On a Semiclassical Formula for Non-Diagonal Matrix Elements

Let H(?)=?? ²d²/dx ²+V(x) be a Schrödinger operator on the real line, W(x) be a bounded observable depending only on the coordinate and k be a fixed integer. Suppose that an energy level E intersects the potential V(x) in exactly two turning points and lies below V _∞=lim?inf?_|x|→∞ V(x). We consider the semiclassical limit n→∞, ?=? _n →0 and E _n =E where E _n is the nth eigenenergy of H(?). An asymptotic formula for 〈n|W(x)|n+k〉, the non-diagonal matrix elements of W(x) in the eigenbasis of H(?), has been known in the theoretical physics for a long time. Here it is proved in a mathematically rigorous manner.     

Diminishing blocking interval in particle-conveying channel bundles

We consider a channel bundle consisting of N_c parallel channels conveying a particulate flux. Particles enter these channels according to a homogeneous Poisson process and exit after a fixed transit time, τ. An individual channel blocks if N particles are simultaneously present. When a channel is blocked the flux previously entering it is redistributed evenly over the remaining open channels. We perform event driven simulations to examine the behaviour of an initially empty channel bundle with a total entering flux of intensity Λ. The mean blockage time of the kth channel is denoted by ? t_k ? ,k = 1,...,N_c. For N = 1, as shown previously, the interval between successive blockages is constant, while for N> 1 an accelerating cascade, i.e. one in which the interval between successive blockages decreases, is observed. After an initial transient regime we observe a well-defined universal regime that is characterized by\hbox{$\Delta_k^{(N)} = (-1)^{N-1}\frac{[(N-1)!]^2}{(\Lambda\tau)^N}$}Δk(N)=(?1)N?1[(N?1)!]2(Λτ)Nwhere \hbox{$\Delta_k^{(1)}=\langle t_k \rangle-\langle t_{k-1}\rangle$}Δk(1)=?tk???tk?1? and \hbox{$\Delta_k^{(j)}=\Delta_k^{(j-1)}-\Delta_{k-1}^{(j-1)}$}Δk(j)=Δk(j?1)?Δk?1(j?1) denotes the jth order difference.     

Vibronic-spin-orbit interactions in heterocyclic analogues of fluorene with the N and O heteroatoms

The transition dipole moments P _0n ^s for the transitions from the electronic triplet state ³ B ²(ππ*) to vibrational sublevels of the vibrational out-of-plane modes n of the carbazole and dibenzofuran molecules are calculated. The values of the radiative deactivation rate constant k _rad ^s of the triplet sublevels T ^s are determined along with the components k _SO ^s and k _VSO ^s of this constant, which depend on the intramolecular spin-orbit (SO) and vibronic-spin-orbit (VSO) interaction. It is ascertained that k _rad ^z > k _rad ^y . For different structural units of the molecules (the heteroatom and the carbon atoms of the dibenzene fragment), the effect of the SO coupling on the constant k _VSO～Σ_{s, n} (P _0n ^s )² is studied. A competition between the effects on k _VSO from the SO coupling in the carbon atoms and in the light N and O heteroatoms is revealed. This competition accounts for the weak influence of the heteroatom on this component of the rate constant k _rad in these molecules. It is ascertained that the intensity distribution among the vibronic lines in the phosphorescence spectra of carbazole and dibenzofuran I _0n ～Σs (P _0n ^s )² is different due to the substantially different influence of the N and O heteroatoms on the deactivation of the triplet sublevel T ^y .     

Scaling of the conductance and resistance of square lattices with an exponentially wide spectrum of the resistances of links

The conductance G? and \(\overline {{G^{ - 1}}} \) resistance average over realizations of disorder have been calculated for various sizes of square lattices L. In contrast with different direction of change in the two quantities at percolation in lattices with the binary spread of conductances of links (g _i = 0 or 1), it has been found that the mean conductance and resistance of lattices decrease simultaneously with an increase in L in the case of an exponential distribution of local conductances g _i = exp(?kx_i), where x _i ∈ [0,1] are random numbers. When L is smaller than the disorder length L₀ = bk^v, G?(L) and \(\overline {{G^{ - 1}}} \)(L) are proportional to L^?n with n = k/5 and k/6, respectively. A similar behavior is characteristic of the distributions of conductances of links, which simulate a transition between the open and tunneling regimes in semiconducting lattices of antidots created in a two-dimensional electron gas.     

