Optimization of the deflagration to detonation transition: reduction of length and time of transition

The aim of this experimental investigation is the study of Deflagration to Detonation Transition (DDT) in tubes in order to (i) reduce both run-up distance and time of transition (L _DDT and t _DDT) in connection with Pulsed Detonation Engine applications and to (ii) attempt to scale L _DDT with λ_CJ (the detonation cellular structure width). In DDT, the production of turbulence during the long flame run-up can lead to L _DDT values of several meters. To shorten L _DDT, an experimental set-up is designed to quickly induce highly turbulent initial flow. It consists of a double chamber terminated with a perforated plate of high Blockage Ratio (BR) positioned at the beginning of a 26 mm inner diameter tube containing a “Shchelkin spiral” of BR ≈ 0.5. The study involves stoichiometric reactive mixtures of H₂, CH₄, C₃H₈, and C₂H₄ with oxygen and diluted with N₂ in order to obtain the same cell width λ_CJ≈10 mm at standard conditions. The results show that a shock-flame system propagating with nearly the isobaric speed of sound of combustion products, called the choking regime, is rapidly obtained. This experimental set-up allows a L _DDT below 40 cm for the mixtures used and a ratio L _DDT/λ_CJ ranging from 23 to 37. The transition distance seems to depend on the reduced activation energy (E _a/RT _c) and on the normalized heat of reaction (Q/a ₀ ²). The higher these quantities are, the shorter the ratio L _DDT/λ_CJ is. PACS 47.40.Rs · 47.60.+i · 47.70.Pq · 47.80.CbThis paper was based on the work that was presented at the 19th International Colloquium on the Dynamics of Explosions and Reactive Systems, Hakone, Japan, July 27–August 1, 2003.     

In-line measurement of rheological properties of polymer melts

Shear viscosity (), first normal stress difference (N ₁), and extensional viscosity ( _E ) of polymer melts measured under processing conditions are important in process modeling, quality control, and process control. A slit rheometer that could simultaneously measure , N ₁, and the planar extensional viscosity ( _p ) was designed and tested by attaching it in-line to a laboratory model single-screw extruder. A tube (circular cross-section) rheometer to measure and the uniaxial extensional viscosity ( _u ) simultaneously was also designed and tested. Two commercial grades of LDPE (low density polyethylene) with melt index values of 6 and 12 were used as test materials for the study. Exit and hole pressure methods were used to estimate N ₁, and the entrance pressure drop method using the analyses of Cogswell, Binding, and Gibson (the last analysis used with the axisymmetric case only) was used to estimate _E .The hole pressure method was considered better than the exit pressure method to estimate N ₁ (due to the greater susceptibility of the latter to experimental errors). From the hole pressure method N ₁ was obtained from 100 kPa to 500 kPa over a range of shear rates from 40 s^–1 to 700 s^–1. Among the analyses used to estimate the extensional viscosity, Cogswell's is recommended due to its simpler equations without loss of much information compared to the other analyses. The range of extension rates achieved was 1 to 30 s^–1. The combination of the hole pressure and entrance pressure drop methods in a slit rheometer is a feasible design for a process rheometer, allowing the simultaneous measurement of the shear viscosity, first normal stress difference and planar extensional viscosity under processing conditions. Similarly, combining the entrance pressure drop measurements with a tube rheometer is also feasible and convenient.     

Effect of transverse stress on switch-toughening of ferroelectrics

Testing data indicated that T stress significantly altersR-curves of ferroelectrics. The model of stress-induced polarization switching is adopted to evaluate the fracture toughness of ferroelectrics under K field and T stress. Analytical solution is obtained to estimate the steady state fracture resistance of mono-domain ferroelectrics. The result is generalized to multi-domain ferroelectric ceramics via Reuss approximation, which enables us to explain quantitatively R-curves under two testing configurations.     

Spectral Analysis of the Balance Equation of Ground Water Hydrology

The spectral analysis of the balance equation of ground water flow, associated to an asymptotic expansion of the conductivity (K) and head (h) fields, permits to show that the high wave number components of the source terms, F, and of the conductivity, K, are attenuated when h is computed as solution to the balance equation. This has important consequences on the inverse mapping (h, F) → K: in fact it is not possible to recover in a reliable way the high wave number components of K, because small errors on the corresponding components of h are amplified so that they can hidden the true signal.     

