吡啶酰胺在Cd(Ⅱ)存在下的醇解反应及结构表征（英文）

X-射线晶体结构分析表明,在90℃的水热条件下,N-(8-喹啉基)吡啶-3-酰胺在Cd2+的存在下发生醇解.醇解产物为8-氨基喹啉(HL1)和吡啶-3-羧乙酯(HL2),它们与Cd (Ⅱ)配位形成四方锥型化合物.该配合物为单斜晶系,空间群P21/c.a=18.1089(1)A,b=8.9986(1)A,c=19.3070(2)A,β=113.085(1)和Z=4.     

含硫代酰胺的新三唑类化合物的合成、结构表征及生物活性研究

由取代苯乙酮出发，经过多步反应，制得2-苯甲酰基-N-苯基-2-(1,2,4-三唑-1-基)硫代乙酰胺 (1) 和2-(4-氯苯甲酰基)-N-苯基-2-(1,2,4-三唑-1-基)硫代乙酰胺 (2), 通过元素分析、核磁共振氢谱、红外光谱和质谱进行表征。并利用单晶X射线衍射法测定化合物1。晶体属单斜晶系, P2₁/c空间群, a = 0.8806(2) nm, b = 1.2097(2) nm, c = 1.4809(3) nm, β=105.88˚, Z=4, V=1.5173(6) nm³, D_c=1.411 Mg/m³, μ=0.22 mm^-1, F(000)=672, R₁=0.040. 采用离体平皿法对它们的杀菌活性进行了比较，同时测定了它们的植物生长调节活性。测定结果表明化合物2对黄瓜子叶生根具有较强的促进作用，促进率达131％。     

具有新结构类型的化合物CsIn[PO3(OH)]2的合成与结构(英)

水热法合成了新结构类型化合物CsIn[PO₃(OH)]₂，并通过单晶X-射线衍射表征结构。标题化合物空间群为P1 2₁/c 1 (No.14)，晶体学参数为：M_r=439.69，mP56，a=0.532 86(6) nm，b=0.916 53(7) nm，c=1.478 39(14) nm，β=93.849(9)°，V=0.720 4(1) nm³，Z=4，D_x=4.054 g·cm^-3，μ=8.713mm^-1，F(000)=800，R₁= 0.032 5，wR₂=0.087 4。在该化合物中，2个InO₆八面体和4个PO₄四面体形成交连的六元环柱，并沿a轴方向形成近六方密堆积并连接成Cs⁺离子占据的十二元环结构隧道，六元环和十二元环连接构筑了三维网络结构。与类似化学计量比化合物Na₂In₂[PO₃(OH)]₄·H₂O比较，标题化合物中十二元环的形成明显取决于隧道阳离子的大小，其拓扑构造可看作扩展的6，3-网格连接，化合物 RbIn[PO₃(OH)]₂与之同构。     

N-(6-氯吡啶-3-基)羰基-2-取代芳基磺酰胺的合成、结构及除草活性研究

通过6-氯吡啶-3-甲酸与2-取代芳基磺酰胺的缩合反应合成了5个N-(6-氯吡啶-3-基)羰基-2-取代芳基磺酰胺化合物3a～3e, 产物结构经元素分析, ¹H NMR, IR确证. 由X射线衍射法测定了化合物3a的晶体结构, 该晶体属于三斜晶系, 空间群为 . 以测试除草活性常用的植物玉米、黄瓜和油菜为试材测定了目标化合物的除草活性, 初步试验表明3a～3d有较好的活性, 而且它们对双子叶植物的抑制作用优于对单子叶植物.     

酰胺型配体的镍(Ⅱ)和锌(Ⅱ)配合物的合成、晶体结构及荧光性质

合成并通过单晶衍射表征了配合物[M(nbqa)(NO3)(H2O)2]NO3(M=Ni,1;Zn,2;nbqa=N-苄基-2-(8-喹啉氧基)乙酰胺)。在配合物1和2中,金属离子采取扭曲的八面体配位构型。来自配体nbqa的1个氧原子和2个氮原子,来自硝酸根的1个氧原子及来自2个配位水分子的氧原子和中心金属离子配位。乙腈溶液中配合物2在430 nm有强荧光发射。     