Brownian motion on a manifold as a limit of Brownian motions with drift

Let ?ⁿ be n-dimensional Euclidean space and let M ? ?ⁿ be a smooth compact m-dimensional Riemannian manifold (without boundary) embedded in ?ⁿ. By a Brownian motion on M we mean a Markovian process whose transition semigroup is defined by the generator ?½Δ_M, where Δ_M stands for the Laplace-Beltrami operator on M (see, e.g., [2]). This note extends a series of papers in which a measure generated by a Brownian motion on M on the space of trajectories (with values in M) can be represented as the weak limit of measures on the space of trajectories in the ambient space ?ⁿ (see [7–10]). Namely, we claim that a sequence of diffusion processes on ?n which are Brownian motions with drift (in the direction of the manifold) with infinitely increasing modulus converges in distribution to a Brownian motion on the manifold.     

Competing contact processes in the Watts-Strogatz network

We investigate two competing contact processes on a set of Watts–Strogatz networks withthe clustering coefficient tuned by rewiring. The base for network construction isone-dimensional chain of N sites, where each site i is directly linked tonodes labelled as i ±1 and i ±2. So initially, each node has the same degree k_i =4. The periodic boundary conditions are assumed as well. For each nodei the linksto sites i +1 and i +2 are rewired to two randomly selected nodes so far not-connected tonode i. Anincrease of the rewiring probability q influences the nodes degree distribution and thenetwork clusterization coefficient ??. For given values of rewiring probabilityq the set ??(q)={??₁,??₂,...,??_M} of M networks is generated. The network’s nodes aredecorated with spin-like variables s_i ∈ { S,D}. During simulation each S node having a D-site in its neighbourhoodconverts this neighbour from D to S state. Conversely, a node in D state having at least oneneighbour also in state D-state converts all nearest-neighbours of this pairinto D-state. The latter is realized with probabilityp. We plotthe dependence of the nodes S final density n_S^T on initial nodes S fraction n_S⁰. Then, we construct the surface of the unstable fixedpoints in (??, p, n_S⁰) space. The system evolves more often toward n_S^T for (??, p, n_S⁰) points situated above this surface while startingsimulation with (??, p, n_S⁰) parameters situated below this surface leads system to n_S^T=0. The points on this surface correspond to such value ofinitial fraction n_S^* of S nodes (for fixed values ?? and p) for which their final density is n_S^T=1/2.     

The Condensation Phase Transition in Random Graph Coloring

Based on a non-rigorous formalism called the “cavity method”, physicists have put forward intriguing predictions on phase transitions in diluted mean-field models, in which the geometry of interactions is induced by a sparse random graph or hypergraph. One example of such a model is the graph coloring problem on the Erd?s–Renyi random graph G(n, d/n), which can be viewed as the zero temperature case of the Potts antiferromagnet. The cavity method predicts that in addition to the k-colorability phase transition studied intensively in combinatorics, there exists a second phase transition called the condensation phase transition (Krzakala et al. in Proc Natl Acad Sci 104:10318–10323, 2007). In fact, there is a conjecture as to the precise location of this phase transition in terms of a certain distributional fixed point problem. In this paper we prove this conjecture for k exceeding a certain constant k₀.     

Zero-sound branches in asymmetric nuclear matter

A polarization operator constructed in the random phase approximation is used to obtain zero-sound excitations in isospin asymmetric nuclear matter (ANM). Two families of the complex solutions ω_sτ(k),τ= p,n are presented. The imaginary part of the solutions corresponds to the damping of the collective mode due to its overlapping with the particle-hole modes and the subsequent emission of a proton (ω_sp(k)) or a neutron (ω_sn(k)). The dependence of the solutions on the asymmetry parameter is studied.     

