用布里渊散射测量水的体粘滞系数

提出了一种直接测量水的体粘滞系数的实验方法－布里渊散射方法,通过分析剪切粘滞系数和体粘滞系数与布里渊散射线宽的关系,得到了布里渊散射线宽和频移与水的体粘滞系数关系的公式,建立了实验测量水的体粘滞系数的基础,给出了不同温度下水的体粘滞系数的实验测量结果,估算了这种方法的测量误差,实验和理论分析都表明这是一种直接测量水的体粘滞系数的快速而精确的方法。     

毛细管两端压强差对液体粘度测量的影响

利用毛细管法测定水的粘度,探讨了毛细管两端不同压强差对水粘度测量的影响。结果表明不同压强差对测量粘度有一定的影响,压差的减小使测量结果的误差增大,与理论相符。     

Measurement of the feedback coefficient by monitoring the power difference at power jump point in self-mixing vibration signal

This paper proposed a new method for measuring the feedback coefficient in the self-mixing interference. In experiment, the value of feedback coefficient is obtained by measuring the power difference at power jump point that based on the self-mixing vibration sensing system. It realized the measurement of feedback coefficient in range of 1–7.8 and shows a good agreement with the theoretical derivation and the corresponding simulation. Meanwhile, there is a good fitting result with the determination coefficient of 0.98 and line-width broadening factor of 3.245 respectively, which also realized measurement of feedback coefficient and line-width broadening factor at the same time.     

Influence of phonon confinement on the optically detected magneto-phonon resonance line-width in quantum wells

We investigate the influence of phonon confinement on the optically detected magneto-phonon resonance (ODMPR) effect and ODMPR line-width in quantum wells. The ODMPR conditions as functions of the well's width and the photon energy are also obtained. The shifts of ODMPR peaks caused by the confined phonon are discussed. The numerical result for the GaAs/AlAs quantum well shows that in the two cases of confined and bulk phonons, the line-width (LW) decreases with increasing well's width and increases with increasing temperature. Furthermore, in the small range of the well's width, the influence of phonon confinement plays an important role and cannot be neglected in reaching the ODMPR line-width.     

Suitability of artificial bulk viscosity for large-eddy simulation of turbulent flows with shocks

The artificial bulk viscosity method to numerically capture shocks is investigated for large-eddy simulation (LES). Different variations of this method are tested on a turbulent flow over a cylinder at Reynolds number of 10,000 and free-stream Mach number of 0.85. The artificial bulk viscosity model by Cook and Cabot, which is parameterized by the strain rate magnitude, is found to provide unnecessary bulk viscosity in turbulent regions away from shocks. While developed turbulent structures are found unaffected, this extra bulk viscosity is shown to significantly damp the sound field. An alternative formulation of the model which is parameterized by the rate of dilatation is proposed. This formulation is shown to avoid the unnecessary bulk viscosity and enhance the sound-prediction capability of the model. It was found that standard LES combined with artificial bulk viscosity is a promising approach for simulation of turbulent flows with shocks. The formulation of the model on curvilinear coordinates is presented in the appendix.     

磁场中夸克物质的黏滞系数

研究了磁场中夸克非轻子弱作用过程的反应率和黏滞系数. 改进了在弱磁场情况下的近似计算方法, 给出了非轻子过程的反应率与夸克物质的体黏滞系数的表达式, 显示出在弱磁场情况下, 黏滞系数的温度依赖关系与零磁场情况下一致, 但黏滞系数的大小依赖磁场的强度.     

Equilibrium molecular dynamics calculation of the bulk viscosity of liquid water

Twenty independent equilibrium molecular dynamics simulations were performed in NVE ensemble to calculate the bulk viscosity of water at a temperature of 303 K and a density of 0.999 gcm^?3. The energy of each simulation with a production time of 200ps was conserved within 1 part in 10⁴. By stopping the velocity-scaling procedure at a proper step, the energies of independent simulations were specified precisely. This caused the simulations of different start configurations to sample the same NVE ensemble. The shear viscosity of SPC/E water obtained in the present study was 6.5±0.4 × 10^?4 Pas, which is in close agreement with a previous calculation in the NVT ensemble (Balasubramanian, S., Mundy, C. J., and Klein, M. L., 1996, J. clzern. Phys., 105, 11 190). The bulk viscosity was 15.5 ± 1.6 × 10^?4 Pas, which is 27% smaller than the experimental value. Thus, like its behaviour in predicting the shear viscosity, the SPC/E model also underestimates the bulk viscosity of real water.     

