Supramolecular block copolymers: graphene oxide composites for memory device applications

Bistable resistive switching characteristics obtained using a supramolecular hybrid route to hydrogen-bonded block copolymers (BCP) and graphene oxide (GO) as charge storage materials are reported for write-once-read-many-times (WORM) memory devices.     

ESIPT-regulated Mechanoresponsive Luminescence Process byIntroducing Intramolecular Hydrogen Bond in NaphthalimideDerivatives#br#

Herein, two compounds, 4-2′-hydroxybenzylidenehydrazinyl-N-butyl-1,8-naphthalimide(BN-1) and 4-benzylidenehydra-zinyl-N-butyl-1,8-naphthalimide(BN-2), were synthesized to explore the hydrogen bonding effect on mechanoresponsive luminescent(MRL). The results showed that compound BN-1 exhibited strong emission in solution and solid-state compared with compound BN-2. After grinding, the emission intensity of compound BN-1 sharply decreased by as much as 15 times with an obvious red-shift from 552 nm to 577 nm. The control compound BN-2, by contrast, did not change so much before and after grinding. Single crystal analysis suggests that BN-1 molecule formed strong intramolecular interaction via ―N=N···H―O hydrogen bond with a distance of 0.2632 nm. An excited-state intramolecular proton transfer(ESIPT) based fluorophore featured this intramolecular hydrogen bond. The intramolecular hydrogen bond as well as other intermolecular interactions can rigidify the molecular conformation of compound BN-1 in solid-state, and thus suppress the nonradiative pathways, resulting in strong emission. These intra- and intermolecular interactions were destroyed by mechanical stimuli, accompanied by molecular conformation change that decreases the luminescence and blocks the ESIPT process. The MRL process was also demonstrated by scanning electron microscopy and powder X-ray diffraction. The molecular stacking mode changed from crystalline to a disordered amorphous state after grinding.     

Characterization of chemically modified steroids for doping control purposes by electrospray ionization tandem mass spectrometry

The discovery of the designer steroid tetrahydrogestrinone (THG) in elite athletes' doping control samples in 2003 demonstrated the availability of steroid derivatives prepared solely for doping purposes. Modern mass spectrometers utilizing electrospray ionization and collisionally activated dissociation (CAD) of analytes allow the structural characterization of steroids and their derivatization sites by the elucidation of fragmentation behaviors. A total of 21 steroids comprising either a 4,9,11-triene, a 3-keto-4-ene or a 3-keto-1-ene nucleus were investigated regarding their dissociation pathways, deuterated analogues were synthesized and fragmentation routes were postulated, permitting the identification of steroidal structures and modifications. Compounds based on a 4,9,11-triene steroid with an ethyl residue at C-13 (gestrinone analogues) generate abundant fragment ions at m/z 241 and 199, whereas the substitution of the C-13 ethyl group by a methyl residue (trenbolone analogues) results in a shift of m/z 241 to 227. Substances related to testosterone with a 3-keto-4-ene structure give rise to abundant fragment ions at m/z 109 and 97 whereas steroids with a 3-keto-1-ene nucleus eliminate the A-ring including the carbons C-1-C-4, in addition to C-19 that is proposed to migrate from C-10 to C-1 under CAD conditions.     

High Performance Nonvolatile Transistor Memories Utilizing Functional Polyimide‐Based Supramolecular Electrets

We report pentacene‐based organic field‐effect transistor memory devices utilizing supramolecular electrets, consisting of a polyimide, PI(6FOH‐ODPA), containing hydroxyl groups for hydrogen bonding with amine functionalized aromatic rings (AM) of 1‐aniline (AM1), 2‐naphthylamine (AM2), 2‐aminoanthracene (AM3), and 1‐aminopyrene (AM4). The effect of the phenyl ring size and composition of AM1–AM4 on the hole‐trapping capability of the fabricated devices was investigated systematically. Under an operating voltage under ±40 V, the prepared devices using the electrets of 100 % AM1–AM4/PI ratios exhibited a memory window of 0, 8.59, 25.97, and 29.95 V, respectively, suggesting that the hole‐trapping capability increased with enhancing phenyl ring size. The memory window was enhanced as the amount of AM in PI increased. Furthermore, the devices showed a long charge‐retention time of 10⁴ s with an ON/OFF current ratio of around 10³–10⁴ and multiple switching stability over 100 cycles. This study demonstrated that the electrical characteristics of the OFET memory devices could be manipulated through the chemical compositions of the supramolecular electrets.     