Measurement of extensional viscosity of polymer solutions

A filament stretching technique for measuring the extensional viscosity of polymer solutions at constant stretch rate is presented. The liquid sample is held between two coaxial discs and stretched by moving the bottom disc downwards with a speed that increases exponentially with time. This is illustrated using a constant viscosity, elastic fluid consisting of 0.185% polyisobutylene in a solvent of kerosene and polybutene. For the case of this particular fluid, two distinct stretch rate regions are found to arise. The stretch rate in the first region is much higher than in the second, which is, in most cases, close to the overall stretch rate imposed on the sample. Nonetheless, all the results of any given run can be represented using an average extensional rate. The extensional stress growth data, plotted as the Trouton ratio against time, show an initial linear viscoelastic region where T_R rises to a value of 3, independent of extensional rate. Beyond this region, T_R depends on the stretch rate and rises dramatically to values in excess of 10³; the higher the extensional rate, the faster is the increase in T_R. These data do not seem to reach a steady state and appear to be similar to polymer melt data obtained by others in the past. The reproducibility of the results is very good and all this suggests that it is now possible to obtain unambiguous constant-stretch-rate stress-growth data for polymer solutions stretched from a state of rest.     

A Critique of Atomistic Definitions of the Stress Tensor

Current interest in nanoscale systems and molecular dynamical simulations has focussed attention on the extent to which continuum concepts and relations may be utilised meaningfully at small length scales. In particular, the notion of the Cauchy stress tensor has been examined from a number of perspectives. These include motivation from a virial-based argument, and from scale-dependent localisation procedures involving the use of weighting functions. Here different definitions and derivations of the stress tensor in terms of atoms/molecules, modelled as interacting point masses, are compared. The aim is to elucidate assumptions inherent in different approaches, and to clarify associated physical interpretations of stress. Following a critical analysis and extension of the virial approach, a method of spatial atomistic averaging (at any prescribed length scale) is presented and a balance of linear momentum is derived. The contribution of corpuscular interactions is represented by a force density field f. The balance relation reduces to standard form when f is expressed as the divergence of an interaction stress tensor field, T ⁻. The manner in which T ⁻ can be defined is studied, since T ⁻ is unique only to within a divergence-free field. Three distinct possibilities are discussed and critically compared. An approach to nanoscale systems is suggested in which f is employed directly, so obviating separate modelling of interfacial and edge effects.      

Effect of different size and orientation of rectangular rotary blades on quality of puddling

The effect of different combinations of size and orientation of rectangular blades of a wet land puddler, on puddling index, force requirement and performance index was investigated under controlled conditions in a soil-bin from the study. It was observed with the blade size of 15-cm width × 8.5-cm depth and a blade angle of 30° with respect to shaft gave better performance than other combinations in terms of minimum puddling index, minimum horizontal force, vertical force, specific energy and maximum performance index. The values are, respectively, 67.95%, 105.12 N, 33.85 N, and 9.71 kJ/m³ and 6.69. The above-mentioned parameters of the blade were found to be very close to the predicted values obtain through MREG computer programme for optimization of size and orientation of puddler blades.     

Numerical simulations of necking during tensile deformation of aluminum single crystals

Finite element simulations are used to study strain localization during uniaxial tensile straining of a single crystal with properties representative of pure Al. The crystal is modeled using a constitutive equation incorporating self- and latent-hardening. The simulations are used to investigate the influence of the initial orientation of the loading axis relative to the crystal, as well as the hardening and strain rate sensitivity of the crystal on the strain to localization. We find that (i) the specimen fails by diffuse necking for strain rate exponents m < 100, and a sharp neck for m > 100. (ii) The strain to localization is a decreasing function of m for m < 100, and is relatively insensitive to m for m > 100. (iii) The strain to localization is a minimum when the tensile axis is close to (but not exactly parallel to) a high symmetry direction such as [1 0 0] or [1 1 1] and the variation of the strain to localization with orientation is highly sensitive to the strain rate exponent and latent-hardening behavior of the crystal. This behavior can be explained in terms of changes in the active slip systems as the initial orientation of the crystal is varied.     

