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Reinhard Lipowsky 《Interface Science》2001,9(1-2):105-115
Recent theoretical and experimental studies have shown that structured surfaces, which contain patterns of lyophilic surface domains, lead to morphological wetting transitions at which the wetting layer changes its shape in a characteristic and typically abrupt manner. These transitions have been determined for several specific surface domain patterns consisting of circular, striped, or ring-shaped domains, as well as for slit pores and slabs bounded by striped surfaces. Such transitions are predicted to be rather generic and to occur for any type of structured surface. 相似文献
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本文通过改变肋柱宽度和间距, 构造了二级和多级梯度微结构表面, 采用格子-Boltzmann方法对液滴在两种梯度表面上的铺展过程进行了研究, 探析液滴运动的机理和调控方法. 结果表明, 在改变肋柱间距的二级梯度表面上, 当液滴处于Cassie态时, 接触角滞后大小与粗糙度梯度成正比关系; 当液滴从Cassie态转换为Wenzel态或介于两者之间的不稳定态时, 这一正比关系不再遵循. 在改变肋柱宽度的二级梯度表面上, 接触角滞后大小与粗糙度梯度始终成正比关系. 在多级梯度表面上, 随液滴初始半径增大, 接触角滞后减小, 但液滴平衡位置相较于初始位置偏离增大. 对梯度微结构表面上液滴运动和接触角滞后的定量分析, 可为实现梯度微结构表面液滴运动调控提供理论依据. 相似文献
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The factors influencing the state and wetting transition of droplets on a rough surface are both complex and obscure. The
change in wetting is directly reflected by changes under the contact condition of the droplets with the surface. The recent
study about the wettability of the superhydrophobic surface under the condensing condition arouses the new understanding about
the apparent state of droplets on a rough surface. In this work, to validate the existence of droplets in an intermediate
state, a microscale pillar topological polydimethylsiloxane (PDMS) surface was manufactured and its wettability under various
conditions was studied. According to the experimental data, it is proposed that the wetting state of a rough surface may be
embodied using the contact area ratio of a solid/liquid/gas droplet with the projective plane. A general calculation model
for the apparent contact angle of droplets is given and expressed diagrammatically. It is found that the measured apparent
contact angles of droplets at different states on the surface falls within the range predicted by our proposed equation.
Supported by the National Natural Science Foundation of China (Grant No. 50606025) 相似文献
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通过用毛细管测量纯水表面张力系数实验,得到管内径d与接触角θ的相对误差之间的关系曲线,由此说明实验测得的表面张力系数α和理论公式相比呈现一定的偏差,并简单地讨论了实验的理想状态与实际情况的差别. 相似文献
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喷雾冷却具有散热能力强、冷却工质需求量小等优点,在解决电子器件散热方面具有广阔的应用前景。纯水中添加醇类可以有效提升喷雾冷却性能。为进一步探索醇类添加剂强化喷雾冷却性能的机理,本文开展醇水混合溶液表面张力和接触角的实验测定研究。分别在水中加入不同浓度的乙醇、正丙醇、正丁醇、正戊醇、正己醇、正庚醇和正辛醇等醇类,利用悬滴法探究醇类浓度对溶液的表面张力的影响规律;利用Young-Laplace坐滴法探究醇类浓度对接触角的影响规律。结果表明,水中添加醇类后表面张力降低,且其随醇类溶质浓度的增加而变小,且其下降速率均随浓度的增加越来越慢;添加低醇类添加剂均可降低溶液的接触角,而高醇类接触角随浓度变化没有明显的变化规律。 相似文献