Tunable UV radiation at short wavelengths (188–240 nm) generated by sum-frequency mixing in lithium borate

Sum-frequency mixing (₃=₁+₂) of UV laser radiation (₁=266 nm and 213 nm) and tunable coherent infrared light (₂=1.2–2.6 m) in lithium borate (LBO) generates radiation at short wavelengths (₃=188–242 nm). The UV radiation at ₁ is produced by the fourth and fifth harmonic of a pulsed Nd-YAG laser. The infrared light is generated with an optical parametric oscillator of beta barium borate. The phase-matching angle is measured as function of ₃ and compared with calculated values. For UV laser radiation at shorter wavelengths (173 nm₁213 nm) the calculations predict an extension of the tuning range of the sum-frequency generated at ₃ to wavelengths as short as the LBO transmission cutoff at 160 nm.     

Analyticity of scattering for the ϕ4 theory

We consider scattering for the equation (+m ²)+³=0 on four-dimensional Minkowski space. Form>0, one-to-one and onto wave operatorsW _± :HH are known to exist for all 0, whereH denotes the Hilbert space of finite-energy Cauchy data. We prove that the maps (,u)W _± (u) and (,u)(W _± )^–1 (u) are continuous from [0, )×H toH, and extend to real-analytic functions from an open neighborhood of {0}×H×{0}×H to the Hilbert spaceH _–1 of Cauchy data with Poincaré-invariant norm. Form=0, wave operatorsW _± are known to exist as diffeomorphisms ofH for all 0, where hereH denotes the Hilbert space of finite Einstein energy Cauchy data. In this case we prove that the maps (,u)(W _± ) (u) and (,u)(W _± )^–1 (u) extend to real-analytic functions from a neighborhood of [0, )×H×H toH.     

Superradiating 4P-4S-3P cascade of sodium vapour arising on the leading edge of the exciting laser pulse

Investigations of the superradiating cascade of sodium vapour 4P-4S-3P ₁ = 2.21 µm and ₂=1.14 µm) arising on the leading edge of the exciting laser pulse were carried out. The dependences of the actual delay time _D of the ₁ pulse on the population rise time of the laser-excited 4P state were measured and compared with those calculated following the existing theoretical model. The dependence of the actual delay time _D on the inverse density of excited atoms 1/N* is also presented. Analysis of this dependence revealed the influence of the Doppler dephasing and of the second, ₂, transition on the formation of the ₁ superradiance.     

Geometry and combinatorics of Julia sets of real quadratic maps

For real a correspondence is made between the Julia setB forz(z–)², in the hyperbolic case, and the set of-chains±(±(±..., with the aid of Cremer's theorem. It is shown how a number of features ofB can be understood in terms of-chains. The structure ofB is determined by certain equivalence classes of-chains, fixed by orders of visitation of certain real cycles; and the bifurcation history of a given cycle can be conveniently computed via the combinatorics of-chains. The functional equations obeyed by attractive cycles are investigated, and their relation to-chains is given. The first cascade of period-doubling bifurcations is described from the point of view of the associated Julia sets and-chains. Certain Julia sets associated with the Feigenbaum function and some theorems of Lanford are discussed.Supported by NSF grant No. MCS-8104862.Supported by NSF grant No. MCS-8203325.     

The ground state energy of Sdhrödinger operators

We studye()=inf spec(-+V) and examine whene()<0 for all 0. We prove thatc ²e()–d ² for suitableV and all small ||.Research partially funded under NSF grant number DMS-9101716.     

Mean-Field Critical Behavior for the Contact Process

The contact process is a model of spread of an infectious disease. Combining with the result of ref. 1, we prove that the critical exponents take on the mean-field values for sufficiently high dimensional nearest-neighbor models and for sufficiently spread-out models with d>4:()– _c as _c and ()( _c–)^–1 as _c, where () and () are the spread probability and the susceptibility of the infection respectively, and _c is the critical infection rate. Our results imply that the upper critical dimension for the contact process is at most 4.     

