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1.
The structure of galactomannans isolated from seeds of G. delavayi and G. aquatica was studied by 1H and 13C NMR spectroscopy. It was found that the galactomannans consisted mainly of β-1-4-bound mannopyranoses, a part of which was substituted on the C-6 hydroxyl by terminal units of α-galactopyranose.__________Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 12–13, January–February, 2005.  相似文献   

2.
This study concerns the removal of the 137Cs+ and 60Co2+ β+γ-radioactive ions in Azolla caroliniana Willd. water fern. The living fern and two different types of biosorbent prepared from Azolla caroliniana were tested to remove the above-mentioned radioactive ions from dilute solutions, in the absence and in the presence of the ionic competition. Effective 137Cs+ and 60Co2+ ions removal from low radioactive wastewaters was demonstrated. The time dependent K d (t) values were calculated from the absorption data. These results indicate that removal process achieved equilibrium in about 120 min and that it involves two steps: rapid and slow absorption; the active process (metabolic bioaccumulation on the living fern) was responsible for above one half of the total removal process. A thin layer radiochromatography study leads to the conclusion that the biochemical components in which 137Cs+ and 60Co2+ place themselves are of a polysaccharide and lipoid fractions.  相似文献   

3.
The selectivity of deuterium distribution between the nonequivalent positions in 3-carene (1), 4-α-acetyl-2-carene (2), and 4-(1-hydroxyethyl)-2-carene (3) has been measured by 2H-{1H} NMR spectroscopy at the natural abundance of deuterium. These “H/D-isotope portraits” were shown to be typical of terpenes and terpenoids produced in plants via the biosynthetic DXP pathway. The mechanism of acylation of 1 was studied by the density functional theory method (PBE functional, TZ2p basis set). The six-membered ring in compound 1 is planar. However, the endo attack of electrophiles on this ring is more favorable both kinetically and thermodynamically. It was shown both experimentally and theoretically that the elimination of a hydrogen atom in the second reaction step proceeds stereoselectively at the C(2) atom from the anti position with respect to the three-membered ring and occurs with pronounced nucleophilic assistance from the carbonyl group. For Part 2, see Ref. 1. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1657–1664, August, 2008.  相似文献   

4.
A novel uranyl ion-selective bulk optode membrane, incorporating tri-n-octylphosphine oxide for cation recognition and a lipophilic chromoionophore dibenzoylmethane, has been prepared. The PVC membrane composition was optimized to result in the widest working concentration range. The response range of the proposed optode is 4.1×10–6 to 2.0×10–4 mol L–1 UO22+. The probe works at pH 4.0. Ion interference is low and selectivity, reproducibility, and stability are good.  相似文献   

5.
The reaction of [Cp*2RuBr]+Br with bromine in CH2Cl2 (CD2Cl2) in an inert atmosphere at room temperature produces the complexes [Cp*Ru(Br)C5Me4CH2Br]+Br3 (syn conformer), [Cp*Ru(Br)C5Me3(CH2Br)2]+ (syn and anti conformers), and [Ru(Br)(C5Me4CH2Br)2]+ (syn conformer). All complexes were characterized by 1H and 13C NMR spectroscopy; the former complex, by elemental analysis. These complexes were also prepared by the reaction of [Cp*RuC5Me4CH2]+BF4 with bromine in CH2Cl2. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2712–2718, December, 2005.  相似文献   

6.
The photoluminescence properties of xZnO–(100−x)SiO2 (x = 0, 5, 10, 20) containing 1% Eu2O3 prepared by a sol–gel method were systematically investigated. The results indicated that the relative proportion of f–f transitions to charge transfer (CT) absorption decreased with the increase of ZnO concentration. The intensity of 5D07FJ transitions of Eu3+ ions was enhanced with the increase of ZnO content due to local structure changes and decreased quantities of Eu3+ ions clusters. The results of fluorescence line narrow (FLN) spectra indicated that Eu3+ ions occupied one site in SiO2 glass and two sites in ZnO–SiO2 glasses. The second-order crystal field parameters were calculated. B20 and B22 for site 1 increased with excitation energy, while ones hardly changed for site 2.  相似文献   

