Quantum well infrared photodetector simultaneously working in two atmospheric windows

We have demonstrated a two-contact quantum well infrared photodetector (QWIP) exhibiting simultaneous photoresponse in both the mid- and the long-wavelength atmospheric windows of 3–5 μm and of 8–12 μm. The structure of the device was achieved by sequentially growing a mid-wavelength QWIP part followed by a long-wavelength QWIP part separated by an n-doped layer. Compared with the conventional dual-band QWIP device utilizing three ohmic contacts, our QWIP is promising to greatly facilitate two-color focal plane array (FPA) fabrication by reducing the number of the indium bumps per pixel from three to one just like a monochromatic FPA fabrication and to increase the FPA fill factor by reducing one contact per pixel; another advantage may be that this QWIP FPA boasts broadband detection capability in the two atmospheric windows while using only a monochromatic readout integrated circuit. We attributed this simultaneous broadband detection to the different distributions of the total bias voltage between the mid- and long-wavelength QWIP parts.     

Aerospace diagnostics of natural environment with the use of a SKIF spectrometer

We describe investigations carried out by means of a SKIF spectrometer from the orbital stations “Salyut-7” and “Mir”, as well as from aircraft carriers. We present basic technological characteristics of the device, describe the details of the construction and the application procedures. The spectral characteristics of underlying surfaces are generalized in the form of a catalogue and atlas of spectra with geographic, meteorological, time, and subject allocation. We give samples of the presentation of materials in the catalogue and atlas, as well as summary tables of the data that characterize the place, time, and other conditions of the experiments. The results of the application of the device for detecting narcotic-containing crops from aircrafts and space vehicles are described. Research and development in the field of aerospace instrument manufacture and remote spectrophotometry of the earth surface were initiated at the Institute of Physics of the Academy of Sciences of Belarus by L. I. Kisilevskii and at first were conducted under his leadership. B. I. Stepanov Institite of Physics, Academy of Sciences of Belarus, 70, F. Skorina Ave., Minsk, 220072, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 5, pp. 691–697, September–October, 1997.     

High-performance IR detectors at SCD present and future

For over 27 years, SCD has been manufacturing and developing a wide range of high performance infrared detectors, designed to operate in either the mid-wave (MWIR) or the long-wave (LWIR) atmospheric windows. These detectors have been integrated successfully into many different types of system including missile seekers, time delay integration scanning systems, hand-held cameras, missile warning systems and many others. SCD’s technology for the MWIR wavelength range is based on its well established 2D arrays of InSb photodiodes. The arrays are flip-chip bonded to SCD’s analogue or digital signal processors, all of which have been designed in-house. The 2D focal plane array (FPA) detectors have a format of 320×256 elements for a 30-μm pitch and 480×384 or 640×512 elements for a 20-μm pitch. Typical operating temperatures are around 77–85 K. Five years ago SCD began to develop a new generation of MWIR detectors based on the epitaxial growth of antimonide based compound semiconductors (ABCS). This ABCS technology allows band-gap engineering of the detection material which enables higher operating temperatures and multi-spectral detection. This year SCD presented its first prototype FPA from this program, an InAlSb based detector operating at a temperature of 100 K. By the end of this year SCD will introduce the first prototype MWIR detector with a 640×512 element format and a pitch of 15 μm. For the LWIR wavelength range SCD manufactures both linear Hg_1−xCd_xTe (MCT) detectors with a line of 250 elements and time delay and integration (TDI) detectors with formats of 288×4 and 480×6. Recently, SCD has demonstrated its first prototype uncooled detector which is based on VO_x technology and which has a format of 384×288 elements, a pitch of 25 μm, and a typical NETD of 50 mK at F/1. In this paper, we describe the present technologies and products of SCD and the future evolution of our detectors for the MWIR and LWIR detection. The paper presented there appears in Infrared Photoelectronics, edited by Antoni Rogalski, Eustace L. Dereniak, Fiodor F. Sizov, Proc. SPIE Vol. 5957, 59570S (2005).     

