共查询到20条相似文献,搜索用时 31 毫秒
1.
V. N. Makhov T. V. Uvarova M. Kirm S. Vielhauer 《Bulletin of the Lebedev Physics Institute》2016,43(12):348-351
Thermal quenching of interconfigurational 5d-4f luminescence of Er3+ and Tm3+ ions in BaY2F8 crystals is studied in the temperature range of 330–790 K. The quenching temperatures are ~575 and ~550 K for Er3+ and Tm3+, respectively. It is shown that quenching of 5d-4f luminescence of Tm3+ ions is caused by thermally stimulated ionization of 5d electrons to the conduction band. 相似文献
2.
Yu. K. Voron’ko E. V. Zharikov D. A. Lis A. V. Popov V. A. Smirnov K. A. Subbotin 《Physics of the Solid State》2008,50(9):1605-1610
Single crystals of double sodium-containing lanthanum and gadolinium molybdates doped with Tm3+ ions were synthesized by the Czochralski method. The spectroscopic properties of these crystals were investigated from the viewpoint of their use as active media in diode-pumped lasers. The polarized spectra of absorption on the 3 H 4 and 3 F 4 levels and the polarized spectra of luminescence due to the 3 F 4-3 H 6 laser transition were recorded, and the lifetimes of the 3 H 4 and 3 F 4 excited states of the Tm3+ ions were determined. The luminescence cross sections were calculated using the Füchtbauer-Ladenburg formula. The simulation of the decay curve of the 3 H 4 excited state according to the Golubov-Konobeev-Sakun method revealed that, in the crystals under investigation, the interaction between Tm3+ ions predominantly occurs through the dipole-dipole mechanism. 相似文献
3.
This paper reports on the spectroscopic properties and energy transfer analysis of Tm3+-doped BaF2-Ga2O3-GeO2-La2O3 glasses with different Tm2O3 doping concentrations (0.2, 0.5, 2.0, 2.5, 3.0, 3.5, 3.5, 4.0 wt%). Mid-IR fluorescence intensities in the range of 1,300 nm−2,200 nm
have been measured when excited under an 808 nm LD for all the samples with the same pump power. Energy level structure and
Judd-Ofelt parameters have been calculated based on the absorption spectra of Tm3+, cross-relaxation rates and multi-phonon relaxation rates have been estimated with different Tm2O3 doping concentrations. The maximum fluorescence intensity at around 1.8 μm has been obtained in Tm2O3-3 wt% sample and the maximum value of calculated stimulated emission cross-section of Tm3+ in this sample is about 0.48 × 10−20 cm2 at 1,793 nm, and there is not any crystallization peak in the DSC curve of this sample, which indicate the potential utility
of Tm3+-doped BaF2-Ga2O3-GeO2- La2O3 glass for 2.0-μm optical fiber laser. 相似文献
4.
Yb3+-Tm3+ co-doped up-conversion powder phosphors using Zn(AlxGa1-x)2O4 (ZAGO) as the host materials were synthesized via solid-state reaction successfully. In addition, the morphology, structural characterization and up-conversion luminescent properties were all investigated by scanning electron microscope (SEM), x-ray diffraction (XRD) and fluorescence spectrophotometer (F-7000), respectively. Under the excitation of a 980 nm laser, all as-prepared powders can carry out blue emission at about 477 nm (corresponding to 1G4 → 3H6 transition of Tm3+ ions), and red emission at about 691 nm (attributed to 3F3 → 3H6 transition of Tm3+ ions). Also, the influence of doping Al3+ ions were investigated. In brief, the doping of Al3+ ions has no effect on the position of emission peak. Howbeit the up-conversion efficiency and intensity of ZAGO:Yb,Tm phosphors are stronger than ZGO:Yb,Tm and ZAO:Yb,Tm phosphors, while the crystallinity is the opposite. More particularly, all as-prepared powder phosphors emit strong luminescence, which is observable by the naked eye, demonstrating the potential applications in luminous paint, luminescent dye, etc. 相似文献
5.
