Zinc selenide doped with Sn and (Sn, Dy) phosphors has been prepared by firing the samples in an atmosphere of nitrogen gas. The voltage and frequency dependence of electrolyte brightness has been studied. Voltage dependence of electroluminescence (EL) brightness reveals an acceleration collision mechanism in the Schottky barrier at the metal–semiconductor interfaces. EL and photoluminescence (PL) spectra and thermoluminescence (TL) glow curves of these phosphors have also been recorded to understand the nature and mechanism involved in the luminescence process. The trapping parameters are calculated for the glow curves of these phosphors. 相似文献
The voltage-tunable EL was obtained upon cathodic bias of n-type PS in contact with aqueous solution containing the persulphate ion. The EL behavior as a function of the external voltage and time was investigated. The results suggest that the mechanisms of voltage-tunable EL of n-typt PS cannot easily be attributed to quantum confinement effect. 相似文献
An electrochemical optical sensor system with luminescence response was proposed for the continuous determination of hydrogen peroxide or peroxydisulphate concentration in aqueous solutions. The electroluminescence (EL) of TiO(2) film electrodes, which arises under conditions of the cathodic polarization as a result of the hole injection into the TiO(2) from high-energy OH or SO(4)(2-) radicals produced by the electroreduction of H(2)O(2) or S(2)O(8)(2-) ions on the electrode surface, was used as the analytical signal. The EL response is linearly related, in a logarithmic scale, to the hydrogen peroxide or peroxydisulphate concentration ranging from 10(-3) to 10(-1) M H(2)O(2) and from 5 x 10(-4) to 1 M Na(2)S(2)O(8). It was shown that a substantial increase in the quantum efficiency of the EL and, as a consequence, in the sensitivity of the sensor system can be achieved by doping TiO(2) films with chromium. The potential dependence of the EL spectrum for TiO(2) electrodes in S(2)O(8)(2-) solutions differs essentially from that in H(2)O(2) solutions which allows measurement of the concentration of S(2)O(8)(2-) ions when they coexist with H(2)O(2) in solution. 相似文献
Two novel blue light-emitting materials based on bis(tert-butyl)anthracenyl-imidazophenanthrolines (BAIPs) have been synthesized and extensively characterized. Both materials exhibited a non-aggregate feature with high fluorescent quantum efficiency and excellent thermal stability. They can serve both as emissive and electron-transporting materials used in electroluminescence (EL) device for blue emission with high luminescence and external quantum efficiency. This study demonstrates that they are potentially useful for a wide range of applications in EL technology. 相似文献
Anodization of the tantalum electrode with a symmetric double-step potential, (i.e., sequential positive and negative potential pulses with intermittent zero potential pulses), but not with a conventional DC potential, in an electrolyte containing traces of terbium (III) produces a terbium (III)-doped oxide film on the electrode surface. The pulsed cathodic polarization of this doped electrode in the presence of hydrogen peroxide or peroxodisulfate generates sub-bandgap electroluminescence where the oxide-bound terbium (III) is the radiative recombination center. The detailed mechanism for this terbium(III)-based sub-bandgap electroluminescence is discussed, as is the possibility of using the electroluminescence for the determination of trace hydrogen peroxide in aqueous solution. 相似文献
IntroductionIndium-tin-oxide(ITO) has been widely used asthe anode material in organic light-emitting devices(OLEDs) because of its high transmittance in the visi-ble region and low electrical resistivity. In the pastyears, many investigations focused on … 相似文献
It was demonstrated that light-emitting materials can be produced by the photochemical dissolution of aluminum in composites based on a cresol–formaldehyde novolak resin and CBr4in the presence of triphenylmethane dyes such as aluminon, pyrocatechol violet, and malachite green. The electroluminescence (EL) is due to the formation of organoaluminum complexes. The SnO2(anode)/novolak resin + pyrocatechol violet/Al (cathode) diodes exhibited the highest EL intensity. Compositions based on aluminon are characterized by weak EL, which increased by a factor of 30 upon the additional introduction of silica gel into the composition. As a result of supporting a PVA film on the diode surface (on the cathode side), the EL increased by a factor of 1.5 and became as high as 10 cd/m2. This value is comparable to the EL of pyrocatechol violet–containing diodes. The possible mechanism of the influence of silica gel and the importance of a PVA film for increasing the EL intensity are discussed. In the aluminon-based compositions, the dependence of EL on the diode storage time both with and without an applied voltage was measured. 相似文献
