Experimental investigation on martensitic transformation and fracture morphologies of austenitic stainless steel

Formation and nucleation mechanisms (i.e. γ → ε, γ → α′, γ → deformation twins → ε → α′ and γ → ε → α′) of deformation- induced martensite (DIM) have been studied through analytical transmission electron microscopy (TEM) after tensile deformation of AISI 304LN stainless steel at various strain rates (SR) at room temperature (RT). Quantitative metallography has been employed extensively to assess martensitic transformation (MT) as function of strain and SR. It has been observed that the enhancement of SR during tensile deformation promotes the early formation of DIM, while suppressing its saturation value at fracture. Fracture surface morphologies and dimple geometries (i.e. dimple density, dimple diameter and dimple size distribution) have been quantified through image processing (IP) of tensile fractographs. It is noted that at lower SR, dimple density is high while dimple diameter is smaller, and vice versa. Concomitantly, the strength is noted to be low and ductility is high at lower SR, and vice versa. DIM has been found to be responsible for high dimple density at low SR. At high SR, MT is suppressed and hence low dimple density. The variation in SR dependent MT accounts for the variation in dimple metrics vis-à-vis tensile properties.     

Non-coaxiality of strain increment and stress directions in cross-anisotropic sand

An experimental program was carried out in a recently developed torsion shear apparatus to study the non-coaxiality of strain increment and stress directions in cross-anisotropic deposits of Fine Nevada sand. Forty-four drained torsion shear tests were performed at constant mean confining stress, σ_m, constant intermediate principal stress ratios, as indicated by b = (σ₂ − σ₃)/(σ₁ − σ₃), and constant principal stress directions, α. The experiments were performed on large hollow cylinder specimens deposited by dry pluviation and tested in an automated torsion shear apparatus. The specimens had height of 40 cm, and average diameter of 20 cm, and wall thickness of 2 cm. The stress–strain behavior of Fine Nevada sand is presented for discrete combinations of constant principal stress direction, α, and intermediate principal stress. The effects of these two variables on the non-coaxiality are presented. The experiments show that the directions of the strain increments do not in general coincide with the directions of stresses, and there is a switch from one to the other side between the two quantities.     

Exact solutions for the flow of a generalized Oldroyd-B fluid induced by a constantly accelerating plate between two side walls perpendicular to the plate

The unsteady flow of an incompressible generalized Oldroyd-B fluid induced by a constantly accelerating plate between two side walls perpendicular to the plate has been studied using Fourier sine and Laplace transforms. The obtained solutions for the velocity field and shear stresses, written in terms of the generalized G and R functions, are presented as sum of the similar Newtonian solutions and the corresponding non-Newtonian contributions. For α = β = 1 and λ_r → λ these solutions are going to the corresponding Newtonian solutions. Furthermore, the solutions for generalized Maxwell fluids as well as those for ordinary Oldroyd-B and Maxwell fluids, performing the same motion, are also obtained as limiting cases of our general solutions. In the absence of the side walls, namely when the distance between the two walls tends to infinity, the solutions corresponding to the motion over an infinite constantly accelerating plate are recovered. For λ_r → 0 and β → 1, these solutions reduce to the known solutions from the literature. Finally, the effect of the material parameters on the velocity profile is spotlighted by means of the graphical illustrations.     

Modelling of laminated microstructures in stress-induced martensitic transformations

This paper is concerned with micromechanical modelling of stress-induced martensitic transformations in crystalline solids, with the focus on distinct elastic anisotropy of the phases and the associated redistribution of internal stresses. Micro-macro transition in stresses and strains is analysed for a laminated microstructure of austenite and martensite phases. Propagation of a phase transformation front is governed by a time-independent thermodynamic criterion. Plasticity-like macroscopic constitutive rate equations are derived in which the transformed volume fraction is incrementally related to the overall strain or stress. As an application, numerical simulations are performed for cubic β₁ (austenite) to orthorhombic γ₁′ (martensite) phase transformation in a single crystal of Cu-Al-Ni shape memory alloy. The pseudoelasticity effect in tension and compression is investigated along with the corresponding evolution of internal stresses and microstructure.     