7.
Comparative quantum chemical calculations of structural parameters, chemical shifts of 11B NMR spectra, and atomic charges in 10-vertex boron hydride anions [1-CB9H10] and [1-B10H9N2] were performed using the restricted Hartree-Fock method with the 6-31++G(D,P) basis set. Dedicated to Academician G. A. Abakumov on the occasion of his 70th birthday. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1853–1855, September, 2007.  相似文献   

8.
Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3] with aromatic aldehydes afforded Schiff bases [1-B10H9NH=CHAr] (Ar=Ph, C6H4-2-OMe, or C6H4-4-NHCOMe). The reduction of the latter with sodium borohydride gave the corresponding benzylamino derivatives [1-B10H9NH2CH2Ar].Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2004–2007, September, 2004.  相似文献   

9.
Summary. The regioselective reaction of N1-benzyl-N2-(4-nitrophenyl)ethanediamide with dialkyl acetylenedicarboxylates or alkyl propiolates in the presence of triphenylphosphine leads to dialkyl 4-benzylamino-1-(4-nitrophenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2,3-dicarboxylates or alkyl 4-benzylamino-1-(4-nitrophenyl)-2-oxo-5-pyrrolidinecarboxylates in good yields.  相似文献   

10.
The keto-enol-enethiol tautomerism in 3-oxo-3-R1-N-R2-propanethioamides under vacuum and in acetone was studied in terms of density functional theory. It was established that the equilibrium depends on the structure of the 3-oxo-3-R1-N-R2-propanethioamides and on the nature of the solvent, but the most stable form is as a rule the keto form stabilized by an intramolecular hydrogen bond. __________ Translated from Teoreticheskaya i Eksperimental'naya Khimiya, Vol. 41, No. 5, pp. 272–277, September–October, 2005.  相似文献   

11.
Distribution of 40K and 137Cs in tissues of the Citrus aurantifolia was measured by gamma spectrometry. A simple theoretical model is also proposed to describe the temporal evolution of 40K activity concentration in such tropical woody fruit species. This model exhibits close agreement with the 40K experimental results, in the leaf growing and fruit ripening processes of lemon trees.  相似文献   

12.
Liquid state, high resolution 13C NMR spectroscopy and mass spectrometry were used to study the composition and structure of soil organic matter (SOM) using soil extracts from two long-term experiments at the Rothamsted Experimental Station. Both one- and two-dimensional NMR techniques were applied. 13C NMR sub-spectra of the CH n (n=0...3) groups, obtained by the Distortionless Enhancement by Polarisation Transfer (DEPT) technique, were used for the elucidation of the qualitative and quantitative composition of humic and fulvic acids in the soils. The chemical structure of SOM was further analysed at the molecular level through Fast Atom Bombardment Mass Spectrometry (FABMS) and Gas Chromatography-Mass Spectrometry (GC/MS). Humic and fulvic extract results were not only compared to each other, but also to the solid state 13C NMR results for the complete soil sample.  相似文献   

13.
The ion-exchange equilibrium in network polymers obtained from cis-2,8,14,20-tetraphenyl-4,6,10,12,16,18,22,24-octahydroxycalix[4]arene by template synthesis on cations Na+, K+, and Ba2+ as matrices was studied. The selectivity coefficients of ion exchanges Ba2+-H+, Na+-H+, K+-H+, Na+-K+, and Na+-NH4 + were determined. The template synthesis enhanced the affinity of the polymers to matrix-forming cations by 6–8 kJ mol−1. __________ Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1919–1922, August, 2005.  相似文献   

14.
The flower-like phosphors of Sr2MgSi2O7: Eu2+, Dy3+ with high brightness and long afterglow were obtained by sol–gel method. X-ray diffraction pattern (XRD) shows that single-phased Sr2MgSi2O7 phosphor is prepared by sol–gel method under 1250 °C. Scanning electron microscope (SEM) indicates that the phosphor consists of nano-sized whiskers which are detected for the first time in Eu2+ and Dy3+ co-doped long-lasting phosphorescence silicates. Furthermore, the investigation on the mechanism indicates that the internal structure and gas, liquid and solid phase effect play important roles in the formation of flower-like Sr2MgSi2O7: Eu2+, Dy3+ nanostructure. Finally, the optical properties of flower-like Sr2MgSi2O7 nanostructure have been characterized by photoluminescence (PL) spectra.  相似文献   