Slow Eigenvalues of Self-similar Solutions of the Dafermos Regularization of a System of Conservation Laws: an Analytic Approach

The Dafermos regularization of a system of n hyperbolic conservation laws in one space dimension has, near a Riemann solution consisting of n Lax shock waves, a self-similar solution u = u _ε(X/T). In Lin and Schecter (2003, SIAM J. Math. Anal. 35, 884–921) it is shown that the linearized Dafermos operator at such a solution may have two kinds of eigenvalues: fast eigenvalues of order 1/ε and slow eigenvalues of order one. The fast eigenvalues represent motion in an initial time layer, where near the shock waves solutions quickly converge to traveling-wave-like motion. The slow eigenvalues represent motion after the initial time layer, where motion between the shock waves is dominant. In this paper we use tools from dynamical systems and singular perturbation theory to study the slow eigenvalues. We show how to construct asymptotic expansions of eigenvalue-eigenfunction pairs to any order in ε. We also prove the existence of true eigenvalue-eigenfunction pairs near the asymptotic expansions.     

Effect of flow diverters on free convection heat transfer from a pair of vertical arrays of isothermal cylinders

Laminar free convection heat transfer from two vertical arrays of five isothermal cylinders separated by flow diverters is studied experimentally using a Mach-Zehnder interferometer. The width of flow diverters is kept constant to two-cylinder diameters and the cylinders vertical center-to-center spacing is equal to three-cylinder diameter. Effect of the ratio of the horizontal spacing between two cylinder arrays to their diameter (S_h/D) on heat transfer from the cylinders is investigated for various Rayleigh numbers. The experiments are performed for S_h/D = 2-4, and the Rayleigh number based on the cylinder diameter ranging from 10³ to 3 × 10³. It is observed that for small S_h/D ratios, the flow diverters have a negative effect on the total rate of heat transfer from the arrays; while by increasing the horizontal center to center spacing, they tend to enhance the overall cooling rate of the array. Moreover, increasing Ra and S_h/D generally results in a higher average Nusselt number for each cylinder in the array.     

Rheological aspects of the rejuvenation of aged bitumen

Rheological techniques are used to investigate the rejuvenation of aged bitumen. The thermal transition associated with the collapse of the compact structure constituted by asphaltene is determined by Dynamic Mechanical Thermal Analysis. For aged bitumen, this transition shifts to a higher temperature but when rejuvenating agents are added, the transition returns to its original value. The “rutting factor,” G*/sin δ allows to define the maximum temperature the binder can reach without permanent deformation. The employed rejuvenating agents are suitable because permanent deformation is postponed. Viscosity results reveal that aged bitumen needs a high mixing temperature (>200°C) to behave like a fluid material able to wet, adhere, and envelop aggregates. The addition of rejuvenating agents considerably reduces mixing and compaction temperatures. The mixture of 80% aged bitumen—20% recycled motor oil, obtained exclusively from waste materials is an apt binder that can compete satisfactorily with new 60/70 bitumen.Paper presented at the AERC2005. This paper will be part of a special issue of AERC2005.     

Direct simulation of isolated elliptic vortices and of their radiated noise

The aerodynamic evolution and the acoustic radiation of elliptic vortices with various aspect ratios and moderate Mach numbers are investigated by solving numerically the full compressible Navier–Stokes equations. Three behaviours are observed according to the aspect ratio σ = a/b where a and b are the major and minor semi-axes of the vortices. At the small aspect ratio σ = 1.2, the vortex rotates at a constant angular velocity and radiates like a rotating quadrupole. At the moderate aspect ratio σ = 5, the vortex is initially unstable. However the growth of instability waves is inhibited by the return to axisymmetry which decreases its aspect ratio. The noise level becomes lower with time and the radiation frequency increases. For vortices with larger aspect ratios σ ≥ 6, the return to axisymmetry does not occur quickly enough to stop the growth of instabilities, which splits the vortices. Various mergers are then found to occur. For instance in the case σ = 6, several successive switches between an elliptic state and a configuration of two co-rotating vortices are observed. The present results show that the initial value of the aspect ratio yields the relative weight between the return to axisymmetry which stabilizes the vortex and the growth of instabilities which tends to split it. Moreover the noise generated by the vortices is also calculated using the analytical solution derived by Howe (J. Fluid Mech. 71:625–673, 1975) and is compared with the reference solution provided by the direct computation. This solution is found to be valid for σ = 1.2. An extended solution is proposed for higher aspect ratios. Finally, the pressure field appears weakly affected by the switches between the two unstable configurations in the case σ = 6, which underlines the difficulty to detect the split or the merger of vortices from the radiated pressure. This study also shows that elliptic vortices can be used as a basic configuration of aerodynamic noise generation.      

