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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(2):560-563
Achiral inorganic gypsum (CaSO4⋅2 H2O) triggers the asymmetric autocatalysis of pyrimidyl alkanol on its two‐dimensional enantiotopic faces to give highly enantioenriched alkanol products with absolute configurations corresponding to the respective enantiotopic surfaces. This is the first example of highly enantioselective synthesis on the enantiotopic surface of an achiral mineral. 相似文献
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Luca Schiaffino Gianfranco Ercolani 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2008,120(36):6938-6941
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