Evaporation heat transfer coefficient in single circular small tubes for flow natural refrigerants of C3H8, NH3, and CO2

An experimental study of evaporation heat transfer coefficients for single circular small tubes was conducted for the flow of C₃H₈, NH₃, and CO₂ under various flow conditions. The test matrix encompasses the entire quality range from 0.0 to 1.0, mass fluxes from 50 to 600 kg m⁻² s⁻¹, heat fluxes from 5 to 70 kW m⁻², and saturation temperatures from 0 to 10 °C. The test section was made of circular stainless steel tubes with inner diameters of 1.5 mm and 3.0 mm, and a length of 2000 mm in a horizontal orientation. The test section was uniformly heated by applying electric power directly to the tubes. The effects of mass flux, heat flux, saturation temperature, and inner tube diameter on the heat transfer coefficient are reported. Among the working refrigerants considered in this study, CO₂ has the highest heat transfer coefficient. Laminar flow was observed in the evaporative small tubes, and was considered in the modification of boiling heat transfer coefficients and pressure drop correlations.     

Size effects on the martensitic phase transformation of NiTi nanograins

The analysis of nanocrystalline NiTi by transmission electron microscopy (TEM) shows that the martensitic transformation proceeds by the formation of atomic-scale twins. Grains of a size less than about 50 nm do not transform to martensite even upon large undercooling. A systematic investigation of these phenomena was carried out elucidating the influence of the grain size on the energy barrier of the transformation. Based on the experiment, nanograins were modeled as spherical inclusions containing (0 0 1) compound twinned martensite. Decomposition of the transformation strains of the inclusions into a shear eigenstrain and a normal eigenstrain facilitates the analytical calculation of shear and normal strain energies in dependence of grain size, twin layer width and elastic properties. Stresses were computed analytically for special cases, otherwise numerically. The shear stresses that alternate from twin layer to twin layer are concentrated at the grain boundaries causing a contribution to the strain energy scaling with the surface area of the inclusion, whereas the strain energy induced by the normal components of the transformation strain and the temperature dependent chemical free energy scale with the volume of the inclusion. In the nanograins these different energy contributions were calculated which allow to predict a critical grain size below which the martensitic transformation becomes unlikely. Finally, the experimental result of the atomic-scale twinning can be explained by analytical calculations that account for the transformation-opposing contributions of the shear strain and the twin boundary energy of the twin-banded morphology of martensitic nanograins.     

Reissner-Sagoci problem for a homogeneous coating on a functionally graded half-space

This paper is concerned with the axisymmetric elastostatic problem related to the rotation of a rigid punch which is bonded to the surface of a nonhomogeneous half-space. The half-space is composed of an isotropic homogeneous coating in the form of layer, which is attached to the functionally graded half-space. The shear modulus of the FGM is assumed to vary in the direction of axis Oz normal to the boundary as μ₁(z) = μ₀(1 + αz)^β, where μ₀, α, β are positive constants. The punch undergoes rotation due to the action of the internal loads. By using Hankel's integral transforms, the mixed boundary value problem is reduced to dual integral equations, and next, to a Fredholm's integral equation of the second kind, which is solved numerically for the case of β = 2. The final results show the effect of non-homogeneity on the shear stresses and an unknown moment of punch rotation.     

Micromechanical study of formation and evolution of martensite for Cu–Al–Ni single crystal by moiré interferometry

The basic properties of pseudoelasticity of Cu–Al–Ni single crystal are studied to analyze the morphology associated with the formation and evolution of martensite and the shape memory recovery process at different temperatures. Use is made of a multifunctional macro–micro moiré interferometry measurement system. The β₁ to β₁^′ phase changes are identified with the stress-induced transformation of a Cu–13.7%Al–4.18%Ni (wt%) alloy. The invariant plane between the martensite and the parent phase is shown directly by fringe patterns. It is found that martensite appears in the shape of bands or thin plates on the surface of the specimen. The formation of martensite is a very rapid process and martensite ‘jumps' out until the specimen is completely transformed into a single variant. The results reveal the mechanism and process of stress-type and temperature-induced martensitic transformation.     