Electron-induced switching of the supramolecular chirality of optically active polythiophene aggregates

A chiral regioregular polythiophene (PT), poly[3-[4-((R)-4-ethyl-2-oxazolin-2-yl)phenyl]thiophene] (poly-1), forms chiral aggregates which exhibit a unique induced circular dichroism (ICD) in the pi-pi transition region derived from the supramolecular chirality in the presence of various poor solvents or metal salts in chloroform. We report here that the chirality of such supramolecular aggregates can be switched ("on" and "off") through electron transfer. We have found that upon the addition of copper(II) trifluoromethanesulfonate [Cu(OTf)(2)] to the chiral aggregates of poly-1 in a chloroform-acetonitrile mixture, the ICD disappears because of the oxidative doping of the poly-1 main chain, while a further addition of amines such as triethylenetetramine (TETA) induces undoping of the poly-1 which results in the reappearance of the ICDs. Therefore, the supramolecular chirality of the poly-1 assemblies was reversibly controlled by the addition or removal of an electron from the poly-1 main chain. This may be the first example of a reversible supramolecular chirality switch on chiral PT aggregates. We investigated the mechanism of the chirality switch through the doping and undoping process on the polymer main chain by means of absorption and CD spectroscopies, ESR, cyclic voltammetry, X-ray diffraction, and AFM measurements.     

Protonated canthaxanthins as models for blue carotenoproteins

It has been suggested that astaxanthin (3,3'-dihydroxy-beta,beta-carotene-4,4'-dione) in the carotenoprotein alpha-crustacyanin occurs in the diprotonated form. As a model system for protonated astaxanthin in [small alpha]-crustacyanin the reactions of canthaxanthin ([small beta],[small beta]-carotene-4,4[prime or minute]-dione) with Bronsted acids (CF(3)COOH and CF(3)SO(3)H) and the Lewis acid BF(3)-etherate have been investigated. Structures of C-5 protonated, C-7 protonated, enolised O-4 protonated and O-4,4[prime or minute], C-7 triprotonated canthaxanthin have been established by VIS-NIR and NMR spectroscopy. The charge distribution in the cations has been considered by comparison of the (13)C chemical shift difference relative to neutral relevant carotenoid models. The experimental evidence for protonated canthaxanthins differs significantly from previous AM1 calculations. Experimental data for O-4,4[prime or minute], C-7 triprotonated canthaxanthin relative to C-7 protonated canthaxanthin is considered a relevant model for O-4,4[prime or minute] diprotonated canthaxanthin, in comparison with neutral canthaxanthin. The positive charge was mainly located at C-6/6[prime or minute][dbl greater-than] C-8/8[prime or minute] > C-10/10[prime or minute] > C-12/12[prime or minute] > C-14/14[prime or minute][similar] C-15/15[prime or minute] in the polyene chain. Moreover, it was inferred that only 14% of the positive charge is delocalised to the polyene chain, the remaining charge must therefore be located at the protonated carbonyl moiety. The results are discussed in relation to previous solid state NMR studies of (13)C labelled astaxanthin in [small alpha]-crustacyanin and recent X-ray analysis of [small beta]-crustacyanin.     

A Supramolecular Photosynthetic Model Made of a Multiporphyrinic Array Constructed around a C60 Core and a C60–Imidazole Derivative

The photophysical properties of a supramolecular fullerene–porphyrin ensemble resulting from the self‐assembly of a pyrrolidinofullerene–imidazole derivative ( F1 ) with a multimetalloporphyrin array constructed around a hexasubstituted fullerene core ( F(ZnP)₁₂ ) have been investigated. The fullerene hexa‐adduct core of the host system does not play any active role in the cascade of photoinduced events of the supramolecular ensemble, indeed no intercomponent photoinduced processes could be observed in host F(ZnP)₁₂ . In contrast, upon axial coordination with the monosubstituted fullerene guest F1 , a quantitative quenching of the fluorescence signal of the metalloporphyrins was observed for the supramolecular complex [F(ZnP)₁₂(F1) _n ] both in polar and nonpolar solvents. In toluene, the supramolecular ensemble exhibits a charge transfer emission centered around 930 nm, suggesting the occurrence of intramolecular face‐to‐face interactions of F1 with neighboring metalloporphyrin moieties within the self‐assembled photoactive array. This mechanism is supported by the fact that a one order of magnitude increase in the binding constant was observed for the supramolecular complex [F(ZnP)₁₂(F1) _n ] when compared with a reference system lacking the pyrrolidinofullerene unit. In benzonitrile, a long‐lived charge‐separated state (τ=0.3 μs) has been detected for the supramolecular adduct.     

