Statistics of photocounts of blinking fluorescence of quantum dots

The blinking of quantum dots under the action of laser radiation is described based on a model of a binary (two-state) renewal process with on (fluorescent) and off (non fluorescent) states. The T _on and T _off sojourn times in the on and off states are random and power-law distributed with exponents 0 < α < 1 and 0 < β < 1; the averages of the on and off times are infinite. As a consequence of this, the Gaussian statistics is inapplicable and the process is described using a more general statistics. An equation for the density of distribution p(t _on|t) of the total on time during the observation time t is derived that contains derivatives of fractional orders α and β. A solution to this equation is found in terms of fractional stable distributions. The Poisson transform of the density p(t _on|t) leads to the photon counting distribution and determines the fluorescence statistics. It is demonstrated that, if a blinking process with exponents α < β is implemented, then, at fairly long times, the on time will considerably prevail over the off time, i.e., blinking will be suppressed. This behavior is evidenced by the types of distributions of the total fluorescence time, the decay of relative fluctuations, and the Monte Carlo simulated trajectories of the process.     

Influence of ferroelectric polarization on the energetics of the reaction of 2-fluoroethanol on BaTiO3

The influence of ferroelectric polarization on the reaction of 2-fluoroethanol on ferroelectric BaTiO₃ thin films was characterized. 2-Fluoroethanol was found to absorb dissociatively on the BaTiO₃ surface to form an alkoxide that reacts upon heating to produce acetaldehyde, ethylene, and adsorbed fluorine atoms which remain on the surface. Temperature programmed desorption (TPD) studies showed that the activation energy for the production of the acetaldehyde product was a function the orientation of the ferroelectric dipoles with an ∼4 kJ mol⁻¹ higher value on the c+ termination relative to the c− termination.     

Metallographic study of the oxidation of Ni3Al-Ni3Nb alloys

Conclusions A study has been made of the microstructure of the scale formed on single- and two-phase alloys of the system Ni₃Al-Ni₃Nb and also on the compound Ni₃Nb. It was found that the scale on the alloys investigated consists of several layers, and the microhardness of each layer was measured.An X-ray phase analysis was made of each layer of the scale formed on Ni₃Nb after 100 hours oxidation at 1100 °.A scheme has been devised which shows the distribution of the oxides in the scale on the compounds Ni₃Al and Ni₃Nb and also on single- and two-phase alloys at 650 and 900 °. Some ideas concerning the mechanism of formation of the individual oxides are put forward.     

STM studies of PTCDA supramolecular self-assembling on anisotropic surfaces of reconstructed InSb

Self-assembly of 3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA) molecules on a c(8 × 2) reconstructed InSb(0 0 1) surface as well as on an asymmetrical (1 × 3) InSb(0 0 1) is investigated by means of high resolution scanning tunneling microscopy. The formation of well-ordered one-dimensional molecular lines is observed at low coverage on a former face, whereas on the latter molecules are found as isolated entities. At room temperature spontaneous hopping between energetically similar sites is observed within the lines. At a monolayer coverage flat molecular surface is obtained for both reconstructions, on the c(8 × 2) the layer is composed of neighboring one-dimensional lines, on the (1 × 3) molecular structure does not reveal any long range order. Application of the special experimental procedure provides direct comparison of molecule behavior on both reconstructions of the same sample.     

密度泛函理论研究Hg与Auqn(n=1—6, q=0,+1,-1) 团簇的相互作用

采用密度泛函理论中的广义梯度近似对Hg与小团簇Au ^q_n (n=1—6, q=0, +1, -1)的相互作用进行了系统研究. 结果表明,除Au₅^+,-团簇外,前线分子轨道理论可以成功预测大部分Au _n Hg ^q 复合物的最低能量结构. Au_n团簇对Hg的吸附受团簇尺寸大小和团簇所携带电荷的影 关键词： 密度泛函理论 汞 金团簇 吸附能     

An extremely rich repertoire of bursting patterns during the development of cortical cultures

Background  

We have collected a comprehensive set of multi-unit data on dissociated cortical cultures. Previous studies of the development of the electrical activity of dissociated cultures of cortical neurons each focused on limited aspects of its dynamics, and were often based on small numbers of observed cultures. We followed 58 cultures of different densities – 3000 to 50,000 neurons on areas of 30 to 75 mm² – growing on multi-electrode arrays (MEAs) during the first five weeks of their development.     