Simulation and high-precision wavelength determination of?noisy?2D Fabry–Pérot interferometric rings for direct-detection Doppler?lidar and laser spectroscopy

Doppler wind lidar (DWL) measurements by the fringe-imaging technique in front of aircrafts at flight speed require rapid processing of backscattered signals. We discuss the measurement principle to derive the 3D wind vector from three line-of-sight (LOS) measurements. Then we simulate realistic fringe patterns of a Fabry–Pérot-interferometer (FPI) on a 2D charge-coupled device (CCD) localized at the focal plane behind it, taking atmospheric and instrument properties like scattering and noise into account. A laser at 355 nm with pulse energies of 70 mJ at 100 Hz repetition rate and a range bin of only 10 m were assumed. This yields count rates of 24 (13) million photons per pulse at 56 (76) m distance and 8.5 km altitude that are distributed on a CCD with up to 960×780 pixels without intensification and therefore generate noisy pixel signals. We present two methods for the precise determination of the radii, i.e., wavelengths of these simulated FPI rings and show that both are suitable for eliminating pixel noise from the output and coping with fringe broadening by Rayleigh scattering. One of them proves to reach the accuracy necessary for LOS velocity measurements. A standard deviation of 2.5 m/s including center determination can be achieved with only 20 images to average. The bias is 7 m/s. For exactly known ring centers, each can be even better than 2 m/s. The methods could also be useful for high-resolution laser spectroscopy.     

An active imaging digital image correlation method for deformation measurement insensitive to ambient light

Varying ambient light may cause serious decorrelation effect in the images recorded using an ordinary optical imaging device, which prevent digital image correlation (DIC) from out-of-laboratory use. In this paper, we describe an easy-to-implement yet effective monochromatic light illuminated active imaging DIC method for obtaining high-quality images suitable for high fidelity deformation measurement. Experiments reveal that the active imaging DIC method is able to provide reliable and accurate measurements even though the ambient light has been seriously changed. The active imaging DIC method is promising for developing flexible and robust in situ deformation measurement systems for use in both laboratory and non-laboratory environment, and should therefore have more potential engineering applications.     

Planetary Fourier spectrometer: An interferometer for atmospheric studies on board Mars 94 mission

Summary PFS is a two-channel Fourier spectrometer operating in the infra-red wavelengths between 1.25 and 45 μm. The instrument will be used mainly in the study of the Martian atmosphere. The principal goals are the measurements of the atmospheric temperature and pressure, atmospheric constituents, aerosol and clouds, ground pressure for surface topography, optical and thermophysics properties of the Martian soil. PFS will fly on the Mars 94 spacecraft which should be launched in 1994 and reach the planet in 1995. It is essentially constituted by two different interferometers located in the same box which is divided into two parts. A dichroic placed on the PFS entrance is used to separate the spectral range into two parts, a division needed by the different optical materials which have to be used in each spectral range. The optical layout of the experiment is very compact. Each channel uses two cubic mirrors mounted on an L-structure pivoted on a motor. The motor moves the mechanics and permits the optical-path difference between the arms to be varied. Each interformeter operates in a different spectral range, respectively, between (1.25÷4.8) μm (8000÷2083cm⁻¹) and (6÷45)μm (1666÷220)cm⁻¹). The spectral resolution is 2 cm⁻¹. The entrance aperture area is 30 cm² per channel and the field of view is 2 and 4 degrees. Every measurement lasts about 4 s. The time and, therefore, the relative optical-path difference for the measurement of every point of the interferogram is given by the zero crossings of the interferogram of a reference monochromatic channel at 1.2 μm which uses a laser diode as source. The two interferograms are double-sided and will have 16384 and 4096 points, respectively, corresponding to spectra of 6250 and 1823 useful points. Paper presented at the 6th Cosmic Physics National Conference, Palermo, 3–7 November 1992.     

Setup and performance of a streak camera apparatus for transient absorption measurements in the ns to ms range

We describe the setup and performance of an apparatus for simultaneous time- and spectrally resolved measurements of transient absorption. The key component in this apparatus is a streak camera, yielding, for every excitation of the sample, a two-dimensional data array with 512 × 512 data points. The apparatus covers the spectral range 350–750 nm and time windows ranging from 500 ns up to 10 ms. Due to the large dynamic range of the streak camera of 10,000:1 we obtain a multiplex factor of more than 100 compared with sequential measurements at individual wavelengths. This makes it possible to extract the maximum amount of information from small amounts of sample, e.g. light-sensitive proteins. We show that already a single pump probe pulse sequence can yield useful spectra in a 20-μs time range, and that 10 pump-probe pulse sequences yield good time constants from a global lifetime analysis. An iterative method is presented for the treatment of artifacts due to scattered excitation laser light or strong fluorescence. As an alternative to a global lifetime analysis we propose a maximum entropy-based inverse Laplace transform for analysis of the data. This results in a wavelength-dependent distribution of amplitudes p(k, λ) for all rate constants k accessible with a given time window. This analysis is model free and yields a direct visual evaluation of the uncertainties in the rate constants.     