We report on 2.0-μm emission characteristic and energy transfer of Ho3+-doped tellurite glass sensitized by Tm3+ upon excitation of a conventional 808 nm laser diode. The Judd-Ofelt strength parameters, spontaneous radiative transition
probabilities and radiative lifetime of Ho3+ have been calculated from the absorption spectra by using the Judd-Ofelt theory. Significant enhancement of 2.0-μm emission
of Ho3+ has been observed with increasing Tm3+ doping up to 0.7 mol%. The energy transfer coefficient of the forward Tm3+→Ho3+ is approximately 17 times larger than that of the backward Tm3+←Ho3+ energy transfer. Our result indicates that the maximum gain of 2.0-μm emission, assigned to the transition of 5I7→5I8 of Ho3+, might be achieved from the tellurite glass at the concentration of 0.5 mol% of Tm2O3 and 0.15 mol% of Ho2O3. The high gain coefficient and quantum efficiency (1.16) along with the large value of the product of the stimulated emission
cross-section and the measured radiative lifetime (4.12×10−27 m2s) of the Ho3+/Tm3+-codoped tellurite glasses might find potential applications in efficient 2.0-μm laser. 相似文献
6.
We measured the absorption and luminescence spectra of Nd3+ ions in an inorganic solvent POCl3-BCl3. The spectra were analyzed in terms of the Judd-Ofelt theory. We calculated the Judd-Ofelt parameters, oscillator strengths,
spontaneous emission probabilities, luminescence quantum yield, and the stimulated emission cross section for the laser transition
4
F
3/2 → 4
I
11/2 of the neodymium ion in a POCl3-BCl3-Nd3+ solution. 相似文献
7.
Vacuum ultraviolet luminescence of Er3+ ions in LiYF4 and BaY2F8 crystals has been investigated. It is revealed that under excitation by 193 nm radiation from an ArF excimer laser the interconfigurational 5d–4f radiative transitions in Er3+ ions are observed. It is shown that from the LiYF4:Er crystal only the spin-forbidden luminescence (λ = 165 nm) is detected, whereas both the spin-forbidden (λ = 169 nm) and spin-allowed (λ = 160.5 nm) components are observed from the BaY2F8:Er crystal. 相似文献
8.
V. M. Marchenko L. D. Iskhakova A. V. Kir’yanov V. M. Mashinsky N. M. Karatun E. M. Sholokhov 《Laser Physics》2012,22(1):177-183
Yb2O3 polycrystals with a size of up to 10 mm are synthesized using the sintering and melting of the ultrapure Yb2O3 powders by the CO2-laser radiation with the power P
L ≤ 100 W at the wavelength λ = 10.6 μm at the melting point T
m = 2703 K, forming due to surface tension in melt, and crystallization in air. The analysis of the polycrystal microstructure
using the methods of optical and electron microscopy and X- ray diffractometry shows that perfect oxide crystallites are formed
in the course of crystallization after melting-through. The transformation of the luminescence and selective heat radiation
(SHR) spectra of the Yb2O3 polycrystals is studied under the resonant excitation at λ ≈ 975 nm using a laser diode and the laser heating at the wavelength
λ = 10.6 μm. When the resonant excitation power of the Yb3+ ions increases from 0.15 to 4.5 W, the Stokes luminescence of the Yb2O3 polycrystals is sequentially transformed into SHR and the thermal radiation of the crystal lattice. The transformation of
the emission spectra of the Yb2O3 polycrystals with an increase in the laser heating intensity by about four orders of magnitude can be represented as the
low-temperature heat radiation, spectral burst of the thermodynamically nonequilibrium SHR of the Yb3+ ions, and the high-temperature radiation of the crystal lattice. The temperature dependence of the luminescence spectra and
SHR of the Yb2O3 polycrystals on the intensity of the laser and laser-thermal excitation and the concentration quenching of the Yb3+ luminescence in oxides indicate the key role of the interaction of the f-electron shell of the Yb3+ ions with the natural oscillations of the crystal lattice in the processes of the multiphonon excitation and nonradiative
(multiphonon) and radiative (vibronic) relaxation. 相似文献
9.
YVO4:Yb3+,Er3+; YVO4:Yb3+,Tm3+; and YVO4:Yb3+,Er3+,Tm3+ were all synthesized via sol-gel method with a subsequent thermal treatment. Specifically, YVO4:Yb3+,Er3+,Tm3+ phosphors were prepared with different annealing temperatures to study the influence of temperature. The transmission electron microscope (TEM), scanning electron microscope (SEM), X-ray diffractometer (XRD), and photoluminescent (PL) spectrofluorometer were used to investigate the morphology, crystal structure, and up-conversion luminescent properties of all samples. In summary, all samples were granular-like nanoparticles and well crystallized with the same tetragonal phase as YVO4. Under the irradiation at 980 nm, YVO4:Yb3+,Er3+ phosphors can generate green emission at 525 and 553 nm and red emission at 657 nm, while YVO4:Yb3+,Tm3+ phosphors can generate blue emission at 476 nm, red emission at 648 nm, and near-infrared emission at 800 nm. Notably, YVO4:Yb3+,Er3+,Tm3+ samples can exhibit green emission, blue emission, red emission, and near-infrared emission at the same time, which might endow the as-prepared samples with potential applications in many fields, such as luminous paint, infrared detection, and biological label. 相似文献
10.
