Effect of small additives of oligomer on the viscoelastic properties of carbon fiber plastics

The viscoelastic properties of carbon fiber composites whose phenol-formaldehyde matrix is modified by thermodynamically incompatible isocyanate derivatives have been investigated. Data are given on fiber wetting (Table 11), internal stress (Table 2), viscoelastic properties (Fig. 1), and tensile strength (Fig. 2). The modified composites are strengthened by the addition of 0.5–4% oligomer additive. This process involves the formation of a two-phase structure, in which the additive phase microparticles act as a polymer filler. Due to selective interactions, the intermediate layer formed at the fiber-binder interface leads to changes in the viscoelastic properties and tensile strength of the matrix and improved maintenance characteristics for the material as a whole.Translated from Mekhanika Kompozitnykh Materialov, Vol. 29, No. 4, pp. 440–445, July–August, 1993.     

Regulation of the mechanical properties of thermoplastic carbon fiber-reinforced plastics by changing their production conditions and surface treatment of the fibers

The effect of technological parameters of processing and surface treatment of carbon fibers on the mechanical properties of carbon fiber-reinforced plastics (CFRPs) was investigated. The copolymer of 1,3,5-trioxane with 1,3-dioxolane was used as the polymer matrix, and medium-modulus hydrated cellulose Ural LO-24 carbon fibers served as the reinforcing filler. The polymer matrix was mixed with the carbon fibers by the method of combined extrusion. The dependence of the mechanical properties of CFRPs on the technological parameters of screw-disk extrusion was studied. It was found that the properties of the composites were greatly affected by the size of the working disk gap, the disk rotation rate, and the temperature in the zone of normal stresses. The surface of the carbon fibers was activated with atmospheric oxygen in the temperature range of 450–600°C, with mass loss of the fibers no greater than 3–4%. A 30–40% increase in the mechanical properties of the CFRPs was achieved. A decrease in the melt index of the 1,3,5-trioxane copolymer with 1,3-dioxolane reinforced with oxidized carbon fibers was observed, which should be taken into account in processing the composites into products. Introduction of carbon fibers in the 1,3,5-trioxane copolymer with 1,3-dioxolane allows us to increase the wear resistance and decrease the friction coefficient, which makes it possibile to use these materials in the friction units of machines and mechanisms, such as plain bearings, gears, and flange packings.Presented at the 10th International Conference on the Mechanics of Composite Materials (Riga, April 20–23, 1998).Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 34, No. 5, pp. 673–682, September–October, 1998.     

Effect of thermal treatment temperature on the structure and properties of carbon fibers

Conclusions 1. It has been shown that the presence of a maximum in the dependence of strength on Young's modulus for carbon fibers made from PAN fiber may be explained by an effect of the process of temperature stress accumulation which takes place under the conditions of isometric heating. The start of this process, which causes a rearrangement of the internal structure of the high-modulus fiber, coincides with the start of the anomalous rise in fiber density.2. The interconnection between surface and internal defects and the elastic-strength properties of carbon fibers made in the temperature treatment range 600–3000°C has been studied.3. Original data on the elastic-strength properties of borided carbon fibers have been obtained; the structure of these is marked by a high degree of perfection. It has been shown that in boriding, which facilitates graphitization of the carbon, the process of regular reduction in fiber strength which is reached in the precrystallization stage is somewhat retarded.All-Union Scientific-Research Institute of Aviation Materials, Moscow. Translated from Mekhanika Polimerov, No. 6, pp. 1036–1042, November–December, 1976.     

Effect of silicon carbide coatings on the strength of carbon fibers

Conclusion The character of the effect of silicon carbide coatings on the strength of carbon fibers is a function of the strength of the coating, which decreases with an increase in its thickness. The results obtained permit hoping for a significant increase in the strength of fibers by application of high-modulus coatings. It can be attained as a result of increasing the critical value of the coating thickness due to optimization of the conditions of preparation, which will improve the structure of the articles.Translated from Mekhanika Kompozitnykh Materialov, No. 4, pp. 604–608, July–August, 1988.     

