The reaction partition function is suited to show the distribution of the different species over the different enthalpy levels of the reacting ensemble. The dispersion of the distributions are represented by second derivatives of the partition function.
The information contained in the entropy axis of the thermodynamic space for reacting ensembles concerning the induced dilution of the bound ligand and final dilution of the free ligand can be spanned to a formation function diagram where free energy of reaction can be graphically represented. 相似文献
The non-reacting ensembles can be distinguished into microcanonical, thermal, osmotic, thermo-osmotic ensembles, depending on the type of exchange with the surroundings which is connected to the fluctuations of the ensemble variables. The reacting ensembles can be distinguished into thermal, osmotic, thermo-osmotic, electrochemical, electro-osmotic, electro-thermal, electro-thermo-osmotic ensembles, depending on the type of reaction and of exchange with the surroundings. 相似文献
Herrn Prof. Dr.J. Derkosch, Universität Wien, zum 60. Geburtstag gewidmet. 相似文献