Simulation of the NaGd(MoO4)2–NaEu(MoO4)2 and Na2Gd4(MoO4)7–Na2Eu4(MoO4)7 Solid Solutions by the Interatomic Potential Method

Physics of the Solid State - Simulation of the solid solutions in the system of double sodium–gadolinium and sodium–europium molybdates, which are promising matrices for solid state...     

Phase transitions and energy storage properties of some compositions in the (1−x)Li2SO4–xNa2SO4 system

In the binary system (1?x)Li₂SO₄–xNa₂SO₄, the solid–solid phase transitions and energy storage properties of Li₂SO₄, Na₂SO₄, the binary compound LiNaSO₄ and two eutectoids (E₁: 0.726Li₂SO₄–0.274Na₂SO₄; E₂: 0.03Li₂SO₄–0.97Na₂SO₄) were investigated by X-ray diffraction and differential scanning calorimetry. Li₂SO₄ has a solid–solid phase transition at 578 °C with the transition enthalpy 252 J g^?1. The binary compound LiNaSO₄ gives a slightly lower enthalpy value, 214 J g^?1 and its transition temperature is clearly reduced to 514 °C. The transition enthalpy of the eutectoid E₁ is maintained to 177 J g^?1 and its transition temperature is further reduced to 474 °C. Li₂SO₄, LiNaSO₄ and the eutectoid E₁ are applicable phase transition materials because of their large transition enthalpies. The enthalpies of Na₂SO₄ and the eutectoid E₂ are not very high (～45 J g^?1), but their transition temperatures are quite low (～250 °C); thus their transition properties may be applied at such low temperatures.     

Variability of the atmospheric N2O line (J=3→4)

We analyze the results of observations of the radio emission of atmospheric N₂O in the line J=3→4 at frequency near 100.5 GHz. Observations aimed at monitoring the nitrous oxide content at altitudes h>20 km were performed in Nizhny Novgorod from March to May, 1997. We discover variations of the optical-depth decrement in the line, which can be explained by the redistribution of nitrous oxide over the altitude range h=20–55 km. This assumption does not contradict published data on in-situ measurements of N₂O density at h=5–35 km. Using the obtained data we calculate the rotational-line spectra of atmospheric N₂O. We point out that the measured decrements of the optical depths are greater than the calculated ones. We discuss observations of the N₂O lines in the mm-wave band as a promising method for monitoring the vertical mixing in the atmosphere. N. I. Lobachevsky State University, Nizhny Novgorod, Russia. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 42, No. 10, pp. 933–939, October 1999.     

He-broadening and shifting coefficients of HCl lines in the (1←0) and (2←0) infrared transitions

ABSTRACT

We report experimental results on the broadening and shifting coefficients in a large interval of J quantum numbers in the fundamental and first overtone vibration–rotation bands of the HCl molecule in mixtures with helium. Many of the values, especially for the overtone transition, are novel. The uncertainties for the isotope-averaged broadening coefficients amount to 2% on average for the fundamental and 1.5% for the overtone bands. Shifts have a typical uncertainty of 3%.     

类锂等电子系列(1s2p2p)~4 P~e和(1s2s2p)~4 P~0态的能量和精细结构研究

利用改进的马鞍点方法,截断变分方法,并考虑能量的相对论修正和质量极化效应,计算和研究了类理等电子系列的两个四重态（１ｓ２ｐ２ｐ）４Ｐ０和（１ｓ２ｓ２ｐ）４Ｐｅ态的精细结构和平均跃迁波长,并与实验和其它理论计算结果进行了比较。     

Spin-Exchange Collisions in the K–Li System

Optics and Spectroscopy - Spin-exchange cross sections and the magnetic-resonance frequency shift in collision of lithium and potassium atoms in the ground state have been calculated for the first...     