Temperature Dependence of the Thermal Conductivity of a Trapped Dipolar Bose-Condensed Gas

The thermal conductivity of a trapped dipolar Bose condensed gas is calculated as a function of temperature in the framework of linear response theory. The contributions of the interactions between condensed and noncondensed atoms and between noncondensed atoms in the presence of both contact and dipole-dipole interactions are taken into account to the thermal relaxation time, by evaluating the self-energies of the system in the Beliaev approximation. We will show that above the Bose-Einstein condensation temperature (T?>?T _BEC ) in the absence of dipole-dipole interaction, the temperature dependence of the thermal conductivity reduces to that of an ideal Bose gas. In a trapped Bose-condensed gas for temperature interval k _B T?<<?n ₀ g _B , E _p ?<<?k _B T (n ₀ is the condensed density and g _B is the strength of the contact interaction), the relaxation rates due to dipolar and contact interactions between condensed and noncondensed atoms change as \( {\tau}_{dd12}^{-1}\propto {e}^{-E/{k}_BT} \) and τ _c12?∝?T ^?5, respectively, and the contact interaction plays the dominant role in the temperature dependence of the thermal conductivity, which leads to the T ^?3 behavior of the thermal conductivity. In the low-temperature limit, k _B T?<<?n ₀ g _B , E _p ?>>?k _B T, since the relaxation rate \( {\tau}_{c12}^{-1} \) is independent of temperature and the relaxation rate due to dipolar interaction goes to zero exponentially, the T ² temperature behavior for the thermal conductivity comes from the thermal mean velocity of the particles. We will also show that in the high-temperature limit (k _B T?>?n ₀ g _B ) and low momenta, the relaxation rates \( {\tau}_{c12}^{-1} \) and \( {\tau}_{dd12}^{-1} \) change linearly with temperature for both dipolar and contact interactions and the thermal conductivity scales linearly with temperature.     

Retardation of unimolecular reactions in the solid phase

The retardation coefficient, K _R = k _l/k _s, for a homogeneous reaction in the bulk of a crystal was calculated within the framework of the free-volume model of unimolecular reactions in the solid phase in the approximation of an isotropic continuum. The key parameters entering into the working formula, more specifically, the additional activation volume for the solid phase and the compressibility coefficient, were estimated using semiempirical methods. The calculated values of K _R range from several units to several thousand units, an interval that encompasses all the experimental values of this quantity. Low values of K _R are indicative of reactions in the bulk of the crystal lattice. In addition, reactions on defects can occur, being predominant at K _R > 100. In all cases, the calculated values of K _R give an upper estimate of the degree of retardation, above which no experimental values have been obtained.     

Coexistence of superconducting and spiral spin orders: Models of ruthenate

The effect of a spiral spin structure on superconducting (SC) pairing in a three-band Hubbard model related to Sr₂RuO₄ is analyzed in the mean-field approximation. Such a structure with incommensurate vector Q=2π (1/3, 1/3) is the simplest one that removes the nesting instability of α and β bands. It is assumed that there is an intralayer pairing interaction between two types of neighbor sites, those with attraction in a singlet channel and with attraction in both two-singlet and triplet channels. In both cases, a mixed singlet-triplet SC order is observed in the γ band: a d-wave singlet order is accompanied by the formation of p-wave triplet pairs (k,-k-Q)? and (k,?k+Q)? with large total momenta ?Q and the spin projections ±1 onto an axis perpendicular to the spin rotation plane of the spiral spin structure. Both the SC and normal states are states with broken time-reversal symmetry. In contradiction to the experiment, the models give different scales of T _c for the γ band and for α and β bands. This fact shows that the models with intralayer interactions or with the spin structure assumed are insufficient.     

<Emphasis Type="Italic">Ab initio</Emphasis> theory of the electronic structure and spectra of impurity <Emphasis Type="Italic">nl</Emphasis> ions

The fundamentals of the theory of the electronic structure of impurity clusters and the results of numerical calculations for the iron-, lanthanum-, and actinium-group ions in Me⁺ⁿ: [L]_k clusters are presented. The effects of the interionic distance and ligands in the Me⁺ⁿ: [L]_k clusters on the electronic structure of the nl ^N and nl^N?1n′l′ configurations of the 3d, 4f, and 5f ions are considered. The correspondence between the optical and x-ray spectra of different impurity crystals is also analyzed.     