Accuracy and repeatability of QRAPMASTER and MRF-vFA

Our purpose is to evaluate bias and repeatability of the quantitative MRI sequences QRAPMASTER, based on steady-state imaging, and variable Flip Angle MRF (MRF-VFA), based on the transient response.Both techniques are assessed with a standardized phantom and five volunteers on 1.5 T and 3 T clinical scanners. All scans were repeated eight times in consecutive weeks.In the phantom, the mean bias±95% confidence interval for T1 values with QRAPMASTER was 10 ± 10% on 1.5 T and 4 ± 13% on 3.0 T. The mean bias for T1 values with MRF-vFA was 21 ± 17% on 1.5 T and 9 ± 9% on 3.0 T. For T2 values the mean bias with QRAPMASTER was 12 ± 3% on 1.5 T and 23 ± 1% on 3.0 T. For T2 values the mean bias with MRF-vFA was 17 ± 1% on 1.5 T and 19 ± 2% on 3.0 T. QRAPMASTER estimated lower T1 and T2 values than MRF-vFA. Repeatability was good with low coefficients of variation (CoV). Mean CoV ± 95% confidence interval for T1 were 3.2 ± 0.4% on 1.5 T and 4.5 ± 0.8% on 3.0 T with QRAPMASTER and 2.7% ± 0.2% on 1.5 T and 2.5 ± 0.2% on 3.0 T with MRF-vFA. For T2 were 3.3 ± 1.9% on 1.5 T and 3.2 ± 0.6% on 3.0 T with QRAPMASTER and 2.0 ± 0.4% on 1.5 T and 5.7 ± 1.0% on 3.0 T with MRF-vFA.The in-vivo T1 and T2 are in the range of values previously reported by other authors.The in-vivo mean CoV ± 95% confidence interval in gray matter were for T1 1.7 ± 0.2% using QRAPMASTER and 0.7 ± 0.5% using MRF-vFA and for T2 were 0.9 ± 0.4% using QRAPMASTER and 2.4 ± 0.5% using MRF-vFA. In white matter were for T1 0.9 ± 0.3% using QRAPMASTER and 1.3 ± 1.1% using MRF-vFA and for T2 were 0.7 ± 0.4% using QRAPMASTER and 2.4 ± 0.4% using MRF-vFA. A GLM analysis showed that the variations in T1 and T2 mainly depend on the field strength and the subject, but not on the follow-up repetition in different days. This confirms the high repeatability of QRAPMASTER and MRF-vFA.In summary, QRAPMASTER and MRF-vFA on both systems were highly repeatable with moderate accuracy, providing results comparable to standard references. While repeatability was similar for both methods, QRAPMASTER was more accurate. QRAPMASTER is a tested commercial product but MRF-vFA is 4.77 times faster, which would ease the inclusion of quantitative relaxometry.     

Calculation of the probability of optical transitions in strong electric fields

An algorithm is proposed for calculating the spectrum of the cross section for photoionization of carriers on deep centers in electric fields on the basis of the form function of an optical transition.An experiment and calculations were performed for the complex V_Ga-S_As in GaAs. The proposed model is compared with theoretical works based on the single-coordinate approximation. It is concluded that the single-coordinate model is applicable for describing the field-dependence of the cross section for photoionization of an electron on a V_Ga-S_As center. Data on the influence of an external electric field on the change in the moments of the form function of the absorption band of the complex V_Ga-S_As in GaAs are obtained. It is concluded that an electric field influences the adiabatic potentials of the center investigated.     