A survey of exact solutions of inviscid field equations in the theory of shear flow instabilty

This paper presents a survey of undisturbed flows that take one or another of the field equations of inviscid shear flow instability theory (e.g. theRayleigh equation,Taylor-Goldstein-Haurwitz equation or theKuo equation) to a differential equation satisfied by aknown transcendental function forarbitrary complex values of the parameters. Some mean velocity profiles having this feature are well known. Thus, piecewise linear mean velocity profiles take theRayleigh equations to a constant-coefficient differential equation and the exponential mean velocity profile takes theRayleigh equation to theGauss hypergeometric equation. Less well known is the fact that a variety of mean velocity profiles take theRayleigh equation to a differential equation due toKarl Heun. These profiles include: (i) the sinusoidal profile; (ii) the hyperbolic tangent profile (an example pointed out byMiles (1963)); (iii) the profile in the form of the square of a hyperbolic secant (theBickley jet); and, (iv) a skewed velocity profile in which each component has the form of a quadratic function of the variable exp(–z/l) (in whichz is the cross-stream coordinate andl is a length scale). In all of these cases, one or another author has previously identified aregular neutral mode solution of theRayleigh equation and has expressed that solution in the form of elementary functions. Such regular neutral modes apparently represent cases in which the solution ofHeun's equation (which is normally an infinite series) truncates to a single term. The survey concludes by noting that the parabolic mean velocity profile takes theRayleigh equation to thedifferential equation of the spheroidal wave function.Dedicated to Mårten T. Landahl on the occasion of his sixty-fifth birthday by a former apprentice as a token of his respect and gratitude.     

Forced oscillations of a layer of a viscoelastic material under the action of a convective pressure wave

The longitudinal and transverse components of deformation of the surface of a flat layer of a viscoelastic material glued onto a solid base under the action of a traveling pressure wave are determined. The coating compliance is described by two components corresponding to two components of surface displacement. The dimensionless compliance components depend only on the viscoelastic properties of the material, the ratio of the wave length to the layer thickness λ/H, and the ratio of the wave velocity to the velocity of propagation of shear oscillations V/C _t ⁰ . Data on the dynamic compliance are presented for 0.3 < λ/H < 30 and 0.1 < V/C _t ⁰ < 10. The compliance is demonstrated to be determined by its absolute value and by the phase lag of strain from pressure. The effect of viscous losses in the material and compressibility of the latter on the dynamic compliance is analyzed. An anomalous behavior of the compliance with the wave velocity being greater than a certain critical value is explained. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 48, No. 2, pp. 90–97, March–April, 2007.     

Sensitivity of mesh spacing on simulating macrosegregation during directional solidification of a superalloy

The sensitivity of mesh spacing on simulations of macrosegregation, particularly ‘freckles’, during vertical directional solidification of a superalloy in a rectangular mold was systematically analyzed to achieve accurate predictions in finite element calculations. It was observed that a coarser mesh spacing in the x‐direction horizontal tends to minimize the simulated macrosegregation, whereas a coarser mesh spacing in the y‐direction vertical artificially tends to make the system appear to have more macrosegregation. When solidification conditions either lead to a well‐established freckling case or to a well‐established non‐freckling case, the simulated results are not sensitive to the mesh spacing provided the elements are no larger than about 2d₁ by 2 D/V and 3d₁ by 4 D/V respectively, where d₁ is the primary dendrite arm spacing, D is the diffusivity of the alloy solute with the smallest diffusivity in the liquid, and V is the growth rate. However, when solidification conditions are very close to the transition between freckling and no freckling, the simulated results are sensitive to the mesh spacing, especially in the y‐direction. Based on the mesh sensitivity analysis from the two‐dimensional simulations of rectangular castings of René N5, the mesh with element dimensions no larger than 2d₁ in the x‐direction and 1.5 D/V in the y‐direction are recommended as the most stringent element size. Copyright © 2001 John Wiley & Sons, Ltd.     