Tm3+/Yb3+ codoped transparent glass ceramic containing β-PbF2 nanocrystals was successfully prepared. After thermal treatment, emissions from the 1G4 state of Tm3+ excited by 980 nm laser were greatly quenched by cross relaxation and the 700 nm luminescence from Tm3+:3F2,3→3H6 transition was strongly enhanced. A nearly monochromatic red luminescence band was observed. Based on the luminescence decay curves and Judd-Ofelt analysis, the strengthened cross relaxation played an important role in such phenomenon. 相似文献
11.
F. Song L. Han C. Zou J. Su K. Zhang L. Yan J. Tian 《Applied physics. B, Lasers and optics》2007,86(4):653-660
Upconversion blue emissions of Tm3+-ion-heavy-doped NaY(WO4)2 crystals are investigated with three different near-infrared pump mechanisms. The dependence of upconversion efficiency on
the pump mechanism is analyzed from the scope of the concentration quenching effect. Three cross-relaxation processes, , , and , which influence the upconversion dominantly in the Tm3+-heavy-doped system, are demonstrated theoretically and experimentally. The results indicate that Yb3+ ions can weaken the concentration quenching effect of Tm3+ ions significantly so that the blue emission efficiency can be enhanced by one order of magnitude. At the same time, the
wavelength of the pump source also has considerable influence on both the population of some crucial energy levels and the
upconversion mechanism. Experiments show that the upconversion blue emission in Tm3+/Yb3+ co-doped NaY(WO4)2 crystal under 980-nm laser diode excitation is the most intensive of these three different near-infrared pump mechanisms.
The conclusions are confirmed by spectra measurements and calculations of Judd–Ofelt theory and Miyakawa–Dexter theory.
PACS 42.70.Hj; 78.55.-m 相似文献
12.
Mustafa İlhan Mete Kaan Ekmekçi Rıza Gürcan Oraltay Ali Sadi Başak 《Journal of fluorescence》2017,27(1):199-203
Undoped and Nd3+ doped lutetium niobate phases have been prepared by a conventional solid state reaction method using lutetium acetate and niobium oxide at 1250 °C for 6 h. X-ray diffraction patterns of the 6 mol% Lu3NbO7 sample exhibited a cubic fluorite single phase. Phase structure exhibited interesting crystallization behaviour depending on increasing Nd3+ concentration which led to a Lu3NbO7 single phase formation during the heat treatment process. SEM investigations were also in agreement with the XRD results. Morphologies of Nd3+ doped lutetium niobate powders exhibited oval like shapes and grain sizes varied between 0.3 and 5 μm. Near-infrared luminescence properties of Nd3+ doped Lu3NbO7 were also studied. 1.06 μm laser transition characteristics of Nd3+ doped lutetium niobate have been observed. Concentration quenching phenomenon was not detected depending on increasing Nd3+ doping concentrations at room temperature. 相似文献
13.
Photoluminescence studies of pure and Dy3+, Eu3+ doped Sr2CeO4 compounds are presented by oxalate precipitation method for solid state lighting. The prepared samples also characterized by XRD, SEM (EDS) and FTIR spectroscopy. The pure Sr2CeO4 compound displays a broad band in its emission spectrum when excited with 280 nm wavelength, which peaks centered at 488 nm, which is due to the energy transfer between the molecular orbital of the ligand and charge transfer state of the Ce4+ ions. Emission spectra of Sr2CeO4 with different concentration of Dy3+ ions under near UV radiation excitation, shows that intensity of luminescence spectra is found to be affected by Dy3+ ions, and it increases with adding some percentages of Dy3+ ions. The maximum doping concentration for quenching is found to be Dy3+?=?0.2 mol % to Sr2+ions. The observed broad spectrum from 400 to 560 nm is mainly due to CT transitions in Sr2CeO4 matrix and some fractional contribution of transitions between 4F9/2 → 6H15/2 of Dy3+ ions. Secondly the effect of Eu3+ doping at the Sr2+ site in Sr2CeO4, have been studied. The results obtained by doping Eu3+ concentrations (0.2 mol% to 1.5 mol%), the observed excitation and emission spectra reveal excellent energy transfer between Ce4+ and Eu3+. The phenomena of concentration quenching are explained on the basis of electron phonon coupling and multipolar interaction. This energy transfer generates white light with a color tuning from blue to red, the tuning being dependent on the Eu3+ concentration. The results establish that the compound Sr2CeO4 with Eu3+?=?1 mol% is an efficient “single host lattice” for the generation of white lights under near UV-LED and blue LED irradiation. The commission internationale de I’Eclairage (CIE) coordinates were calculated by Spectrophotometric method using the spectral energy distribution of prepared phosphors. 相似文献
14.
