共查询到2条相似文献,搜索用时 0 毫秒
1.
Mahmoud Heidari Abdolrahman Bahrami Ali Reza Ghiasvand Farshid Ghorbani Shahna Ali Reza Soltanian 《Analytica chimica acta》2013
A needle trap device (NTD) packed with silica composite of multi-walled carbon nanotubes (MWCNTs) prepared based on sol–gel technique was utilized for sampling and analysis of volatile organohalogen compounds (HVOCs) in air. The performance of the NTD packed with MWCNTs/silica composite as sorbent was examined in a variety of sampling conditions and was compared with NTDs packed with PDMS as well as SPME with Carboxen/PDMS-coated fibers. The limit of detection of NTDs for the GC/MS detection system was 0.01–0.05 ng mL−1 and the limit of quantitation was 0.04–0.18 ng mL−1. The RSD were 1.1–7.8% for intra-NTD comparison intended for repeatability of technique. The NTD-MWCNTs/silica composite showed better analytical performances compared to the NTD-PDMS composite and had the same analytical performances when compared to the SPME-Carboxen/PDMS fibers. The results show that NTD-MWCNTs-GC/MS is a powerful technique for active sampling of occupational/environmental pollutants in air. 相似文献
2.
Raitza M Wegmann J Bachmann S Albert K 《Angewandte Chemie (International ed. in English)》2000,39(19):3486-3489