The effect of bulk viscosity on single bubble dynamics and sonoluminescence

In our previous paper, we derived a new single bubble model including the effect of bulk viscosity. To confront it to experiments, single bubble dynamics was measured here in 30% (v/v) glycerol-water mixture under different acoustic amplitudes and compared to models including or not the effect of bulk viscosity. The results showed that calculated bubble dynamics were not significantly affected by the bulk viscosity within the experimental conditions used in this study. However, there was a noticeable delay for the first rebound when bulk viscosity was considered. The corresponding sonoluminescence intensities were collected and compared with theoretical predictions. The results did not allow to discriminate between the two models (one includes the effect of bulk viscosity, the other does not), confirming the negligible effect of bulk viscosity in this condition (30% (v/v) glycerol-water mixture). Due to the instability of a single bubble in higher viscosity solutions, we could not implement experiments that can discriminate between the two models.     

基于自发瑞利-布里渊散射的氮气体黏滞系数的测量

体黏滞系数是从微观角度认识气体分子黏滞性的重要参数,传统的兆赫兹声频范围的声波吸收方法无法直接应用于声波弛豫效应在千兆赫兹范围的高频领域,而瑞利-布里渊散射则能实现对声波弛豫效应在千兆赫兹的气体体黏滞系数的测量.本文测量了532 nm激光激发的常温下压强分别为1-9 bar的氮气的自发瑞利-布里渊散射光谱,利用已知温度和压强的理论模型对测量光谱进行了比较,获得了准确的散射角.利用该散射角并结合χ~2值最小原理反演得到不同压强(4—9 bar)下氮气的平均体黏滞系数为(1.46±0.14)×10~(-5)kg·m~(-1)·s~(-1),该结果与文献中利用自发瑞利-布里渊散射获得的结果和理论计算结果相近,但与相干瑞利-布里渊散射的测量结果相差明显.利用该平均体黏滞系数对氮气在不同压强下的温度进行了反演,得到各压强下的温度与实际温度的绝对误差小于2.50 K,反演温度的平均值与实际温度误差小于0.15 K,该结果证明了实验测量得到的氮气的体黏滞系数具有较高的准确性,同时也说明利用瑞利-布里渊散射反演气体参数具有较高的准确性和可靠性.     

表面张力对PEO稀溶液粘度行为的影响

测定了不同分子量聚氧化乙烯 (PEO)在水和苯溶剂中的粘度 ,发现在低浓度区PEO水溶液的比浓粘度出现负偏离 ,PEO苯溶液比浓粘度与浓度之间依旧满足线性关系 .表面张力测定结果表明 ,PEO分子显著降低了水的表面张力 ,而苯的表面张力则不受影响 .PEO水溶液和纯溶剂水表面张力的不同干扰了高分子溶液和溶剂在粘度计中流过时间的测量 ,导致低浓度区PEO水溶液比浓粘度出现负偏离 .利用PEO水溶液和水表面张力测定结果 ,结合乌式粘度计的几何尺寸 ,定量分析了PEO水溶液和纯溶剂水表面张力的差异对粘度测量结果的影响 ,计算结果与实验结果基本相符 .如果用PEO水溶液流过时间对浓度作图的外推值t0 计算相对粘度 ,可以完全消除PEO水溶液和水表面张力差异对粘度测量的影响     

Quadrupole relaxation in nitrogen nuclear resonances

The ¹⁴N resonance line-widths have been measured for a wide range of nitrogen compounds. The variation of line-width with viscosity of MeCn, EtCN, PrCN and Me₂NCHO in various solvents is discussed in terms of the theories of molecular correlation times. The values of the line-widths in substituted nitrobenzenes are discussed in terms of the quadrupole coupling constants. The relative line-widths in the azide ion are discussed in terms of its electronic structure.     

毛细管法测量液体黏度实验再设计

设计了简单的毛细管法测量液体黏度的实验装置,通过测量液面高度与时间的变化,拟合实验数据得到液体的黏度,省去了传统的恒压液槽的设计.通过毛细管外加恒温管的方法,可较准确地测量不同温度下液体黏度的变化.通过实验给出泊肃叶公式中液体流速与毛细管长度、内径以及两端压强差的关系.     

Assessment of localized artificial diffusivity scheme for large-eddy simulation of compressible turbulent flows

The localized artificial diffusivity method is investigated in the context of large-eddy simulation of compressible turbulent flows. The performance of different artificial bulk viscosity models are evaluated through detailed results from the evolution of decaying compressible isotropic turbulence with eddy shocklets and supersonic turbulent boundary layer. Effects of subgrid-scale (SGS) models and implicit time-integration scheme/time-step size are also investigated within the framework of the numerical scheme used. The use of a shock sensor along with artificial bulk viscosity significantly improves the scheme for simulating turbulent flows involving shocks while retaining the shock-capturing capability. The proposed combination of Ducros-type sensor with a negative dilatation sensor removes unnecessary bulk viscosity within expansion and weakly compressible turbulence regions without shocks and allows it to localize near the shocks. It also eliminates the need for a wall-damping function for the bulk viscosity while simulating wall-bounded turbulent flows. For the numerical schemes used, better results are obtained without adding an explicit SGS model than with SGS model at moderate Reynolds number. Inclusion of a SGS model in addition to the low-pass filtering and artificial bulk viscosity results in additional damping of the resolved turbulence. However, investigations at higher Reynolds numbers suggest the need for an explicit SGS model. The flow statistics obtained using the second-order implicit time-integration scheme with three sub-iterations closely agrees with the explicit scheme if the maximum Courant–Friedrichs–Lewy is kept near unity.     

