共查询到20条相似文献，搜索用时 15 毫秒
1.
Hyukmin Kwon Sunwoo Park Seokwoo Kang Hayoon Lee Jongwook Park 《Molecules (Basel, Switzerland)》2022,27(13)
Three organic blue-light-emitting tetraphenylethylene (TPE) derivatives that exhibit aggregation-induced emission (AIE) were used as additives in the preparation of inorganic perovskite-structured green-light-emitting materials for three-color white-light emission. For these organic–inorganic light-emitting materials, two-color (blue and green) light-emitting films based on the CsPbBr3 perovskite-structured green-light-emitting inorganic material were prepared. The three TPE derivatives were prepared by varying the number of bromide groups, and a distinct AIE effect was confirmed when the derivatives were dissolved in a water–tetrahydrofuran mixed solvent containing 90 vol% water. When 0.2 molar ratio of the 1,1,2,2-tetrakis(4-bromophenyl)ethylene (TeBrTPE) additive was mixed with nanocrystal-pinning toluene solvent, the green-light-emission photoluminescence quantum efficiency (PLQY) value at 535 nm was 47 times greater than that of the pure bulk CsPbBr3 without additives and a blue emission at 475 nm was observed from the TeBrTPE itself. When a CBP:Ir(piq)3 film was prepared on top of this layer, three PL peaks with maximum wavelength values of 470, 535, and 613 nm were confirmed. The film exhibited white-light emission with CIE color coordinates of (0.25, 0.36). 相似文献
2.
Yue Yang Diandian Deng Xiaowen Deng Zhao Chen Shouzhi Pu 《Molecules (Basel, Switzerland)》2022,27(15)
The development of mechanochromic fluorophors with high-brightness, solid-state fluorescence is very significant and challenging. Herein, highly solid-state emissive triphenylamine, carbazole and tetraphenylethylene-functionalized benzothiadiazole derivatives were developed. These compounds showed remarkable aggregation-induced emission and solvatochromic fluorescence characteristics. Furthermore, these fluorogenic compounds also displayed different mechanically triggering fluorescence responses. 相似文献
3.
Zhang‐wei Ning Song‐ze Wu Guang‐jian Liu Yan‐ming Ji Li‐yan Jia Xiao‐xiao Niu Rong‐fang Ma Yuan Zhang Guo‐wen Xing 《化学:亚洲杂志》2019,14(13):2220-2224
Water‐soluble ratiometric AIE‐active fluorescent organic nanoparticles 2OA‐FON for the specific sensing of cysteine over other biothiols are reported. The obtained amphiphilic probe included olefin aldehyde as recognizing unit, tetraphenylethylene as fluorescence reporter and lactose moiety as a hydrophilic group. This work provides a general design strategy based on the introduction of a sugar moiety into a hydrophobic AIEgen to develop ratiometric water‐soluble fluorescent organic nanoparticles. 相似文献
4.
Prof. Dr. Xiang Li Qin Zhou Miao Zhu Wei Chen Beibei Wang Prof. Dr. Ye Sha Prof. Dr. Hong Yan 《化学:亚洲杂志》2021,16(7):757-760
A novel kind of expanded tetraphenylethylene (TPE)-carborane-TPE pentad has been synthesized by using two adjacent carborane moieties as central bridges and three TPE units in lateral positions. Its solid-state fluorescence quantum yield was substantially increased to 68.2% by expanding the number of bridges between carborane and TPE. Subsequently, the emission color shifted from blue to orange-yellow (126 nm). Mechanical insights into the electronic structure of the extended TPE-carborane-TPE pentads were obtained from density functional theory (DFT) calculations. 相似文献
5.
Guangfeng Li Zhixuan Zhou Chang Yuan Zhewen Guo Yuhang Liu Dong Zhao Kai Liu Jun Zhao Hongwei Tan Xuzhou Yan 《Angewandte Chemie (International ed. in English)》2020,59(25):10013-10017
Herein, the trackable supramolecular transformation of a two‐component molecular cage to a three‐component cage through supramolecular fusion with another two‐component molecular square is described. The use of tetraphenylethene (TPE), a chromophore with aggregation‐induced emission (AIE) character, as a component for the molecular cages enables facile fluorescence monitoring of the transformation process: while both cages exhibit fluorescence emission via the restriction of intramolecular motion of the TPE motif, the interactions between TPE and 4,4′‐bipyridine introduced in the supramolecular fusion process result in partial fluorescence quenching and shifts in the emission maximum. This study provides a simple and efficient approach towards complex supramolecular cages with emergent functions and demonstrates that AIE features could provide unique opportunities for the characterization of complex, dynamic supramolecular transformation processes. 相似文献
6.
