共查询到17条相似文献,搜索用时 112 毫秒
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以Alq3作为发光层,在OLED串联型制作系统上成功制备出ITO/TPD/Alq3/LiF/Al结构的有机发光器件,并建立了一套OLED电流(J)、电压(V)、亮度(B)自动测试系统,在氮气和空气环境下测试并分析了OLED的发光特性。结果表明,基于Alq3的双层OLED的正向J-V特性可以用陷阱电荷限制流来描述;反向工作时,低压下的反偏电流可能是针孔产生的漏电流,高压下反偏OLED的J-V特性应满足F-N隧穿机制。随着电流进入快速增长阶段,B-J曲线近似地呈线性关系;在低场下,发光效率随电压升高而增大,在高场下,发光效率随电压升高而减小。实验中,还观察到了在电压V=4V左右时,器件具有明显的负阻特性(NDR),进一步的分析表明,由针孔引起的丝状电流可能是负阻特性的成因。 相似文献
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制备了常规有机发光二极管ITO/NPD/Alq3/LiF/Al,测量了该器件发光的磁场效应.发现尽管在1T范围内的磁场对发光层Alq3的光致发光没有影响,但磁场作用下器件的电致发光(MEL)却呈现出明显的磁效应,且MEL与器件的偏压有很强的依赖关系:在小偏压时,随着磁场的增加MEL是单调递增,且在大小约为40kA/m的磁场下达到饱和,之后即使磁场增大到约1T 的情况下也没有变化;但当偏压变大时,MEL则呈现先增加,在40kA/m处达到峰值后却又减弱,而且偏压越大该MEL的减弱则越明显.对所观察到的实验结果进行了定形解释,即三线态激子相互淬灭产生单线态激子和三线态激子与器件中的非平衡载流子相互作用是此效应的物理机理.
关键词:
有机发光
磁场效应
激子淬灭 相似文献
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介绍了具有可调节发光光谱的高效红光有机发光二极管(OLED)器件,利用具有高三重态能量的9.9-螺二芴二苯基氧化磷(SPPO1)作为发光层的主体材料及空穴阻挡层,二(1-苯基异喹啉)(乙酰丙酮)合铱(III) (Ir(piq)2(acac))作为客体发光材料,在发光层内SPPO1的能量分别由福斯特和迪克斯特传递到Ir(piq)2(acac)的单重态和三重态从而发出红色磷光,通过调节磷光客体材料的比例得到最优器件结构,从而得到具有较好发光效率和发光亮度并可调节色纯的有机发光二极管器件。 相似文献
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介绍了具有可调节发光光谱的高效红光有机发光二极管(OLED)器件,利用具有高三重态能量的9.9-螺二芴二苯基氧化磷(SPPO1)作为发光层的主体材料及空穴阻挡层,二(1-苯基异喹啉)(乙酰丙酮)合铱(III) (Ir(piq)2(acac))作为客体发光材料,在发光层内SPPO1的能量分别由福斯特和迪克斯特传递到Ir(piq)2(acac)的单重态和三重态从而发出红色磷光,通过调节磷光客体材料的比例得到最优器件结构,从而得到具有较好发光效率和发光亮度并可调节色纯的有机发光二极管器件。 相似文献
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采用双极性材料4,4'-bis(carbazol-9-yl)biphenyl(CBP)为主体,蓝色荧光染料N-(4-((E)-2-(6-((E)-4-(diphenylamino)styryl)naphthalen-2-yl)vinyl)phenyl)-N-phenylbenzenamine(N-BDAVBi)和橙色磷光染料Iridium(III)bis(4-phenylthieno[3,2-c]pyridinato-N,C2')acetylacetonate(PO-01)为客体,制备了双发光层结构的白色有机电致发光器件,通过调整发光层的位置及在两个发光层之间引入间隔层,研究了器件的光电特性.间隔层的引入调整了发光层中激子的分布,改善了器件的光电性能.器件的最大电流效率和功率效率分别为19.6cd/A和12.3lm/W.发光亮度从15cd/m2增加至10 310cd/m2的过程中,器件的色坐标从(0.438,0.476)变化至(0.316,0.389),始终处于白光区. 相似文献
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硅片上顶发射的有机电致发光器件 总被引:2,自引:0,他引:2
为了更好地实现有机发光器件在硅片上的有源矩阵显示,有必要探讨在硅片上直接制作透明阴极的顶发射有机发光器件。在顶发射发光器件中,为了到达高的发光效率,底部阳极一般采用高反射率的金属。在通常所用的各种金属当中,金属银对可见光具有很高的反射率,然而由于其具有相当低的功函数,导致与有机材料间能级的不匹配,从而引起有机发光器件中阳极空穴注入的不理想而影响器件的性能。我们在硅片上制备顶发射的有机发光器件,用薄层QAD(quinacridone)作为发光层,表面修饰的银作为阳极,制备的有机发光器件的亮度在外加电压10V时达到13700cd/m^2,器件的最大电流效率在7V时达到4.3cd/A,是没有薄层QAD器件的2倍多,是由在器件中存在Alq3与QAD之间Foester能量转移机制引起的。 相似文献
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对于RGB有机电致发光器件(OLEDs),蓝光非常重要.在现有各种蓝光材料中,聚芴(PFO)非常稳定且荧光量子效率可达80%,但它有一个非常大的缺点:电致发光会产生异常绿光带.这严重影响了PFO相关器件的饱和色纯度.本文使用分子基磁性材料Fe(NH2trz)3·(BF4)2掺杂PFO方法,解决了这一难题.以ITO为衬底,制作了结构为ITO/PEDOT:PSS/PFO:Fe(NH2trz)3·(BF4)2/CsCl/Al的器件.报道了利用Fe(NH2trz)3·(BF4)2特殊的电子自旋态调制PFO的光电特性,实现了PFO的强烈纯正蓝光发射.详细研究了Fe(NH2trz)3·(BF4)2对PFO光电特性的影响.在4 V至9 V电压的偏置下,没有Fe(NH2trz)3·(BF4)2的器件,发出特别异常的绿光.然而,与此形成明显对照的是:Fe(NH2trz)3·(BF4)2掺杂的器件发出强烈的本征蓝光;PFO绿色发光带被成功压制;随着电压的变化,器件光谱的蓝光部分在整个EL谱所占比例没有改变.运用光电磁一体化测量技术,进一步研究了PFO掺杂Fe(NH2trz)3·(BF4)2器件的磁发光(MEL)和磁电导(MC)效应.发现PFO:Fe(NH2trz)3·(BF4)2和纯PFO薄膜内都没有激基缔合物产生.运用发光动力学理论,分析了Fe(NH2trz)3·(BF4)2阻断PFO异常绿光发射的机理. 相似文献
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有机电致发光器件(OLED)经过近三十年的发展,已经在照明和显示上得到一定程度的应用.OLED具有全固态、响应速度快、易于实现柔件显示等优点.由于磷光材料的应用,其内量子效率几乎达到了理论的极限值100%,但其外量子效率却只有20%左右,制约外量子效率进一步提高的主要因素是器件的光取出效率.本文从提高OLED光取出效率的方法入手,综述了国内外关于顶发射和底发射有机发光器件光取出效率增强的研究现状、最新进展及以后的研究方向. 相似文献