Micromechanical strength analysis of fiber reinforced plastics

Strength of an unidirectional lamina is computed with a representative volume element. An approximative “voxel” meshing method is used in conjunction with continuum damage mechanics to simulate crack growth in the RVE. Two material models for the nonlinear material behaviour of the epoxy resin are compared. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Effect of curvature of the fibers on the elastic properties of unidirectionally reinforced plastics

An approximate method is proposed for determining the reduced elastic constants of reinforced plastics (glass-reinforced plastics) with allowance for the curvature of the reinforcing fibers. All the conclusions relate to plane stress. The results of model tests are presented as confirmation of the theoretical conclusions.Mekhanika Polimerov, Vol. 3, No. 5, pp. 858–863, 1967     

The effect of glass fiber inelasticity on the long-term strength of reinforced plastics subject to uniaxial tension along the fibers

Relationships are presented for determining the long-term strength of reinforced plastics subject to uniaxial tension by a constant load directed along the fibers; these relationships are based on the rheological characteristics of the components of the plastics. The proposed expressions agree quite well with experiment. Treatment of the experimental data by mathematical statistics showed that the relative strain at fracture remains constant; it does not depend either on the relative reinforcement content or on the applied load (i. e., on the time to fracture).Mekhanika Polimerov, Vol. 3, No. 4, pp. 719–725, 1967     

Study of the effect of the dressing of carbon fibers on the properties of carbon-fiber-reinforced plastics based on polyacetals

Studies are made of the mechanical and friction engineering properties of a copolymer of trioxane-1,3,5 with dioxolan-1,3 reinforced with dressed carbon fibers based on hydrated cellulose. Polyalkyloxysilanes are used as the finishes. The optimum concentrations of the finishes on the fibrous filler are determined. Relations are obtained to describe the dependence of the mechanical properties of carbon-fiber-reinforced plastics on the type of finish and its effect on the condition of the phase boundary between filler and the polymer matrix. The effect of adhesion of the polymer to the fibrous filler on the properties of a randomly reinforced thermoplastic composite is also determined. The dependences of the friction engineering properties of polyacetal-based carbon-plastics on the loading parameters of the friction-loading unit are examined. The material that is developed has high values of strength, elastic modulus, and notch toughness and low values of the friction coefficient and shrinkage. The material can be used as structural and anti-friction elements in rocketry, aviation, and the automobile industry.Ukrainian State Chemical Engineering University, Dnepropetrovsk. Translated from Mekhanika Kompozitnykh Materialov, No. 1, pp. 90–97, January–February, 1997.     

Effect of surface modification on the adhesion and mechanical properties of glass-reinforced plastics

The adhesion of an epoxy-polyester resin to glass fibers with clean and modified surfaces has been determined. The effect of this adhesion on some of the properties of glass-reinforced plastics (bending, tension, shear) is investigated.Mekhanika polimerov, Vol. 1, No. 1, pp. 93–99, 1965     

Effect of stability of the structural parameters of laminated reinforced plastics on their strength properties

Conclusion As a result of the completed analysis, we estimated the effect of scatter of the strength properties of the layers, instability of the layers' strain properties, and instability of the geometry of the structure on the strength properties of multidirectional LRP's in a plane stress state. It was established that instability of the structural parameters produces two negative tendencies: a reduction in the mean values of LRP strength and an increase in their scatter. From the viewpoint of ensuring the reliability of structures (structural elements) made of such materials, these tendencies reinforce one another and are thus even more dangerous. It follows from this that the production method employed should not only (or not even mainly) solve the problem of increasing the values of the parameters of the materials (and their semifinished structural elements), it should also address the problem of alleviating their instability — improving the quality of production.The numerical analysis established the limits at which it is necessary to account for instability of structural parameters in engineering calculations: for the strain properties of the layers — a coefficient of variation of the elastic modulus greater than 10%; for the scatter of the angles of orientation of the layers — a standard deviation greater than 5 °. These numerical results and the computer program developed may prove useful in evaluating the actual properties of structural parameters determined in indirect tests of LRP's, as well as in more adequately comparing empirical data with corresponding calculations based on structural theories. The development of such an approach to analyzing the strength properties of multidirectional LRP's in bending also holds promise.Translated from Mekhanika Kompozitnykh Materialov, No. 4, pp. 659–666, July–August, 1990.