Periodic deformation and viscous flow of polymer solutions and melts

The transition from the start of deformation to the establishing of a stationary state of nonlinear, periodic shear deformation and the kinetics of the change in the mechanical characteristics after deformation at finite amplitudes has ceased have been investigated. The calculated values have been compared with those obtained experimentally.For Communication 2 see [3].Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Institute of Mechanics Problems, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 3, pp. 521–529, May–June, 1970.     

Experimental determination of the influence of periodic shear deformation and filling on the effective viscosity of solutions of synthetic rubber

The influence of periodic shear deformation on the effective viscosity of filled solutions of synthetic rubber has been studied. The study was carried out on an amplitude-frequency viscosimeter developed by the authors. It has been established that during periodic deformation a linear region exists in which the effective viscosity is independent of the vibration rate, and a nonlinear region where the effective viscosity of the solutions decreases with increase in amplitude of the speed of relative deformation.Presented at the IV Symposium on Rheology of Polymers at the A. V. Topchiev Institute for Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow, May 27–30, 1969.Institute for Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 3, 514–520, May–June, 1970.     

Periodic deformation and viscous flow of polymer melts and solutions (communication 1)

The principles of the theory of thixotropy are formulated. The basic relations are obtained for cases of periodic vibration superimposed on shear flow. The effect of stationary shear flow on the linear dynamic characteristics of an elastic liquid is investigated. The calculated values are compared with the experimental data.Institute of Problems of Mechanics, Academy of Sciences of the USSR, Moscow. Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 3, pp. 519–527, May–June, 1969.     

Possible flow mechanisms of polymer solutions and melts

The experimental results on combined parallel stationary flow and linear periodic deformation are analyzed. The correlation limits of the frequency viscoelastic functions and the stationary flow characteristics, determined by the flow mechanisms at different shear rates, are established.Presented at the 5th Symposium on Rheology, Moscow, May, 1970.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 3, pp. 546–549, May–June, 1971.     

High-frequency periodic deformation of polymers in the viscous-flow state

The propagation of high-frequency periodic vibrations in melts and solutions is considered in the case where the acoustic characteristics of the material are determined by the deformation amplitude. It is shown that in sufficiently large specimens the consequences of periodic deformation are concentrated near the vibration source, as a result of which a layer of material with strongly modified mechanical characteristics develops. It is suggested that when periodic high-frequency deformation is superimposed on steady-state flow, owing to the presence of a boundary layer there is effective slippages of the material at the vibration-emitting surfaces.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 4, pp. 722–728, July–August, 1973.     

Variation of the elasticoviscous characteristics of a heavily filled rubber after periodic shear deformation

The results of an investigation of the recovery of the elasticoviscous characteristics after thixotropic reduction by periodic deformation in the nonlinear zone are reported. The rate of recovery of the mechanical properties depends on the deformation frequency and the previous history of dynamic deformation is shown to affect the dependence of the elasticoviscous characteristics on the shear rate gradient. The effects of stationary and dynamic deformation regimes on the relaxation spectrum of the material are compared.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 3, pp. 528–533, May–June, 1969.     

Nonlinear periodic deformation of thixotropic media

The experimental procedure and the processing of results on the nonlinear periodic deformation of polymeric and dispersed system melts are examined. Experimental data are given on the effect of the amplitude of harmonic deformation on nonlinear stress distortions.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 4, pp. 689–696, July–August, 1972.     

Variation of the frequency and amplitude of periodic deformation in a Weissenberg rheogoniometer

The stresses that develop in the material due to changes in the frequency or amplitude of periodic deformation in a Weissenberg rheogoniometer are described. Examples of stress buildup and relaxation are presented for a filled low-density polyethylene melt.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 5, pp. 936–938, September–October, 1970.     

Thixotropy of filled-polyethylene melts subjected to periodic shear deformation

As a result of the action of periodic finite-amplitude shear deformations filled high-pressure polyethylene melts exhibit thixotropic properties. The effect of the previous deformation history on the frequency dependence of the complex dynamic shear modulus is investigated.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR Riga. Translated from Mekhanika Polimerov, Vol. 4, No. 5, pp. 927–931, September–October, 1968.     

Periodic shear deformation of a curing epoxy composition

The curing of an epoxy resin with amines is investigated in relation to the changes in the viscoelastic shear characteristics. The effect of the shear deformation amplitude on the curing kinetics is considered.Presented at the Symposium on Polymer Rheology, Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow, May, 1970.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 2, pp. 301–306, March–April, 1971.     

