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Background
Statistical learning is a candidate for one of the basic prerequisites underlying the expeditious acquisition of spoken language. Infants from 8 months of age exhibit this form of learning to segment fluent speech into distinct words. To test the statistical learning skills at birth, we recorded event-related brain responses of sleeping neonates while they were listening to a stream of syllables containing statistical cues to word boundaries.Results
We found evidence that sleeping neonates are able to automatically extract statistical properties of the speech input and thus detect the word boundaries in a continuous stream of syllables containing no morphological cues. Syllable-specific event-related brain responses found in two separate studies demonstrated that the neonatal brain treated the syllables differently according to their position within pseudowords.Conclusion
These results demonstrate that neonates can efficiently learn transitional probabilities or frequencies of co-occurrence between different syllables, enabling them to detect word boundaries and in this way isolate single words out of fluent natural speech. The ability to adopt statistical structures from speech may play a fundamental role as one of the earliest prerequisites of language acquisition. 相似文献2.
M. Abu-Kharma 《Journal of Molecular Spectroscopy》2005,232(2):369-374
Enhancement spectra of the collision-induced absorption (CIA) in the first overtone region 5000-7000 cm−1 of D2 in D2-N2 were studied at 298 K for a base density of D2 of 73 amagat and for partial densities of N2 in the range 150-370 amagat. The observed spectra were modeled with a total of 1176 components of double vibrational transitions. Binary and ternary absorption coefficients were determined from the integrated absorption of the band. Profile analysis of the spectra was carried out using the Birnbaum-Cohen line-shape function for the individual components of the band, and characteristic line-shape parameters were determined from the analysis. Good agreement was obtained between the experimental and calculated spectral profiles. 相似文献
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S. Southworth W.D. Brewer C.M. Truesdale P.H. Kobrin D.W. Lindle D.A. Shirley 《Journal of Electron Spectroscopy and Related Phenomena》1982,26(1):43-51
The photoelectron asymmetry parameters of H2 and D2 have been measured using synchrotron radiation over the photon energy range 19–27 eV. The results are compared with previous measurements and several theoretical calculations. A few of the theoretical calculations are in good agreement with experiment, but most of them predict asymmetries which are too large. Essentially identical β values were measured for H2 and D2. This result is discussed in terms of differences which could arise due to vibrational and rotational structure. 相似文献
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James R. Gillis Ronald D. Blatherwick Francis S. Bonomo 《Journal of Molecular Spectroscopy》1985,114(1):228-233
The infrared spectrum of ν2 of D2S was recorded from 740 to 1100 cm?1 on the University of Denver 50-cm FTIR spectrometer system. We have assigned 655 transitions from D232S and 129 from D234S, and have analyzed them using Watson's A-reduced Hamiltonian evaluated in the Ir representation. We used the recently published D232S and D234S ground state Hamiltonian constants [C. Camy-Peyret, J. M. Flaud, L. Lechuga-Fossat and J. W. C. Johns, J. Mol. Spectrosc.109, 300–333 (1985)]. Upper state Hamiltonian constants were obtained from a fit of the ν2 transitions, keeping the ground state constants fixed while varying the upper state constants. The standard deviation of the D232S ν2 fit is 0.0025 cm?1. The standard deviation of the D234S ν2 fit is 0.0041 cm?1. 相似文献
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Mass spectroscopic studies reveal the role of H2 in HCN-laser plasma. This is confirmed by laser experiments with different gas mixtures containing H2 and D2. 相似文献
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Intensity dependent polarization change and rotation of elliptically polarized light are observed and analyzed in the D1 and D2 resonance lines of sodium. The characteristics of these effects in terms of the difference between self- and cross- saturation coefficients are discussed for transitions with arbitrary values of total angular momentum J. 相似文献
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Generation of UV laser light by stimulated Raman scattering in D2, D2/Ar and D2/He using a pulsed Nd:YAG laser at 355nm 下载免费PDF全文
A pulsed Nd:YAG laser at 355nm is used to pump Raman cell filled with D_2, D_2/Ar and D_2/He. With adequately adjusted parameters, the maximum photon conversion efficiency of the first-order Stokes light (S_1, 396.796nm) reaches 33.33% in D_2/Ar and the stability of S_1 in pure D_2 is fairly high, the energy drift being less than 10% when the pump energy drifts in the range of 5%. The conversion efficiency and stability, which are functions of the composition and pressure of the Raman medium and the energy of pump laser, are investigated. The result has been used to optimize the laser transmitter system for a differential absorption lidar system to measure NO_2 concentration profiles. 相似文献