Circular polarization of the (1s2p)2 → (1s2)0 line emitted by 205Tl79+ ions after collisional excitation by an unpolarized electron beam

The circular polarization of the (1s2p)_J=2 → (1s²)_J=0 line emitted by the helium-like ion ²⁰⁵Tl⁷⁹⁺ following impact excitation by a nonpolarized electron beam is theoretically studied. The probability for the hyperfine induced E1 transition (1s2p)₂F=3/2→1s² has been determined from the first order perturbation theory. Various collision strengths for excitation of thallium ions to the (1s2p)₂M_J=0, 1 and 2 magnetic sublevels have been used. It is found that the interference between M2 and E1 radiation occurring in the line can give rise to a significant degree of circular polarization. This revised version was published online in August 2006 with corrections to the Cover Date.     

Precision measurement of the (3p–1s) X-ray transition in muonic hydrogen

The (3p — 1s) X-ray transition to the muonic hydrogen ground state was measured with a highresolution crystal spectrometer. The assumption of a statistical population of the hyperfine levels of the muonic hydrogen ground state was directly confirmed by the experiment and measured values for the hyperfine splitting can be reported. The measurement supplements studies on line broadening effects induced by Coulomb de-excitation hindering the direct extraction of the pion-nucleon scattering lengths from pionic hydrogen and deuterium X-ray lines.     

The spectrum and structure of the He2 molecule: Characterization of the triplet states associated with the UAO's 4pπ and 5pπ

The He₂ band systems $\text{4pπ i}{}^3\text{Π}{}_{\mathrm{g}}\text{→ 2s a}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ and $\text{5pπ l}{}^3\text{Π}{}_{\mathrm{g}}\text{→ 2s a}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ are described in detail, and the i and l states characterized. A number of significant perturbations in the i and l states are identified, and the possible perturber states discussed. The following molecular constants (cm^?1) are reported:

     

11.

Optical second harmonic generation studies of the nature of the oxide-covered and clean c(4 × 4) and (2 × 4) reconstructed GaAs(001) surfaces     

《Surface science》1993,291(3):L751-L755

We report the application of the “epioptic” technique of optical second harmonic generation (SHG) to the study of surface chemical processes occurring at the technologically important (001) surfaces of the non-centrosymmetric compound semiconductor GaAs. SHG has been used to monitor the thermal removal of surface contamination from an GaAs(001) substrate mounted in a conventional molecular beam epitaxy (MBE) chamber. Rotational anisotropy plots of the reflected SH signal recorded at near-normal incidence indicate that the oxide layer is not fully disordered and possesses some structural anisotropy, i.e. some preferred net surface orientation. In addition the rotational anisotropy plots were observed to change in both intensity and apparent phase between the oxide-covered surface and the clean reconstructed surfaces. Following heating to 850 K under the background As₂ flux present in the chamber, the SH signal from the clean, reconstructed surface was approximately 5 × weaker than that observed for the contaminated surface and was subsequently found to be insensitive to the reconstruction change between the (2 × 4) and c(4 × 4) surfaces, in agreement with theoretical predictions for surfaces having 2mm and 4mm symmetry, respectively.These data are discussed in terms of the difficulties encountered when attempting to observe a surface SH response from a non-centrosymmetric substrate. The sensitivity of the technique towards the thin oxide overlayer suggests that for overlayers which are likely to possess net oriented in-plane dipoles due to the structural mismatch with the substrate, an SH response may be observed in preference to a bulk response when a normal incidence geometry is employed.     

12.

A study of the reaction (π+, π+ p) in 12C and 6Li     

《Nuclear Physics A》1987,462(4):605-620

We have measured the angular and momentum distributions of the scattered pions from the reaction ¹²C(π⁺, π⁺p)¹¹B and ⁶Li(π⁺, π⁺ p)⁵He in a coincidence experiment. We compare our results with the plane and distorted wave impulse approximations.     

13.

H2-broadening,shifting and mixing coefficients of the doublets in the ν2 and ν4 bands of PH3 at room temperature     

Jamel Salem  Ghislain Blanquet  Muriel Lepère  Rached ben Younes 《Molecular physics》2018,116(10):1280-1289