Testing of a scintillator and fibre optic based radiation sensor

We describe the optimisation of RadLine^®; a small, real time, remotely operated radiation detector, which consists of an inorganic scintillation crystal coupled to a fibre optic cable transporting produced photons to a CCD camera some distance away. RadLine^® is tested in a beta and gamma narrow radiation field of 2.4 GBq, from a Caesium-137 (662 KeV) source, at doses rates between 0.125 mSvhr⁻¹ and 10 mSvhr⁻¹. Our results establish that the lower limit of the device corresponds to a dose rate of 0.2 mSvhr⁻¹, constrained by the signal to noise ratio of the instrument. We also demonstrate the process of characterising the RadLine^® for utilisation underwater due to its partial electrical inactiveness; and to consider how the instrument might perform in aquatic environments and ultimately in a First Generation Magnox Storage Ponds (FGMSP). The RadLine^® brings a marked difference to actual underwater radiation monitoring devices such as; HPGe, CZT and GM detectors, which not only incorporate the whole electronics within and are more bulky, only perform over a short range. The RadLine^®’s design offers signification value for intermediate (>100 m) and long range detection.     

Energy-filtered XPEEM with NanoESCA using synchrotron and laboratory X-ray sources: Principles and first demonstrated results

The importance of energy filtering in PEEM-based imaging methods has been shown in recent years with the availability of powerful instruments. A new instrument, the NanoESCA, combines a fully electrostatic PEEM column and an aberration corrected double hemispherical analyser as energy filter. This paper reports on recently demonstrated XPEEM results using the first commercially available NanoESCA instrument operated with both synchrotron soft X-rays and monochromatic laboratory Al Kα radiation. The implementation of elemental and bonding-state specific imaging is shown with both excitation sources. The presently achieved (but not yet ultimate) lateral resolutions on energy filtered core-level images are 150 nm with a large synchrotron spot and below 1 μm with a focused laboratory source. To date this is the unique example of laboratory XPEEM core-level imaging.     

Space-borne remote sensing of CO2, CH4, and N2O by integrated path differential absorption lidar: a sensitivity analysis

CO₂, CH₄, and N₂O are recognised as the most important greenhouse gases, the concentrations of which increase rapidly through human activities. Space-borne integrated path differential absorption lidar allows global observations at day and night over land and water surfaces in all climates. In this study we investigate potential sources of measurement errors and compare them with the scientific requirements. Our simulations reveal that moderate-size instruments in terms of telescope aperture (0.5–1.5 m) and laser average power (0.4–4 W) potentially have a low random error of the greenhouse gas column which is 0.2% for CO₂ and 0.4% for CH₄ for soundings at 1.6 μm, 0.4% for CO₂ at 2.1 μm, 0.6% for CH₄ at 2.3 μm, and 0.3% for N₂O at 3.9 μm. Coherent detection instruments are generally limited by speckle noise, while direct detection instruments suffer from high detector noise using current technology. The wavelength selection in the vicinity of the absorption line is critical as it controls the height region of highest sensitivity, the temperature cross-sensitivity, and the demands on frequency stability. For CO₂, an error budget of 0.08% is derived from our analysis of the sources of systematic errors. Among them, the frequency stability of ± 0.3 MHz for the laser transmitter and spectral purity of 99.9% in conjunction with a narrow-band spectral filter of 1 GHz (FWHM) are identified to be challenging instrument requirements for a direct detection CO₂ system operating at 1.6 μm. PACS 42.68.Wt; 95.75.Qr     

Modular High-Intensity Monochromatic In Situ Illumination Set-Up for Investigating ESR Photoactive Centers in Semiconductors