15.
The effects of La3+ on inward K+ channels at plasma membrane in vicia guard cells are investigated using the whole-cell patch-clamp recording mode. It is shown that La3+ on both sides of plasma membrane blocks inward K+ currents in a concentration-dependent manner, indicating that La3+ binding sites may exist on both sides of plasma membrane in guard cells in vicia. The dose response is fitted by the Michaelis-Menten relation characterized by an inhibitor constant K i of 2.56±0.25 μmol · L−1 (outside membrane) and (1.18±0.11)×10−15 mol · L−1 (inside membrane). Intracellular La3+ has much stronger inhibitory effect on inward K+ currents than extracellular La3+ does, suggesting there may exist stronger binding sites inside membrane than outside membrane. Since ion channel activities of guard cells directly affect plant stomatal movement and water status, our results imply that rare earth elements might have potential practical values in regulating plant water status and strengthening plant drought endurance.  相似文献   

16.
N-Bromo and N-chlorosuccinimides add to 1-phenyltricyclo[4.1.0.02,7]heptane in CH2Cl2 with cleavage of the C(1)-C(7) bond to give isomeric 1 : 1 Markownikoff-type endo, anti-adducts of the norpinane structure in a ∼3 :7 ratio corresponding to N and O alkylation of succinimide.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No.2, pp. 457–460, February, 2005  相似文献   

17.
The mechanism of the spin-forbidden reaction Ti+(4F, 3d24s1) + C2H4→TiC2H2 + (2A2) + H2 on both doublet and quartet potential energy surfaces has been investigated at the B3LYP level of theory. Crossing points between the potential energy surfaces and the possible spin inversion process are discussed by means of spin-orbit coupling (SOC) calculations. The strength of the SOC between the low-lying quartet state and the doublet state is 59.3 cm−1 in the intermediate complex IM1-4B2. Thus, the changes of its spin multiplicity may occur from the quartet to the doublet surface to form IM1-2A1, leading to a sig-nificant decrease in the barrier height on the quartet PES. After the insertion intermediate IM2, two distinct reaction paths on the doublet PES have been found, i.e., a stepwise path and a concerted path. The latter is found to be the lowest energy path on the doublet PES to exothermic TiC2H2 +(2A2) + H2 products, with the active barrier of 4.52 kcal/mol. In other words, this reaction proceeds in the following way: Ti++C2H44IC→IM1-4B24,2ISC→IM1-2A1→[2TSins]→IM2→[2TSMCTS]→IM5→TiC2H2 +(2A2)+H2. Supported by ‘Qinglan’ Talent Engineering Funds by Tianshui Normal University.  相似文献   

18.
The structure of a new compound was determined using PMR and 13C NMR spectroscopy (HHCOSY, HSBC, HMBC, ROESY) as 2-[3′-methoxy,4-O-β-D-galactopyranos-1-yl)benzyl]-3-(3″,4″-dimethoxybenzyl)-4hydroxybutyric acid, which was isolated for the first time from seeds of Scotch thistle Onopordum acanthium L. *For No. XII, see [1]. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 53–55, January–February, 2009.  相似文献   

19.
Fluorescence and spectral hole burning properties of Eu3+ ions were studied in nanocrystals-precipitated SnO2-SiO2 glasses. The glasses were prepared to contain various amount of Eu2O3 using the sol-gel method, in which SnO2 nanocrystals were precipitated by heating in air. In the glasses containing Eu2O3 less than 1%, the Eu3+ ions were preferentially doped in the SnO2 nanocrystals and their fluorescence intensities were enhanced by the energy transfer due to the recombination of electrons and holes excited in SnO2 crystals. The SnO2 nanocrystals-precipitated glasses exhibited the persistent spectral holes with the depth of ∼25% of the total fluorescence intensities of the Eu3+ ions. With the increasing Eu2O3 concentration, the amount of SnO2 nanocrystals decreased and the Sn4+ ions formed the random glass structure together with the silica network. This structure change induced the fluorescence intensities and the hole depth to decrease.  相似文献   

20.
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