Novel electrical properties of nanoscale thin films of a semiconducting polymer: quantitative current-sensing AFM analysis

Thin films (20-150 nm thickness) of poly(o-anthranilic acid) with various doping levels were prepared on silicon substrates with deposited indium tin oxide, and their topography and current-voltage (I-V) characteristics were quantitatively investigated using current-sensing atomic force microscopy with a platinum-coated tip. The films were found to have a surface morphology like that of orange peel, with a periodic modulation and a surface roughness. The films exhibited nonuniform current flows and I-V characteristics that depended on the doping level as well as on the film thickness. Films with a high doping level were found to exhibit Zener diode switching behavior, whereas the films with a very low doping level (or that were dedoped) exhibited no current flow at all, and so are insulators. Interestingly, self-doped films (which are at an intermediate doping level) were found to have a novel electrical bistability, i.e., a switching characteristic like that of Schottky diodes, and increasingly insulating characteristics as the film thickness was increased. The films with thickness < or =62 nm, which exhibited this novel and stable electrical bistability, can potentially be used in the fabrication of high-density, stable, high-performance digital nonvolatile memory devices based only on transistors. The measured current images and I-V characteristics indicate that the electrical switching and bistability of the films are governed by local filament formation and charge traps.     

聚(3-己基)噻吩薄膜中电荷传导的研究

对两种具有相同化学结构的聚(3-己基)噻吩膜进行了电荷传导研究以检验膜的结构对载流子迁移率的影响. 一种膜是由3-己基噻吩单体经电化学合成直接制备的膜(原位生长膜); 另一种膜是将原位生长膜溶于三氯甲烷后重新滴涂而成的(滴涂膜). 研究表明, 虽然两种膜的制备方法不一样, 但在最低(0.02%)和较高(20%～30%)掺杂率下两膜中的载流子迁移率相一致; 然而在中等掺杂率区域, 两膜中的载流子迁移率明显不同. 对于原位生长膜, 载流子迁移率在低掺杂区域几乎保持不变, 当掺杂率大于1%后开始上升; 而在滴涂膜中, 随着掺杂率的增加, 迁移率先下降然后迅速升高. 上述两种迁移率变化特征分别与以前研究中观察到的电化学合成高分子膜和化学合成高分子旋涂或滴涂膜中迁移率的变化特征相一致, 表明了迁移率随掺杂率变化特征的改变是由膜的结构变化而引起的     

Effects of doping La and Cu on photoinduced charge properties of TiO_2 and its relationships with photocatalytic activity

In recent years, nanosized TiO2 materials have been widely studied in photocatalytic and photoelectric conversion fields because of their intrinsic characteris- tics, such as stable chemical property, strong oxidizing capability and nontoxicity[1,2]. And the preparation, characterization and modification of nanosized TiO2 are always crucial contents in semiconductor photo- electric chemistry and photocatalytic researches[3,4]. To further improve TiO2 performance, doping metal ion is consider…     

表面电荷转移掺杂石墨烯的研究进展

表面电荷转移掺杂是调制石墨烯电学特性的重要手段。发展高效、稳定的表面电荷转移掺杂剂对于提高石墨烯的电学和光电性能、从而推动其在电子和光电领域中的应用具有重要意义。本文围绕高效与稳定两个方面综述了近年来石墨烯表面电荷转移掺杂剂的研究现状以及掺杂石墨烯在光电器件应用方面的进展。根据掺杂剂的类型，着重介绍了最新发展的高效p型和n型掺杂剂，并概述了稳定掺杂方面的重要研究工作。此外，专门介绍了基于掺杂石墨烯透明电极的高性能光电器件。最后，根据表面电荷转移掺杂研究面临的主要挑战，对其未来的发展方向进行了展望。     

Mass spectrometric analysis of androstan-17β-ol-3-one and androstadiene-17β-ol-3-one isomers

