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1.
The high-resolution infrared spectrum of the Δv = 2 transitions of 7LiI has been measured at temperatures near 1050 K. The observations include vibrational transitions ranging from 2-0 to 10-8. The data were fit to a set of Dunham potential constants complete through the a6 term, from which the Dunham rovibrational constants were calculated. The band centers for the v = 1-0 and v = 2-0 transitions were determined to be 491.17398 ± 0.00026 cm−1 and 976.73042 ± 0.00038 cm−1, respectively.  相似文献   

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3.
Twenty-four transitions of the v2 = 2 av2 = 1 s hot band of 15NH3 have been observed by an infrared microwave sideband laser spectrometer. In addition, 149 transitions of the band have been obtained by a Fourier transform spectrometer at a resolution of 0.02 cm−1. A weighted least-squares analysis has been carried out and the rms deviation of the fit is 0.00097 cm−1. It was necessary to include the Δ(Kl) = ±3 interaction between the v2 = 2 a and the v4 = a states in the analysis.  相似文献   

4.
Twenty-one transitions of the v2 = 2 av2 = 1 s hot band of 14NH3 have been observed by an infrared microwave sideband laser spectrometer with an absolute accuracy of 0.00002 cm−1. One hundred and seventeen transitions of the band have been obtained by a Fourier transform infrared spectrometer at a resolution of 0.005 cm−1. A weighted least-squares analysis of these data has been carried out to yield 17 molecular parameters for the v2 = 2 a state. These parameters reproduce the experimental frequencies with a root mean square deviation of 0.000123 cm−1. To calculate the frequencies to this accuracy it was necessary to take into account the Δ(Kl) = ±3 interaction between the v2 = 2 a and v4 = 1 a states.  相似文献   

5.
We describe some recent results on isospin breaking corrections which are of relevance for predictions of the leading order hadronic contribution to the muon anomalous magnetic moment aμ^had.LO when using τ lepton data. When these corrections are applied to the new combined data on the π^±π^0 spectral function, the prediction for aμ^had.LO based on τ lepton data gets closer to the one obtained using e^+e^- data.  相似文献   

6.
Because the copper vapor laser(CVL)can supply high average output power of severalhundred wattes and it's emission spectra are an excellent match for the absorption band of Ti:sapphire,the potential application of Ti:sapphire laser pumped by CVL is increasing greatly.  相似文献   

7.
The irradiation of human lymphocytes with a He-Ne laser(632.8nm,56J/cm~2)does not express interleukin-2 receptors on membrances of T-lymphocytes  相似文献   

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9.
Majorana zero modes(MZMs) are exotic excitations(in condensed matter systems) of fundamental scientific interest and hold great promise as the basis of fault-tolerant topological quantum computation. Though MZMs have been predicted in many platforms, their existence is still under debate. In this paper, we review the recent progress in engineering and detecting MZMs in semiconductor-superconductor heterostructures. We also briefiy review the protocols for implementing topological quantum computa...  相似文献   

10.
Quasi-classical trajectory theory is used to study the reaction of O(3p) with H2 (D2) based on the ground 3A″ potential energy surface (PES). The reaction cross section of the reaction O+H2→+OH+H is in excellent agreement with the previous result. Vector correlations, product rotational alignment parameters (P2(j′. k)) and several polarizeddependent differential cross sections are further calculated for the reaction. The product polarization distribution exhibits different characteristics that can be ascribed to different motion paths on the PES, arising from various collision energies or mass factors.  相似文献   

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12.
We find an analytic solution of the Bethe–Ansatz equations (BAE) for the special case of a finite XXZ spin chain with free boundary conditions and with a complex surface field which provides for Uq(sl(2)) symmetry of the Hamiltonian. More precisely, we find one nontrivial solution, corresponding to the ground state of the system with anisotropy parameter Δ= $\frac{1}{2}$ corresponding to q3=?1. With a view to establishing an exact representation of the ground state of the finite size XXZ spin chain in terms of elementary functions, we concentrate on the crossing parameter η dependence around η=π/3 for which there is a known solution. The approach taken involves the use of a physical solution Q of Baxter's T-Q equation, corresponding to the ground state, as well as a non-physical solution P of the same equation. The calculation of P and then of the ground state derivative is covered. Possible applications of this derivative to the theory of percolation have yet to be investigated. As far as the finite XXZ spin chain with periodic boundary conditions is concerned, we find a similar solution for an assymetric case which corresponds to the 6-vertex model with a special magnetic field. For this case we find the analytic value of the “magnetic moment” of the system in the corresponding state.  相似文献   

13.
J. Hietanen 《Molecular physics》2013,111(5):1029-1038
In the infrared spectrum of C2H2 around the fundamental v 5, the hot bands starting from the levels 2v 5, 2v 4 and v 4 + v 5 have been investigated. From the analysis of about 20 different bands, 40 molecular constants describing the bending modes v 4 and v 5 have been derived.  相似文献   

14.
Optical properties and nonlinearity on phase-matching (PM) of two (yellow and orange) phase crystals were investigated in details. Damage threshold was determined in comparison with middle infrared (IR) crystal at identical experimental conditions. Second harmonic generation (SHG) of 30 ns TEA CO2 laser pulses was realized with 5% efficiency in energy and 6.9% in peak power.  相似文献   