Dr. Shunjie Liu Dr. Yanhua Cheng Haoke Zhang Zijie Qiu Dr. Ryan T. K. Kwok Dr. Jacky W. Y. Lam Prof. Ben Zhong Tang 《Angewandte Chemie (International ed. in English)》2018,57(21):6274-6278
A facile and efficient approach is demonstrated to visualize the polymerization in situ. A group of tetraphenylethylene (TPE)‐containing dithiocarbamates were synthesized and screened as agents for reversible addition fragmentation chain transfer (RAFT) polymerizations. The spatial‐temporal control characteristics of photochemistry enabled the RAFT polymerizations to be ON and OFF on demand under alternating visible light irradiation. The emission of TPE is sensitive to the local viscosity change owing to its aggregation‐induced emission characteristic. Quantitative information could be easily acquired by the naked eye without destroying the reaction system. Furthermore, the versatility of such a technique was well demonstrated by 12 different polymerization systems. The present approach thus demonstrated a powerful platform for understanding the controlled living radical polymerization process. 相似文献
7.
Masaki Furukawa Kazuhiro Nakabayashi Hideharu Mori 《Journal of polymer science. Part A, Polymer chemistry》2021,59(6):532-546
Aggregation-induced emission (AIE)-active nanoparticles (NPs) exhibiting multicolor fluorescence and high-quantum yields independent of the environment are important for the further development of next-generation smart fluorescent materials. In this work, AIE-active amphiphilic block copolymers were designed and synthesized by RAFT polymerization of a brominated tetraphenylethene (TPE)-containing acrylate (A-TPE-Br). The block copolymer exhibited typical AIE effects in selective solvents, which can be explained by hydrophobic TPE aggregated in the core during micelle formation. Luminescent core–shell NPs with a crosslinked AIE core (fixed structure) were synthesized by the Suzuki coupling reaction of the bromine groups of the assembled block copolymer and boronic acid compounds. The NPs composed of TPE/thiophene crosslinked core showed green emission in both diluted state and solid state, implying the ability to fluoresce regardless of environmental changes and molecular dispersion. Multicolor luminescent NPs capable of changing color from blue to red were synthesized by changing the coupling compounds, such as anthracene for electron-rich units and benzothiadiazole for electron-deficient units. The effects of the nature of the donor and acceptor, as well as their combination (TPE/donor/acceptor sequence), on the color and fluorescent intensity of the core crosslinked NPs in the nonpolar and polar solvents, and solid state, were investigated. 相似文献
8.
Yan‐ming Ji Guang‐jian Liu Cui‐yun Li Yi‐chen Liu Min Hou Guo‐wen Xing 《化学:亚洲杂志》2019,14(19):3295-3300
Two water‐soluble carbohydrate‐coated AIE‐activate fluorescent organic nanoparticles TPE3G and TPE4G were designed and synthesized for the detection of heparin. Different from the reported strategy, we not only utilized the general detection mechanism of electrostatic interactions, but also introduced the concept of carbohydrate‐carbohydrate interactions (CCIs) to enrich the detection mechanism of heparin. TPE3G can serve as an efficient “turn‐on” probe with higher selectivity towards heparin than TPE4G . TEM studies revealed that the micro‐aggregated TPE3G was encapsulated with the heparin chain to form a complex self‐assemblied composite and emits strong fluorescence. It is believed that the results illustrated in this study provide a novel strategy based on CCls to design water‐soluble and more efficient bio‐probes for various biological and clinical applications. 相似文献
9.
Yuewei Wu Chaoxian Yan Dongxu Li Chengshan Yuan Jibin Sun Shuyun Zhou Hao‐Li Zhang Xiangfeng Shao 《化学:亚洲杂志》2019,14(10):1860-1869
Four tetraphenylethylenes ( 2 a – d ) containing an electron‐rich 2,3,4,6‐tetrahydro‐1,6‐dithia‐3a‐azaphenalene (THDTAP) moiety have been synthesized. The 2 a – d show aggregation‐induced emission (AIE) with yellowish green photoluminescence (PL) in THF‐H2O (v/v, 1:9) solution and in the solid state. Compounds 2 a – d undergo 1,2‐migratory shift in oxidative cyclodehydrogenation reactions to afford the unexpected products 3 a – d which display green PL in CH2Cl2 solution and are non‐emissive in the solid state. The PL intensities of 3 a – d are clearly enhanced in the presence of meta‐chloroperoxybenzoic acid (mCPBA) owing to the oxidation of the S‐atoms on the THDTAP moiety. In contrast, the PL of 2 a – d in THF‐H2O (v/v, 1:9) solution is quenched by adding mCPBA, ascribable to the oxidation of the C=C bond on the ethylene moiety. It is found that the absorption of 3 a – d is distinctly red‐shifted from the UV/Vis region to the NIR region upon acidification, arising from the protonation of the N‐atom on the THDTAP moiety. Furthermore, 3 a – d display nonlinear optical response (NLO) and optical limiting (OL) behaviour which is superior to that of the well‐known OL material C60. 相似文献
10.