Mass spectrometric identification and characterization of steroids using electrospray ionization and tandem mass spectrometry has advantages in drug testing and doping control analysis attributable to limitations of gas chromatography followed by electron ionization mass spectrometry. Steroids with an androstadiene-17beta-ol-3-one nucleus and double bonds located either at C-1 and C-4, C-4 and C-9, or C-4 and C-6 were used to determine characteristic fragmentation pathways. Diagnostic dissociation routes are proposed using deuterium labeling, MS3 experiments, and analyses of structurally closely related compounds. Steroids such as boldenone (androst-1,4-diene-17beta-ol-3-one) produced characteristic product ions at m/z 121, 135, and 147. Compounds with double bonds at C-4 and C-9 generated abundant product ions at m/z 145 and 147. Conjugated double bonds at C-4 and C-6 gave rise to an intense and characteristic signal at m/z 133. Stereochemical differentiation between 5alpha- and 5beta-isomers of androstan-17beta-ol-3-ones was possible because of significant differences in relative abundance of product ions generated by elimination of acetone from alpha,beta-saturated 3-keto steroids.     

Design, syntheses, and studies of supramolecular porphyrin-fullerene conjugates, using bis-18-crown-6 appended porphyrins and pyridine or alkyl ammonium functionalized fullerenes

Photoinduced electron-transfer processes in cis and trans functionalized bis-18-crown-6 porphyrin self-assembled with fullerene functionalized with pyridine or alkylammonium cation entities are reported. The structural integrity of the newly formed supramolecular conjugates was accomplished by optical absorption and emission, electron spray ionization mass, electrochemistry, and semiempirical PM3 calculations. A 1:2 stoichiometry of the supramolecular porphyrin:fullerene conjugates was deduced from these studies. The conjugates revealed stable "two-point"' binding involving metal-ligand coordination and alkylammonium cation-crown ether binding or only the latter type of binding depending upon the functionality of the fullerene and metal ion in the porphyrin cavity. The effect of the variation on free energy changes of charge separation and the charge recombination was achieved by varying the metal ion in the porphyrin cavity. The charge-separation rates (k(CS)) determined from the picosecond time-resolved emission studies were generally higher for the cis bis-crown functionalized porphyrins than those of the corresponding trans ones. A comparison of the k(CS) values reported earlier for 1:1 porphyrin-fullerene conjugates with a similar self-assembly mechanism suggested that employing a higher number of acceptor entities improves the electron-transfer rates. The calculated charge-recombination rates (k(CR)) were 2-3 orders of magnitude smaller than the k(CS) values, suggesting the occurrence of the charge recombination process in the Marcus inverted region. The lifetimes of the radical ion pair (tau(RIP)) ranged between 46 and 233 ns indicating charge stabilization in the studied conjugates.     

Bodipy–C60 triple hydrogen bonding assemblies as heavy atom-free triplet photosensitizers: preparation and study of the singlet/triplet energy transfer

Supramolecular triplet photosensitizers based on hydrogen bonding-mediated molecular assemblies were prepared. Three thymine-containing visible light-harvesting Bodipy derivatives (B-1, B-2 and B-3, which show absorption at 505 nm, 630 nm and 593 nm, respectively) were used as H-bonding modules, and 1,6-diaminopyridine-appended C₆₀ was used as the complementary hydrogen bonding module (C-1), in which the C₆₀ part acts as a spin converter for triplet formation. Visible light-harvesting antennae with methylated thymine were prepared as references (B-1-Me, B-2-Me and B-3-Me), which are unable to form strong H-bonds with C-1. Triple H-bonds are formed between each Bodipy antenna (B-1, B-2 and B-3) and the C₆₀ module (C-1). The photophysical properties of the H-bonding assemblies and the reference non-hydrogen bond-forming mixtures were studied using steady state UV/vis absorption spectroscopy, fluorescence emission spectroscopy, electrochemical characterization, and nanosecond transient absorption spectroscopy. Singlet energy transfer from the Bodipy antenna to the C₆₀ module was confirmed by fluorescence quenching studies. The intersystem crossing of the latter produced the triplet excited state. The nanosecond transient absorption spectroscopy showed that the triplet state is either localized on the C₆₀ module (for assembly B-1·C-1), or on the styryl-Bodipy antenna (for assemblies B-2·C-1 and B-3·C-1). Intra-assembly forward–backward (ping-pong) singlet/triplet energy transfer was proposed. In contrast to the H-bonding assemblies, slow triplet energy transfer was observed for the non-hydrogen bonding mixtures. As a proof of concept, these supramolecular assemblies were used as triplet photosensitizers for triplet–triplet annihilation upconversion.     