Tunable UV laser photolysis of organometallics with product detection by laser mass spectroscopy: Trimethylaluminum

We use tunable UV laser light in the region 200–320 nm, produced by frequency doubling the output of a dye laser, for the decomposition of organometallic compounds. This method has been applied to TMA, trimethylaluminum Al(CH₃)₃. Only the TMA monomer absorbs UV light for >220 nm. TMA decomposes by one-photon absorption mainly into two channels: aluminum atoms Al plus organic fragments, and aluminummonomethyl AlCH₃ molecules plus organic fragments. The ratio [Al]/[AlCH₃] is wavelength dependent. We present a mechanism to explain the photolysis of trimethyl compounds of group III elements (Al, Ga, In).     

Loss in low-finesse Ti:LiNbO3 optical waveguide resonators

We propose to measure the contrast of Fabry-Perot resonances in low-finesse (end face polished) integrated optical resonators to determine an upper limit of the waveguide attenuation coefficient. The method is discussed; its absolute accuracy increases with decreasing loss. As example, experimental results are presented for 3 and 10 m wide Ti: LiNbO₃ strip guides; the attenuation coefficients are 0.46 dB/cm (EH₁₁) in the narrower guide at =0.63 m, respectively 0.19 dB/cm (EH₁₁) and 0.09 dB/cm (HE₁₁) in the 10 m wide guide at =1.15 m.     

Modified London model for the determination of λ and ζ in a high κ superconductor

We present a modified London model suggested by Brandt [1–3] which introduces a finite vortex core size appropriate for isotropic superconductors in which the average internal field is less than approximately (1/4)H _c2. TheSR lineshape resulting from this model possesses a distinctive shape due to the magnetic penetration depth and the vortex core diameter (approximately equal to twice the coherence length ). However, for a given lineshape, there is a large range of values of and which produce nearly the same lineshape. Lineshape smearing caused by disorder in the vortex lattice increases uncertainty in values for and . If well-determined values of either (T) or (T) are not available from another technique, both of them can be determined bySR measurements alone if runs in more than one applied field at the same temperature are fit with and as shared parameters. We also present our method of estimating the degree of disorder in the vortex lattice.     

Exact Solution of the Infinite-Range-Hopping Bose–Hubbard Model

The thermodynamic behavior of the Bose–Hubbard model is solved for any temperature and any chemical potential. It is found that there is a range of critical coupling strengths _c1 < _c2 < _c3 < in this model. For coupling strengths between _c,k and _c,k+1, Bose–Einstein condensation is suppressed at densities near the integer values = 1,...,k with an energy gap. This is known as a Mott insulator phase and was previously shown only for zero temperature. In the context of ultra-cold atoms, this phenomenon was experimentally observed in 2002(1) but, in the Bose–Hubbard model, it manifests itself also in the pressure-volume diagram at high pressures. It is suggested that this phenomenon persists for finite-range hopping and might also be experimentally observable.     

Stability domain of coherent laser waves

The constant-amplitude solutions with wavelength of a semiclassical laser model exhibit three different instabilities in the (, )-plane for pumpparameters above threshold.     

Antibound states for a class of one-dimensional Schrödinger operators

Let (x) be the Dirac's delta,q(x)L ¹ (R)L ² (R) be a real valued function, and , R; we will consider the following class of one-dimensional formal Schrödinger operators on . It is known that to the formal operator may be associated a selfadjoint operatorH(,) onL ²(R). Ifq is of finite range, for >0 and || is small enough, we prove thatH(,) has an antibound state; that is the resolvent ofH(,) has a pole on the negative real axis on the second Riemann sheet.Work done while the author was supported by an undergraduate fellowship of the (Italian) National Research Council (CNR).     

