Design of a highly nonlinear twin bow-tie polymer photonic quasi-crystal fiber with high birefringence

A twin bow-tie polymer-based photonic quasi-crystal fiber with high birefringence, high nonlinearity and low dispersion as well as maintaining single mode operation is presented in the wavelength range 1.8–2.2 μm. Through optimizing fiber structure parameter using a full-vector finite-element method combined with perfectly matched layers boundary condition, the birefringence is as high as 2.43 × 10⁻³, the nonlinearity is as high as 118 W⁻¹ km⁻¹, and the dispersion is only 25 ps/nm/km at 2 μm with the holes pitch of 3.3 μm. From the point of fabrication, the influences of deviation of each air hole diameter are discussed to verify the robustness of the photonic quasi-crystal fiber designed.     

A new design of low-loss and ultra-flat zero dispersion photonic crystal fiber using hollow ring defect

New hollow ring defect structure is introduced in photonic crystal fiber design for ultra- flat zero dispersion with very low waveguide losses. The hollow ring defect consisted of a central hole surrounded by a doped silica ring provides highly flexible defect engineering capabilities in photonic crystal fibers to achieve precise control of dispersion value and dispersion slope while independently maintaining low waveguide losses, which was not attainable in previous designs. A nearly flat zero dispersion of D=0±0.51 ps/nm km was obtained in the wavelength range of 1.44–1.61 μm with the maximum slope of ?2.7×10^?2 ps/nm² km. The confinement loss was less than 5.75×10^?8 dB/m along with the bending loss of 2.8×10^?6 dB/m for the radius of 10 mm, and splice loss of less than 1.57 dB to conventional single mode fiber at 1.55 μm.     

Wide-band fanned-out supercontinuum source covering O-, E-, S-, C-, L- and U-bands

A wide-band supercontinuum source generated by mode-locked pulses injected into a Highly Non-Linear Fiber (HNLF) is proposed and demonstrated. A 49 cm long Bismuth–Erbium Doped Fiber (Bi–EDF) pumped by two 1480 nm laser diodes acts as the active gain medium for a ring fiber laser, from which mode-locked pulses are obtained using the Non-Polarization Rotation (NPR) technique. The mode-locked pulses are then injected into a 100 m long HLNF with a dispersion of 0.15 ps/nm km at 1550 nm to generate a supercontinuum spectrum spanning from 1340 nm to more than 1680 nm with a pulse width of 0.08 ps and an average power of ?17 dBm. The supercontinuum spectrum is sliced using a 24 channel Arrayed Waveguide Grating (AWG) with a channel spacing of 100 GHz to obtain a fanned-out laser output covering the O-, E-, S-, C-, L- and U-bands. The lasing wavelengths obtained have an average pulse width of 9 ps with only minor fluctuations and a mode-locked repetition rate of 40 MHz, and is sufficiently stable to be used in a variety of sensing and communication applications, most notably as cost-effective sources for Fiber-to-the-Home (FTTH) networks.     

Fiber curvature sensor based on spherical-shape structures and long-period grating

A novel curvature sensor based on optical fiber Mach–Zehnder interferometer (MZI) is demonstrated. It consists of two spherical-shape structures and a long-period grating (LPG) in between. The experimental results show that the shift of the dip wavelength is almost linearly proportional to the change of curvature, and the curvature sensitivity are −22.144 nm/m⁻¹ in the measurement range of 5.33–6.93 m⁻¹, −28.225 nm/m⁻¹ in the range of 6.93–8.43 m⁻ and −15.68 nm/m⁻¹ in the range of 8.43–9.43 m⁻¹, respectively. And the maximum curvature error caused by temperature is only −0.003 m⁻¹/°C. The sensor exhibits the advantages of all-fiber structure, high mechanical strength, high curvature sensitivity and large measurement scales.     