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Based on indium tin oxide (ITO)/N,N′diphenyl-N-N′-di(m-tdyl) benzidine (TPD)/Alq3/Al structure, flexible OLEDs on polyethylene terephthalate (PET) substrates were fabricated by physical vapor deposition (PVD) method. Tris(8-hydroxyquinoline)aluminum (Alq3) films were deposited at 90, 120 and 150 °C to examine the influence of the deposition temperature on the structure and performance of OLEDs. Electroluminescence (EL) spectra and current-voltage-luminance (I-V-L) characteristics of the OLEDs were examined. It was found that the device fabricated at a high temperature had a higher external efficiency and longer lifetime. Atomic force microscope (AFM) was adopted to characterize the surface morphology of ITO/TPD/Alq3. The higher uniform morphology of the Alq3 formed at high temperature might contribute to the performance improvement of the OLEDs. 相似文献
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This paper reports on delayed luminescence measurements of tris-(8-hydroxyquinoline)aluminum (Alq3) after optical excitation; these identify two bands in the emission spectrum: delayed fluorescence and phosphorescence. This is shown for different crystalline phases and for evaporated films. The assignment of the low-energy band to the phosphorescence is confirmed by lifetime measurements, and triplet energies of the meridional isomer in the -phase and the facial isomer in the δ-phase are determined from the well-resolved vibronic progressions of the phosphorescence as 2.11±0.1 and 2.16±0.1 eV, respectively. Lifetimes of the delayed fluorescence and the phosphorescence are determined for a temperature range from 6 to 150 K, and we measured the temperature dependence of the delayed photoluminescence spectra. 相似文献
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Y. Sakurai G. Salvan Y. Hosoi H. Ishii Y. Ouchi K. Seki T. U. Kampen D. R. T. Zahn 《Applied Surface Science》2002,190(1-4):382-385
The interaction between Alq3 and potassium was studied by using Raman and infrared spectroscopies. Infrared reflection absorption spectroscopy (IRRAS) spectra of Alq3 films show significant changes after potassium deposition, such as the appearance of new bands and changes in relative intensity. Surface-enhanced Raman scattering (SERS) spectra obtained using the 413.1 nm line of a Kr+ laser reveal similar changes. Changes are even more obvious when the 530.9 nm line was used for excitation. Changes in the SERS for excitation with the 413.1 nm line are less obvious due to a strong photoluminescence. The vibrational pattern of potassium-doped Alq3 cannot be explained by the formation of radical anion by simple charge transfer, indicating the excess electron is not delocalized over the molecule. The observed spectral change suggests that the potassium atom interacts with both nitrogen and oxygen atoms of Alq3 molecule. 相似文献
