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ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［Ｎａ（ＤＢ１８Ｃ６）（ＣＨ_３ＯＨ）］_２Ｍｏ_６Ｏ_（１９）·（ＤＢ１８Ｃ６）·（ＣＨ_３ＯＨ）￥ＺｈｏｕＹｉｎ－Ｚｈｕａｎｇ；ＴｕＳｈｕ－Ｊｉｅ；ＪｉｎＸｉａｎｇ－Ｌｉｎ；ＬｉｕＳｈｕｎ－... 相似文献
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ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［Ｎａ（ＤＢ１８Ｃ６）（Ｈ_２Ｏ）_２］_２Ｍｏ_６Ｏ_（１９）·３ＤＭＦ·２ＣＨ_３ＯＨＬｕＸｉａｏ－Ｍｉｎｇ；ＺｈａｏＹａ－Ｐｉｎｇ；ＱｕＥｒ－Ｌｉｎｇ；ＸｉａｏＬｉｎｇ－Ｍｅｉ；ＬｉｕＳｈｕ... 相似文献
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SUN Shu Qing WU Pei Ji ZHU Dao Ben 《结构化学》1999,18(2)
１ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅＮｉ（ｄｍｉｔ）２ｍｏｌｅｃｕｌｅｓｇｉｖｅｒｉｓｅｔｏａｎｕｍｂｅｒｏｆｍｏｌｅｃｕｌａｒｃｏｎｄｕｃｔｏｒｓ〔１，２〕ｉｎａｄｄｉｔｉｏｎｔｏｓｕｐｅｒｃｏｎｄｕｃｔｏｒｓ〔３，４〕．Ｔｈｅｍｕｌｔｙｓｕｌｆｕｒｆ... 相似文献
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LU Xiao Ming 《结构化学》2000,(3)
1 ＩＮＴＲＯＤＵＣＴＩＯＮＰｏｌｙｍｏｌｙｂｄａｔｅａｎｉｏｎｓｈａｖｅｂｅｅｎｓｔｕｄｉｅｄｆｏｒｍａｎｙｙｅａｒｓｂｅｃａｕｓｅｏｆｔｈｅｉｒａｐｐｌｉｃａ ｔｉｏｎｉｎｃａｔａｌｙｓｉｓｃｈｅｍｉｓｔｒｙ〔1〕.Ｉｎｔｈｅｓｙｎｔｈｅｓｉｓｏｆｏｒｇａｎｉｃｐｏｌｙｍｏｌｙｂｄａｔｅｄｅｒｉｖａｔｉｖｅｓｕｓｉｎｇａｃｅｔｏｎｅａｓｓｏｌｖｅｎｔ,ｗｅｆｏｕｎｄｔｈａｔｔｈｅｃｏｎｄｅｎｓａｔｉｏｎｒｅａｃｔｉｏｎｏｆａｃｅｔｏｎｅｏｃｃｕｒｒｅｄａｎｄｔｈｅｃｏｎｄｅｎｓａｔｉｏｎｐｒｏｄ… 相似文献
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lINTRODUCTIONThefirstheteronucleartransitionmetalclusterHFeCo,(Co),,wassynthesizedbyChinit13in196Obyusingthepyrolysisofmeta1carbonyldimers.Analysisofcar-bonylIRspectraandX-raypowderpatternsindicatedthatthiscompoundisisostruc-tural.withCo'(CO),,andthushasC,.symmetry(".MaysE'-'ihascarriedoutIRspectraandmassspectraonthiscompoundandkineticisotopestudiesontheprotona-tionoftheanion[FeCo,(CO),,j-,andproposedonthebasisofthisevidencethatthehydrogenatommightbelocatedinthecenterofthecluster.… 相似文献
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Two novel organic base templated nonmetal borates [(CH3)2NH2]2[B5O6(OH)4]2·[HCON(CH3)2] ( ? ) and [NH3CH2CH2NH3]2[B14O20(OH)6] ( II ) have been synthesized under hydrothermal conditions, and characterized by elemental analyses, FT‐IR spectroscopy, X‐ray diffraction, and TG‐DTA. Their crystal structures were determined from single crystal X‐ray diffraction. The crystal structure of compound I is characterized by forming a 3D supramolecular structure with large channels along axes b and c through O? H···O hydrogen‐bonding among the [B5O6(OH)4]? anions. The crystal structure of compound II is characterized by forming a 3D supramolecular structure with large channels along axis a and direction [111] through O? H···O hydrogen‐bonding among the [B14O20(OH)6]4? anions. The templating organic amine cations in I and II are both obtained through in situ hydrothermal reactions, and are both located in the channels of the 3D supramolecular structure, respectively. Their thermal behavior has been also investigated. 相似文献
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WANG Xiao-Guang 《结构化学》1997,(3)
