共查询到18条相似文献,搜索用时 156 毫秒
1.
沙国河及其工作组于1995年发表了CO A1Π(v=0)~e3∑-(v=1)与He1,Ne及其它碰撞伴的碰撞过程中转动传能的碰撞量子干涉现象,并得到了积分干涉角,陈等从理论和实验上发现了Na2(A1∑u ,v=8~b3Π0u,v=14)体系与Na(3s)碰撞的碰撞量子干涉现象,孙等计算了其积分干涉角,但是对微分干涉角没有过多的计算.本文作为对原子-双原子体系碰撞诱导转动传能的进一步理论研究,在含时一级波恩近似的基础上考虑各向异性相互作用势和长程相互作用势,计算了单叁混合态的Na2(A1∑u ,v=8-bΠ0u,v=14)体系与Na碰撞的微分干涉角,并得到了微分干涉角与碰撞参数的关系,此理论模型对理解和进行分子束实验是非常重要的. 相似文献
2.
3.
4.
5.
6.
团簇碰撞中双团簇分子(Na_9)_2的形成研究 总被引:1,自引:1,他引:0
采用紧密结合分子动力学模型 ,对Na9+Na9碰撞系统在质心系中单原子的轰击能量为Ecm/n =0 .0 0 63eV的对心碰撞进行了研究。从动力学的观点对双团簇分子 (Na9) 2 的形成给予了证明 ,结合所谓“突然冷却”技术 ,鉴别出了所形成的 (Na9) 2 ,并给出了其结构性质。 相似文献
7.
受激发射泵浦得到的LiCs高位振动态与CO_2碰撞,研究了LiCs不同能量对碰撞能量转移过程的影响.利用高分辨率瞬时激光感应荧光(LIF)测量得到CO_2(0000,J=2-74)原生转动态分布.转动布居数的半对数描绘给出了一个双指数结构,得到了一个T_a=660±73K[对LiCs(E=4300cm~(-1))]和550±61K[对LiCs(E=3700cm~(-1))]的低能分布,一个T_b=2380±261K[对LiCs(E=4300cm~(-1))]和1980±217K[对LiCs(E=3700cm~(-1))]的高能分布,低能分布属于弹性或弱非弹性碰撞,高能分布属于强非弹性碰撞.转动分布对LiCs能量是敏感的.但弹性与非弹性分支比基本是相同的.在一次碰撞的条件下,测量了各J态的出现和倒空速率系数,它们仅弱依赖于LiCs激发能.出现和倒空速率系数对不同LiCs能量基本一致,是振动-转动/平移弛豫轨道的重要证据. 相似文献
8.
利用含时量子波包动力学理论在HLi2 基态势能面上研究了H+Li2 → LiH+Li 反应的动力学性质. 计算得到了体系在0-0.4 eV 范围内J = 0 不同振动量子数(v = 0, 1, 2, 3), v = 0 不同转动量子数(J = 0, 5, 10,15) 下的反应概率、积分反应截面和热速率常数, 在此基础上讨论了释能反应的反应阈能随总角动量量子数的变化规律以及振动量子数对反应概率的影响等问题. 研究发现, 随着转动量子数的增大, 反应阈能也在逐渐增大; 然而随着振动量子数的增大, 由于反应为释能反应, 反应发生的概率却在逐渐减小. 分析了碰撞能对积分散射截面的影响以及温度对反应速率常数影响的规律. 相似文献
9.
采用距离相关紧束缚的分子动力学模型 ,在不同初始温度T0 =0 .0 2K、50K、10 0K、2 0 0K、30 0K、4 0 0K时 ,对Na8 Na8在质心系轰击能量为 0 .0 12 5eV/n的中心碰撞时的反应动力学进行了研究。发现团簇碰撞动力学与初始温度密切相关。在T0 <10 0K时 ,初始温度不影响反应动力学 ,而在T0 =4 0 0K时将对反应动力学有强烈影响。 相似文献
10.
在前期计算电子能量分布函数的基础上, 求出弱电离大气等离子体中各碰撞反应过程的电子能量损失. 由于在弹性碰撞中电子-重粒子能量交换很少, 同时氮气、氧气分子又有很多能量阈值较低的转动、振动能级存在, 因此在大气等离子体中弹性碰撞电子能量损失所占份额很小(直流电场下小于6%). 研究发现, 弱电离大气等离子体中在不同能量区间占主导的能量损失过程不同. 随着有效电子温度(或约化场强)增加, 占主导的电子能量损失过程依次为转动激发、振动激发、电子态激发、碰撞电离、加速电离产生的二次电子. 在约化场强E/N=1350 Td (或有效电子温度为14 eV)附近, 平均电离一个电子所需的能量最小, 约为57 eV. 因此可以根据不同的需求调节电场强度, 从而达到较高的能量利用率.