Photoabsorption of BCl3 Gas under pulsed ArF excimer laser irradiation

The gas immersion laser doping (GILD) technique requires the measurement of the fraction of incident light absorbed in the gas phase during the irradiation with a pulsed laser. Here we report the absorption of boron trichloride (BCl₃) gas at the wavelength of a pulsed ArF excimer laser (=193 nm). We have determined the one-photon (₁) and two-photon () absorption cross sections of this dopant gas for 193 nm. The values of ₁ and are 3.6×10^–20 cm² and 9×10^–45 cm⁴·s, respectively. However, the distinction between simultaneous and sequential absorption has not been possible. Based on these results, we have established a relationship which allows the calculation of the fraction of incident light absorbed as a function of incident intensity and gas pressure.     

The central limit theorem for the spectrum of the random one-dimensional Schrödinger operator

Let H_L = –d²/dt²+q(t,) be an one-dimensional random Schrödinger operator in ²(–L, L) with the classical boundary conditions. The random potential q(t,) has a form q(t, )=F(x_t), where x_t is a Brownian motion on the Euclidean v-dimensional torus, FS^v R¹ is a smooth function with the nondegenerated critical points, min_s ^v F = 0. Let are the eigenvalues of H_L) be a spectral distribution function in the volume [– L,L] and N() = lim_L(1/2L)N_L() be a corresponding limit distribution function.Theorem 1. If L then the normalized difference N _L ^* ()=[N_L() -2L·N()]2L tends (in the sense of Levi-Prokhorov) to the limit Gaussian process N^*(); N^*()0, 0, and N^*() has nondegenerated finitedimensional distributions on the spectrum (i.e., > 0). Theorem 2. The limit process N^*() is a continuous process with the locally independent increments.     

A multidimensional continued fraction and some of its statistical properties

The problem of simultaneously approximating a vector of irrational numbers with rationals is analyzed in a geometrical setting using notions of dynamical systems theory. We discuss here a (vectorial) multidimensional continued-fraction algorithm (MCFA) of additive type, the generalized mediant algorithm (GMA), and give a geometrical interpretation to it. We calculate the invariant measure of the GMA shift as well as its Kolmogorov-Sinai (KS) entropy for arbitrary number of irrationals. The KS entropy is related to the growth rate of denominators of the Euclidean algorithm. This is the first analytical calculation of the growth rate of denominators for any MCFA.Glossary L ⁺ set of positive integers - [.] Gauss integer symbol (Section 2) - h entropy - I of irrationals to be simultaneously approximated - d dimension of the vector of convergents (equal to I+1) - ^P unit hypercube inp dimensions - support of the invariant measure (see Section 5) - E_ij elementary matrix, with klth component _kl + _{ik jl} - E-string product of elementary matrices given by the algorithm - verticesV _i corners of the elementary simplex adjoined to the origin (Section 3) - mediantsM _ik a direct sum of any two of the vertices (Section 3) - focus sum of all the vertices (Section 3) - Euclidean reverse of the E-string procedure (see Section 2) algorithm - OCF ordinary continued-fraction algorithm - GMA generalized mediant algorithm: the subject of this paper - JP Jacobi-Perron: the most well-studied MCFA - MCFA Multidimensional continued-fraction algorithm - KS entropy Kolmogorov-Sinai entropy - T _OCF ordinary continued-fraction shift map - FS Farey shift map - (a,..., z) irrational vector withI components; each element is an irrational - d(x) invariant measure - (x) invariant density =d(x)/dx] - ₁, ₂,..., _d thed Oseledec eigenvalues of the E-string (see Section 4) ordered ₁>1>₂₃... - ₁,...,_d–1 Oseledec eigenvalues of the shift map (Section 4) ordered greatest to smallest; all the _i>1, and _i=₁/_d i+1 - ln ₁,..., In _{d– 1} Oseledecexponents of the shift map (Section 4) - Perm a permutation matrix (Section 4)     

Effective stimulated emission and excited-state absorption cross-section spectra of para-phenylene-ethynylene polymers