The photoluminescence and photoexcitation spectra as well as the luminescence decay kinetics of Er3+ ions in the visible ultraviolet and vacuum ultraviolet (VUV) regions have been studied by the method of low-temperature,
time-resolved VUV-spectroscopy on excitation by synchrotron radiation. In the VUV spectral region of the luminescence of SrF2:1% Er3+, the 146.5-nm band with a time of decay of less than 0.6 nsec was revealed together with the well-known emission band at
164.3 nm (decay constant in the microsecond range). Its possible nature is discussed. The specific features of the formation
of photoexcitation spectra of the f-f and f-d transitions in the Er3+ ion are considered. Competition between the processes of excitation of f-f and d-f luminescence has been revealed. It manifests
itself in the inverse relationship of their photoexcitation spectra in a range of energies of incident photons that are close
to the position of the 4fn−15d configuration levels.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 4, pp. 519–523, July–August, 2005. 相似文献
15.
Na0.4Y0.6F2.2:Tm3+ crystals with a thulium content from 1 to 100 at % have been grown by the Stockbarger-Bridgman method. The optical spectra of Na0.4Y0.6F2.2:Tm3+ crystals were investigated in detail at room and low (10 K) temperatures, and the luminescence kinetics was analyzed using different excitation methods. The structure of the Stark splitting of thulium levels as “quasi-centers,” characterized by inhomogeneous broadening of the Stark components, is determined from analysis of the absorption spectrum at 10 K. The oscillator strengths of the transitions from the ground state to excited multiplets are determined from the absorption cross-section spectra at 300 K for ten transitions in the range 5000–38 500 cm?1 and seven transitions in the range 5000–28 500 cm?1. The transition intensity parameters Ω t , obtained by the Judd-Ofelt method from the spectra due to the transitions to ten and seven excited levels, were found to be, respectively, (i) Ω2 = 1.89 × 10?20, Ω4 = 2.16 × 10?20, and Ω6 = 1.40 × 10?20 cm2 and (ii) Ω2 = 2.04 × 10?20, Ω4 = 2.01 × 10?20, and Ω6 = 1.44 × 10?20 cm2. These values of the intensity parameters were used to calculate the radiative transition probabilities and branching ratios and to estimate the multiphonon nonradiative transition probabilities for NYF:Tm. The luminescence decay kinetics from thulium radiative levels upon their selective excitation by nanosecond laser pulses has been studied and the lifetimes of thulium radiative levels in NYF crystals have been found. 相似文献
16.
P. A. Rodnyĭ I. V. Berezovskaya A. S. Voloshinovskii G. B. Stryganyuk A. S. Potapov 《Optics and Spectroscopy》2003,94(4):550-555
Spectral and kinetic characteristics of the luminescence and luminescence excitation spectra of polycrystalline SrB4O7:Pr (1%) and SrB6O10:Pr (1%) samples are studied at 150–170 K. The samples show an intense luminescence band in the vicinity of 405 nm (1 S 0→1 I 6 transitions of Pr3+) and shorter wavelength bands also assigned to transitions from the 1 S 0 level. The main luminescence decay constant is ~2×10?7 s. The excitation spectra of the 1 S 0 luminescence in these crystals are significantly different. The SrB4O7:Pr crystal shows three well-resolved bands at 6.14, 6.55, and 6.91 eV in the region of the 4f 2→4f 15d transitions and a complex structure in the region of interband transitions (7.1–20 eV), whereas the SrB6O10:Pr crystal shows a weakly structured band at 6.31 eV and no excitation in the region of the interband transitions. The physical mechanisms that may be responsible for the observed features of the spectra are discussed. 相似文献
17.
