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1.
Sorption properties of porous copolymers 1-vinyl-2-pyrrolidone-divinylbenzene (VP-DVB) were investigated by thermogravimetry. Water, n-butanol and n-heptane were used as sorptives. The current studies were performed for VP-DVB copolymers which were synthesized under different condition and vary in terms of porous structure. Additionally, VP-DVB 5 sample has more polar character comparing with other samples. It was demonstrated that porous structure of the adsorbent has the fundamental impact on the adsorption process but not only the value of specific surface area but also the pore diameter plays important role. Sorption of water is enhanced by the presence of micropores and polar character of the adsorbent. 相似文献
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A. I. Skushnikova É. I. Brodskaya V. V. Dorokhova E. S. Domnina G. G. Skvortsova 《Russian Chemical Bulletin》1979,28(6):1290-1291
Conclusions Using the IR spectroscopy method it was shown that 1-vinylimidazole exhibits intermolecular reaction with 1-vinyl-2-pyrrolidone to give the 11 associate.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1378–1379, June, 1979. 相似文献
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Wolfgang Will Gerhard Hoffmann Andreas Zober 《Fresenius' Journal of Analytical Chemistry》1992,342(9):744-745
Summary A simple method is described which allows the quantification of 1-vinyl-2-pyrrolidone (NVP) in human serum. NVP is extracted from serum with diethylether and determined with HPLC/UV-detection. 1-Cyclohexyl-2-pyrrolidone serves as an internal standard. The detection limit is 0.1 mg/l. The method has shown that NVP can enter the organisms of workers occupationally exposed to this substance. 相似文献
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Licheng M. Han Richard B. Timmons 《Journal of polymer science. Part A, Polymer chemistry》1998,36(17):3121-3129
The RF plasma induced polymerization of 1-vinyl-2-pyrrolidone was examined under variable duty-cycle pulsed-plasma conditions. Large-scale progressive changes in the composition of the resultant polymeric films were observed with sequential changes in the plasma duty cycle employed during polymerization, all other plasma variables held constant. The film compositional changes obtained are in the direction of increased retention of the lactam ring of the monomer in the resultant polymers as the duty cycles employed (i.e., the ratio of plasma on to plasma off times) were decreased. Particularly significant are the relatively linear polymeric structures obtained under the exceptionally low-average power deposition conditions made accessible with the pulsed plasma technique. XPS and FTIR spectroscopic examination of these latter films reveal compositions that are similar to those obtained by conventional (i.e., nonplasma) synthesis of the linear polymer. The film chemistry controllability demonstrated in the present study is achieved while maintaining the many advantages of the plasma polymerization approach for surface modifications. This work provides additional support for use of the pulsed operational mode as an effective means of film chemistry control, in particular extending the plasma polymerization technique to include synthesis of linear polymers, in lieu of the more highly crosslinked structures typically produced in conventional continuous-wave plasma polymerization processes. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 3121–3129, 1998 相似文献
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B. Ocik-Mendyk B. Gawdzik R. Kusak 《Journal of Polymer Science.Polymer Physics》1998,36(12):2019-2024
The adsorptive properties of four porous copolymers were investigated. They contained different functional groups in the internal structure. Adsorption measurements were made using the static method. Three two-component and one three-component solutions with different physicochemical properties were used. The adsorptive centers of the copolymers were evaluated based on the analysis of excess adsorption isotherms of the polar solution component. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 2019–2024, 1998 相似文献
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The alternating cooligomers of carbon monoxide and 5-vinyl-2-norbornene have been first synthesized in the presence of catalysts based on palladium complexes containing N^N and P^P ligands. It has been shown that the insertion of carbon monoxide proceeds for the most part via a C(2)-C(3) bond of the norbornene ring. The degree of involvement of both olefinic bonds of diene in alternating copolymerization is decreased when the reaction is carried out in a protic solvent (methanol). The structure of terminal groups of the copolymers depends on the nature of a bidentate ligand and acid. 相似文献
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Maciejewska Małgorzata Rogulska Magdalena 《Journal of Thermal Analysis and Calorimetry》2021,144(3):699-711
Journal of Thermal Analysis and Calorimetry - Porous microspheres obtained from 2,3-epoxypropyl methacrylate (GMA) and 1,4-di(methacryloyloxymethyl) naphthalene (DMN) were modified by the reaction... 相似文献
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T. G. Ermakova N. P. Kuznetsova A. S. Pozdnyakov L. I. Larina S. A. Korzhova I. V. Mazyar V. S. Shcherbakova A. V. Ivanov A. I. Mikhaleva G. F. Prozorova 《Russian Chemical Bulletin》2016,65(2):485-489
A radical copolymerization of 1-vinyl-1,2,4-triazole (VTA) with 1-vinyl-4,5,6,7-tetrahy-droindole (VTHI) was studied. New thermally stable functional copolymers of different composition, well soluble in organic solvents were synthesized. It was found that VTA has higher reactivity as compared to VTHI. A new soluble polymeric nanocomposite with metallic silver nanoparticles encapsulated into the matrix of synthesized copolymer was obtained. 相似文献
10.