N,N''''-双(4-甲基-2-苯并噻唑基)-2,6-吡啶二酰胺钴(Ⅱ) 配合物的合成和晶体结构

0IntroductionCobaltcomplexeswithnonmacrocyclicchelatingligandscontainingtheamidefunctionalityhavere鄄ceivedmuchattentioninpastyears[1~3].Somestudieshaverevealedthatdeprotonatednitrogensoforganicamides,beinganionicinnature,arecapableofstabi鄄lizingthetriva…     

具有二维网格结构的5-(4-硝基苯基)四唑-锌(Ⅱ)配合物

A zinc(Ⅱ) complex [(5-(4-nitrophenyl)tetrazolato)₂Zn]_n was obtained by the hydrothermal treatment of ZnBr₂ and NaN₃ with 4-nitrobenzonitril in water at 120 ℃ in Pyrex tube. The crystal belongs to orthorhombic system with space group Pbcn, and a=1.040 7(5) nm, b=1.382 1(7) nm, c=2.435 1(13) nm, V=3.503(3) nm³, Z=8. This complex is a good blue fluorescent material in solid state at room temperature. CCDC: 684226.     

3,5-二氨基苯甲酸构筑的Zn(Ⅱ)、Cd(Ⅱ)两种配合物的合成及晶体结构(英文)

利用3,5-二氨基苯甲酸配体合成了2种新的配合物[Cd(diaba)(phen)2]NO3·H2O(1)和[Zn(diaba)(2,2′-bipy)2](2)(H2diaba=3,5-diaminobenzoic acid;phen=1,10-phenanthroline,2,2′-bipy=2,2′-bipyridine),并对其进行了元素分析、红外光谱和X射线单晶衍射测定。配合物1属于正交晶系,空间群为Fddd,a=1.425 81(7)nm,b=2.564 62(13)nm,c=3.092 47(17)nm。配合物2属于单斜晶系,空间群为C2/c,a=1.273 62 nm,b=1.592 78 nm,c=1.519 35 nm,β=107.334°。配合物1和2都为单核晶体。配合物1的结构单元由1个CdII、1个3,5-二氨基苯甲酸和2个phen构成。配合物2的结构单元由1个ZnII、1个3,5-二氨基苯甲酸和2个2,2′-bipy构成。两种配合物再通过氢键或π-π堆积形成三维超分子网络。研究了配合物的热稳定性和荧光性质。     

N，N′-双(4-甲基-2-苯并噻唑基)-2，6-吡啶二酰胺钴(Ⅱ)配合物的合成和晶体结构(英)

Treatment of deprotonated N，N′-bis(4-methyl-2-benzothiazolyl)-2, 6-pyridicarboxamide (L^2-) with CoCl2·6H2O yields the mononuclear complex, (Et₄N)₂[CoL₂]·0.5H₂O. Single crystal X-ray structural determination has been carried out for the complex, crystal system: Monoclinic, space group: P2₁/c, a=1.444(1) nm, b=1.969(1) nm, c=2.448(1) nm, β=118.02(1)°, V=6.143 0(15) nm³, Z=4. In this complex, the central Co(Ⅱ) atom is in an octahedron environment, with four deprotonated amide-N atoms in the equatorial plane and two pyridine-N atoms in the axial positions. CCDC: 252558.     

新型手性多元β-酰胺醇的合成

用两种方法合成了7个新型的手性多元β-酰胺醇。方法1是多元羧酸与SOCl2反应形成相应的多元酰氯,然后与手性α-氨基醇反应合成了目标物,产率为3·7%~78·8%。方法2是在N2保护120~145℃下,多元羧酸与手性α-氨基醇反应3~12h,一步反应合成了目标物,产率为71·2%~95·7%。     

Investigation of Copper Halide:Hydrothermal Syntheses and Characterization of CuBr2(C12H8N2) and Cu3Br3(C12H8N2)2

The reaction of CuBr₂ with 1,10‐phen‐H₂O (1,10‐phen = 1,10‐phenanthroline) gave two compounds: CuBr₂(C₁₂H₈N₂) and Cu₃Br₃(C₁₂H₈N₂)₂. Their structures have been characterized by single‐crystal X‐ray diffraction analysis, elemental analyses, thermogravimetric analyses (TGA) and measurement of variable temperature magnetic susceptibility. Crystal data for CuBr₂(C₁₂‐H₈N₂): monoclinic, space group P2₁/n, a = 0.9977(3) nm, b = 0.65138(14) nm, c = 1.8207(4) nm, β = 91.624(18)°, V = 1.1828(5) nm³, Z = 2. Crystal data for Cu₃Br₃(C₁₂H₈N₂)₂: monoclinic, space group C2/c, a = 1.00167(11) nm, b = 1.4523(4) nm, c = 1.6295(3) nm, β = 94.386(14)°, V = 2.3635(8) nm³, Z = 3.     