《化学:亚洲杂志》2017,12(9):1013-1019
Apart from sensing and imaging, luminogens with aggregation‐induced emission (AIE) are also interesting for photosensitizing. The photosensitizing behavior and bacteria‐killing performance of a pyridinium‐substituted tetraphenylethylene with an alkyne group ( TPE‐A‐Py+ ) is reported herein. Interestingly, TPE‐A‐Py+ exhibits higher photosensitizing efficiency than TPE‐Py+ (without alkyne group) when I− was used as a counteranion. This is well explained by the fact that the ΔΕ ST between the excited singlet state (S 1) and triplet state (T 1) was lower for TPE‐A‐Py+ than for TPE‐Py+ , according to theoretical calculations. Moreover, replacement of I − with other anions (PF6−, N(SO2CF3)2− and BPh4−) led to a decrease of photosensitizing efficiency for TPE‐A‐Py+ . Notably, TPE‐A‐Py+ could be used as an efficient photosensitizer to photo‐inactivate ampicillin‐resistant (ampr) E. coli at low concentration under white‐light irradiation very quickly. 相似文献
11.
A tetraphenylethylene (TPE) derivative bearing two dimethylformamidine units was synthesized. The dihydrogen chloride salt of this TPE derivative was soluble in water and showed almost no emission. By addition of phosphate anions, the dihydrogen chloride salt could be transformed into the monohydrogen chloride salt, which was barely soluble and emitted strong fluorescence through aggregation‐induced emission (AIE), while many other anions could not bring about a fluorescence enhancement. Meanwhile, the dihydrogen chloride salt and monohydrogen chloride salt could be reversible transformed by addition of acid and base alternately in the presence of phosphate anion, which led to fluorescence turn‐on and turn‐off. Therefore, the TPE dimethylformamidine holds potential for selectively sensing phosphate anions in water and use as fluorescence pH switch. This study provided a new approach to AIEgen sensors by using formamidine groups. 相似文献
12.
《化学:亚洲杂志》2017,12(17):2207-2210
Tetraphenylethylene (TPE)–carborane hybrids are constructed, and the impact of carborane substituents on the aggregation‐induced emission (AIE) characteristics of TPE‐cores has been investigated. When altering the 2‐R‐group on the carborane unit with ‐H, ‐CH3 or phenyl group, the luminescent quantum yield of the corresponding TPE derivatives can be manipulated from 0.18 to 0.63 in the solid state. The emission color exhibits an obvious 100 nm shift (from blue to yellow). 相似文献
14.
Kazuhiro Nakabayashi Mizuki Takata Masaki Furukawa Hideharu Mori 《Journal of polymer science. Part A, Polymer chemistry》2020,58(6):852-859
Luminescent core–shell nanoparticles (NPs) with crosslinked aggregation-induced emission (AIE) core structures, which exhibited excellent emission independent of the dispersion state of the NPs, have been developed by a facile one-pot method based on the self-assembly of an amphiphilic block copolymer poly(PEGMA)-b-poly(DB3VT). Core–shell micelles with a poly(DB3VT) core were formed from poly(PEGMA)-b-poly(DB3VT) in tetrahydrofuran (THF)/H2O condition, and the crosslinked AIE-based structure was selectively incorporated into the core by the Suzuki coupling reaction between poly(DB3VT) blocks and tetraphenylethylene (TPE)-based coupling monomers at the same time. This method afforded a uniform NP with a crosslinked TPE-based AIE core structure. The obtained NP exhibited excellent emission both in diluted solution and solid states. This result indicated that the formed TPE-based AIE core structure was always aggregated regardless of NP dispersion owing to the crosslinking as we expected. The crosslinked TPE-based AIE core structure, which was related to the emission property, was readily tuned by the selection and combination of coupling monomers in the Suzuki coupling reaction. By incorporating electron-deficient units into the core, the emission color could be successfully tuned from yellow-green to orange and red while maintaining the emission property independent of the state of the NP dispersion. These results demonstrated that NPs with the crosslinked AIE core structures are a promising luminescent material design motif to realize emission independent on molecular dispersion. 相似文献
15.