Highly birefringent ZBLAN photonic quasi-crystal fiber with four circular air holes in the core

A highly birefringent ZBLAN photonic quasi-crystal fiber with a rectangular array of four relatively small circular air holes in the core region is proposed. Through optimizing fiber structure parameters using a full-vector finite-element method combined with perfectly matched layers boundary condition, its birefringence is up to 2.88 × 10⁻² and the confinement losses of both polarized modes are less than 4.95 × 10⁻⁴ dB/m at 2 μm. To our knowledge, this is the first simulation study showing that a birefringence can be achieved with the order of 10⁻² by all-circular-hole PQFs around 2 μm.     

Design of single polarization single mode dispersion compensating photonic crystal fiber

In this paper, we present a photonic crystal fiber based on hexagonal structure for improved negative dispersion as well as high birefringence in the telecom wavelength bands. It is demonstrated that it is possible to obtain negative dispersion coefficient of −712 ps/(nm km) and relative dispersion slope (RDS) perfectly match to that of single mode fiber (SMF) of about 0.0036 nm⁻¹ at the operating wavelength 1550 nm. The proposed fiber exhibits high birefringence of the order 2.11 × 10⁻² with nonlinear coefficient about 57.57 W⁻¹ km⁻¹ at 1550 nm. Moreover, it is confirmed that the designed fiber successfully operates as a single mode in the entire band of interest.     

Polarization maintaining holey fibers for residual dispersion compensation over S + C + L wavelength bands

We report on a highly birefringent holey fiber for broadband dispersion compensation covering the S, C, and L telecommunication bands i.e. wavelength ranging from 1460 to 1625 nm. The finite element method with circular perfectly matched layer boundary condition is used to investigate the guiding properties. Numerical analysis demonstrates that it is possible to obtain negative dispersion coefficient of about −470 to −850 ps/nm/km over S to L-bands and a relative dispersion slope perfectly matched with single mode fiber (SMF) of about 0.0036 nm⁻¹ at 1550 nm. At the same time birefringence of the order 2.53 × 10⁻² is realized at 1550 nm wavelength. Owing to superior optical properties of the proposed holey fiber, this can be a promising candidate for broadband dispersion compensation and sensing applications.     

Maintaining single polarization and dispersion compensation with modified rectangular microstructure optical fiber

In this paper, we propose and numerically demonstrate a highly birefringent microstructure optical fiber which shows negative dispersion coefficient of about −288 to −550 ps/(nm km) covering S to L wavelength bands and −425 ps/(nm km) at the excitation wavelength 1550 nm. This proposed design successfully compensate the dispersion covering S to L communication bands ranging from 1460 to 1625 nm along with relative dispersion slope (RDS) perfectly matched to that of single mode fiber of about 0.0036 nm⁻¹. Apart from dispersion compensation, the designed MOF offers high birefringence of 2.94 × 10⁻² at 1550 nm and better compensation ratio with design simplicity due to circular air-holes in the fiber cladding.     

Hydrophilic polyaniline nanofibrous architecture using electrosynthesis method for supercapacitor application

An electrosynthesis process of hydrophilic polyaniline nanofiber electrode for electrochemical supercapacitor is described. The TGA–DTA study showed polyaniline thermally stable up to 323 K. Polyaniline nanofibers exhibit amorphous nature as confirmed from XRD study. Smooth interconnected fibers having diameter between 120–125 nm and length typically ranges between 400–500 nm observed from SEM and TEM analysis. Contact angle measurement indicated hydrophilic nature of polyaniline fibers. Optical study revealed the presence of direct band gap with energy 2.52 eV. The Hall effect measurement showed room temperature resistivity ∼3 × 10⁻⁴ Ω cm and Hall mobility 549.35 cm⁻²V⁻¹ s⁻¹_. The supercapacitive performance of nanofibrous polyaniline film tested in 1 M H₂SO₄ electrolyte and showed highest specific capacitance of 861 F g⁻¹ at the voltage scan rate of 10 mV/s.     