Synthesis and Structural Characterization of a New Polyoxovanadium Borate: (H_3NCH_2CH_2NH_3)_4[(VO)_6(B_(10)O_(22))_2]·(H_3O)_7

1 INTRODUCTION Transition metal oxide clusters and their deriva- tives offer an unmatched variety of structural motifs and wide ranging applications in several areas, such as analytical chemistry, materials science and cataly- sis, nanotechnology, chemical sensing, environmental decontamination, biochemical and geochemical pro- cesses, and medicine[1～3]. Polyoxovanadates or vana- dium oxide clusters constitute an important subclass of polyoxometalates and have been studied exten- sively.…     

基于3，4-吡啶二羧酸的二维层状聚合物的合成和晶体结构

A metal-organic coordination polymer {[La(PDC)(N-HPDC)]·H₂O}_n (1) (H₂PDC=pyridine-3,4-dicarboxylic acid) has been hydrothermally synthesized and structurally characterized by X-ray diffraction single-crystal structure determination, elemental analyses and IR spectroscopy. The complex crystallizes in the monoclinic system, space group P2₁/c with a=1.452 8(2) nm, b=0.681 59(11) nm, c=1.464 0(2) nm, β=94.270(2)°, V=1.445 6(4) nm³, D_c=2.243 Mg·m^-3, Z=4, M_r=488.14, F(000)=944, μ(Mo Kα)=3.015 mm^-1, R=0.031 0 and wR=0.076 2 for 2 424 observed reflections (I>2σ(I)). There are La-O-C-O-C-La double chains in the complex. The chelating carboxylate O atoms and pyridyl N atoms lead the compound to 2D layers structure, which is extended to 3D supramolecular architecture through intermolecular hydrogen bonds. It is interesting that the polymer containing one-dimensional channels. CCDC: 708868.     

具有[3~4~48~4]笼状结构单元的微孔磷酸镓Ga_3P_2O_8(OH)_3(H_2O)的合成、晶体结构及表征

开放骨架结构金属磷酸盐不仅具有丰富的结构和组成多样性,而且在吸附、分离、和催化等方面具有潜在的应用前景[1￣3]。同磷酸铝一样[2,3],磷酸镓是开放骨架磷酸盐中一个重要的家族,其结构主要由交替的GaOn多面体(GaO4,GaO5及GaO6)和PO4四面体构成。目前,已有近百种磷酸镓在水热/溶剂热体系下成功的合成出来[4￣8],其中最著名的例子是具有二十员环超大孔磷酸镓Cloverite[5]。这些磷酸镓不仅具有结构上的新颖性,同时还具有丰富的组成计量比(Ga/P:1/2￣3/2)[9],它们的结构由多种次级结构单元(SBU)构成,拓扑相关性为定向设计提供了重要基…     

Hydrothermal Synthesis and Structure Analysis of a Chromium Complex [Cr(aea)]2(OH)2(aea=N-(2-Aminoethyl)aspartate)

A dimeric chromium compound has been synthesized by hydrothermal method and characterized by IR,EPR spectra and TG-DTA technique.The title compound [Cr(aea)]2(OH)2(aea=N-(2-aminoethyl)aspartate)crystallizes in monoclinic,space group P21/c with a=8.9393(10),b=6.7198(7),c=14.6791(16)(A),β=91.0580(10)°,V=881.63(17)(A)3,Z=2,Mr=486.34,Dc=1.832g/cm3,F(000)=500,μ=1.296 mm-1,R=0.0271 and wR=0.0756.Single-crystal X-ray structural analysis indicates that the title compound consists of two Cr(aca)units linked by two bridging hydroxyl groups.The geometry around each chromium center is approximately octahedral and completed by two hydroxyls and a quadridentate ligand which is formed when ethylenediamine reacts with maleie acid.     