The effective stimulated emission cross-section spectra, em,eff(), the stimulated emission cross-section spectra, em(), and the excited-state absorption cross-section spectra, ex()=em()–em,eff(), of the conjugated polymers poly(2,5-dioctadecyloxy-paraphenylene-ethynylene-co-2,5-thienyl) (OPT) and poly(2,5-dioctadecyloxy-paraphenylene-ethynylene-co-2,5-pyridinyl) (OPP) in tetrahydrofuran are determined in the fluorescence region. em,eff() determined by a fluorescence amplification technique is found to be small compared to em() indicating that ex() is nearly as large as em(). The laser excitation to the wide inhomogeneously broadened S1-absorption band leads to the formation of spectrally structured inhomogeneously broadened lattice relaxed exciton conformations extending on average over two monomer units which are thought to be responsible for upper-to-lower-state stimulated emission and lower-to-upper-state (excited-state) absorption.     

Soliton mass and surface tension in the (λ|Ø|4)2 quantum field model

The spectrum of the mass operator on the soliton sectors of the anisotropic (|ø|⁴)₂—and the (ø⁴)₂—quantum field models in the two phase region is analyzed. It is proven that, for small enough >0, the mass gapm _s() on the soliton sector is positive, andm _s()=0(^–1). This involves estimatingm _s() from below by a quantity () analogous to the surface tension in the statistical mechanics of two dimensional, classical spin systems and then estimating () by methods of Euclidean field theory. In principle, our methods apply to any two dimensional quantum field model with a spontaneously broken, internal symmetry group.A Sloan Foundation Fellow; Research supported in part by the U.S. National Science Foundation under Grant No. MPS 75-11864.Supported in part by the National Science Foundation under Grant No. PHY 76-17191     

The asymmetric contact process on a finite set

The contact process onZ has one phase transition; let _c be the critical value at which the transition occurs. Let _N be the extinction time of the contact process on {0,...,N}. Durrett and Liu (1988), Durrett and Schonmann (1988), and Durrett, Schonmann, and Tanaka (1989) have respectively proved that the subcritical, supercritical, and critical phases can be characterized using a large finite system (instead ofZ) in the following way. There are constants ₁() and ₂() such that if < _c , lim _{N N} /logN = 1/₁(); if > _c , lim _N log _N /N = ₂(); if = _c , lim _{N N} /N= and lim _{N N} /N ⁴=0 in probability. In this paper we consider the asymmetric contact process onZ when it has two distinct critical values _c1< _c2. The arguments of Durrett and Liu and of Durrett and Schonmann hold for < _c1 and > _c2. We show that for [ _c1< _c2), lim _{N N} /N=-1/, (where _i is an edge speed) and for = _c2, lim _N log _N /logN=2 in probability.     

The vacuum energy forP(ø)2: Infinite volume limit and coupling constant dependence

LetE(g) be the vacuum energy for theP(ø)₂ Hamiltonian with space cutoffg(x)0 and coupling constant 0. For suitable families of cutoffsg1, the vacuum energy per unit volume converges; i.e., –E(g)/g(x)dx (). We obtain bounds on the dependence of () for large and small . These lead to estimates forE(g) as a functional ofg that permit a weakening of the standard regularity conditions forg. Typical of such estimates is the linear lower bound, –E(g)const g(x)² dx, valid for allg0 provided thatP is normalized so thatP(0)=0. Finally we show that the perturbation series for () is asymptotic to second order.Research partially supported by AFOSR under Contract No. F 44620-71-C-0108.Postal address after September 30, 1972: via A. Falcone 70, 80127, Napoli, Italy.     

Strong far-infrared laser action in carbonyl fluoride and vinyl fluoride

Intense far-infrared laser action is reported for carbonyl fluoride and vinyl fluoride. Eleven new lines with wavelengths between 339 m538 m were obtained by optically pumping carbonyl fluoride with numerous lines of the 10.4 m band of a cw CO₂ laser. Twenty-three lines with wavelengths in the range 172 m783 m were detected when pumping the recently discovered efficient FIR laser molecule vinyl fluoride. In addition, three very weak new lines were found using 1.1-difluoroethylen.