论结合实验数据的拟合分析方法是成功的。     

新型绿光敏感光致聚合物高密度全息存储特性

用实验方法研究了一种新合成的绿光敏感光致聚合物的高密度全息存储性质.结果表明该种光致聚合物具有较高的衍射效率、大的动态范围和折射率调制度,适合做高密度数字全息存储的记录材料,但材料的灵敏度需要提高,同时读出过程必须考虑曝光过程所导致的布拉格偏移;利用角度复用技术在样品的同一位置记录了20个数字化数据信息页,存储密度达到0.125GBcm3,平均误码率达到5.15×10 关键词： 光致聚合物 高密度数字全息存储 布拉格偏移     

Theory of light diffraction in thick anisotropic reflection holographic gratings

Diffraction of light in thick anisotropic holographic media is considered. Solutions for the wave amplitude, diffraction efficiency, and angular mismatch are given in the reflection geometry for the case of refractive index modulation. A comparison with Kogelnik’s isotropic theory is made.     

Effect of recording conditions on the anisotropic diffraction of volume holographic gratings

The anisotropic Bragg diffraction of the volume holographic gratings in photorefractive crystals are investigated based on the model of anisotropic coupled-wave theory. The effect of the initial intensity ratio and the recording angles of the two recording waves on the anisotropic Bragg diffraction properties is discussed. It is shown that both the ratio of the initial intensity and the incident angles of the recording waves are selective action for the anisotropic Bragg diffraction efficiency of the volume holographic gratings, while these two recording conditions are not selective action for the isotropic Bragg diffraction. Furthermore, the Bragg phase matching condition of anisotropic diffraction is analyzed when the recording angles change.     

碱性品红光致聚合物薄膜的光致光衍射

本文研究了全息存储实验中以波长532 nm的半导体激光器作为记录和读出光源,碱性品红作为光敏剂的丙烯酰胺基光致聚合物薄膜的光致光衍射现 象.它可以考虑为透过全息干涉条纹的原始入射光和反射光,与来自光聚物中未曝光的不均匀表面和内部的散射光四波混频的结果.根据简并四波混频理论中的位相匹配条件对双光束全息写入时产生的衍射光锥,以及单光束辐照复现时产生的衍射光锥现象分别做出了理论解释;并且利用全息散射理论结合三角学知识对入射光的入射角与衍射光锥的锥角的依赖关系进行了深入讨论. 关键词： 全息 光致聚合物 衍射光锥 碱性品红     

Methods for producing two-coordinate holographic diffraction gratings

Methods for the preparation of two-coordinate holographic diffraction gratings using a two-, three- and four-beam interferometer are considered. The analytical relationship of the interference fringe intensity distribution in the output aperture of these interferometers is presented. Experimental results are given.     

Dark diffusional enhancement of holographic multiplexed gratings in phenanthrenequinone doped poly（methyl methacrylate） photopolymer

In this paper, we experimentally investigate the dark diffusional enhancement of the optimized multiplexed grating in the phenanthrenequinone doped poly (methyl methacrylate) (PQ-PMMA) photopolymer. The possibility of improving the holographic characteristics of the material through the dark enhancement is demonstrated. The optimal preillumination exposure and the optimal time interval between exposures are extracted to obtain the optimized diffraction efficiency, and their values are 3.4×10³ mJ/cm² and 2 min, respectively. The dark enhancement of the multiplexed grating is presented as an effective method to improve the response region and the dynamic range and to prevent saturation of the material. The dependence of the phenanthrenequinone concentration on the increment of the refractive index modulation is quantitatively studied, which provides a significant basis for improving the homogeneity in the multiplexed gratings using a quantitative strategy. Finally, a simple experimental procedure using the dark enhancement is introduced to improve the homogeneity of the diffraction efficiency and to avoid the complex schedule exposure.     

双波长非水溶性光致聚合物全息光栅的研究

介绍了一种对488 nm蓝光和632.8 nm红光均敏感的双色非水溶性光致聚合物制成的二重全息光栅.理论分析得出此光栅的分辨率＞5 000 line/mm,温度变化时中心波长的漂移几乎为零.实验仪器测得光栅的衍射效率最高达到90%以上,而且该光栅具有成本低和一次成型的优点,适合制作波分复用器.与单波长的二重光栅相比,它解决了由于光的相干性出现的串扰问题,串扰更小,所以在制作光栅时两束光不但可以选择角度入射也可以选择平行入射,同时具有良好的波长选择性和角度选择性.     