Gas-dynamic signs of explosive eruptions of volcanoes. 2. Model of homogeneous-heterogeneous nucleation. Specific features of destruction of the cavitating magma

The dynamics of state of the crystallite-containing magma is studied within the framework of the gas-dynamic model of bubble cavitation. The effect of crystallites on flow evolution is considered for two cases: where the crystallites are cavitation nuclei (homogeneous-heterogeneous nucleation model) and where large clusters of crystallites are formed in the magma in the period between eruptions. In the first case, decompression jumps are demonstrated to arise as early as in the wave precursor; the intensity of these jumps turns out to be sufficient to form a series of discrete zones of nucleation ahead of the front of the main decompression wave. Results of experimental modeling of an explosive eruption with ejection of crystallite clusters (magmatic “bombs”) suggest that a cocurrent flow of the cavitating magma with dynamically varying properties (mean density and viscosity) transforms to an independent unsteady flow whose velocity is greater than the magma flow velocity. Experimental results on modeling the flow structure during the eruption show that coalescence of bubbles in the flow leads to the formation of spatial “slugs” consisting of the gas and particles. This process is analyzed within a combined nucleation model including the two-phase Iordansky-Kogarko-van Wijngaarden model and the model of the “frozen” field of mass velocities in the cavitation zone. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 50, No. 2, pp. 167–177, March–April, 2009.     

PFC2D平节理模型细观参数标定方法

细观参数的快速准确确定对PFC正确模拟岩石力学性能非常重要.目前,平节理模型细观参数的标定研究均未考虑对泊松比和压拉比有很大影响的黏结比例φb和影响岩石强度及裂纹产生难易程度的黏结强度变异系数Rsd这两个细观参数,且未考虑作为判断围岩损伤范围重要指标的宏观参数起裂强度σci在参数中新增φb,Rsd和σci,采用正交数值试验方法研究了平节理模型8个细观参数与岩石6个宏观参数之间的相关性,确定了各宏观参数与主要细观参数之间的拟合关系,并分析了宏细观参数间的趋势关系.在此基础上,提出了平节理模型细观参数的标定流程,然后根据片麻花岗岩物理试验的宏观力学参数确定了模型的细观参数并进行数值试验,模拟结果与物理试验结果基本吻合,说明标定流程可行.     

Pressure and velocity of air during drying and storage of cereal grains

A common method of drying cereal grains is to ventilate a large static mass of grain with an even flow of air at near ambient temperature. After the grain has been dried it is often stored in the same container and kept cool by aeration with a lower velocity of air than is used in drying. To analyse the airflow through this mass of grain a nonlinear momentum equation for flow through porous media is used where the resistance to flow is a + b ¦ν¦. This equation, together with the assumption that the air is incompressible, defines the problem which is solved numerically, using the finite element method, and the results compared with experimental values. The small parameter ε = bν _r /a, where ν _r is the velocity scale, is used in a perturbation analysis to examine the nonlinear effects of the resistance on the airflow. When ε = 0 the equations reduce to those for potential flow, while for small values of ε there are first-order corrections to the pressure p ₁ and the stream function χ ₁. The nonlinear problem is simplified by changing to curvilinear coordinates (s, t) where s is constant on the potential flow isobars while t is constant on the streamlines. General conclusions are derived for p ₁ and χ ₁, for example that they depend on the curvature of the potential flow solution with a large curvature of the isobars leading to larger values of p ₁ and similarly for the streamlines. The potential flow solution p ₀ and the first order solution p ₀ + εp ₁ are close to the solution of the full nonlinear problem when ε is small. To illustrate this for a typical grain storage problem, the solution p ₀ is shown to be very close to the finite element solution (with a difference of less than 1%) when ε < 0.03 while for the first order solution p ₀ + εp ₁ the difference is less than 1% when ε < 0.1.     

An experimental investigation of pore-scale distributions of nonaqueous phase liquids at residual saturation

A set of experiments was conducted to analyze the size distribution of nonaqueous phase liquid (NAPL) blobs as a function of aqueous phase velocities, NAPL densities, and interfacial tension between the aqueous phase and the NAPL. Blob size distributions were analyzed in a model cell after a state of residual saturation was achieved, using image analysis methods. Blob lengths parallel to the direction of flow and parallel to the direction of gravity ranged over about two orders of magnitude, while blob areas varied over about three orders of magnitude. Form factors, which are a measure of blob shapes, varied over a single order of magnitude, with a median form factor of about 0.6. Blobs with smaller areas occurred much more frequently than larger blobs. However, the few larger blobs contributed to the majority of the total NAPL saturation in the model cell. The geometric standard deviations of blob length parallel to the direction of gravity and square root of area exhibited inverse relationships to Bond number (Bo), for 1.3×10^–2–2. Blob length parallel to the direction of flow and area exhibited a weak inverse correlation with capillary number (Ca), for 3×10^–8–5.