共查询到14条相似文献,搜索用时 171 毫秒
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乳状液膜法分离水中汞的研究 总被引:3,自引:0,他引:3
报道了用乳状液膜法分离汞的研究。确定了最佳分离条件;流动载体TBP(磷酸三丁酯)和表面活性剂Span80的浓度均9%,内相溶液NaOH和外相溶液HCl的浓度分别为0.4mol/L和0.02mol/L,制乳时间和混合时间分别为10min和5min,乳水比和油内比分别为0.5和0.8。 相似文献
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乳状液膜分离技术具有快速高效、选择性强、富集比大等优点[1-4],但该技术目前大多还处在实验阶段,要实现工业化则必须解决液膜稳定性、有毒试剂的使用及二次污染等问题.表面活性剂对于乳状液膜的形成和稳定至关重要[5-7],而在液膜体系中采用复合表面活性剂,能改善液膜性能,提高膜稳定性及传质效率[8].本文研究了铜(Ⅱ)在span80-SDS-NH3液膜体系中的迁移行为.体系中无流动载体,利用内、外相中被分离物的浓度梯度促进物质迁移.当Cu2+进入内相时,与NH3产生络合反应,使内相中游离的铜离子浓度趋于零而促使其由外相进入内相,实现Cu2+与外相溶液的分离. 相似文献
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PMBP为载体的乳状液膜提取钪的研究 总被引:4,自引:0,他引:4
研究了以1-苯基-3-甲基-4-苯甲酰基吡唑酮-5(PMBP)为流动载体的乳状液膜(ELM)法提取钪,确定最佳液膜体系组成为0.4%PMBP-3%Span80-5%液体石蜡-煤油-3mol/LHCl,Roi=1:1(油内比).Rwe(水乳比)可达20:1.用该体系对钪与混合稀土进行分离,钪的回收率可达95.5%,分离系数β(SC/RE)=32.0。 相似文献
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乳状液膜法分离水中的铬 总被引:3,自引:0,他引:3
乳状液膜法由于其独特的物理化学性质,已广泛用于金属离子的萃取分离[1~3]。本文以span80-煤油-NaOH液膜体系分离水中铬。不加流动载体,利用内、外相中被分离物的浓度梯度实现物质迁移。当Cr2O2-7进入内相时,与内相的NaOH发生反应,在内相高浓度的NaOH存在下,可保持Cr2O2-7在液膜两侧有最大的浓度梯度,促使Cr2O2-7的迁移,实现Cr2O2-7与外相溶液的分离。1 实验部分1 1 仪器与试剂D40-1型电动搅拌器(杭州仪表电机厂),78-1型磁力加热搅拌器(江苏金坛新一佳仪器厂),721型分光光度计(上海第三分析仪器厂)。铬标准溶液(100ml/L):准… 相似文献
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Diptendu Das V. A. Juvekar S. B. Roy R. Bhattacharya 《Journal of Radioanalytical and Nuclear Chemistry》2014,300(1):333-343
Equilibrium and kinetics of co-extraction of hexavalent uranium and mineral acids from aqueous solutions into a hydrocarbon phase (paraffin) using tri n-butyl phosphate (TBP), tri-n-octyl phosphine oxide (TOPO) and tri-n-octyl amine (TOA) has been studied. Relative rates of extraction of uranium(VI) and mineral acid by different complexing ligands were measured simultaneously using bulk-liquid membrane system. Acid extraction by complexing ligands was found to be significant. Wherever there was a possibility of the formation of the third phase, isodecanol was used as an organic phase modifier. Study revealed that isodecanol promotes acid extraction and substantially reduces distribution coefficient of U(VI) into the hydrocarbon phase. The rate of acid extraction by different ligand was in the order of TOPO > TOA > TBP–isodecanol > TBP, whereas the rate of extraction of uranium(VI) was in the order TOPO > TOA > TBP > TBP–isodecanol. A kinetic model was developed to predict concentration of acid and U(VI) in the feed, organic and the strip phase during extraction. The mass transfer coefficients for acid and metal were determined by fitting the model to the observed concentration–time data. 相似文献
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《印度化学会志》2023,100(9):101081
This study explores the use of novel green emulation liquid membranes (GELMs) for the simultaneous extraction and stripping of Cd (II) from aqueous solutions. A solute is transported through the membrane due to the presence of the carrier and then concentrated in the internal phase. Soybean, sunflower, corn, and canola oils were used to form green substitutes to petroleum-based organic diluents for use as GELMs. Bis-(2-ethylhexyl) phosphate (D2EHPA), tri-butyl- phosphate (TBP), and trioctylamine (TOA) were the extractants, span 80 was the emulsifier, and HCl or H2SO4 was used as the stripping agent. The best conditions for maximum extraction efficiency (98.68%), stripping efficiency (97.14%), and lowest membrane breakage (0.9%) were achieved using a mixture of sunflower oil and kerosene in the ratio of 70:30. The other optimum values of the variables were: 2% (v/v) Span 80, 10 min emulsification time, 12700 rpm emulsification speed, 400 rpm of agitation speed, 5% (v/v) D2EHPA, an external phase pH was 3.5, an internal phase of 0.25 M HCl, and 5:1 of the treat ratio (external phase to emulsion) at 10 min contact time. The synthesized membrane was reused eight times, with approximately the same efficiency and no significant breakage during the first seven cycles. 相似文献
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Sarah Chaouchi 《Journal of Dispersion Science and Technology》2014,35(9):1278-1288
This work aims to the extraction of the priority pollutant 4-nitrophenol (4-NP) from water by emulsion liquid membrane (ELM). Liquid membrane consists of a diluent (hexane) and a surfactant (Span 80). Sodium carbonate solution was used as internal aqueous phase. Effects of important experimental conditions governing the stability of the W/O emulsion were investigated. Influence of operating parameters that affects the permeation of 4-NP such as surfactant concentration, emulsification time, sulfuric acid concentration in external phase, acid type in external phase, internal phase concentration, type of internal phase, stirring speed, volume ratio of internal phase to membrane phase, treatment ratio, 4-NP initial concentration, and diluent type was examined. This study also evaluated the effect of Na2CO3 concentration in the internal aqueous phase on the stripping of 4-NP. Additionally, the reuse of the recovered membrane was studied. Under most favorable conditions, practically all the 4-NP and aniline (AN) molecules present in the feed phase were extracted. The recovery of the membrane phase was total and the extraction of 4-NP was not decreased. The ELM treatment process represents a very interesting advanced separation process for the removal of 4-NP and AN from aqueous solutions. 相似文献