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钪—铬天青S—镍—邻菲罗啉混合多核配合物显色反应的研究 总被引:5,自引:0,他引:5
在弱酸介质中,钪与铬天青S形成的阴离子配合物,可以和镍-邻菲啉配阳离子通过静电引力成缔合型混合多核配合物。本文详细地研究了钪一铬天青S-镍-邻菲罗啉配合物的形成条件及反应过程。配合物的最大吸收峰位于630nm处,摩尔吸光系数ε530=3.31×10^4L.mol^-^1.cm^-^1,各组分的摩尔比;Sc+CAS+Ni+Phen=2+6+3+3,相应的分子式为[Sc(CAS)3]2[NiPhen 相似文献
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本文研究了钪—偶氮氯膦Ⅲ—铜—邻菲罗啉配合物的形成条件。在pH3.6醋酸钠—盐酸介质中配合物的最大吸收峰在606nm处,摩尔吸光系数ε_(606)=7.02×10~(-4)L·mol~(-1)·cm~(-1)。配合物各组分摩尔比Sc∶R ∶Cu∶Phen=1∶1∶1∶3。分子式为[ScOH·H_4R][Cu(Phen)_3]。应用于以铜基合金合成试样中钪的直接测定,结果较好。 相似文献
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钪—铋—三溴偶氮胂混合多核络合物显色反应及其在钪光度分析中应用研究 总被引:3,自引:0,他引:3
本文研究了钪-铋-三溴偶氮胂络合物的共显色反应。实验表明,共显色反应是由于形成混合多核络合物所致。钪络合物最大吸收峰在635nm,表观摩尔吸光系数为7.1×10~4L·mol~(-1)·cm~(-1)。钪在0~5μg/25ml遵守比尔定律。 相似文献
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研究了铅-铋-三溴偶氮胂络合物的显色反应条件。试验表明,显色反应帅于形成混合多核络合物所致,铅络合物的最大吸收峰在638nm。获得满意结果。 相似文献
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在微波辐射下用低温固相配位反应合成出多核配合物.通过元素分析确定配合物组成为La2(CoL2)3(L=-S2CNHCH2CO-2),并研究了该配合物的摩尔电导、红外光谱、紫外光谱和核磁共振氢谱.配合物的抗癌活性测定结果表明Co(HL)2和La2(CoL2)3有一定的抗癌活性;La2(CoL2)3对肝癌细胞生长有显著抑制作用,对正常肝细胞的生长无影响. 相似文献
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The reactivity of the reduced anthracene complex of scandium [Li(thf)3][Sc{N(tBu)Xy}2(anth)] ( 2-anth-Li ) (Xy=3,5-Me2C6H3; anth=C14H102−, thf=tetrahydrofuran) toward Brønsted acid [NEt3H][BPh4] and azobenzene is reported. While a stepwise protonation of 2-anth-Li with two equivalents of [NEt3H][BPh4] afforded the scandium cation [Sc{N(tBu)Xy}2(thf)2][BPh4] ( 3 ), reduction of azobenzene gave a thermolabile, anionic scandium reduced azobenzene complex [Li(thf)][Sc{N(tBu)Xy}2(η2-PhNNPh)] ( 4 ), which slowly lost one of the anilide ligands to form the neutral scandium azobenzene complex dimer [Sc{N(tBu)Xy}(μ-η2:η2-Ph2N2)]2 ( 5 ). Exposure of 3 to CO2 produced the scandium carbamate complex [Sc{κ2-O2CN(tBu)(Xy)}2][BPh4] ( 6 ) as a result of CO2 insertion into the Sc−N bonds. In an attempt to prepare scandium hydrides, the reaction of 3 with the hydride sources LiAlH4 and Na[BEt3H] led to the terminal aluminum hydride [AlH{N(tBu)Xy}2(thf)] ( 7 ) and the scandium n-butoxide [Sc{N(tBu)(Xy)}2(μ-OnBu)] ( 8 ) after Sc/Al transmetalation and nucleophilic ring-opening of THF, respectively. All reported compounds isolated in moderate to good yields were fully characterized. 相似文献
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Some of rare earth-β-diketone-2,2'-bipyridyl-N,N'-dioxide ternary complexes have been studied1,2. Very few work dealing with 4,4'-bipyridyl-N,N'-dioxide complex appeared. In our previous work, some ternary complexes of europium with β-diketones and 4,4'-bipyridyl-N,N'-dioxide with the formula of Ln (β-dik)3·0.5(bipyN2O2) have been isolated and well characterized.3 Here we report a newly synthesized ternary complex [La (bipyN2O2) (TFA)3]n. Crystal analysis showed it had an infinite on… 相似文献
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A new polynuclear silver complex with bridging diphorsphine ligand has been synthesized and characterized by :single cryatsl X-ray diffraction method The compound crystallizes in the triclinic space group P1 with a=1.27489, b=1.34715, c=1.47015 nm; α=59.747, β=63.949, γ=70.196°; V=1.9369 nm. The simplest formularis [Ag_4· dppe)_3(NO_3)_4], Mr=1874.79, D_c=1.607 g·cm~(-3), Dm=1.62 g·cm~(-3), μ(MoKa)=11.69 cm~(-1), F(OOO)=942. The structure was solved by conventional heavy-atom techniques and refined by full-matrix least squares to give discrepany indices of R=0.048 and RW=0.060(W=1/[σ(Fo)~2+(PWT*Fo)~2+QWT]-Fo) for 5052 reflections. An empirical absorption correction program DIFABS was performed.Silver atoms are linked by bridging ligands of dppe and nitrate, forming a network extending in space. Each structural unit contains two binuclear subunits, of which silver atoms are bridged by nitrates. The two subunits are connected by one dppe ligand. Silver atoms are not equivalent in subunit and one of the nitrates functions not only as a monodentate bridging ligand, but also as an asymmetric bidentate chelating lingand. All coordinate configurations of silver are shown as distorted tetrahedron. 相似文献
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本文系统研究了在阳离子表面活性剂存在下钪与溴邻苯三酚红及三乙烯四胺形成多元络合物的条件,测定了络合物的最大吸收波长和摩尔吸光系数,确定了络合物的组成。并初步探讨了反应机理。 相似文献
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Three metal ion bridged self-assembled(SA)films of cis-di(thiocyanato)-bis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium were fabricated and characterized by contact angle,UV spectra,cyclic voltammetry and XPS.Theirphotoinduced electron transfer properties(PETP)were examined.Among the titled systems,the highest steady an-odic photocurrent of 1773—1843 nA/cm~1 and the highest quantum yield of 3.2% were achieved.The effects of in-cident light intensity,bias voltage,and electron donor were also studied.The possible mechanism of electron trans-fer was proposed.The results reveal that different metal ion in SA films could affect significantly the photoinducedelectron transfer property.Our experimental results clearly show that bridging metal ions can play both functionaland structural roles in these self-assembled systems.This method of forming functional films can provide a new ap-proach to regulate the property of similar systems. 相似文献