Hydrothermal Synthesis and Structure Analysis of a Chromium Complex [Cr（aea）]2（OH）2 （aea = N-（2-Aminoethyl）aspartate）

A dimeric chromium compound has been synthesized by hydrothermal method and characterized by IR, EPR spectra and TG-DTA technique. The title compound [Cr（aea）]2（OH）2 （aea = N-（2-aminoethyl）aspartate） crystallizes in monoclinic, space group P21/c with a = 8.9393（10）, b = 6.7198（7）, c = 14.6791（16） A, β = 91.0580（10）°, V= 881.63（17） A3, Z= 2, Mr = 486.34, De= 1.832 g/cm3, F（000） = 500,μ = 1.296 mm-1, R = 0.0271 and wR = 0.0756. Single-crystal X-ray structural analysis indicates that the title compound consists of two Cr（aea） units linked by two bridging hydroxyl groups. The geometry around each chromium center is approximately octahedral and completed by two hydroxyls and a quadridentate ligand which is formed when ethylenediamine reacts with maleic acid.     

一种新颖层状磷酸镓化合物[Ga3(PO4)4](H3NCH2CH2)2NH2的合成与结构表征

晶体结构;水热合成;一种新颖层状磷酸镓化合物[Ga3(PO4)4](H3NCH2CH2)2NH2的合成与结构表征     

Synthesis and Structural Characterization of Two Molybdenum~phosphate Cluster Compounds: (C_(14)N_(14)H_(63) )Na(H_2Mo_6P_4O_(31))_2·8H_2Oand(C_(14)N_(14)H_(63))Na(H_2Mo_6P_4O_(31) )_2·5H_2O

ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｓｙｎｔｈｅｓｉｓａｎｄｓｏｒｐｔｉｏｎｐｒｏｐｅｒｔｉｅｓｏｆｏｐｅｎｆｒａｍｅ ｗｏｒｋｓｏｌｉｄｓｓｕｃｈａｓｚｅｏｌｉｔｅｓ1ａｎｄｍｅｔａｌｍｏｌｙｂｄｅｎｕｍｐｈｏｓ ｐｈａｔｅ2 ,3ｗｉｔｈｌａｒｇｅｃａｖｉｔｉｅｓｐｒｏｖｏｋｅｄｅｎｏｒｍｏｕｓｉｎｔｅｒｅｓｔｂｅ ｃａｕｓｅｏｆｔｈｅｉｒｐｏｔｅｎｔｉａｌａｐｐｌｉｃａｔｉｏｎｉｎｃａｔａｌｙｓｉｓ .Ｏｎｅ ,ｔｗｏ ａｎｄｔｈｒｅｅ ｄｉｍｅｎｓｉｏｎａｌｓｏｌｉｄｃｏｍｐｏｕｎｄｓｃｏｎｓｉｓｔｉｎｇｏ…     

Hydrothermal Synthesis and Crystal Structure of a Cd~(2+) Supramolecular Coordination Complex{[Cd_2(HCAM)_2(H_2O)_4]·3.5H_2O}_n with a 3D Metal-organic Open Framework

<正>A three-dimensional coordination polymer {[Cd_2(HCAM)_2(H_2O)_4]·3.5H_2O}_n was synthesized by the hydrothermal reaction of H_3CAM(H_3CAM=4-hydroxypyridine-2,6-dicerboxylic acid)and Cd(NO_3)_2·4H_2O.The structure was characterized by elemental analysis,thermal gravimetric analysis,infrared spectroscopy and single-crystal X-ray diffraction.It crystallizes in triclinic,space group P_1~-with a= 9.4389(19),b=11.009(2),c=11.192(2)(?),α=87.87(3),β= 74.63(3),γ=81.22(3)°,V=1108.2(4)(?)~3,Z=2,D_c=2.164g/cm~3,μ=2.011 mm~(-1),F(000)=710,R =0.0419 and wR=0.1170.X-ray analysis reveals that the title compound adopts a one-dimensional staircase structure by carboxyl of H_3CAM and water molecules,and it is further linked by hydrogen bonds to form a 3-D metal-organic open framework.The thermal gravimetric analysis displays that the framework exists stably below 300℃.