The broadening, shifting and mixing coefficients of the doublet spectral lines in the ν₂ and ν₄ bands of PH₃ perturbed by H₂ have been determined at room temperature. Indeed, the collisional spectroscopic parameters: intensities, line widths, line shifts and line mixing parameters, are all grouped together in the collisional relaxation matrix. To analyse the collisional process and physical effects on spectra of phosphine (PH₃), we have used the measurements carried out using a tunable diode-laser spectrometer in the ν₂ and ν₄ bands of PH₃ perturbed by hydrogen (H₂) at room temperature. The recorded spectra are fitted by the Voigt profile and the speed-dependent uncorrelated hard collision model of Rautian and Sobelman. These profiles are developed in the studies of isolated lines and are modified to account for the line mixing effects in the overlapping lines. The line widths, line shifts and line mixing parameters are given for six A₁ and A₂ doublet lines with quantum numbers K = 3n,?(n = 1,?2, …) and overlapped by collisional broadening at pressures of less than 50 mbar.     

14.

Resonant charge transfer in slow Li~+–Li(2s) collision          下载免费PDF全文

《中国物理 B》2015,(10)

The resonant charge transfer process for Li+–Li(2s) collision is investigated by the quantum-mechanical molecular orbital close-coupling(QMOCC) method and the two-center atomic-orbital close-coupling(AOCC) method in an energy range of 1.0 e V/u–104e V/u. Accurate molecular structure data and charge transfer cross sections are given. Both the allelectron model(AEM) and one-electron model(OEM) are used in the QMOCC calculations, and the discrepancies between the two models are analyzed. The OEM calculation can also give a reliable prediction of the cross sections for energies below 1 ke V/u.     

15.

X-Ray spectral and theoretical investigations of the electronic structure of phenylcyclosilanes (SiPh2) n (n = 4–6)     

T. N. Danilenko  V. G. Vlasenko  M. M. Tatevosyan 《Physics of the Solid State》2013,55(12):2582-2591

The X-ray emission SiKα_{1, 2} and SiKβ₁ spectra of a series of phenylcyclosilanes (SiPh₂) _n (n = 4–6) have been obtained. Using the results of quantum-chemical calculations in the density functional theory approximation, the fine structure of SiKβ₁ spectra has been interpreted. Distributions of densities of electron states of silicon atoms over the valence band have been constructed and the types of chemical bonds providing the Si-Si and Si-Ph interactions have been established. Based on the theory of natural bond orbitals, the chemical bonding in the studied series of phenylcyclosilanes has been analyzed.     

16.

Physics and Performance of the Upgraded T2K’s Near Detector     

Blanchet  Adrien 《Physics of Atomic Nuclei》2021,84(4):519-523

Physics of Atomic Nuclei - Tokai-to-Kamioka (T2K) is a long-baseline neutrino oscillation experiment currently ongoing in Japan. T2K has been the first experiment to detect the appearance of...     

17.

Dipole Oscillation in a Bose–Fermi Superfluid Mixture of ~(41)K and ~6Li          下载免费PDF全文

张仁 《中国物理快报》2018,(4)

We study the relation between the bosonic frequency shift of a dipole oscillation and the fermionic compressibility in a Bose-Fermi super fluid mixture. Our results show that the A transition occurs in such a system, which interprets the perplexing phenomenon observed in the recent experiment [arXiv:1705.04496]. In that experiment,the frequency shift of the bosonic gas was measured with different fermion-fermion s-wave scattering lengths af. The most striking feature of their measurement is that the frequency shift shows a puzzling non-monotonic behavior around 1/kFaf(?)-0.2 with k_F being the Fermi momentum. In the present work, the relation between the bosonic frequency shift and the compressibility of the Fermi gas is revealed by means of the equation of state of the super fluid mixture. Making use of the relation, we find that the compressibility of Fermi gas shows a ∧-like shape around 1/k_Faf(?)-0.2. We would like to stress that no free parameter is used in our calculation and our results can be further testified in a future experiment.     

18.

Relaxation of the analyzing power of the (p, τX) and (p, αX) reactions in the continuum     

《Nuclear Physics A》1986,449(2):251-255

The observed continuous decrease of the analyzing power for the reactions ($\text{p}$, τX) and ($\text{p}$, αX) on ⁹⁰Zr and ²⁰⁹Bi at E_p = 72 MeV as a function of the excitation energy of the final nucleus is described by a phenomenological relaxation process.     

19.