Concentration of Laplace Eigenfunctions and Stabilization of Weakly Damped Wave Equation

In this article, we prove some universal bounds on the speed of concentration on small (frequency-dependent) neighbourhoods of sub-manifolds of L²-norms of quasi modes for Laplace operators on compact manifolds. We deduce new results on the rate of decay of weakly damped wave equations.     

Theory of magnetic-breakdown oscillations of the galvanomagnetic properties of aluminum taking account of the spin of the conduction electrons

The theory of magnetic breakdown, taking account of the spin of the conduction electrons, is used to calculate the galvanomagnetic properties of aluminum, where the system of electron trajectories in a magnetic field contains small β orbits. Expressions are obtained for the magnetoresistance and Hall resistance in the case of a two-dimensional magnetic-breakdown network of trajectories on the basis of stochastic electron motion on large orbits and coherent electron motion on the β orbits. Qualitative agreement is obtained with the existing experimental data. Zh. éksp. Teor. Fiz. 111, 1651–1666 (May 1997)     

SERS and XPS observation of the adsorption behavior of NO and NO2 on a silver powder surface

The influence of H₂O on the adsorption behavior of NO or NO₂ on a silver powder surface was studied by SERS and XPS at room temperature. Water vapor was found to be responsible for the adsorption of NO on the silver powder surface. When surface species such as Ag₂O are present on the surface, some of the NO₂ molecules are adsorbed on the surface species to produce NO^-₃, whereas NO molecules are adsorbed on a different site to produce NO^-₂.     

Covalent immobilization of myosin forin-vitro motility of actin

The present study reports the covalent immobilization of myosin on glass surface andin-vitro motility of actin-myosin biomolecular motor. Myosin was immobilized on poly-L-lysine coated glass using heterobifunctional cross linker EDC and characterized by AFM. Thein-vitro motility of actin was carried out on the immobilized myosin. It was observed that velocity of actin over myosin increases with increasing actin concentration (0.4–1.0 mg/ml) and was found in the range of 0.40–3.25 μm/s. The motility of actinmyosin motor on artificial surfaces is of immense importance for developing nanodevices for healthcare and engineering applications     

Functional integral representations of partition function without limiting procedure. Techniques of calculation of moments

A definition of the Feynman path integral which does not rest on a limiting procedure based on time-slicing has been given by DeWitt-Morette. We present in this paper a discussion of real Gaussian measures and formulate expressions for the quantum statistical partition function directly in terms of measures of integration on the topological vector space ø₀ of continuous functions defined on the time intervalT = (t _a ,t _b ), such thatx(t _a ,t _b )=0 for allx ? ø₀. We give a definition of a measure for the space ø₀ equivalent to the path integral based on the Uhlenbeck-Ornstein probability distribution. We give expressions for the partition function using the Wiener-Feynman measure and the Uhlenbeck-Ornstein measure. As an exercise in the use of the new techniques, we present calculations of moments of potential functions. The techniques will enable one to solve in a rigorous manner practical problems in quantum statistical mechanics.     

Interaction of dyes with nanoclusters adsorbed on the surface of AgBr microcrystals

We have performed a comparative luminescence investigation into spectral sensitization with dyes of holographic emulsions that contain AgBr microcrystals and are subjected to chemical sulfur or reducing sensitization. We show that, upon spectral sensitization of silver sulfide (Ag₂S) _n nanoclusters located on AgBr microcrystals, the polylayer adsorption of dyes on the surface of nanoclusters is observed, which is caused by van der Waals forces in the J-aggregated state. For silver oxide (Ag₂O) _m nanoclusters located on AgBr micro-crystals, the adsorption of dyes on their surface occurs only if chlorine atoms of heterocyclic residues of the dye interact with the nanocluster surface, which determines the adsorption of the dye as its chemisorption. In the remaining investigated cases, the polylayer adsorption of dyes during the spectral sensitization occurs not on the surface of nanoclusters but rather on the surface of AgBr microcrystals, initially in the J-aggregated state and then in the molecular- and H-aggregated states.     