Inflation of the early cold Universe filled with a nonlinear scalar field and a nonideal relativistic Fermi gas

We consider a possible scenario for the evolution of the early cold Universe born from a fairly large quantum fluctuation in a vacuum with a size a ₀ ? l _P (where l _P is the Planck length) and filled with both a nonlinear scalar field φ, whose potential energy density U(φ) determines the vacuum energy density λ, and a nonideal Fermi gas with short-range repulsion between particles, whose equation of state is characterized by the ratio of pressure P(n _F ) to energy density ε(n _F ) dependent on the number density of fermions n _F . As the early Universe expands, the dimensionless quantity ν(n _F ) = P(n _F )/ε(n _F ) decreases with decreasing n _F from its maximum value ν_max = 1 for n _F → ∞ to zero for n _F → 0. The interaction of the scalar and gravitational fields, which is characterized by a dimensionless constant ξ, is proportional to the scalar curvature of four-dimensional space R = κ[3P(n _F )–ε(n _F )–4λ] (where κ is Einstein’s gravitational constant), and contains terms both quadratic and linear in φ. As a result, the expanding early Universe reaches the point of first-order phase transition in a finite time interval at critical values of the scalar curvature R = R _c =–μ²/ξ and radius a _c ? a ₀. Thereafter, the early closed Universe “rolls down” from the flat inflection point of the potential U(φ) to the zero potential minimum in a finite time. The release of the total potential energy of the scalar field in the entire volume of the expanding Universe as it “rolls down” must be accompanied by the production of a large number of massive particles and antiparticles of various kinds, whose annihilation plays the role of the Big Bang. We also discuss the fundamental nature of Newton’ gravitational constant G _N .     

Gamow Vectors and Borel Summability in a Class of Quantum Systems

We analyze the detailed time dependence of the wave function ψ(x,t) for one dimensional Hamiltonians \(H=-\partial_{x}^{2}+V(x)\) where V (for example modeling barriers or wells) and ψ(x,0) are compactly supported.We show that the dispersive part of ψ(x,t) is the Borel sum of its asymptotic series in powers of t ^?1/2, t→∞. The remainder, the difference between ψ and the Borel sum, i.e., the exponential part of the transseries of ψ, is a convergent expansion of the form \(\sum_{k=0}^{\infty}g_{k}\Gamma_{k}(x)e^{-\gamma_{k} t}\), where Γ _k are the Gamow vectors of H, and iγ _k are the associated resonances; generically, all g _k are nonzero. For large k, γ _k ～const?klog?k+k ² π ² i/4. The effect of the Gamow vectors is visible when time is not very large, and the decomposition defines rigorously resonances and Gamow vectors in a nonperturbative regime, in a physically relevant way.The decomposition allows for calculating ψ for moderate and large t, to any prescribed exponential accuracy, using optimal truncation of power series plus finitely many Gamow vectors contributions.The analytic structure of ψ is perhaps surprising: in general (even in simple examples such as square wells), ψ(x,t) turns out to be C ^∞ in t but nowhere analytic on ?⁺. In fact, ψ is t-analytic in a sector in the lower half plane and has the whole of ?⁺ a natural boundary. In the dual space, we analyze the resurgent structure of ψ.     

Mechanism of charge transfer in <Emphasis Type="Italic">n</Emphasis>-CdS/<Emphasis Type="Italic">p</Emphasis>-CdTe heterojunctions

The capacitance-voltage and current-voltage characteristics of the n-CdS/p-CdTe heterosystem are investigated. Analysis of these characteristics demonstrates that the CdTe_1?x S _x solid solution formed at the n-CdS/p-CdTe heterointerface is inhomogeneous in both the conductivity and composition. The thickness of solid solutions is estimated from the capacitance-voltage characteristics. It is shown that, for the n-CdS/p-CdTe heterosystem, the current-voltage characteristic in the current density range 10^?8-10^?5 A cm^?2 is governed by the thermal electron emission, whereas the current in the heterostructure at current densities in the range 10^?4-10^?2 A cm^?2 is limited by recombination of charge carriers in the electroneutral region of the CdTe_1?x S _x solid solution. The lifetime and the diffusion length of minority charge carriers in the CdTe_1?x S _x solid solution and the surface recombination rate at the interface between the CdS layer and the CdTe_1?x S _x solid solution are determined. It is demonstrated that the n-CdS/p-CdTe heterostructure operates as a p-i-n structure in which CdTe is a p layer, CdTe_1?x S _x is an i layer, and CdS is an n layer.     