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Tris(8-hydroxyquinoline) metal complex (AlQ3) is a widely used light-emitting material in organic light-emitting devices (OLEDs). The environmental stability is still a major problem with OLEDs and needs further improvements. In this report, we examine the optical properties of the thin films of this material and the effect of environment on it. The annealing in different ambients were done with the aim to understand the physical phenomenon involved in AlQ3 thin films. An enhanced photoluminescence intensity is observed for the samples annealed in oxygen near 100 °C. Sudden change in roughness which may be as a consequence of change in surface morphology due to phase change and fraction of new phase is estimated by phase images taken by Atomic Force Microscopy (AFM). The enhanced photoluminescence is understood in terms of formation of a new phase. 相似文献
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Photocurrent analysis of organic photovoltaic cells based on CuPc/C60 with Alq3 as a buffer layer
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The performance of an organic photovoltaic(OPV) cell based on copper phthalocyanine CuPc/C60 with a tris(8-hydroxyquinolinato) aluminum(Alq3) buffer layer has been investigated.It was found that the power conversion efficiency of the device was 1.51% under illumination with an intensity of 100 mW/cm2,which was limited by a squareroot dependence of the photocurrent on voltage.The photocurrent-optical power density characteristics showed that the OPV cell had a significant space-charge limited photocurrent with a varied saturation voltage and a three quarters power dependence on optical power density.Also,the absorption spectrum was measured by a spectrophotometer,and the results showed that the additional Alq3 layer has a minor effect on photocurrent generation. 相似文献
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利用x射线衍射和磁测量研究了不同稳定元素Co以及Ti,V和Cr替代对Nd3Fe29-x-yCoxMy(M=Ti,V,Cr)化合物结构和磁性的影响.研究发现:每一个稳定元素都有一替代量极限,在此极限以内所有化合物均为Nd3(Fe,Ti)29型结构,A2/m空间群.不同稳定元素的溶解极限不同.Co的替代量与稳定元素有关,当以Cr作为稳定元素时,Cr的替代量随着Co含量的提高而提高
关键词:
3(Fe')" href="#">Nd3(Fe
Co
29')" href="#">M)29
结构
磁性 相似文献
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The adsorption of NH3 molecule on the Si(1 1 1)-7 × 7 surface modelled with a cluster has been studied using density functional theory (DFT). The results indicate the existence of a precursor state for the non-dissociative chemisorption. The active site for the molecular chemisorption is the adatom; while the NH3 molecule adsorbs on the Si restatom via this preadsorbed state, the adsorption on the Si adatom is produced practically without an energy barrier. The ammonia adsorption on the adatom induces an electron transfer from the dangling bond of this atom to the dangling bond of the adjacent Si restatom, hindering this site for the adsorption of a second NH3 incoming molecule. However, this second molecule links strongly by means of two H-bonds. The dissociative chemisorption process was studied considering one and two ammonia molecules. For the dissociation of a lonely NH3 molecule an energy barrier of ∼0.3 eV was calculated, yielding NH2 on the adatom and H on the restatom. When two molecules are adsorbed, the NH3-NH3 interaction yields the weakening of a N-H bond of the ammonia molecule adsorbed closer the Si surface. As a consequence, the dissociation barrier practically disappears. Thus, the presence of a second NH3 molecule at the adatom-restatom pair of the Si(1 1 1)-7 × 7 surface makes the dissociative reaction self-assisted, the total adsorption process elapsing with a negligible activation barrier (less than 0.01 eV). 相似文献