A versatile, modular in situ high-intensity monochromatic illumination set-up installed on a standard Q-band ESR spectrometer equipped with a cryostat and probe head for measurements at cryogenic temperatures, which can be easily assembled from commercially available optical components is presented. Using as monochromatic light sources pig-tailed laser diodes (LDs) or fiber-coupled light-emitting diodes (LEDs), a high efficiency of the light transfer (more than 95%) through an optical guide inserted in the sample holder is achieved in the sample area of the microwave cavity. With various LEDs and LDs, one can perform ESR in situ illumination experiments from UV to far-IR, in both cw and pulse mode. Its operation is illustrated with an experiment revealing the presence of certain ESR silent defects in oxygen-doped floating-zone ultrapure Si samples irradiated at room temperature with high-energy–high-fluence electron beams and pulse annealed up to 300 °C. New information is obtained by comparing the ESR spectra recorded at T = 120 K, without and with 1.06 µm across-the-gap in situ illumination.     

Frequency jitter and spectral width of an injection-seeded Q-switched Nd:YAG laser for a Doppler wind lidar

The design of a 50 Hz single longitudinal mode, diode-pumped and frequency-tripled Nd:YAG master oscillator power amplifier is described, and the first measurements of output parameters are presented. The laser oscillator is injection-seeded by a tuneable monolithic Nd:YAG ring laser and frequency stabilized by minimising the Q-switch build-up time. The laser system will be an integral part of an airborne instrument demonstrator for a first satellite based Doppler wind lidar to measure vertical profiles of one component of the atmospheric wind vector. This paper focuses on the investigation of the frequency jitter and the linewidth of the laser, which are measured on a pulse-to-pulse basis. For this purpose a compact, high accuracy beat frequency monitoring system has been developed at DLR. By operating the amplifier stage at half the repetition rate (50 Hz) of the oscillator, we could reduce the frequency stability from 10 MHz (rms) to 1.3 MHz (rms) (over a 14 s period). We have determined a mean linewidth of 15 MHz (FWHM) at 1064 nm. These measured laser parameters enable wind velocity measurements in the atmosphere (0–15 km) at an accuracy of 1 to 2 m/s. PACS 42.55.Xi; 42.60.Lh; 42.68.Wt     

Depth‐selective elemental imaging of microSD card by confocal micro XRF analysis

A semiconductor device, a microSD card, was measured by using two XRF instruments. 2D elemental images were obtained using a micro‐XRF system with a spatial resolution of 10 µm. Elemental distributions of the near‐surface region of the sample were clearly shown. Titanium was observed in the resin constituting the sample. Nickel and gold were observed on a terminal and localization of the sample. Elemental distribution of copper reflected the circuit structure of the measurement area that was in the neighborhood of the sample surface. Moreover, the elemental depth distributions of the sample were measured by using a confocal micro‐XRF instrument. The confocal micro‐XRF instrument was constructed in the laboratory with fine‐focus polycapillary x‐ray optics. The depth resolution of the developed spectrometer was 13.7 µm at an energy of Au Lβ (11.4 keV). The elemental images obtained at near‐surface by confocal micro‐XRF were the same as the results obtained from 2D micro‐XRF. However, different Cu images were obtained at a depth of several tens of micrometers. This indicates that microSD cards consist of a few different Cu‐circuit structure designs. The elemental depth distributions of each circuit structure of the semiconductor device were clearly shown by confocal micro‐XRF. Copyright © 2013 John Wiley & Sons, Ltd.     

Millimeter/submillimeter mixing based on the nonlinear plasmon response of two-dimensional electron systems

The nonlinear plasmon response of a two-dimensional electron system with an incorporated defect to monochromatic and bichromatic microwave radiation has been investigated. The operation of an electronic device (mixer) based on the plasmon response with a record operational speed has been demonstrated and analyzed. It has been found that the system response time is no more than τ = 25 ps. It has been shown that the nonlinear response of the system is caused by a new physical mechanism of nonlinearity induced by the presence of an inhomogeneity in the electron system.     