Evolution of the structure of Rb2ZnCl4 over the temperature range 4.2–310 K     

B. Sh. Bagautdinov  V. Sh. Shekhtman 《Physics of the Solid State》1999,41(6):987-993

X-ray diffraction is used to study the temperature dependence of the lattice parameters and the sequence of structural realignments in crystalline Rb₂ZnCl₄ over temperatures of 4.2–310 K. The appearance of and changes in the system of satellite reflexes indicative of structural ordering are studied. Below 74 K, on going into the monoclinic phase (space group A11a), anomalies are observed in the behavior of the lattice parameters, and superstructural reflexes develop with wave vectors q=a ^*/3+b ^*/2+c ^*/2 corresponding to an increase by a large factor in initial parameters a, b, and c of the Pnma-phase. Fiz. Tverd. Tela (St. Petersburg) 41, 1084–1090 (June 1999)     

20.

Study of the 7Be(p, γ)8B and 7Li(n, γ)8Li capture reactions using the shell model embedded in the continuum     

《Nuclear Physics A》1999,651(3):289-319

     

State	$\text{ω}{}_{\mathrm{e}}$	$\text{xω}{}_{\mathrm{e}}$	$\text{B}{}_{\mathrm{e}}$	$\text{α}{}_{\mathrm{e}}$	$\text{r}{}_{\mathrm{e}}\text{(}\text{A}\text{?}\text{)}$
$\text{i}{}^3\text{Π}{}_{\mathrm{g}}$	1707.95	35.00	7.242g	0.222	1.0782
$\text{l}{}^2\text{Π}{}_{\mathrm{g}}$	1703.86	34.97	7.2264	0.2188	1.0794

Optical second harmonic generation studies of the nature of the oxide-covered and clean c(4 × 4) and (2 × 4) reconstructed GaAs(001) surfaces

We report the application of the “epioptic” technique of optical second harmonic generation (SHG) to the study of surface chemical processes occurring at the technologically important (001) surfaces of the non-centrosymmetric compound semiconductor GaAs. SHG has been used to monitor the thermal removal of surface contamination from an GaAs(001) substrate mounted in a conventional molecular beam epitaxy (MBE) chamber. Rotational anisotropy plots of the reflected SH signal recorded at near-normal incidence indicate that the oxide layer is not fully disordered and possesses some structural anisotropy, i.e. some preferred net surface orientation. In addition the rotational anisotropy plots were observed to change in both intensity and apparent phase between the oxide-covered surface and the clean reconstructed surfaces. Following heating to 850 K under the background As₂ flux present in the chamber, the SH signal from the clean, reconstructed surface was approximately 5 × weaker than that observed for the contaminated surface and was subsequently found to be insensitive to the reconstruction change between the (2 × 4) and c(4 × 4) surfaces, in agreement with theoretical predictions for surfaces having 2mm and 4mm symmetry, respectively.These data are discussed in terms of the difficulties encountered when attempting to observe a surface SH response from a non-centrosymmetric substrate. The sensitivity of the technique towards the thin oxide overlayer suggests that for overlayers which are likely to possess net oriented in-plane dipoles due to the structural mismatch with the substrate, an SH response may be observed in preference to a bulk response when a normal incidence geometry is employed.     

A study of the reaction (π+, π+ p) in 12C and 6Li

We have measured the angular and momentum distributions of the scattered pions from the reaction ¹²C(π⁺, π⁺p)¹¹B and ⁶Li(π⁺, π⁺ p)⁵He in a coincidence experiment. We compare our results with the plane and distorted wave impulse approximations.     

H2-broadening,shifting and mixing coefficients of the doublets in the ν2 and ν4 bands of PH3 at room temperature

The broadening, shifting and mixing coefficients of the doublet spectral lines in the ν₂ and ν₄ bands of PH₃ perturbed by H₂ have been determined at room temperature. Indeed, the collisional spectroscopic parameters: intensities, line widths, line shifts and line mixing parameters, are all grouped together in the collisional relaxation matrix. To analyse the collisional process and physical effects on spectra of phosphine (PH₃), we have used the measurements carried out using a tunable diode-laser spectrometer in the ν₂ and ν₄ bands of PH₃ perturbed by hydrogen (H₂) at room temperature. The recorded spectra are fitted by the Voigt profile and the speed-dependent uncorrelated hard collision model of Rautian and Sobelman. These profiles are developed in the studies of isolated lines and are modified to account for the line mixing effects in the overlapping lines. The line widths, line shifts and line mixing parameters are given for six A₁ and A₂ doublet lines with quantum numbers K = 3n,?(n = 1,?2, …) and overlapped by collisional broadening at pressures of less than 50 mbar.     