Relaxation time and viscosity of water near hydrophilic surfaces

Recently results of microwave spectroscopy have shown that the water relaxation time is lengthened near the surface of aggregates of hydrogen bond-forming molecules, an effect corresponding to an enhanced viscosity [1–3]. In this communication properties of the so-called bound water are treated by a percolation calculation on the water cluster sizes. The values combined with the statistical model of the dielectric response of bulk water by Haggis et al. [4] yield the bound water relaxation time and in this way its viscosity. Fair agreement with the experimental data is obtained. The new analysis represents a keystep for a better understanding of bound water in physico-chemical and biological systems. Dedicated to Professor Karlheinz Seeger on the occasion of his 60th birthday     

Viscous water meniscus under nanoconfinement

A dramatic transition in the mechanical properties of water is observed at the nanometer scale. For a water meniscus formed between two hydrophilic surfaces in the attractive region, with < or = 1 nm interfacial separation, the measured viscosity is 7 orders of magnitude greater than that of bulk water at room temperature. Grand canonical Monte Carlo simulations reveal enhancement in the tetrahedral structure and in the number of hydrogen bonds to the surfaces as a source for the high viscosity; this results from a cooperative effect of hydrogen bonding of water molecules to both hydrophilic surfaces.     

反向碰撞法测量Sn的高压卸载声速

采用任意反射面速度干涉系统,通过对窗口碰撞面做特殊防护处理,发展了反向加载测量高压卸载声速的实验技术,解决了以往因使用缓冲层而不能得到样品材料体积声速的局限.利用该方法测量了Sn样品在37—80 GPa压力范围内的高压卸载声速,得到了较高精度的声速测量结果(纵波声速测量误差约为2%,体积声速误差约为5%),且与热力学理论计算结果一致. 关键词： 卸载声速 反向碰撞法 任意反射面速度干涉系统 Sn     

A kinetic theory of dense fluids

A new kinetic equation is developed which incorporates the desirable features of the Enskog, the Rice-Allnatt, and the Prigogine-Nicolis-Misguich kinetic theories of dense fluids. Advantages of the present theory over the latter three theories are (1) it yields the correct local equilibrium hydrodynamic equations, (2) unlike the Rice-Allnatt theory, it determines the singlet and doublet distribution functions from the same equation, and (3) unlike the Prigogine-Nicolis-Misguich theory, it predicts the kinetic and kinetic-potential transport coefficients. The kinetic equation is solved by the Chapman-Enskog method and the coefficients of shear viscosity, bulk viscosity, thermal conductivity, and self-diffusion are obtained. The predicted bulk viscosity and thermal conductivity coefficients are singular at the critical point, while the shear viscosity and self-diffusion coefficients are not.     

高温近似下奇异夸克物质的体粘滞系数

在准粒子描述下,采用自洽的热力学方法,考虑奇异夸克物质(SQM?)的介质效应,计算了高温近似下奇异夸克物质的体粘滞系数.发现介质效应对奇异夸克物质的体粘滞系数有很大影响,这使得观测数据不再排除两味色超导相奇异星的存在.     

激光空泡特性实验与数值计算研究

基于激光空泡内物质以水蒸气为主的特征,选择特定的Rayleigh-Plesset方程形式,确定激光空泡的动态泡壁位置,并考虑水中气体与激光空泡之间的质量扩散、水蒸气的凝结与蒸发、水的压缩性及热传导、声辐射、黏性、表面张力等因素.建立激光空泡的产生、照相和声压测量系统.通过数值计算与实验结果相结合的办法,使泡内压力的计算值与实验值之间相对误差控制在10%以内,揭示吸收的激光脉冲能量与激光空泡的半径、泡内压力和温度之间的对应关系,以及吸收的激光脉冲能量不变时半径、压力和温度的变化规律.旨在为激光空泡的相关研究提供一定的参考. 关键词： 激光空泡 水蒸气 数值模拟 Rayleigh-Plesset方程     

相因子判断法分析菲涅耳波带片的衍射场

基于波前相因子判断法,并考虑到波带片孔径的影响,揭示了波带片的衍射场所含基元成分及各成分在衍射场的积分表达式,并导出了沿轴的衍射场振幅分布公式及沿轴的振幅分布曲线,得到多个实焦斑的横向半值线宽和轴向半值线宽公式.本研究为波带片作为一种光学元件提供了一理论基础.