Telecom-grade fiber laser-based difference-frequency generation and ppb-level detection of benzene vapor in air around 3 μm

We report on the development of a field deployable compact laser instrument tunable over ∼232 cm⁻¹ from 3.16 to 3.41 μm (2932.5–3164.5 cm⁻¹) for chemical species monitoring at the ppb-level. The laser instrument is based on widely tunable continuous-wave difference-frequency generation (DFG), pumped by two telecom-grade fiber lasers. DFG power of ∼0.3 mW near 3.3 μm with a spectral purity of ∼3.3 MHz was achieved by using moderate pumping powers: 408 mW at 1062 nm and 636 mW at 1570 nm. Spectroscopic performance of the developed DFG-based instrument was evaluated with direct absorption spectra of ethylene at 3.23 μm (∼3094.31 cm⁻¹). Absorption spectra of vapor-phase benzene near 3.28 μm (∼3043.82 cm⁻¹) were recorded with Doppler-limited resolution. Line intensities of the most intense absorption lines of the ν ₁₂ band near 3043.8 cm⁻¹ were determined to support development of sensitive mid-infrared trace gas detection of benzene vapor in the atmosphere. Detection of benzene vapor in air at different concentration levels has been performed for the first time using multi-pass cell enhanced direct absorption spectroscopy at ∼3.28 μm with a minimum detectable concentration of 50 ppb (1σ).     

Optical–feedback cavity–enhanced absorption: a compact spectrometer for real–time measurement of atmospheric methane

We report on the application of the new technique of optical–feedback cavity–enhanced absorption spectroscopy to the real–time quantitative measurement of tropospheric methane traces from an airplane using a compact, low cost instrument based on a telecommunication–type diode laser operating close to room temperature. Methane concentration is obtained by fitting the absorption line centered at 1658.96 nm (6026.23 cm^-1) which belongs to the first overtone transition of the CH stretch vibration. The measurement rate is about 30 Hz, but the response time is limited to about 0.3 s by the gas flow in the measurement cell. The instrument provides the absolute ambient methane concentration accurate to ±1% (±20 ppb) without need for a periodic calibration. This is demonstrated by a hands–off comparison with a self–calibrating chromatographic setup during 10 days. The observed measurement stability can be extrapolated to much longer time periods. With respect to the short–term performance (minutes) fast concentration changes at the level of 1 ppb can be detected, and we believe this performance can be extended to the long term. Finally, a laboratory comparison with a lead–salt mid–infrared diode laser multipass spectrometer (operating close to 3028 cm^-1 at liquid nitrogen temperature) demonstrates a similar performance. PACS 07.88.+y; 42.55.Px; 42.62.Fi     

Development of an open-path incoherent broadband cavity-enhanced spectroscopy based instrument for simultaneous measurement of HONO and NO2 in ambient air

We report on the development of an optical instrument based on incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) for simultaneous open-path measurements of nitrous acid (HONO) and nitrogen dioxide (NO₂) in ambient air using a UV light emitting diode operating at ∼366 nm. Detection limits of ∼430 pptv for HONO and ∼1 ppbv for NO₂ were achieved with an optimum acquisition time of 90 s, determined by an Allan variance analysis. Based on a 1.85 m long high optical finesse open-path cavity, the effective optical path length of 2.8 km was realized in aerosol-free samples or in an urban environment at modest aerosol levels. Such a kilometer long optical absorption is comparable to that achieved in the well established differential optical absorption spectroscopy (DOAS) technology while keeping the instrument very compact. Open-path detection configuration allows one to avoid absorption cell wall losses and sampling induced artifacts. The demonstrated sensitivity and specificity shows high potential of this cost-effective and compact infrastructure for future field applications with high spatial resolution.     

Characteristics of a multi-keV monochromatic point x-ray source based on vacuum diode with laser-produced plasma as cathode

Temporal, spatial and spectral characteristics of a multi-keV monochromatic point x-ray source based on vacuum diode with laser-produced plasma as cathode are presented. Electrons from a laser-produced aluminium plasma were accelerated towards a conical point tip titanium anode to generate K-shell x-ray radiation. Approximately 10₁₀ photons/pulse were generated in x-ray pulses of ∼18 to ∼28 ns duration from a source of ∼300 μm diameter, athυ = 4.51 keV (K _α emission of titanium), with a brightness of ∼10²⁰ photons/cm²/s/sr. This was sufficient to record single-shot x-ray radiographs of physical objects on a DEF-5 x-ray film kept at a distance of up to ∼10 cm.