Resonant charge transfer in slow Li~+–Li(2s) collision

The resonant charge transfer process for Li+–Li(2s) collision is investigated by the quantum-mechanical molecular orbital close-coupling(QMOCC) method and the two-center atomic-orbital close-coupling(AOCC) method in an energy range of 1.0 e V/u–104e V/u. Accurate molecular structure data and charge transfer cross sections are given. Both the allelectron model(AEM) and one-electron model(OEM) are used in the QMOCC calculations, and the discrepancies between the two models are analyzed. The OEM calculation can also give a reliable prediction of the cross sections for energies below 1 ke V/u.     

X-Ray spectral and theoretical investigations of the electronic structure of phenylcyclosilanes (SiPh2) n (n = 4–6)

The X-ray emission SiKα_{1, 2} and SiKβ₁ spectra of a series of phenylcyclosilanes (SiPh₂) _n (n = 4–6) have been obtained. Using the results of quantum-chemical calculations in the density functional theory approximation, the fine structure of SiKβ₁ spectra has been interpreted. Distributions of densities of electron states of silicon atoms over the valence band have been constructed and the types of chemical bonds providing the Si-Si and Si-Ph interactions have been established. Based on the theory of natural bond orbitals, the chemical bonding in the studied series of phenylcyclosilanes has been analyzed.     

Physics and Performance of the Upgraded T2K’s Near Detector

Physics of Atomic Nuclei - Tokai-to-Kamioka (T2K) is a long-baseline neutrino oscillation experiment currently ongoing in Japan. T2K has been the first experiment to detect the appearance of...     

Dipole Oscillation in a Bose–Fermi Superfluid Mixture of ~(41)K and ~6Li

We study the relation between the bosonic frequency shift of a dipole oscillation and the fermionic compressibility in a Bose-Fermi super fluid mixture. Our results show that the A transition occurs in such a system, which interprets the perplexing phenomenon observed in the recent experiment [arXiv:1705.04496]. In that experiment,the frequency shift of the bosonic gas was measured with different fermion-fermion s-wave scattering lengths af. The most striking feature of their measurement is that the frequency shift shows a puzzling non-monotonic behavior around 1/kFaf(?)-0.2 with k_F being the Fermi momentum. In the present work, the relation between the bosonic frequency shift and the compressibility of the Fermi gas is revealed by means of the equation of state of the super fluid mixture. Making use of the relation, we find that the compressibility of Fermi gas shows a ∧-like shape around 1/k_Faf(?)-0.2. We would like to stress that no free parameter is used in our calculation and our results can be further testified in a future experiment.     

Relaxation of the analyzing power of the (p, τX) and (p, αX) reactions in the continuum

The observed continuous decrease of the analyzing power for the reactions ($\text{p}$, τX) and ($\text{p}$, αX) on ⁹⁰Zr and ²⁰⁹Bi at E_p = 72 MeV as a function of the excitation energy of the final nucleus is described by a phenomenological relaxation process.     

Evolution of the structure of Rb2ZnCl4 over the temperature range 4.2–310 K

X-ray diffraction is used to study the temperature dependence of the lattice parameters and the sequence of structural realignments in crystalline Rb₂ZnCl₄ over temperatures of 4.2–310 K. The appearance of and changes in the system of satellite reflexes indicative of structural ordering are studied. Below 74 K, on going into the monoclinic phase (space group A11a), anomalies are observed in the behavior of the lattice parameters, and superstructural reflexes develop with wave vectors q=a ^*/3+b ^*/2+c ^*/2 corresponding to an increase by a large factor in initial parameters a, b, and c of the Pnma-phase. Fiz. Tverd. Tela (St. Petersburg) 41, 1084–1090 (June 1999)