Is the (hfac)Cu(I)–(tmvs) bond intrinsically weak?

Density functional theory studies were performed to study the structure and bonding of (hexafluoroacetylacetonate)-copper(I)-(trimethylvinylsilane) [Cu(hfac)(tmvs)], an ideal and important Cu(I)-CVD compound. A popular three-parameter hybrid density functional (B3LYP) with 6-311+G(d,p) and an effective core potential included LanL2DZ basis set was utilized for this purpose. The (hfac)Cu–(tmvs) bond energy of approximately 30?kcal?mol^?1 obtained at the B3LYP/6-311+G(d,p) level of theory reveals that the Cu–olefin bond in Cu(hfac)(tmvs) is not as weak as previously estimated/assumed and, hence, that the substrate plays a vital role in copper film formation from Cu(hfac)(tmvs). Bonding analysis reveals that fairly strong (hfac)Cu–(tmvs) bonding is the result of DCD-model σ-donation and π-back-bonding between the copper and tmvs in Cu(hfac)(tmvs).     

How to Determine the Spin of the ξ(2230)

The possibility for increasing the statistics by summing up the events of decaying into two pseudo scalar mesons from the existing data samples is discussed.     

Interpretation of Z_b(10610)and Z_b(10650)in the ISPE mechanism and the Charmonium Counterpart~

The initial single pion emission(ISPE) mechanism is applied to the processes γ(55)→πB~((*))B~((*)),whose details have been recently reported at ICHEP2012,and we obtain reasonable agreement with Bell's measurements;that is,we succeed in reproducing the enhancement structures of Zb(10610) and Zb(10650).Inspired by this success,we also predict the corresponding enhancement structures in open charm one-pion decays of higher charmonia near the thresholds of D*D and D*D*.     

Hyperons Analogous to the Λ(1405)

The low mass of the Λ(1405) hyperon with j ^P =  1/2^?, which is higher than the ground state Λ(1116) mass by 290 MeV, is difficult to understand in quark models. We analyze the hyperon spectrum in the bound state approach of the Skyrme model that successfully describes both the Λ(1116) and the Λ(1405). This model predicts that several hyperon resonances of the same spin but with opposite parity form parity doublets that have a mass difference of around 300 MeV, which is indeed realized in the observed hyperon spectrum. Furthermore, the existence of the ${\Xi(1620)}$ and the ${\Xi(1690)}$ of j ^P  = 1/2^? is predicted by this model. Comments on the Ω baryons and heavy quark baryons are made as well.     

On the role of the Δ(1232) on the transverse nuclear response in the (e,e′) reaction

The transverse nuclear response to an electromagnetic probe which is limited to create (or destroy) a particle-hole (ph) or delta-hole (Δh) pair is analyzed. Correlations of the random phase approximation (RPA) type and self-energy insertions are considered. For RPA correlations we have developed a scheme which includes explicitly the Δ and the exchange terms. Self-energy insertions over ph and Δh bubbles are studied. Several residual interactions based on a contact plus a (π + ϱ)-meson exchange potential are used. All calculations are performed in non-relativistic nuclear matter. The main effect of the Δ is to reduce the intensity over the nuclear quasi-elastic peak. Exchange RPA terms are very important, while the terms with self-energy insertions depend strongly on the residual interaction employed. Our results are compared with data for ⁴⁰Ca at momentum transfer q = 410 and q = 550 MeV/c, where the longitudinal response is also briefly discussed.     

Comment on the quark masses in the SU(5)×U(1) model derived from the 4D fermionic superstring

In this letter, the problems of the up-quark and neutrino mass matrix, as well as the lepton non-conservation are discussed within the N=1 supersymmetric SU(5)×U(1) model derived from the four-dimensional fermionic superstring.     

Violation of the Okubo-Zweig-Iizuka rule in the decay mode B(1235) →φ(1020) +π

The Okubo-Zweig-Iizuka rule forbids the transitionB(1235)→φπ. Unitarity, however, induces a non-vanishing amplitude forB→φπ. We estimate the amplitude using dispersion relation. The absorptive part is shown to be small contributing less than 100 keV to the partial width Γ (B→φπ). For the dispersive part we evaluate the contributions of the and intermediate states and point out that the state does not contribute significantly. The dispersive part contributes about 300 keV to the partial width. Thus unitarity correction to the Okubo-Zweig-Iizuka rule gives the partial width Γ(B→φπ) to be around 300–400 keV compared with the present experimental upper limit of 1·9 MeV.     

Isolating the Λ(1405) in lattice QCD

The odd-parity ground state of the Λ baryon lies surprisingly low in mass. At 1405 MeV, it lies lower than the odd-parity ground-state nucleon, even though it has a valence strange quark. Using the PACS-CS (2+1)-flavor full-QCD ensembles, we employ a variational analysis using source and sink smearing to isolate this elusive state. For the first time we reproduce the correct level ordering with respect to nearby scattering thresholds. With a partially quenched strange quark to produce the appropriate kaon mass, we find a low-lying, odd-parity mass trend consistent with the experimental value.     