The utilization of photocatalytic techniques for achieving light-to-fuel conversion is a promising way to ease the shortage of energy and degradation of the ecological environment. Fluorescent metallacycles and metallacages have drawn considerable attention and have been used in widespread fields due to easy preparation and their abundant functionality including photocatalysis. This review covers recent advances in photocatalysis in discrete supramolecular fluorescent metallacycles and metallacages. The developments in the utilization of the metallacycles skeletons and the effect of fluorescence-resonance energy transfer for photocatalysis are discussed. Furthermore, the use of the ligands decorated by organic chromophores or redox metal sites in metallacages as photocatalysts and their ability to encapsulate appropriate catalytic cofactors for photocatalysis are summarized. For the sake of brevity, macrocycles and cages with inorganic coordination complexes such as ruthenium complexes and iridium complexes are not included in this minireview. 相似文献
16.
Jinyu Li Xiao Han Qing Bai Tong Shan Ping Lu Yuguang Ma 《Journal of polymer science. Part A, Polymer chemistry》2017,55(4):707-715
A carbazole functionalized electro-active AIE-activity molecule, TPE-DFCz , was designed, synthesized, and well characterized. The clear difference in oxidation potentials between tetraphenylethylene (TPE) unit and carbazole groups was found which guaranteed that polymerization occurred only at the peripheral carbazole groups and the TPE unit remained unchanged. Its luminescent network film was prepared conveniently by electrochemical polymerization (EP). The cross-linked film exhibited green emission with high quantum efficiency of 63%, relatively smooth surface, and good thermal stability. The effect of different scan cycles on the optical property was also investigated. The electroluminescent device using the optimized polymer film as active layer showed a maximum luminance of 3200 cd m−2 and a maximum luminance efficiency of 1.16 cd A−1 with very low roll-off of the efficiency. The AIE-active EP films afford more opportunities to develop polymer films with high quantum efficiency via a simple, effective method and promote the potential applications in display devices. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 707–715 相似文献
17.
Wenbin Xi Junru Yu Mengru Wei Qianqian Qiu Pengfei Xu Prof. Zhaosheng Qian Prof. Hui Feng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(17):3733-3737
It is attractive but highly challenging to achieve controllable regulation of photophysical properties of pure organic luminogens, due to distinct work mechanisms and molecular structures. Here, a strategy to regulate in a controllable way the emission behavior of luminogens is reported, according to which long-lived aggregation-induced emission (AIE) can be switched to short-lived dual-state emission (DSE) by an isomer-based substitution reaction. Three luminogens with sharply different photophysical behaviors, including aggregation-induced phosphorescence and dual-state fluorescence emission, were obtained through a substitution reaction with three isomers. Freely rotating structures are attributed to aggregation-induced phosphorescence behavior, whereas twisted rigidification of the molecule greatly contributes to its dual-state emission phenomenon. This work contributes to the controlled regulation of photophysical behaviors through simple reactions and provides a solid evidence to support the key role of the prohibition of intramolecular rotation in aggregation-induced emission process and molecular design of dual-state emitters. 相似文献
18.
19.
Xing Wei Meng-Jiao Zhu Prof. Dr. Hong Yan Dr. Changsheng Lu Prof. Dr. Jing-Juan Xu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(55):12671-12683
The emergence of the rising alliance between aggregation-induced emission (AIE) and electrochemiluminescence (ECL) is defined as aggregation-induced electrochemiluminescence (AIECL). The booming science of AIE has proved to be not only distinguished in luminescent materials but could also inject new possibility into ECL analysis. Especially in the aqueous phase and solid state for hydrophobic materials, AIE helps ECL circumvent the dilemma between substantial emission intensity and biocompatible media. The wide range of analytes makes ECL an overwhelmingly interesting analytical technique. Therefore, AIECL has gained potential in clinical diagnostics, environmental assays, and biomarker detections. This review will focus on introduction of the novel concept of AIECL, current applied luminophores, and related applications developed in recent years. 相似文献
20.
ABSTRACTTetraphenylethylene (TPE) related (supra)molecules have been intensively investigated due to their aggregation-induced emission (AIE) effect based on the restriction of intramolecular rotation (RIR). Meanwhile, boron-dipyrromethene (BODIPY) tends to emit intense fluorescence with high quantum yields. Herein, we combined TPE, BODIPY and terpyridine (TPY) into one system to study the emissive behaviour of organic building block as well as a self-assembled metallo-supramolecule. The TPY and BODIPY substituents with bulky sizes provide strong hindrance to restrict the rotation of the phenyl groups on TPE, leading to enhancement of emissive properties in both solution and aggregation states. Furthermore, the BODIPY-TPE-TPY ligand (L) was assembled with Zn (II) through coordination-driven self-assembly to form a cyclic dimer (D) with typical AIE characteristics. 相似文献