15.
Rotationally resolved spectral lines in the C - X (1, 0) band of carbon monoxide are investigated under high resolution using a coherent vacuum ultraviolet laser source, continuously tunable near 107 nm. Transition frequencies are determined by calibrating against a reference standard of iodine lines, recorded with saturation spectroscopy in the visible range, yielding an absolute accuracy of 0.003 cm-1 in the vacuum ultraviolet. Improved molecular constants for the excited state are derived and no effects of perturbation are found at the present level of accuracy. Line broadening measurements result in information on the excited state lifetime of the C 1 Σ + , v = 1 state for five natural isotopomers of carbon monoxide: τ( 12 C 17 O ) = 280 ps, τ( 12 C 18 O ) = 210 ps, τ( 13 C 16 O ) = 295 ps, τ( 13 C 17 O ) = 160 ps, and τ( 13 C 18 O ) = 150 ps. Within the accuracy of the present measurements no effects of J-dependent lifetimes were observed, for neither of the isotopomers. In addition direct time domain measurements of the lifetime of the C 1 Σ + , v = 0 and v = 1 states of the main isotopomer are performed in a pump-probe experiment using a picosecond VUV-laser, yielding τ( 12 C 16 O ) = 1780 ps for v = 0 and τ( 12 C 16 O ) = 625 ps for v = 1. For C 1 Σ + , v = 0 in 12C16O and 13C16O the same lifetime is found; this lifetime matches experimental values of the oscillator strength and hence supports previous results showing pure radiative decay in this state; the error margins however do not exclude some low level of predissociation. The measurements indicate that the C 1 Σ + , v = 0 state of the 13C18O isotopomer is predissociated with an estimated yield of 17% (i.e. above the level of predissociation for 12C16O.) From the combined data predissociation yields upon excitation of the C 1 Σ + , v = 1 state are derived, lying in the range 0.84-0.91 for the five less abundant isotopomers; for the main 12C16O isotopomer a strongly deviating predissociation yield of 0.65 is deduced. Received 21 December 2000 and Received in final form 26 March 2001  相似文献   

16.
Using the classical Mie scattering theory and Fraunhofer diffraction theory,adetailed analysis of the differences of the light energy distribution falling on the multi-elementconcentric photo-detector of a diffraction based laser particle sizer is given.Numerical calcula-tions and computer simulation are carried out. Experimental studies are also made with latexspheres as Standard Reference Material.Our research shows that when the classical Mie scat-tering theory is used,the accuracy of the particle sizer can be essentially improved not only inthe small size range,but also for large paticles.At the same time the time needed for data re-duction in both cases is almost the same.  相似文献   

17.
Rui Zheng  Yu Zhu  Song Li 《Molecular physics》2013,111(6):823-830
The rovibrational spectra of four isotopomers of the Kr–N2O van der Waals complex, namely 82Kr–N2O, 83Kr–N2O, 84Kr–N2O and 86Kr–N2O, were measured in the v 1 vibrational band region of the N2O monomer (~1285?cm?1) using a tunable diode laser spectrometer to probe a pulsed supersonic slit jet. Rotational constants for both ground and excited vibrational states of these four isotopomers were accurately determined. The band-origin of Kr–N2O was observed to shift by +0.1065?cm?1 from that of the monomer. The band-origin shifts of Rg–N2O (Rg?=?Ne, Ar, Kr) in the v 1 vibrational band region could also be well explained by the model based on a Buckingham intermolecular potential [W.A. Herrebout, H.-B. Qian, H. Yamaguchi and B.J. Howard, J. Mol. Spectrosc. 189, 235 (1998)]. But the band-origin shift of He–N2O was found to deviate significantly from this model. The possible reason is discussed and the band-origin shift of Xe–N2O predicted.  相似文献   

18.
The S21 lines of the OH radical for the A2Σ+ (v′ = 1)←X2Π (v″ = 0) transition have been observed in the 278–280 nm region from the laser-excitation spectrum. The OH radical was generated from either the H + NO2 or the H + O3 reaction in a flow system and the fluorescence passing through a 309.6 nm interference filter was detected with a photomultiplier-boxcar integrator arrangement. The weak S21 lines were observed at laser energies above 0.2 mJ. The observed peak wavenumbers are in excellent agreement with those predicted for the S21 bands of the A (v>′ = 1)←X (v″ = 0) transition from the known spectroscopic parameters. Observation of the corresponding S21 system for OD in the 286.0–286.9 nm region further confirms this assignment. The relative absorption cross-sections of about one-tenth those of the P1 lines are in good agreement with theoretical considerations.  相似文献   

19.
We report the observation of the hitherto undetected v′=8←v=0 vibrational overtone in trapped HD+ molecular ions, sympathetically cooled by laser-cooled Be+ ions. The overtone is excited using 782 nm laser radiation, after which HD+ ions in v=8 are photodissociated by the 313 nm laser used for Be+ cooling. The concomitant loss of HD+ is detected by the method of secular excitation (Roth et al. in Phys. Rev. A. 74:040501(R), 2006). We furthermore present details of the experimental setup, and we show that results from spectroscopy of v′=8←v=0 overtones in combination with accurate ab initio calculations may yield a new value for the proton–electron mass ratio with an accuracy of order 1 ppb.  相似文献   

20.
《Nuclear Physics A》1988,481(4):765-780
The relativistic corrections, corresponding to the transverse and longitudinal excitation of the Δ, are included in the original Blomqvist-Laget model. They are calibrated against the pion photoproduction data. The measurement of the transverse-longitudinal interference cross sections of the (e, e′ π0) reaction is the most promising way to study the longitudinal coupling of the Δ.  相似文献   

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