pH‐Responsive Pillar[6]arene‐based Water‐Soluble Supramolecular Hexagonal Boxes

We describe the preparation of the first water‐soluble pH‐responsive supramolecular hexagonal boxes (SHBs) based on multiple charge‐assisted hydrogen bonds between peramino‐pillar[6]arenes 2 with the molecular “lid” mellitic acid ( 1 a ). The interaction between 2 and 1 a , as well as the other “lids” pyromellitic and trimesic acids ( 1 b and 1 c , respecively) were studied by a combination of experimental and computational methods. Interestingly, the addition of 1 a to the complexes of the protonated form of pillar[6]arene 2 , that is, 3 , with bis‐sulfonate 4 a or 4 b , immediately led to guest escape along with the formation of closed 1 a₂2 supramolecular boxes. Moreover, the process of the openning and closing of the supramolecular boxes along with threading and escaping of the guests, respectively, was found to be reversible and pH‐responsive. This study paves the way for the easy and modular preparation of different SHBs that may have myriad applications.     

Electrospun Supramolecular Hybrid Microfibers from Conjugated Polymers: Color Transformation and Conductivity Evolution

A type of novel electrospun supramolecular hybrid microfibers comprising poly(9-(4-(octyloxy)-phenyl)-2,7-fluoren-9-ol)(PPFOH) and poly(N-vinylcarbazole)(PVK) are successfully prepared for intriguing multi-color emission properties. The supramolecular tunable PPFOH aggregation in PVK matrix endows the complex with a smart energy transfer behavior to obtain the multi-color emissions. In stark contrast to PVK fibers, the emission color of PPFOH/PVK fibers with an efficient dispersion of PPFOH fluorophores at a proper dope ratio can be tuned in a wide spectrum of blue(0.1%), sky blue(0.5%), nearly white(1%), cyan(2%), green(5%) and yellow(10%). Besides, conductive behaviors of the microfiber were demonstrated in accompany with the increment of the doping ratio of PPFOH to PVK. Successful fabrication of polymer lightemitting diode(PLED) based on the blended electrospun fiber provided a further evidence of its excellent electrical property for potential applications in optoelectronic devices.     

Negative Ion CID Fragmentation of <Emphasis Type="Italic">O-</Emphasis>linked Oligosaccharide Aldoses—Charge Induced and Charge Remote Fragmentation

Collision induced dissociation (CID) fragmentation was compared between reducing and reduced sulfated, sialylated, and neutral O-linked oligosaccharides. It was found that fragmentation of the [M – H]^– ions of aldoses with acidic residues gave unique Z-fragmentation of the reducing end GalNAc containing the acidic C-6 branch, where the entire C-3 branch was lost. This fragmentation pathway, which is not seen in the alditols, showed that the process involved charge remote fragmentation catalyzed by a reducing end acidic anomeric proton. With structures containing sialic acid on both the C-3 and C-6 branch, the [M – H]^– ions were dominated by the loss of sialic acid. This fragmentation pathway was also pronounced in the [M – 2H]^2– ions revealing both the C-6 Z-fragment plus its complementary C-3 C-fragment in addition to glycosidic and cross ring fragmentation. This generation of the Z/C-fragment pairs from GalNAc showed that the charges were not participating in their generation. Fragmentation of neutral aldoses showed pronounced Z-fragmentation believed to be generated by proton migration from the C-6 branch to the negatively charged GalNAc residue followed by charge remote fragmentation similar to the acidic oligosaccharides. In addition, A-type fragments generated by charge induced fragmentation of neutral oligosaccharides were observed when the charge migrated from C-1 of the GalNAc to the GlcNAc residue followed by rearrangement to accommodate the ^0,2A-fragmentation. LC-MS also showed that O-linked aldoses existed as interchangeable α/β pyranose anomers, in addition to a third isomer (25% of the total free aldose) believed to be the furanose form.     