We report synthesis of ZnS quantum dots by chemical method at room temperature. In this technique, ZnS quantum dots are produced by simple chemical reactions where zeolite, acts as matrix, plays the key role in controlling particle growth during synthesis. Quantum dots exhibit luminescence properties such as Zn2+ related emission, efficient low voltage electroluminescence, and super linear voltage-brightness EL characteristics. This study demonstrates the technological importance of semiconductor nanosystems prepared by low cost chemical route. 相似文献
The cathodic light emission observed during electrolysis of solutions of simple inorganic salts (e.g. LiClO4, NaBF4 and Tb3+ salts) in solvents such as dimethylformamide, dimethylsulphoxide, and POCl3 at potentials higher than 6 V has been analyzed using spectroscopic, microscopic and electroanalytical techniques.Experimental results indicate that insulating (“passive”) layers on the cathode play an essential role in the mechanism of this electroluminescence. High current densities in the pores of these layers heat the solution and finally lead to local vaporization and decomposition of the solvent, thus creating insulating gas-filled cavities in the pores. If the applied voltage is sufficiently high, an electrical breakdown can develop across this cavity producing the observed luminescence phenomena.The luminescence emission spectra are indicative of excited gaseous species. Insulating model-layers obtained by glow-discharge polymerization were deposited on the cathode and used as models for electrodes with passive layers. Light emission was significantly more reproducible at such electrodes and allowed us to obtain reproducible voltage—current—light curves which support the proposed mechanism. The luminescence from Tb3+-ions occurs by energy transfer from the gas discharge. 相似文献
Symmetric double-step potential (i.e., positive and negative potential) pulses with intermittent zero potential pulses at the oxide-covered aluminum electrode generates anodic and cathodic electroluminescence in an aqueous environment in the presence of potassium peroxodisulfate. Organic fluorescent compounds generate changes in the cathodic electroluminescence but not in the anodic emission: intensity is greatly enhanced and the spectrum of a fluorophor-enhanced electroluminescence becomes similar to the fluorescence spectrum of the fluorophor. The mechanism of the fluorophor-enhanced peroxodisulfate-induced cathodic electroluminescence is discussed. It is demonstrated by means of salicylic acid as the model fluorophor that this electroluminescence can be exploited to determine trace organic fluorescent compounds. 相似文献
Summary: Homopolymers and a series of copolymers with tris‐8‐hydroxyquinoline aluminum (Alq3) as the cross‐links are synthesized. All these polymers show improved electroluminescence (EL) efficiency over their previously reported counterparts. Among them, the copolymers containing Alq3 and carbazole groups show higher EL efficiency than that of the homopolymers. We also demonstrate the feasibility of generating patterns using the homopolymers via photopolymerization. The cross‐linked nature, selectivity of patterning, high thermal stability, and EL efficiency might render these polymers a promising material in fabricating large‐scaled multilayered sub‐pixellation organic light‐emitting diodes (OLEDs).
Current–voltage and the electroluminescence–voltage curve of two‐layer devices for the Alq3‐homopolymers and the Alq3‐copolymers (luminance is shown by the symbols without lines). 相似文献
A series of novel praseodymium(Pr)-bonded polymers were successfully synthesized via the coordination reaction and palladium-catalyzed Suzuki coupling reaction of 2,7-dibromo-9,9'-dioctylfluorene and different amounts of 5,5'-dibromo-2,2'-bipyridine. The resulting polymers were characterized by ~1H-NMR and GPC. The photoluminescence(PL) and electroluminescence(EL) properties of the resulting polymers were studied to explore the effects of the Pr triisopropyloxide. The results showed that the incorporation of Pr into the polymers caused better coplanarity and effective intermolecular or intramolecular interaction, leading to the higher emission intensity at long-wavelength. Further, it was also found that the emission light color could be tuned from blue to green by introduction of a small amount of Pr into the polymer main chain. A single-layer green emitting EL device based on PF(Bipy Pr)6 with 6 mol% Pr content was fabricated. The device had a low turn-on voltage of 6 V, a brightness of 705.3 cd·m~(-2), the maximum luminous efficiency of 1.53 cd·A~(-1) and the maximum power efficiency of 0.69 lm·W~(-1). 相似文献