Characterization of the channel walls roughness in photonic crystal fibers

We present electron microscope (FEI NanoSEM) and atomic force microscopy measurements of surface roughness in nanochannels in photonic crystal fibers (PCF). A method was invented to cleave the PCF along the axis without damaging the surface structure in the nanochannels allowing us to characterize the morphology of the nanochannels in the PCF. A multi-wall carbon nanotube mounted onto commercial AFM probes and super sharp silicon non-contact mode AFM probes were used to characterize the wall roughness in the nanochannels. The roughness is shown to have a Gaussian distribution, and has an amplitude smaller than 0.5 nm. The height–height correlation function is an exponential correlation function with an autocorrelation length of 13 nm, and 27 nm corresponding with scan sizes of 200×100 nm², and 1600×200 nm², respectively.     

Er/Yb co-doped fiber amplifier with wavelength-tuned Yb-band ring resonator

Erbium-ytterbium co-doped fiber amplifier with wavelength-tuned Yb-band loop resonator is presented. The amplified spontaneous emission (ASE) from Yb ions is utilized to stimulate a laser emission at several wavelengths from the 1 μm band in the 1550 nm amplifier. The wavelength of this lasing is tuned by introducing a fiber Bragg grating (FBG). The results show, that the overall efficiency of the amplifier at nominal 1550 nm wavelength can be increased by introducing a feedback loop with 1040 nm and 1050 nm FBG. This loop also protects the Er/Yb amplifier from parasitic lasing at 1 μm and allows significant output power scaling without risk of self-pulsing.     

Visible,near-infrared and infrared optical properties of silica aerogels

Silica aerogel is an excellent thermal insulation material with a low thermal conductivity and a high porosity and has attracted great concern in applications. This paper was to experimentally investigate the optical properties of optically thick silica aerogel in the visible, near-infrared and infrared spectrum region. The fiber-loaded silica aerogel sample was prepared through sol–gel technique and supercritical drying process. Silica fibers were added into the aerogel during the preparation procedure to strength the skeleton of aerogel. As a comparison with the fiber-load silica aerogel, a silica fiber composite sample with the same chemical component and different physical structure was also prepared. A simplified two-flux model neglecting the boundary effect was used to describe the radiation propagation characteristics inside the samples. The spectral normal-hemispherical reflectances, transmittances, and normal emittances of silica aerogel and silica fiber samples were measured and compared in the wavelengths of 0.38–15 μm. Then the spectral optical constants of samples were determined using the experimental data. The spectral absorption and scattering coefficients of silica aerogel were within (0.01 cm⁻¹, 31.0 cm⁻¹) and (1.4 cm⁻¹, 25.8 cm⁻¹). The results showed that the spectrum region where the scattering coefficient is low usually corresponds to a high absorption coefficient. In addition, the total radiation properties of samples were predicted at high temperatures. The analysis of optical properties of silica aerogel is necessary to provide valuable data in applications.     

Experimental investigation on gain-dependent chromatic dispersion of the semiconductor optical amplifier

Using a chromatic-dispersion analysis method based on K–K transformation of the gain spectrum, we experimentally investigated the chromatic dispersion of semiconductor optical amplifier in detail within the wavelength range from 1530 nm to 1610 nm. Experimental results demonstrate that there are three typical dispersion regions, which are abnormal dispersion, flatten dispersion and normal dispersion region, and three zero-dispersion points, which exist around 1550 nm, 1580 nm and 1600 nm, over the wide wavelength range of 80 nm. With an increase in bias current on SOA, wavelengths of the three zero dispersion points all had a blue shift and the three near-zero dispersion regions corresponding became wider. However, the three near-zero dispersion regions corresponding became narrower when the input optical power increased. Therefore, the dispersion of SOA can be flexibly adjusted by changing the bias current and input optical power to SOA.     

