共查询到20条相似文献,搜索用时 15 毫秒
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Guido Schmitt Dietmar Ullrich Gotthelf Wolmershuser Manfred Regitz Otto J. Scherer 《无机化学与普通化学杂志》1999,625(5):702-704
tBuC≡P as a Synthon for the Formation of a Dinuclear Rhenium Complex with a Bridging and Chiral Phosphinidene Oxide Ligand The one‐pot reaction of [{Cp*(OC)2Re}2] (Re = Re) ( 3 ) with tBuC≡P ( 4 ) and the subsequent oxidation with (Me3Si)2O2 ( 5 ) affords [Re(CO)2C5Me4CH2{μ‐HC(But)P(O)}Re(CO)2Cp*] ( 6 ), a dinuclear rhenium complex with a bridging and chiral phosphinidene oxide ligand. Its structure was confirmed by an X‐ray crystal structure determination. 相似文献
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O. J. Scherer J. Meiers M. Regitz M. A. Hofmann K. Karaghiosoff G. Wolmershuser 《无机化学与普通化学杂志》2001,627(7):1532-1536
[CpR(OC)Mo(μ‐η2:2‐P2)2FeCpR′] as Educt for Heterobimetallic Dinuclear Clusters with P2 and CnRnP4‐n Ligands (n = 1, 2) The cothermolysis of [CpR(OC)Mo(μ‐η2:2‐P2)2FeCpR′] ( 1 ) and tBuC≡P ( 2 ) as well as PhC≡CPh ( 3 ) affords the heterobimetallic triple‐decker like dinuclear clusters [(Cp'''Mo)(Cp*′Fe)(P3CtBu)(P2)] ( 4 ), Cp''' = C5H2tBu3‐1,2,4, Cp*′ = C5Me4Et, and [(Cp*Mo)(Cp*Fe)(P2C2Ph2)(P2)] ( 5 ) with a bridging tri‐ and diphosphabutadiendiyl ligand. 4 and 5 have been characterized additionally by X‐ray crystallography. 相似文献
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[{Cp*(OC)2Re}2(μ‐POH)], a Dinuclear Complex with a Bridging Hydroxiphosphinidene Ligand The reaction of [{Cp*(OC)2Re}4(μ4‐η1 : η1 : η1 : η1‐P2)] ( 1 ) with 0.1 m HCl gives [{Cp*(OC)2Re}2(μ‐POH)] ( 2 ), the X‐ray crystal structure of which reveals a dinuclear rhenium complex with a μ‐POH (hydroxiphosphinidene) ligand. 相似文献
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