Restricting Positive Energy Representations of Diff<Superscript>+</Superscript>(<Emphasis Type="Italic">S</Emphasis><Superscript>1</Superscript>) to the Stabilizer of <Emphasis Type="Italic">n</Emphasis> Points

Let G _n ? Diff⁺(S ¹) be the stabilizer of n given points of S ¹. How much information do we lose if we restrict a positive energy representation \(U^c_h\) associated to an admissible pair (c, h) of the central charge and lowest energy, to the subgroup G _n ? The question, and a part of the answer originate in chiral conformal QFT. The value of c can be easily “recovered” from such a restriction; the hard question concerns the value of h. If c ≤ 1, then there is no loss of information, and accordingly, all of these restrictions are irreducible. In this work it is shown that \(U^c_{h}|_{G_n}\) is always irreducible for n =  1 and, if h =  0, it is irreducible at least up to n ≤  3. Moreover, an example is given for c >  2 and certain values of \(h \neq \tilde{h}\) such that \(U^c_{h}|_{G_1}\simeq U^c_{\tilde{h}}|_{G_1}\) . It is also concluded that for these values \(U^c_{h}|_{G_n}\) cannot be irreducible for n ≥  2. For further values of c, h and n, the question is left open. Nevertheless, the example already shows that, on the circle, there are conformal QFT models in which local and global intertwiners are not equivalent.     

A study of the critical properties of the Ising model on body-centered cubic lattice taking into account the interaction of next behind nearest neighbors

The replica Monte Carlo method has been used to investigate the critical behavior of a threedimensional antiferromagnetic Ising model on a body-centered cubic lattice, taking into account interactions of the adjacent behind neighbors. Investigations are carried out for the ratios of the values of exchange interactions behind the nearest and next nearest neighbors k = J ₂/J ₁ in the range of k ∈ [0.0, 1.0] with the step Δk = 0.1. In the framework of the theory of finite-dimensional scaling the static critical indices of heat capacity α, susceptibility γ, of the order parameter β, correlation radius ν, and also the Fisher index η are calculated. It is shown that the universality class of the critical behavior of this model is kept in the interval of k ∈ [0.0, 0.6]. It is established that a nonuniversal critical behavior is observed in the range k ∈ [0.8, 1.0].     

On the energy transport velocity in a dissipative medium

An exact definition of the group velocity v _g is proposed for a wave process with arbitrary dispersion relation ω = ω′(k) + iω″(k). For the monochromatic approximation, a limit expression v _g (k) is obtained. A condition under which v _g (k) takes the form of the Kuzelev–Rukhadze expression [1] dω′(k)/dk is found. In the general case, it appears that v _g (k) is defined not only by the dispersion relation ω(k), but also by other elements of the initial problem. As applied to the dissipative medium, it is shown that v _g (k) defines the field energy transfer velocity, and this velocity does not exceed thee light speed in vacuum. An expression for the energy transfer velocity is also obtained for the case where the dispersion relation is given in the form k = k′(ω) + ik″(ω) which corresponds to the boundary problem.     

Effective refractive index of a quasi-two-dimensional polydomain film of a conjugated polymer

The relation between the effective ordinary refractive index n* = (n _o n _e )^1/2 of a quasi-two-dimensional polydomain uniaxial film of a conjugated polymer F8BT in the visible transparency region and the refractive indices (n _o,e ) of uniaxial domains with the optical axes randomly oriented in the plane of the film has been confirmed experimentally. The permissible interval of variations in n* has been established and a strong spectral dispersion of this interval near the long-wavelength electronic absorption band of the film has been demonstrated.