Zero bias PIN photodetector based on gradient band distribution and doping gradient profile

Zero bias photodetector which was suitable for top-illuminated and side-illuminated was fabricated. Maximal bandwidth-efficiency product (BEP) value could be achieved when the epitaxial layer structure was optimized. The 3-dB bandwidth of the zero bias was 12.27 GHz, which was numerically above 80% of that maximum value. The measured external quantum efficiency of the photodetector was 17% at the zero bias and 1550 nm. The dark current of the photodetector with 12-μm diameter was less than 9 × 10⁻⁸ A at a reverse bias of 0.1 V. The influence of doping gradient profile on photodetector performance was illustrated by simulation comparison. The important aspects of the design of the high-speed low-bias photodetector were explained. The phenomenon of the photodetector at the reverse bias which was not the higher the better was explained. The improvement in performance of the photodetector was discussed. The fabrication process and the testing process were described in detail.     

Controlled fabrication of Si nanostructures by high vacuum electron beam annealing

Silicon nanostructures, called Si nanowhiskers, have been successfully synthesized on Si(1 0 0) substrate by high vacuum electron beam annealing (EBA). Detailed analysis of the Si nanowhisker morphology depending on annealing temperature, duration and the temperature gradients applied in the annealing cycle is presented. A correlation was found between the variation in annealing temperature and the nanowhisker height and density. Annealing at 935 °C for 0 s, the density of nanowhiskers is about 0.2 μm⁻² with average height of 2.4 nm grow on a surface area of 5×5 μm, whereas more than 500 nanowhiskers (density up to 28 μm⁻²) with an important average height of 4.6 nm for field emission applications grow on the same surface area for a sample annealed at 970 °C for 0 s. At a cooling rate of −50 °C s⁻¹ during the annealing cycle, 10–12 nanowhiskers grew on a surface area of 5×5 μm, whereas close to 500 nanowhiskers grew on the same surface area for samples annealed at the cooling rate of −5 °C s⁻¹. An exponential dependence between the density of Si nanowhiskers and the cooling rate has been found. At 950 °C, the average height of Si nanowhiskers increased from 4.0 to 6.3 nm with an increase of annealing duration from 10 to 180 s. A linear dependence exists between the average height of Si nanowhiskers and annealing duration. Selected results are presented showing the possibility of controlling the density and the height of Si nanowhiskers for improved field emission properties by applying different annealing temperatures, durations and cooling rates.     

Picosecond molecular switch based on the influence of photogenerated electric fields on optical charge transfer transitions

A concept for a picosecond molecular switch is demonstrated using a photoinduced electron transfer reaction in a covalently linked, fixed distance donor–acceptor molecule D–A linked to a perylene-3,4-dicarboximide chromophore, C. The chromophore C possesses a strong charge transfer transition in its optical spectrum. Selective excitation of C within D–A–C using 530 nm, 130 fs laser pulses produces^1 * C, which undergoes singlet–singlet energy transfer to produce^1 * D, which in turn transfers an electron to A. If the D–A–C system is selectively excited with 416 nm, 130 fs laser pulses to produce D ⁺ – A ⁻ –C prior to excitation of C with 530 nm, 130 fs laser pulses, a 25% lower yield of^1 * C is generated. The intense local electric field produced by D ⁺ – A ⁻ causes a 15 nm electrochromic red shift of the charge transfer absorption of C. Thus, the absorption of C at 530 nm is significantly diminished by the presence of D ⁺ – A ⁻ . The need to use two laser pulses with different wavelengths to observe these effects, and the resulting picosecond time response makes it possible to consider applications of this concept in the design of molecular switches.     