关键词:
弱电离大气等离子体
碰撞反应过程
电子能量损失 相似文献
11.
钠原子团簇的碰撞动力学 总被引:1,自引:1,他引:0
采用紧密结合的分子动力学模型,对第一个满壳附近(n=8)钠原子团簇碰撞Nan+Nan的动力学性质进行了系统性研究。对有限温度下的多次模拟事件,在各种碰撞参数与不同轰击能量时,双团簇(Nan)2的稳定性进行了研究。并发现,当质心系单原子能量为0.025eV时,对中心碰撞,(Na8)2能够存在3000fs,而对周边碰撞,(Na8)2能够存在10000fs;不管对中心碰撞还是对周边碰撞,在较低的轰击能量下,这种暂态双团簇结构具有较长的寿命;在相同的单原子轰击能量和相同的碰撞参数,(Na8)2和(Na9)2的动力学寿命没有差别,只是(Na8)2比(Na9)2的温度更低。 相似文献
12.
�����ƣ��ű������ſ��� 《核聚变与等离子体物理》2014,34(3):207-213
The fluid dynamics model was used to study the influence of the existence of the collisions on the dust particles in a dusty plasma sheath. The main collisions in this study consist of the ionization collision, the collision between electron and neutral particle, the collision between ion and neutral particle, the collision between electron and dust particle, the collision between ion and dust particle. Numerical calculation results are obtained by the fourth-order-Rung-Kutta method. It is shown that both the dust particles’ density and corresponding electricity quantity increase as the following collisions’ frequency enhances, such as ionization collision, the collision between electron and neutral particle, the collision between ion and neutral particle. The charge reduces due to the collisions concluding electron-dust particle and ion-dust particle. In addition, the effect produced by ions’ collision is much more obviously compared with electrons’ collision. 相似文献
13.
在一维平板鞘层中应用流体模型研究了尘埃等离子体鞘层中碰撞对尘埃颗粒密度和带电量的影响。 研究所涉及的碰撞主要有电离碰撞,电子、离子分别与中性粒子的碰撞,以及电子、离子分别与尘埃颗粒的碰撞。通过采用四阶龙格库塔法,得到了数值解。结果表明,随着电离碰撞或者电子、离子分别与中性粒子碰撞的频率 增加,都将导致鞘层中尘埃颗粒的数密度增大,数密度的极值位置向鞘边位置靠近,尘埃颗粒带电量增多。电子、离子与尘埃颗粒的碰撞,使得尘埃带电量减小。此外,从研究的结果来看,由离子产生的碰撞要比电子产生的碰 撞对尘埃颗粒的影响明显得多。 相似文献
14.
A kinetic theory for a simple reversible reaction-characterized by a binary mixture of ideal gases whose constituents denoted by A and B undergo a reaction of the type A+A?B+B-is developed by considering the reactive collisions as inelastic ones. The geometry of the collision is taken into account in the line-of-centers differential cross section by allowing that a chemical reaction may occur only when the energy of the relative velocity in the direction of the line which joins the centers of the molecules at collision is larger than the activation energy. It is shown that the restitution coefficients: (i) depend explicitly on the reaction heat and on the relative translational energy in the direction of the line which joins the centers of the molecules during an inelastic collision; (ii) vanish when the reaction heat is zero; (iii) are larger or smaller than one depending on the direction of the reaction and on the sign of the reaction heat. First approximations to the distribution functions are determined from the system of Boltzmann equations for the last stage of a chemical reaction. It is shown that the deviations from the Maxwellian distribution functions and the production terms of the particle number densities: (i) vanish when the reaction heat is zero provided that the affinity is close to zero and (ii) are negative or positive depending on the sign of the reaction heat and on the direction of the reaction. 相似文献
15.
16.
17.
In the case of central collisions,the collision mechanism of complete,incomplete fusion,and fragmentation were systematically studied via the Boltzmann-Uehling-Uhlenbeck theory which included the nuclear mean field dynamics,two-body collisions,and Pauli blocking between 5 and 150MeV/u for 20Ne+20Ne collision system.How the mean field,Pauli blocking of the two-body collisions were affected by bombarding energy and their effect on the reaction mechanism was discussed. 相似文献
18.
From the study of the dynamics for the ring-like soliton clusters, we find that there exists a critical value of the ring radius, dcr, for the stationary rotation of the clusters with respect to the beam centre even in the presence of the relatively strong noise, and that the soliton clusters will not rotate but only undergo periodic collisions in the form of simple harmonic oscillator if the ring radius is large enough. We also show that the direction of the rotation can be opposite to the direction of phase gradient when the relative phase difference is within the domain 0 〈 |θ| 〈 π, while along the direction of phase gradient when the relative phase difference is within the domain π 〈|θ| 〈 2π 相似文献