Carbon dioxide flow boiling in a single microchannel - Part II: Heat transfer

Flow boiling heat transfer coefficients of CO₂ have been measured in a single microchannel. Experiments were carried out in a horizontal stainless steel tube of 0.529 mm inner diameter, for three temperatures (−10, −5 and 0 °C), with the mass flux ranging from 200 to 1200 kg/m² s and the heat flux varying from 10 to 30 kW/m². The investigation covered qualities from zero to the dryout inception, i.e. pre-dryout conditions. Compared to larger microchannels and positive temperatures, a higher contribution of convective boiling was found, with a larger heat transfer coefficient than for pure nucleate boiling. Mainly two heat transfer regimes were found, depending on the boiling number (Bo). For Bo > 1.1 × 10⁻⁴, the heat transfer coefficient was highly dependent on the heat flux and moderately influenced by the quality and the mass flux. For Bo < 1.1 × 10⁻⁴, the heat transfer coefficient was hardly affected by the heat flux but strongly influenced by the quality and the mass flux. In addition, dryout results were reported. The effect of the mass flux on the dryout inception quality was found to be highly dependent on the heat flux and the saturation temperature.     

Modeling lattice strain evolution at finite strains and experimental verification for copper and stainless steel using in situ neutron diffraction

An elasto-plastic self-consistent (EPSC) polycrystal model is extended to account, in an approximate fashion, for the kinematics of large strains, rigid body rotations, texture evolution and grain shape evolution. In situ neutron diffraction measurements of the flow stress, internal strain, texture and diffraction peak intensity evolutions were performed on polycrystalline copper and stainless steel, up to true tensile strains of ε = 0.3. Suitably adjusted slip system hardening model parameters enable the model to quantitatively describe the flow stress of the polycrystalline aggregate. Quantitative predictions of the texture evolution and the internal strain evolution along the stress axis are good, while predictions of transverse internal strains (perpendicular to the tensile loading direction) are less satisfactory. The latter exhibit a large dispersion from grain to grain around a macroscopic average, and the implications of this finding for the interpretation of in situ neutron diffraction method are explored. Finally, as a demonstration of the applicability of the model to problems involving finite rotation, as well as deformation, simulations of simple shear were conducted which predict a texture evolution in agreement with published experimental data, and other modeling approaches as well.     

Screw dislocations and an interfacial blunt crack with viscoelastic interface

This work deals with the influence of Kelvin-type viscoelastic interface on the generation of screw dislocations near the interfacial blunt crack tip in light of a pair of concentrated loads. The stress fields for dislocation and concentrated load have been obtained by using the integral transform and conformal mapping, the stress intensity factor have been studied, the image force acting on dislocation has been analyzed. The region r_b where n screw dislocations are generated by a pair of concentrated loads and dislocation number are obtained by displacement compatibility and stress compatibility conditions of self-consistent and self-equilibrated systems. The results show that: the force acting on dislocation starts with the value that a perfectly bonded interface, then with relaxation of the imperfect interface; the shield effect for dislocation decreases as time goes by; in addition, with time elapsing, the influence of material shear modulus rate on shielding effect becomes weaker and weaker. The scale of multiplier α(r_b/a) increases with relaxation of imperfect interface, the larger ratio of crack geometry c/a and the smaller ratio of shear modulus μ₁/μ₂ will lead the higher scale of multiplier. When μ₁/μ₂ = 1, the screw dislocations number first increases and then decreases with relaxation of imperfect interface, In addition, it possesses the highest value at t₀ ≈ 1 and tends to vanish at t₀ = ∞. When μ₁ < μ₂, the screw dislocations number increases with relaxation of imperfect interface. When μ₁ > μ₂, the screw dislocations number first increases then decreases with relaxation of imperfect interface, and possesses the highest value at t₀ ≈ 1, the negative value are exclude from the discussion.     