Periodic simple shear deformation of polymers in the visco-fluid state

Research on the periodic deformation of polymers in the linear and nonlinear regions is reviewed. Special attention is given to the boundary of the region of linear deformation and to deformation in the nonlinear region. It is shown that deformation in the nonlinear region leads to a reversible fall in the viscosity and elasticity of the system due to the selective destruction of certain types of structural bonds. The effect of mineral fillers and the nature of their surfaces on the mechanical characteristics of polymers in the visco-fluid state is stressed. Use of the theory of thixotropy makes it possible to describe the mechanical characteristics of melts in the regions of nonlinear periodic deformation and combined periodic and steady-state deformation on the basis of the results of trivial rheological measurements.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, Vol. 5, No. 1, pp. 182–188, January–February, 1969.     

Periodic axial and shear deformation of polymers in the viscous-flow state

Results are given of an experimental investigation of the combined periodic axial and shear deformation of polymers in the viscous-flow state. Specimens in the form of right cylinders were disposed between two parallel plates to which the material adhered completely. The experimental data are compared with those obtained under simple shear. The results indicate that, with combined periodic axial and shear deformation, nonlinear shear deformations affect the axial viscoelastic properties and nonlinear axial deformations affect the shear properties of the material.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 5, pp. 880–885, September–October, 1972.     

Polyethylene deformation under proportional and sequential tension and torsion

Experiments were conducted to determine the components of the elasticity tensor of higher orders within a 10–60°C temperature range. It was determined that the characteristics of the material obtained by simple stress fail to describe the deformation process under complex stress.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 3, pp. 399–403, May–June 1970.     

Volume strains of polymers under short-time loading

The effect of the magnitude of the stress, the type of stress, and the previous loading history on the nonlinear deformation characteristics, the lateral strain coefficient, and the volume strains of two crystalline polymers has been investigated.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 5, pp. 828–833, September–October, 1974.     

Effect of steady-state flow of a polyisobutylene solution on its dynamic characteristics measured in the direction of flow

The effect of steady-state flow on the linear dynamic characteristics of a 10% solution of polyisobutylene in cetane, measured in the direction of flow, is investigated. The material characteristics in steady-state flow quantitatively describe the dynamic viscosity and elasticity at deformation frequencies small as compared with the steady-state shear rate.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 5, pp. 913–919, September–October, 1970.     

Dependence of elastic and strength characteristics of high-modulus composites on schemes of reinforcement

The elastic and strength characteristics of high-modulus composites with 12 different reinforcement schemes have been studied thoroughly. The effect of reinforcement schemes on change in elastic and strength characteristics of composites has been evaluated. A calculation of the elastic characteristics of high-modulus composites has been performed from the properties of the reinforcement and binder, and a comparison of the results with experimental data is given. Diagrams of deformation upon extension of the composites studied are given.All-Union Scientific-Research Institute of Aviation Materials, Moscow. Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 6, pp. 1019–1027, November–December, 1974.     

Glass-reinforced plastic high-pressure tanks

The design and fabrication of lens-shaped tanks are described. The results of an investigation of the deformation and strength of the tanks are presented together with the data of cyclic tests.Institute of Mechanics, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Mekhanika Polimerov, No. 1, pp. 149–152, January–February, 1970.     

Numerical characteristics of the degree of anisotropy of the mechanical properties of materials

Conclusions 1. A unique procedure for determination of the numerical characteristics of the degree of anisotropy of the strength and deformation properties of materials is proposed.2. The concepts of the deformability surface and the anisotropy surface of the deformability permit representing graphically the deformation properties of materials.3. The system of integral characteristics of the mechanical properties of materials opens up new possibilities in connection with the analysis and optimization of different reinforcement schemes.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 4, pp. 601–609, July–August, 1978.     

Thermal conductivity of reinforced media

On the basis of a model of an inhomogeneous body a solution is obtained for the problem of the temperature field and thermal conductivities of reinforced media, whose structure is formed by a doubly periodic system of n hollow cylinders of arbitrary diameter with the space between filled by a homogeneous medium. The thermophysical characteristics of the components are assumed given.Institute of Mechanics, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Mekhanika Polimerov, Vol. 4, No. 4, pp. 749–751, July–August, 1968.     

Some negative characteristics of fiber-reinforced materials

The effect of low resistance to shear and tension-compression at right angles to the layers of reinforcement on the state of stress and strain of elements composed of fiber-reinforced materials is analyzed. It is shown that to take these characteristics into account the calculations must be refined. In certain cases this leads to the appearance of qualitatively new effects. Typical problems in which the negative characteristics of the material must be allowed for are examined.Review of research conducted in the Polymer Structures Laboratory of the Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, Vol. 5, No. 1, pp. 140–149, January–February, 1969.