1mTh0DUCTIONHeteropolycomp1exespossessalotofdistinctivecharacteristicsasmolecularm0delofcatalystdesign"'.Considerableattentionhasbeengiventothecrystalstruc-turesofheteropolycomplexescontainingdifferentcomponents,andmanyofthecrystalstructuresofthesec0mplexeshavebeendetermined.Wereportedprevious1ythecrystalstructureoftheheteropolyc0mplexeswithlanthanide,inwhichtw0kindsofelementsarecontainedinthemonolacunaryheteropolyligand".",theorientationsoftheminthecrystalareordered.Inthispaper,thecrystals… 相似文献
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用Ｘ－射线晶体结构衍射法测定了〔Ｃ５Ｈ４Ｃ（ＣＨ３）２ＣＨ２ＣＨ＝ＣＨ２〕Ｓｍ（ＯＨ）Ｃｌ·２ＭｇＣｌ２·４ＴＨＦ的晶体结构。它属三斜晶系,空间群为Ｐ１,ａ＝１０．７７３（２）,ｂ＝１２．８３６（３）,ｃ＝１５．４７８（３）,α＝１１１．４６（３）,β＝１０７．７１（３）,γ＝９２．５４（３）°,Ｖ＝１８６８（１）３,Ｍｒ＝８２７．９１,Ｄｘ＝１．４７２ｇ／ｃｍ３,μ＝２．０００６ｍｍ－１,Ｆ（０００）＝８４０,Ｚ＝２,Ｒ＝０．０４１,ｗＲ＝０．０５０（Ｉ≥３σ（Ｉ））。分子中Ｓｍ原子的配位数为８,形成一个严重扭曲的八面体结构;２个Ｍｇ原子的配位情况相似,它们的配位数都是６,分别构成２个扭曲的八面体。这３个八面体通过３个共平面联接 相似文献
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１ＩＮＴＲＯＤＵＣＴＩＯＮＯｃｔａｃａｒｂｏｎｙｌｄｉｃｏｂａｌｔｉｓａｖｅｒｙｃｏｎｖｅｎｉｅｎｔｓｔａｒｔｉｎｇｍａｔｅｒｉａｌｆｏｒｔｈｅｐｒｅｐａｒａｔｉｏｎｏｆａｌｍｏｓｔａｎｙｃｏｂａｌｔｃｏｍｐｏｕｎｄ〔１〕．Ｔｈｅｒｅａｃｔｉｏｎｓｏ... 相似文献
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１ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｔｅｎｓｅｉｎｔｅｒｅｓｔｉｎｔｒａｎｓｉｔｉｏｎ ｍｅｔａｌｃｌｕｓｔｅｒｓｃｏｎｔｉｎｕｅｓｂｅｃａｕｓｅｔｈｅｙｒｅｐｒｅｓｅｎｔｐｏｓ ｓｉｂｌｅｃｏｎｃｅｐｔｕａｌｂｒｉｄｇｅｓｂｅｔｗｅｅｎｈｏｍｏｇｅｎｅｏ... 相似文献
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INTRODUCTIONPalladiumcomplexesplayanimportantroleinmanycatalyticreactions,especial-lyincarbonylationofolefins.InordertostudytherelationshipbetweenthestructureandproPertyofpalladiumcomplexcatalyst,thetitlecomplexwassynthesizedanditsstructurewascharacterizedbyX-raydiffractionmethod.2EXPERmENT2.1SynthesisAmixtureofmorpholine(o-lmol)andCuCl(O.2mol)inmethanol(8OmL)wasrefluxedfor6h.AftercoolingthesolutionwasfilteredrePeat-edlyunti1theclearfiltratewasobtained.BrownCuCl.C'H,NOcrystalswer… 相似文献
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YANG Xi--Ping SHAO Shi--Bao CHEN Chang-Zhang HUANG Xiao--Ying LIN Zhou--Bin Gao Dong--Shou 《结构化学》1997,(1)
1INTRODUCTIONHeteroPOlymolybdatesareknownwithaverywiderangeofmetalionsithetypeandstabilityoftheclustersshowdependenceonboththeheteroatomandPH"'.TheknownheteroPOlymolybdateswhichincludemanganese(1)ormanganese(IV)havebeenreported.Afewofhetercrg-molybdateanionswiththemanganese(IIV)andnickel(IV)formsarecharacterizedandisostructural[2).Thesehigheroxidationstatespecieshavebeenpreparedpreviouslybyoxidationoflower--valentspecieswithPOwerfuloxidant,suchasPeroxydisulfateorPeroxymonosulfurica… 相似文献
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１ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｒｅｃｅｎｔｙｅａｒｓ,ｈｉｇｈｅｒ ｎｕｃｌｅａｒｉｔｙｃｌｕｓｔｅｒｓｈａｖｅｒｅｃｅｉｖｅｄｃｏｎｓｉｄｅｒａｂｌｅａｔｅｎｔｉｏｎｂｅｃａｕｓｅｏｆｔｈｅｉｒｐｏｔｅｎｔｉａｌａｐｐｌｉｃａｔｉｏｎｓｉｎｍａｎｙ... 相似文献