Part 2: Ultra-short pulse laser patterning of very thin indium tin oxide on glass substrates

We investigate selective patterning of ultra-thin 20 nm Indium Tin Oxide (ITO) thin films on glass substrates, using 343, 515, and 1030 nm femtosecond (fs), and 1030 nm picoseconds (ps) laser pulses. An ablative removal mechanism is observed for all wavelengths at both femtosecond and picoseconds time-scales. The absorbed threshold fluence values were determined to be 12.5 mJ cm⁻² at 343 nm, 9.68 mJ cm⁻² at 515 nm, and 7.50 mJ cm⁻² at 1030 nm for femtosecond and 9.14 mJ cm⁻² at 1030 nm for picosecond laser exposure. Surface analysis of ablated craters using atomic force microscopy confirms that the selective removal of the film from the glass substrate is dependent on the applied fluence. Film removal is shown to be primarily through ultrafast lattice deformation generated by an electron blast force. The laser absorption and heating process was simulated using a two temperature model (TTM). The predicted surface temperatures confirm that film removal below 1 J cm⁻² to be predominately by a non-thermal mechanism.     

Advanced multifunctional optical switch for multimode optical fiber networks

In this work, an advanced multifunctional optical switch based on multimode fibers is proposed. It can work as a 3 × 1 optical multiplexer/combiner, a 2 × 2 optical switch, a variable optical attenuator and a variable optical power splitter. All these functionalities can be developed in the same device without any hardware modification, only by using the proper ports and control electronics.The proposed switch has been developed for being used in the visible and near infrared wavelength range: 450–650 nm for optical fiber automobile applications, 650–850 nm for home broadband applications; and 850–1300 nm for multimode fiber access networks. Up to three different types of twisted nematic liquid crystal cells have been designed and fabricated for fulfilling these different wavelength ranges as part of the proposed device.The multifunctional switch has been implemented and experimentally tested. Crosstalk usually better than ? 15 dB at 532 nm, 660 nm and 850 nm, in any state has been measured. Switching is achieved at voltage levels of 4 Vrms. Fiber to fiber insertion losses when operating as a 2 × 2 optical switch, range from 10 to 15 dB within 200 nm wavelength range; with a non-optimized optics for collimation and coupling.     

Compatibility of field emitter studies of oscillating surface reactions with single crystal measurements: catalytic CO oxidation on Pt

Kinetic oscillations in catalytic CO oxidation on Pt have been studied on large (millimeter size) single crystal planes of Pt as well as on a Pt field emitter tip that exposes different crystal facets of nanometer size. In order to examine the compatibility of results from the two types of experiments, the regions of different dynamical behavior (bifurcation diagram) have been mapped out in p_CO,T-parameter space using a field electron microscope (FEM) and a field ion microscope (FIM). The comparison with the results of single crystal measurements shows that in the case of applied electrostatic fields less than 5 V nm⁻¹ (FEM), the field-induced effects are negligible, but they are significant for fields exceeding 12 V nm⁻¹ (FIM). The field-induced shift of the bifurcation diagram toward lower p_CO values, observed with FIM, is explained in terms of a field-modified interaction of CO and O₂ with Pt studied here with field ion appearance energy spectroscopy. With coadsorbed lithium (submonolayer coverage), the existence range for rate oscillations is shifted toward higher p_CO values. This shift is attributed to a redistribution of the electron density at the surface induced by alkali metal co-adsorption.     

100-mW linear polarization single-frequency all-fiber seed laser for coherent Doppler lidar application

A compact short-cavity fiber laser configured with Er³⁺/Yb³⁺ highly co-doped phosphate glass fiber with stable linear polarization and single frequency output is proposed and investigated experimentally. The fiber laser is composed of a high-reflectivity fiber Bragg grating (HRFBG) and a polarization-maintaining fiber Bragg grating (PMFBG) with the matched wavelengths at 1540.3 nm, which aims at one of the center wavelengths of the atmospheric transmission windows and may be used as the local oscillator (LO) of the coherent Doppler lidar (CDL). The output power of the laser reaches more than 114-mW, the signal-to-noise ratio is larger than 70 dB and the laser linewidth is about 4.1-kHz. Moreover, the linear polarization with 40.5 dB extinction ratio, the power fluctuation of less than ± 0.25% and the frequency fluctuation of less than ± 80 MHz are also obtained. Compared with the DFB fiber laser, the proposed fiber laser is more suitable for the CDL applications.