Nonlinear interfacial waves in a circular cylindrical container subjected to a vertical excitation

Singular perturbation theory of two-time scale expansions was developed in inviscid fluids to investigate the motion of single interface standing wave in a two-layer liquid-filled circular cylindrical vessel, which is subjected to a vertical periodical oscillation. It is assumed that the fluid in the circular cylindrical vessel is inviscid, incompressible and the motion is irrotational, a nonlinear amplitude equation including cubic nonlinear and vertically forced terms, was derived by the method of expansion of two-time scales without taking the influence of surface tension into account. By numerical computation, it is shown that different patterns of interface standing wave can be excited for different driving frequency and amplitude. We found that the interface wave mode become more and more complex as increasing of upper to lower layer density ratio γ$\gamma$. The traits of the standing interface wave were proved theoretically. In addition, the dispersion relation and nonlinear amplitude equation obtained in this article can reduce to the known results for a single fluid when γ=0,_h2→_h1$\gamma =0,h_2\to h_1$.     

Transmission electron microscopy investigation of dislocation slip during superelastic cycling of Ni-Ti wires

Superelastic deformation of thin Ni-Ti wires containing various nanograined microstructures was investigated by tensile cyclic loading with in situ evaluation of electric resistivity. Defects created by the superelastic cycling in these wires were analyzed by transmission electron microscopy. The role of dislocation slip in superelastic deformation is discussed. Ni-Ti wires having finest microstructures (grain diameter <100 nm) are highly resistant against dislocation slip, while those with fully recrystallized microstructure and grain size exceeding 200 nm are prone to dislocation slip. The density of the observed dislocation defects increases significantly with increasing grain size. The upper plateau stress of the superelastic stress-strain curves is largely grain size independent from 10 up to 1000 nm. It is hence claimed that the Hall-Petch relationship fails for the stress-induced martensitic transformation in this grain size range. It is proposed that dislocation slip taking place during superelastic cycling is responsible for the accumulated irreversible strains, cyclic instability and degradation of functional properties. No residual martensite phase was found in the microstructures of superelastically cycled wires by TEM and results of the in situ electric resistance measurements during straining also indirectly suggest that none or very little martensite phase remains in the studied cycled superelastic wires after unloading. The accumulation of dislocation defects, however, does not prevent the superelasticity. It only affects the shape of the stress-strain response, makes it unstable upon cycling and changes the deformation mode from localized to homogeneous. The activity of dislocation slip during superelastic deformation of Ni-Ti increases with increasing test temperature and ultimately destroys the superelasticity as the plateau stress approaches the yield stress for slip. Deformation twins in the austenite phase ({1 1 4} compound twins) were frequently found in cycled wires having largest grain size. It is proposed that they formed in the highly deformed B19′ martensite phase during forward loading and are retained in austenite after unloading. Such twinning would represent an additional deformation mechanism of Ni-Ti yielding residual irrecoverable strains.     

Thermodynamic driving force in ferroelectric crystals with a rank-2 laminated domain pattern, and a study of enhanced electrostriction

The thermodynamic driving force for domain growth in a rank-2 laminated ferroelectric crystal is derived in this article, and we used it, together with a homogenization theory, to study the issue of enhanced electrostrictive actuation recently reported by Burcsu et al. [2004. Large electrostrictive actuation of barium titanate single crystals. J. Mech. Phys. Solids 52, 823-846]. We derived this force from the reduction of Gibbs free energy with respect to the increase of domain concentration. It is shown that both the free energy and the thermodynamic force consist of three parts: the first arises from the difference in M₀ and M₁, the linear electromechanical compliances of the parent and product domains, respectively, at a given level of applied stress and electric field, the second stems from the electromechanical work associated with the change of spontaneous strain and spontaneous polarization during domain switch, and the third from the internal energy due to the distribution of polarizations strain and electric polarization inside the crystal. We prove that the first term is substantially lower than the second one, and the third one is identically zero with compatible domain pattern. The second one is, however, not exactly equal to the commonly written sum of the products of stress with strain, and electric field with polarization during switch, unless both domains have identical moduli in the common global axes. We also show that, with compatible domain patterns and when M₁=M₀, this driving force is identical to Eshelby's driving force acting on a flat interface due to the jump of energy-momentum tensor. Applications of the theory to a BaTiO₃ crystal subjected to a fixed axial compression and decreasing electric field from the [0 0 1] state reveal that the crystal undergoes a three-stage switching process: (i) the 0→90° switch to form a rank-1 laminate, (ii) the 0→180° switch inside the 0° domain to form a laminate I with a concurrent 90°→−90° switch inside the 90° domain to form laminate II, creating a rank-2-laminated domain pattern, and (iii) finally the 90→180° switch. It is the exchange of stability between the 0, 90°, and 180° domains under compression and electric field that is the origin of the enhanced actuation. We illustrate these intrinsic features by showing the evolution of these domains, and demonstrate how the reported large actuation strain can be attained with a rank-2 laminate.     