A new photopolymerizable holographic recording material based on acrylamide and N-hydroxymethyl acrylamide

new polyvinylalcohol-based photopolymeric holographic recording material has been developed. The recording is obtained by the copolymerization of acrylamide and N-hydroxymethyl acrylamide. Diffraction efficiencies near 50% are obtained with energetic exposure of 80mJ/cm². N-hydroxymethyl acrylamide can improve the optical quality of the film. With the increase of the concentration of N-hydroxymethyl acrylamide, the flatness of the film increases, scattering reduces and the straight image is clearer with a small distortion. The postexposure effect on the grating is also studied. The diffraction efficiency of grating increases further during postexposure, gradient of monomer exists after exposure.     

辅助紫光提高菌紫质全息衍射效率的实验和理论研究

由于菌紫质样品的饱和吸收特性，在全息记录中，当记录光强大于样品的饱和光强时，全息光栅透过率随记录光相位差的分布远离余弦型，因此衍射效率的稳定值很低.菌紫质样品在红光和紫光共同作用下存在着双光束互补抑制效应，紫光可以抑制红光的透过率，提高红光的饱和光强，使记录区域由非线性区移至线性区，从而使全息光栅透过率随记录光相位差的分布变为余弦型，可以有效地提高全息衍射效率.实验证明，辅助紫光大大提高了菌紫质样品全息衍射效率的稳定值.根据此原理，建立了三光束全息光存储系统，在红光记录全息图的同时加入辅助紫光，可以使全息图衍射效率及衍射像的像质得到提高. 关键词： 菌紫质 全息存储 衍射效率 饱和吸收     

非水溶性红敏光致聚合物全息性能的改善及其应用研究

为使非水溶性红敏光致聚合物材料的全息性能得到改善,采用复合光敏增感、复合引发和复合单体的方法反复对比实验,改善后体系的灵敏度为0.02 cm2/mJ,衍射效率高达83%,计算得到材料的最大折射率调制度为4.1×10-3.实验结果和理论分析表明,利用该材料制作的新型全息光栅具有损耗低、通道宽度窄、衍射效率高等优点,适于制作光通信中的波分复用器及各种光学元件.     

Producing binary diffraction gratings in the double-diffraction system

In this paper, a method — based on the diffraction of light — for producing binary diffraction gratings is presented. It is shown that using two master gratings of the Ronchi type and utilizing the results of the double diffraction system it is possible to produce binary gratings with an arbitrary opening ratio. The results have been extended for a two-dimensional case and it is shown that producing binary grid gratings with arbitrary opening ratios in both x and y directions is also possible.     

High-density holographic recording parameters under different wavelength of a two dyes-sensitized photopolymer

The high-density holographic recording parameters of a novel two dyes-sensitized photopolymer under different exposure wavelengths are studied. The results show that the maximum diffraction efficiency, exposure sensitivity, maximum refraction index modulation, dynamic range, and the exposure time constant increases with the increase of the exposure wavelength. The analysis indicates that the scattering has an important role in the forming of the holographic grating.     

Grazing-angle scattering of waves in infinitely wide periodic gratings

The approximate method of analysis of grazing-angle scattering (GAS), based on allowance for the diffractional divergence of the scattered wave, is justified and extended to GAS in infinitely wide, slanted, periodic gratings. The analysis has revealed an unusual and strong dependence of the pattern of GAS on small variations of mean structural parameters at the grating boundary. Several times increase of already resonantly large scattered wave amplitudes can be achieved in this case. Sharp resonance-like maximums on the angular dependence of the scattered wave amplitude are predicted inside the grating. The theory is extended to the case of GAS of optical modes guided by a slab with a semi-infinite periodic groove array. Physical interpretation of the obtained results is presented.     

Investigation of the interference field of two spherical waves for holographic recording of precision radial diffraction gratings

Precision radial diffraction gratings with a spatial pitch down to 1 μm, and with a line number over the ring area of up to half a million, are obtained through multiple recordings of a radial interference field segment. The radial field is produced by two spherical coherent waves. The spatial distribution of the interference fringes is analysed. Equations are provided for determination of the coordinates of the wave centres, taking into account the pitch and the radius of the grating to be recorded, as well as for estimation of interference field errors.     

亚微米光栅零级衍射特性的数值研究

用耦合波理论分析了亚微米光栅对光波场的衍射作用,给出了在TE和TM偏振入射条件下矩阵形式的耦合波方程,研究了光栅在TE偏振入射条件下可见光波段内的反射和透射零级衍射特性。亚微米光栅零级衍射效率是波长、偏振和入射角的函数,在不同照明、观察和光栅参数条件下,光栅零级衍射具有非常复杂的光谱结构,经过适当的优化光栅参数,零级衍射具有许多独特的衍射特性,在许多应用领域具有广泛的应用前景。