Belyakova LA Varvarin AM Lyashenko DY Roik NV 《Journal of colloid and interface science》2003,264(1):2-6
Interaction of poly(1-vinyl-2-pyrrolidone) with the surface of highly dispersed silica and character of its thermal destruction were investigated by means of ad-desorption measurement, vibration and electron spectroscopy, and thermal gravimetric analysis with programmed heating. The correlation between the character of polymer keeping on the surface of silicon dioxide and its thermal decomposition was established. 相似文献
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Beata Podkościelna 《Journal of Thermal Analysis and Calorimetry》2014,116(2):785-793
Syntheses of the new photoluminescent copolymers: 2,7-(2-hydroxy-3-methacryloyloxypropoxy)naphthalene with N-vinyl-2-pyrrolidone (NVP) are presented. The obtained compound was copolymerised with different ratios of active diluent (NVP). Thermo- and photo-polymerisations of the compositions with use of the initiators: α,α′-azoiso-bis-butyronitrile and 2,2-dimethoxy-2-phenyl-acetophenone were carried out. The following properties were determined: density, polymerisation shrinkage, glass transition temperature, Young’s modulus, hardness and tensile strength. Moreover, the dynamic-mechanical, thermal and photoluminescent properties were studied. These materials may have potential use as luminophores and coatings filtering harmful UV radiation. 相似文献
12.
Novel pH- and temperature-sensitive polymer matrices based on N-isopropylacrylamide have been developed. The hydrogels were prepared by bulk radical polymerization of N-isopropylacrylamide and 1-vinyl-2-pyrrolidinone in appropriate amounts of distilled water using different mol% of traditional N,N-methylene bisacrylamide (MBA) and the new synthesized N,N,N-tris acryloyl melamine (MAAm) crosslinkers. Lower critical solution transition temperatures (LCST) were measured by differential scanning calorimetry. The synthesized hydrogels have LCST lower than 40°C. The influence of environmental conditions such as temperature and pH on the swelling behavior of these polymeric gels was investigated. The swelling behaviors of the resulting gels show pH sensitivity. The crosslinked NIPAAm/VP with MAAm hydrogels exhibited more rapid deswelling rate than NIPAAm/VP hydrogels crosslinked with MBA in pure water in response to abrupt temperature changes from 20°C to 50°C. 相似文献
13.
Lithium 2-vinyl-1,2-azaboratabenzene 1b has been prepared by a multistep synthesis from 2,2-dibutyl-2,5-dihydro-1-trimethylsilyl-1H-1,2-azastannole 6. The reaction of 1b with one equivalent of [Cp1RuCl]4 gave the very labile sandwich compound 11. However, the reaction of 1b with 2 equiv. of [Cp1RuCl]4 afforded the stable diruthenium complex 12. The X-ray structure of 12 shows that the first Cp1Ru moiety is π-bound to the 1,2-azaboratabenzene ring while the second is bound to Cl and to the nitrogen and the pendant B-vinyl of the 1,2-azaboratabenzene group. 相似文献
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V. A. Ponomarenko N. M. Khomutova A. P. Pavlov 《Chemistry of Heterocyclic Compounds》1967,3(3):305-308
The oxidation, hydrobromination, and bromoacetylation of 1-vinyl-2, 2, 3, 3-tetrafluorocyclobutane are investigated, with a view to preparing its oxide. It is found that the most convenient method of preparing this oxide is acetyl hydroperoxide oxidation of 1-vinyl-2, 2, 3, 3-tetrafluorocyclobutane.The authors wish to thank V. A. Klimova and N. V. Korshun for elementary analyses, and B. V. Lopatina and L. V. Orlova for spectroscopic analyses of the compounds prepared. 相似文献
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G. F. Prozorova T. G. Ermakova N. P. Kuznetsova A. S. Pozdnyakov A. V. Ivanov B. A. Trofimov 《Russian Chemical Bulletin》2015,64(9):2141-2144
New copolymers of 1-vinyl-1,2,4-triazole with N-vinyl-4,5,6,7-tetrahydroindole of different compositions were synthesized. The processes of doping them with diiodine and electrophysical properties were studied. An increase in the electrical conductivity of the diiodinedoped copolymers by seven orders of magnitude due to the formation of charge-transfer complexes was observed. 相似文献
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T. G. Ermakova L. P. Shaulina N. P. Kuznetsova O. A. Burova S. V. Amosova G. F. Myachina 《Russian Journal of Applied Chemistry》2008,81(2):285-289
The possibility of preparing copolymers by radical copolymerization of 1-vinyl-1,2,4-triazole with divinyl sulfide and divinyl diethylene glycol ether in the bulk was examined. The sorption characteristics of the new cross-linked copolymers with respect to mercury(II) ions under static conditions in acid solutions were studied. 相似文献
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A. S. Pozdnyakov E. A. Sekretarev A. I. Emel’yanov G. F. Prozorova 《Russian Chemical Bulletin》2017,66(12):2293-2297
The free-radical copolymerization of 1-vinyl-1,2,4-triazole with vinylsulfonic acid sodium salt was conducted. New thermally stable functional water-soluble copolymers of various composition were synthesized. The structure and properties of the obtained copolymers were confirmed by IR, 1H NMR spectroscopy, and thermogravimetric methods. It was found that 1-vinyl-1,2,4-triazole has higher reactivity than sodium vinylsulfonate. TGA and DSC show that the produced copolymers are stable when heated to 260 °C. 相似文献
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Ermakova T. G. Korzhova S. A. Kuznetsova N. P. Mazyar I. V. Larina L. I. Pozdnyakov A. S. Scherbakova V. S. Mikhaleva A. I. Prozorova G. F. 《Russian Journal of General Chemistry》2015,85(2):472-476
Novel water-soluble co-oligomers of 1-vinyl-1,2,4-triazole and N-vinyl-2-phenylpyrrole have been prepared by radical copolymerization. Copolymerization constants of the monomers and the parameters of cooligomers microstructure have been determined. 1-Vinyl-1,2,4-triazole is more reactive in the monomers pair. The prepared co-oligomers are thermally stable and reveal properties typical of paramagnetic organic semiconductors.
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