Critical phenomena in the β-(2×4) → α-(2×4) reconstruction transition on the (001) GaAs surface

The critical exponents of the β-(2×4) → α-(2×4) reconstruction phase transition on the (001) GaAs surface are determined experimentally. It is found that the phase transition is analogous to a van der Waals transition. The critical parameters T _c , P _c , and Θ_c have been measured experimentally. The mean field theory is applied, and three-parameter isotherms are obtained that agree with the experimental results at the following values of the parameters: E_st = 0.36 eV, ΔE = 0.18 eV, and E _i = 0.134 eV. Precision measurements of the critical exponents β and δ are carried out. Their values β = 1/8 and δ = 15 indicate that the phase transition is truly two-dimensional.     

Photo-induced effect in the layered perovskite manganite La_(1.2)Sr_(1.8)Mn_(1.8)Co_(0.2)O_7

1IntroductionWiththediscoveryofcolossalmagnetoresistance(CMR)effectinmanganites,hole-dopingperovskitemanganiteswithunusualelectronictransportandmagneticpropertieshaveattractedconsiderableattention.Thesepropertiesresultfromanintrinsicinteractionbetweencharge,spin,orbitalandlatticedegreesoffreedomthatarestronglycoupledtoeachother[1—6].DoubleexchangemodelcombinedwithJohn-Tellereffectwasusedtoexplainthesepropertiespartly[7—9].InordertogetbetterunderstandingofthemechanismofCMReffect,externals…     

Estimate of the Δ(1232) component in the 12C nucleus

The cross section for the ¹²C(γ, π⁺ p) reaction was measured in the range of the Δ(1232) isobar. The data were analyzed using the models taking into account the nucleon and isobaric degrees of freedom of the ¹²C nucleus. The conclusion is drawn that in the large-momentum transfer range the π⁺ p pairs are produced in the course of the direct knocking-out of Δ⁺⁺ isobar from the nucleus. The probability of finding the Δ isobar in the ground-state ¹²C nucleus is estimated at 0.018±0.005 Δ isobars per nucleon.     

Phenomenology of the hierarchical lepton mass spectrum in the flipped SU(5)×U(1) string model

A detailed phenomenological analysis of the lepton mass matrices and their implications in the low energy theory are discussed, within the recently proposed SU(5)×U(1) string model. The unification scale is highly constrained while the Yukawa couplings lie in a natural region. The flavour changing decays μ→eγ, μ→3e, μ→e are highly suppressed while the depletion in the in the flux of muon neutrinos reported by the Kamiokande is explained through ν_μ↔ν_τ oscillations.     

Microfacets of the (1 × 2) reconstructed Pt(110) surface seen in the adsorption dynamics of H2

We have detected a strong azimuth dependence of the adsorption dynamics of hydrogen on a Pt(110)(1×2) surface. Adsorption on the (1 ×2) reconstructed surface is found to be governed by the (111) microfacets of the missing row structure. Furthermore we have observed a low temperature α-state in the thermal desorption spectra comparable to the α-states for other fcc (110) surfaces.     

Coherent pion electroproduction on the deuteron in the Δ(1232) resonance region

Coherent pion electroproduction on the deuteron is studied in the ((1232) resonance region in the impulse approximation, i.e., neglecting pion rescattering and two-body effects. The elementary reaction on the nucleon is described in the framework of an effective Lagrangian approach including the dominant P₃₃(1232) resonance and the usual background terms of the Born contributions for ?⁰ production. We have studied the influence of these different contributions on the various structure functions which determine the unpolarized exclusive differential cross section in a variety of kinematic regions.     

Spontaneous SU(2) symmetry violation in the SU(2) L × SU(2) R × SU(4) electroweak model

A new approach to electroweak (EW) composite scalars is developed starting from the fundamental gauge interaction on high scale. The latter is assumed to have the group structure SU(2) _L × SU(2) _R × SU(4), where SU(4) is the Pati-Salam color-lepton group. The topological EW vacuum filled by instantons is explicitly constructed and the resulting equations for fermion masses exhibit spontaneous SU(2) flavor symmetry violation with possibility of very large mass ratios.     

Dispersion of the oxygen-induced bands on Cu (110) - an angle-resolved ups study of the system p(2×1)O/Cu(110)

The two-dimensional electronic energy bands induced by adsorption of atomic oxygen on Cu(110) are measured with angle-resolved photoelectron spectroscopy (ARUPS). Three oxygen-derived bonding bands and two Cu - derived antibonding bands are found below the Fermi energy. The dispersions can be described by assuming nearest-neighbour σ and π CuO bonds along the [001] direction with oxygen in a long bridge site.