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The effects of isotopic variants on stereodynamic properties for the title reactions have been investigated using a quasi-classical trajectory method based on the first excited state NH2(I^2A') potential energy surface [Li Y Q and Varandas A J C 2010 J. Phys. Chem. A 114 9644]. The forward–backward symmetry scattering of the differential cross section can be observed, which demonstrates that all these reactions follow the insertion mechanism. Three angle distribution functions P(θr), P(φr), and P(θr, φr) with different collision energies and target molecules H2/D2/T2 are calculated. It is shown that the product rotational angular momentum is not only aligned, but also oriented along the direction perpendicular to the scattering plane. The title reaction is mainly governed by the "in-plane" mechanism through the calculated distribution function P(θr, φr). The observable influences on the rotational polarization of the product by the isotopic substitution of H/D/T can be demonstrated. 相似文献
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Jarmo Lohilahti Toni A. Kainu Veli-Matti Horneman 《Journal of Molecular Spectroscopy》2005,233(2):275-279
The ν2 band of D213CO in the region of 1570-1760 cm−1 has been analyzed with high accuracy. The limits of the quantum numbers J and Ka are 50 and 16, respectively. The number of the assigned transitions is 3858. A local anharmonic resonance ν2/2ν4 at Ka = 8-12 was observed. The Watson’s A-reduced Hamiltonian and anharmonic resonance term were fitted to the observed transitions. The fit resulted in the band center and rotational parameters of the ν2 band as well as the effective parameters for the 2ν4 band and anharmonic resonance parameter. The rms deviation of the transitions in the ν2 band was 0.000364 cm−1. 相似文献
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We studied reaction of oxygen atoms with D-terminated Si(1 1 1) surfaces from a desorption point of view. As the D (1 ML)/Si(1 1 1) surface was exposed to O atoms D2 and D2O molecules were found to desorb from the surface. The desorption kinetics of D2 and D2O molecules exhibited a feature characterized with a quick rate jump at the very beginning of O exposure, which was followed by a gradual increase with a delayed maximum and then by an exponential decrease. The O-induced D2 desorption spectra as a function of Ts appeared to be very similar to the H-induced D2 desorption spectrum from the D/Si(1 1 1) surfaces. Possible mechanisms for the O-induced desorption reactions were discussed. 相似文献
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The coadsorption of PH3 with H2, D2, O2 and H2O on Rh(100) has been studied using temperature programmed desorption (TPD), Auger electron spectroscopy (AES) and low energy electron diffraction (LEED). The adsorption and molecular desorption of PH3 is not affected by preadsorbed H2, D2 and O2. Preadsorbed PH3 blocks H2 desorption sites while postdosed PH3 displaces H2 (D21) from the Rh(100). When D2 and PH3 are coadsorbed, no D appears in desorbed phosphine. Preadsorbed O2 reduces the amount of H2 desorption (from PH3 decomposition) and increases the H2 desorption temperature. There is also some reaction between O(a) and H(a) to form water. Preexposure to H2O decreases the extent of PH3 adsorption and of PH3 decomposition. 相似文献
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The erosion/sputtering of D2 films on an Au-substrate by 2 keV electrons is roughly inversely proportional to film thicknesses below ≈650 Å. The erosion yield decreases from 200 atoms/electron at 25 Å to 7.8 ± 0.5 for “bulk” targets. The thickness dependent region is apparently unrelated to the penetration depth of the electrons. 相似文献
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Bi Peng Xie Duan Lin Wei Wang Kai Liu Jiang-Ping Tang Yong-Jian Yang Xiang-Dong Lei Hai-Le 《中国物理 B》2013,22(3):34401-034401
A specific-wavelength infrared (IR) light (λ=3140 nm) was irradiated into a solid D2 ice prepared in a cylinder target cell. The temperature in the solid D2 ice oscillated periodically with a high amplitude when irradiated by the IR light. The temperature oscillation has been well explained based on the two-dimensional heat transfer theory plus the IR-irradiation effect. The transmission optical imaging reveals that such a temperature oscillation is favorable to recrystallize the solid D2 ice from multicrystal to quasi single crystal. This suggests an efficient method to layer the solid hydrogen-isotope ice for the inertial-confinement-fusion (ICF) experiments. 相似文献
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R. McLeary 《Physics letters. A》1983,99(8):363-366
The collision-induced fluorescence from vibrationally excited D2 in high-pressure mixtures of D2 and Ar has been investigated. Fluorescence intensity and vibrational lifetime have been measured as a function of total gas density and mixture ratio. 相似文献
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Energies and probabilities of Lyman transitions of high rovibrationally excited H2, HD and D2 molecules have been measured and compared with calculations. The experimental results are obtained from laser-induced fluorescence spectra that have been recorded in the spectral range from 60 500 to 83 500 cm−1, covering 2/3 of the hydrogen Lyman band system. The necessary vacuum-UV radiation is produced by stimulated anti-Stokes Raman scattering, providing a widely tunable radiation source with narrow spectral bandwidth to resolve single Lyman transitions. The highest internal energies of detected hydrogen isotopologues are close to the dissociation limit. This extends the available data base of Lyman transitions from and to higher rotational states (J > 10) of HD and D2. 相似文献