Influence of the ferromagnetic structure on the speed of propagation of magnetoelastic vibrations

The effect of thermomagnetic treatment temperature on the speed of magnetoelastic vibrations propagating in aFe _81.5 B _13.5 Si ₃ C ₂ metal alloy is investigated. A minimum is found in the plot of the dependence of the speed of magnetoelastic vibrations on the thermomagnetic treatment temperature. No minimum is observed in this dependence for amorphous metal alloys treated without magnetic field. It is found that the dependences of the speed of magnetoelastic vibrations on the external magnetic field differ for samples treated differently. The results obtained are explained based on concepts of reorganization of the domain structure of the samples under study. Irkutsk State University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 46–49, September, 1999.     

Ab-initio pseudopotential study of electronic structure and chemisorption of oxygen on aluminium surface

Chemisorption of oxygen atom on aluminium (1 1 1), (1 1 0) and (1 0 0) surfaces is studied using ab-initio plane wave pseudopotential method based on density functional theory (DFT). Oxygen atom chemisorbed on three different high symmetry sites; top, short-bridge and hollow sites on the aluminium surfaces are examined. It has been found that the O-adatom adsorbed at the hollow site on aluminium (1 1 1), (1 1 0) and (1 0 0) plane yield energetically most stable structure. Calculation of chemisorption energies of O-adatom on aluminium surfaces shows that oxygen is most strongly bound to aluminium atoms on Al(1 1 1) plane and the calculated value of the chemisorption energy of O-adatom at the hollow site on Al(1 1 1) surface is 4.8 eV. In this work, the chemisorption energies calculated for O-adatom on Al(1 1 0) and Al(1 0 0) surfaces are reported for the first time. The electronic structures and the electronic charge density distributions of the oxygen chemisorbed aluminium surfaces are also investigated. Calculations show that for aluminium, p orbitals also contribute significantly along with the s orbitals during the bond formation with oxygen atom. Therefore, the possibilities of hybridizations lead to the strong bonding configurations.     

Density of fast electrons on the Axis of a Zylindrical Hollow-Cathode Discharge

Fast electrons leaving a hollow cathode discharge axially through the orifice of a hole probe undergo ionizing collisions with the discharge gas in and behind the orifice. Ar⁺⁺ ions produced in this way are used as a monitor for the density of fast electrons, N_ef, on the axis of the negative glow of a cylindrical hollow cathode discharge. Data on N_ef as dependent on the pressure of the Ar discharge gas and on the discharge current are obtained and an analytical expression for these dependences is found and discussed.     

Effect of isomerization of reactant molecules on kinetics characteristics of reactions

Mathematical modeling is used to study the effect of isomerization of the reactant molecules on the kinetic characteristics of the initial stage of a chemical reaction within the framework of three isomerization mechanisms: unimolecular, with the formation of an intermediate, or associate. It is shown that the behavior of the kinetic curves is determined by the mechanism of the isomerization of the reactant molecules. The dependence of the effective rate constant k _ef on the reaction rate constants k _i for the elementary reaction steps and the constants of equilibrium K _i between the isomers is established. The effect of temperature on the isomeric composition is examined.     

Effect of spin of F3-center on changes in its charge under the action of radiation

Methods of pulse spectroscopy with time resolution were used to investigate creation and annihilation processes of F₂ ⁺-, F₂-, F ₂ ^– -centers, which are noninertial with respect to the duration of an electron pulse of nanosecond duration acting on the crystal. It is concluded on the basis of these studies that the effect of radiation on an F₂-center is a change in its charge and spin states. It is established that the direction of change of an F₂ -center charged state is determined by the value of its spin: localization occurs of a band hole on an F₂-center in the singlet ground state, and of an electron in the on an F₂-center in the triplet state. An F₂-center triplet state is formed during the electron localization process on an F₂ ⁺-center or subsequent localization of band holes and an electron on an F₂-center as a result of a thermally activated intercombination transition from a higher state than the radiating singlet.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 109–120, October, 1991.In conclusion the author is grateful to V. A. Kravchenko for participation in the experiments, and to V. M. Lisitsyn and V. Yu. Yakovlev for interesting discussions.