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A dinuclear cadmium complex [Cd2(phen)2(C14H11O3)4(CH3CH2OH)]·(CH3OH)·(H2O) has been synthesized with benzilic acid and 1,10-phenanthroline by hydrothermal method.The crystal structure was determined by X-ray diffraction with crystal parameters as follows:triclinic system with space group P1,a = 1.21298(10),b = 1.32586(11),c = 2.4815(2) nm,α = 76.2630(10),β = 81.4500(10),γ = 69.1700(10)o,V = 3.6143(5) nm3,Dc = 1.438 g/cm3,Z = 1,F(000) = 1600,the final GOOF = 0.937,R = 0.0521 and wR = 0.1328.In the title complex,the dinuclear structure is defined by carboxyl oxygen atoms adopting a monodentate bridged coordination mode.The coordination environment of Cd(Ⅱ) ion is CdO4N2,giving a distorted octahedral coordination geometry.TG analysis shows that the title complex is stable under 140 ℃. 相似文献
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1 INTRODUCTION Norfloxacin (0.16 g, 5 mmol) and PdCl2 (0.02 g) in methanol solution. The brown solution was filtered Norfloxacin (H-Norf = 1-ethyl-6-fluoro-1,4-dihy- and the filtrate was stood undisturbed. Single crys- dro-4-oxo-7-(1-piperazinyl)-3-quinoline carboxylic tals suitable for X-ray analysis were obtained by slow- acid), a quinolone type compound, is widely used as ly evaporating the methanol solvent at 20 ℃. an antibacterial drug which targets the bacterial type 2. 2 TGA an… 相似文献
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１ＩＮＴＲＯＤＵＣＴＩＯＮＲｅｃｅｎｔｌｙ,ｔｈｅｃｈｅｍｉｓｔｒｙｏｆｃｏｍｐｌｅｘｅｓｃｏｎｔａｉｎｉｎｇｌｏｗ ｖａｌｅｎｃｅｍｅｔａｌａｔｏｍｓｈａｓｉｎｃｒｅａｓ ｉｎｇｌｙａｔｒａｃｔｅｄｔｈｅａｔｅｎｔｉｏｎｆｒｏｍｃｈｅｍｉｓｔｓａｎ... 相似文献
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1INTRoDUCTIoNThiomolybdate(thiotungstate)isafundamentalunitoPsomemolybdenumen-zymesandplaysanimportantroleincoordinationchemistryasaligandforothermet-alstoformanalogouscompoundsofmetalloproteinst'3.Recentlyinterestingnonlinearoptical(NLO)propertieshavebeendiscoveredforthetypeofMo(W)-Cu(Ag)-Sclusterst2.33.Bythevarioussyntheticmethodsseveralhundredmixedmetalclustersandcomplexes,Mo(W)-M-S(M=transitionmetal),havebeensynthesizedt'i.AmongthesecompoundsthecasesofMbeingCu,Ag,Feareusualwhile… 相似文献
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《结构化学》1992,(1)
<正> The title compound C6H16O9Fe, Mr = 288. 13, was synthesized and crystallized in monoclinic space group P21/c, a = 9. 409(4), b = 5. 812(4), c= 22. 122(7)(?) , β=90. 80(3)°. V = 1209. 6(?)3, Z = 4, Dc=1. 572g/cm3, F(000) = 592, μ = 12. 73cm-1, R = 0. 063, Rw= 0. 068 for 1191 observed reflections. The iron atom is surrounded by O(1 - 6) in a distorted octahedron. 相似文献
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１ ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｏｕｒｅｆｆｏｒｔｓｔｏｄｅｖｅｌｏｐｔｈｅｌｏｗ－ｖａｌｅｎｃｅＭｏ－ＳＲｃｏｍｐｏｕｎｄｓ,ｗｅｈａｖｅｆｏｕｎｄａｎＭｏ（０）－ｃｏｍｐｏｕｎｄ,〔Ｍｏ２（ＳＲ）２（ＣＯ）８〕２－,ｗｈｉｃｈｉｓｏｂｔａｉｎｅｄｆｒｏｍｔｈｅｒｅａｃｔｉｏｎｏｆＭｏ（ＣＯ）６ｗｉｔｈＲＳ－ｉｎｈｉｇｈｙｉｅｌｄ,ｐｏｓｓｅｓｓｅｓａｎｉｎｔｅｒｅｓｔｉｎｇｔｗｏ－ｅｌｅｃｔｒｏｎｔｒａｎｓｆｅｒｐｒｏｐｅｒｔｙ．Ｎｕｍｅｒｏｕｓｋｉｎｄｓｏｆｄｉｎｕｃｌｅａｒｍｏｌｙｂｄｅ… 相似文献