Thermo-mechanical response of Al 6061 with and without equal channel angular pressing (ECAP)

The thermo-mechanical responses of Al 6061 before and after equal channel angular pressing (ECAP) at different strain rates and temperatures were measured. Al 6061 was solution heat treated before ECAP pressing at room temperature and subjected to up to three passes. After pressing, the billets were aged at 100 °C for 2 days. An as-received Al 6061-T651 was studied similarly to investigate the differences between processed and non-processed specimens. The responses of ECAP material were determined at −30, 22, 125 and 250 °C, and at strain rates from 10⁻⁵ to 2530 s⁻¹; the 6061-T651 specimens were subjected to uniaxial compressive loading at −31, 22, 85, 150, 230 and 315 °C, and strain rates ranging from 10⁻⁵ to 2200 s⁻¹. It was found that, the ECAP process increases the strength versus the T651 condition. Additionally, the Al 6061 ECAP is not sensitive to strain rate at room and lower temperatures, but the sensitivity increases as the number of passes and/or temperature are increased and this is the same for the non-processed material. Increasing the number of passes increases the flow stress at room and lower temperatures, has almost no effect at 125 °C and decreases at 250 °C. For both materials, the dynamic flow stress is higher than the stress at quasi-static strain rates even when the quasi-static strain rate regime is insensitive to strain rate. The Al 6061 has strong texture after one pass but steadily increases as the number of passes are increased. This is the first study that reports on the thermo-mechanical responses of ECAP and non-ECAP Al 6061 at such a wide range of strain rates, including dynamic, and temperatures.     

A new unified constitutive model with short- and long-range back stress for lead-free solders of Sn–3Ag–0.5Cu and Sn–0.7Cu

A series of tensile tests of Sn–3Ag–0.5Cu and Sn–0.7Cu lead-free solders were investigated at various strain rates from 1 × 10⁻⁴ s⁻¹ to 1 × 10⁻² s⁻¹ and over a wide temperature range from 25 ^oC to 150 ^oC. Two-step strain rate jump tests, three-step short term creep tests with stress jump, and uniaxial ratcheting tests were also conducted. Based on the test data, a new constitutive model was proposed with a simple formulation and only eight material constants which can be easily obtained. The model employs two carefully defined back stress components to simulate the loading/unloading asymmetry phenomenon in uniaxial ratcheting tests. Different evolution rules of short-range back stress were given for loading and unloading stage, which provides the model ability to simulate the asymmetry in hysteresis loops. The proposed model presents good simulation of uniaxial tensile tests, strain rate jump tests, short term creep tests with stress jump, and uniaxial ratcheting tests.     

Similarity solutions in free convection boundary-layer flows adjacent to vertical permeable surfaces in porous media: II prescribed surface heat flux

The equation which governs the similarity solution for free convection boundary-layer flow along a vertical permeable surface with prescribed surface heating and mass transfer rate is discussed. The solution is seen to depend on two non-dimensional parameters;m, the power-law exponent, and γ, the mass transfer parameter. It is shown that solutions exist for allm>?1 for γ>0 (fluid injection) whereas for γ<0 (fluid withdrawal), solution exist form>m ₀(γ), wherem ₀ is determined as a function of γ. Solutions for large mass transfer rates are obtained, for both γ>0 and γ<0. For γ>0 the form of the asymptotic solution for γ large is seen to depend on the value ofm. Solutions form large are derived, these are seen to be different depending on whether γ is positive or negative.