Influences of self-assembled structure on mobilities of charge carriers in pi-conjugated polymers

Mobilities of charge carriers in cast and spun films of poly(3-hexylthiophene)s (PHTs) with regioregularities of 97%, 81%, 70%, and 54% (denoted as PHT97%, PHT81%, PHT70%, and PHT54%, respectively) are evaluated as a function of doping level. A common feature of mobility vs doping level plots for all the PHT films is that the mobility decreases initially with the increase of the doping level and then starts to rise drastically at ca. 1% doping level. No large mobility difference is observed between cast and spun films of each PHT. In contrast, the difference in regioregularity of PHT resulted in a large mobility difference, especially in the low doping regime. At the highest doping levels of ca. 20%, the apparent mobility values reach 0.4 and 0.01 cm(2) V(-1) s(-1) for the cast films of PHT97% and PHT54%, respectively. These features of the mobility plots are discussed in connection with self-assembled structures of PHT films studied by electrochemical, in-situ ESR, in-situ UV-vis-NIR, and X-ray diffraction measurements. It is concluded first that mobilities of polarons are mainly controlled by the rate of an interchain charge hopping and second that the evolution of metallic conduction featured by the sharp mobility increase is irrelevant to the interchain stacking, or rather governed by an intrachain route.     

Bi掺杂NaTaO3中Bi的化学价态对其光催化性能的影响

分别采用NaBiO3和Bi(NO3)3为Bi源制备了Bi掺杂NaTaO3光催化剂,研究了Bi离子的价态对NaTaO3光催化分解水制氢性能的影响.采用X射线衍射(XRD)、拉曼光谱、X射线光电子能谱(XPS)和紫外-可见吸收光谱研究了催化剂的晶体结构、Bi离子的化学状态和催化剂的光学吸收性能.以光催化分解水制氢反应研究了Bi离子掺杂NaTaO3的催化性能. XRD结果表明,对于两个不同Bi源掺杂的NaTaO3样品, Bi离子的掺杂没有改变催化剂的单斜相结构,但拉曼光谱证实Bi离子的掺杂致使Ta–O–Ta键角偏离了180o. XPS结果表明,以Bi(NO3)3为Bi源时, Bi离子以Bi3+掺杂于NaTaO3的A位;当以NaBiO3为原料时, Bi3+和Bi5+共掺杂于NaTaO3的A位.两种不同Bi源掺杂得到的样品在紫外-可见吸收光谱中给出了相似的光学吸收,但Bi3+的掺杂对NaTaO3光催化性能影响不大,而Bi3+和Bi5+共掺杂大大提高了NaTaO3的光解水制氢性能. Bi离子取代Na离子在A位的掺杂,在NaTaO3结构中引入了能够促进载流子分离的空位和缺陷;与此同时, Bi的掺杂导致Ta–O–Ta键角偏离180o而不利于载流子迁移.对于Bi3+掺杂的NaTaO3样品,这两种作用相互抵消,使得其催化性能与NaTaO3相比没有变化;而Bi3+和Bi5+的共掺杂和高价态Bi5+的掺杂引入了更多的空位和缺陷,提高了光生电子-空穴的分离效率,从而提高了光催化产氢性能.研究表明,光催化过程中载流子的迁移是影响催化性能的重要因素,而在ABO3钙钛矿结构的A位引入高价态离子是促进光生载流子分离的有效途径.     

A Supramolecular Approach on Using Poly(fluorenylstyrene)‐block‐poly(2‐vinylpyridine):PCBM Composite Thin Films for Non‐Volatile Memory Device Applications

Supramolecular composite thin films of poly[4‐(9,9‐dihexylfloren‐2‐yl)styrene]‐block ‐poly(2‐vinylpyridine) (P(St‐Fl)‐b‐P2VP):[6,6]‐phenyl‐C₆₁‐butyric acid methyl ester (PCBM) were prepared for write‐once‐read‐many times (WORM) non‐volatile memory devices. The optical absorption and photoluminescence results indicated the formation of charge transfer complexation between the P2VP block and PCBM, which led to the varied PCBM aggregated size and memory characteristics. The ITO/PCBM:(P(St‐Fl)‐b‐P2VP)/Al device exhibited the WORM characteristic with low threshold voltage (−1.6 to −3.2 V) and high ON/OFF ratio (10³ to 10⁵) by tuning the PCBM content. The switching behavior could be explained by the charge injection dominated thermionic emission in the OFF state and field‐induced charge transfer in the ON state. The present study provides a novel approach system for tuning polymer memory device characteristics through the supramolecular materials approach.