The luminescent properties of Eu3+ and Eu2+ ions in sodium pyrophosphate, Na4P2O7, have been studied. The excitation spectrum of the Eu3+ emission in Na4P2O7 consists of several sets of bands in the range 280–535 nm due to 4f–4f transitions of Eu3+ ions and a broad band with a maximum at about 240 nm interpreted to be due to a charge transfer (CT) transition from oxygen
2p states to empty states of the Eu3+ 4f6-configuration. Although the CT band energy is large enough, the quantum efficiency (η) of the Eu3+ emission in Na4P2O7 under CT excitation was estimated to be very low (η ≤ 0.01). In terms of a configurational coordinate model, this fact is
interpreted as a result of the high efficiency of a radiationless relaxation from the CT state to the 7F0 ground state of Eu3+ ions occupying sodium sites in Na4P2O7. A strong reducing agent is required in order to stabilize Eu2+ ions in Na4P2O7 during the synthesis. Several nonequivalent Eu2+ luminescence centers in Na4P2O7 were found. 相似文献
18.
We have investigated various pulsed operation regimes of a diode-pumped Yb3+-doped fiber laser with both an acoustooptic filter and a shutter inside the resonator. To imbed the polarization-sensitive acoustooptic-tunable spectral filter into the polarization-nonmaintaining resonator, based on an “isotropic” single-mode fiber without “polarization’ losses, we have used a CaCO3 single-crystal nondispersive thermostable polarization splitter. Stable smooth bell-shaped laser pulses were obtained in the Q-switch generation regime across the entire wavelength tuning band. Their duration depended on the resonator travel time and their repetition rate was determined exclusively by the outer high-frequency generator controlling the acoustooptic shutter. A pulsed laser radiation tuning bandwidth of more than 20-nm at a repetition rate band of 10–100 kHz was observed in the amplification band of the Yb3+-doped fiber. A stable average power of 30 W of the pulsed 70-ns 100-kHz laser radiation in a near Gaussian beam was reached by means of the two-stage amplifier based on Yb3+-doped fibers with an enlarged mode field diameter (14 μm). The amplifier was pumped by λ = 975 nm CW multimode laser diodes with a maximum average power of 42 W. 相似文献
19.
B. N. Kazakov A. V. Mikheev O. G. Goriev S. L. Korableva V. V. Semashko 《Optics and Spectroscopy》2016,121(4):523-533
The results of a complex analysis of the excitation mechanisms of the up conversion luminescence of Ho3+:LiYbF4 (0.2 at %) crystal are presented. The spatial distribution of the upconversion luminescence intensity is studied by the photographs of longitudinal cross sections at different positions of the laser beam waist with respect to the sample. The surface power density of the pump laser diode radiation (0.755 W, λ = 933 nm) was changed by focusing the beam (similar to Z-scanning). The dependences of the longitudinal luminescence cross sections, as well as of the spectral and kinetic characteristics of Ho3+ and Yb3+ luminescence, on the position of the laser beam waist are determined. It is found that there exist two different mechanisms of the population of the energy levels of Ho3+ ions from which green and red luminescence occur, namely, cooperative sensitization of luminescence and absorption of induced photon groups (JETP Letters, 102 (5), 279 (2015)). It is shown that the contributions of these mechanisms vary both in time and over the crystal volume. All the observed spatial, spectral, and temporal specific features of the upconversion luminescence of Ho3+:LiYbF4 (0.2 at %) crystal are qualitatively explained. 相似文献
20.
P.?A.?Rodny? 《Optics and Spectroscopy》2009,107(2):270-274
The energies of the ground 4f
n
levels of tri- and divalent rare-earth ions with respect to the conduction and valence bands of Gd2O2S crystal has been determined. It is shown that the Pr3+, Tb3+, and Eu3+ ions can be luminescence centers in Gd2O2S. The levels of the Nd3+, Dy3+, Er3+, Tm3+, Sm3+, and Ho3+ ions lie in the valence band; therefore, these ions cannot play the role of activators. The ground 4f level of the Ce3+ ion is near the midgap, due to which Ce3+ effectively captures holes from the valence band and electrons from the conduction band and significantly decreases the afterglow
level of the Gd2O2S:Pr and Gd2O2S:Tb phosphors. 相似文献