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1.
采用全原子分子动力学方法研究了抗衡离子为第一主族离子(Li+、Na+、K+、Rb+和Cs+)的十二烷基硫酸盐表面活性剂的气/液界面性质. 通过分析体系中各组分的密度分布曲线, 考察表面活性剂单分子层在界面的聚集形态, 并利用径向分布函数分析了表面活性剂极性头基与抗衡离子间的相互作用. 研究结果表明: 随着抗衡离子半径的增大, 不同体系的界面水层厚度依次增加, 表面活性剂极性头基与抗衡离子形成的Stern和扩散层厚度也相应增加. 但表面活性剂吸附层的抗衡离子缔合度以及体系表面张力却随抗衡离子半径的增大而减小. 研究表明抗衡离子的差异对十二烷基硫酸盐表面活性剂气/液界面性质有很大影响. 相似文献
2.
十二烷基苯磺酸钠和无机阳离子之间相互作用的密度泛函理论研究 总被引:1,自引:0,他引:1
研究阴离子表面活性剂和阳离子之间的相互作用对于理解阴离子表面活性剂的沉淀和溶解现象具有十分重要的理论和实际意义,但关于两者相互作用的相关理论模型鲜有报道。本文采用密度泛函理论(DFT)方法研究了十二烷基苯磺酸根阴离子(DBS-)与阳离子(Na+, Mg2+和Ca2+)在溶液内及气/液界面处的相互作用。在溶液内,在两种不同溶液环境中(水相和正十二烷)构建DBS-/阳离子相互作用模型,并对其进行优化。结果表明, DBS-能够与阳离子以双齿结构稳定结合。DBS-与阳离子的结合能不仅取决于参与的无机盐离子种类,还与溶剂的性质有关。在气/液界面处, DBS-与六个水分子相互作用形成的水合物DBS-·6H2O最为稳定。但是,无机盐离子的引入会严重破坏DBS-·6H2O水合物的水化层结构。本文定义无量纲参量def用来对水化层结构的变化程度进行评价。无机盐离子对DBS-·6H2O水化层结构破坏程度的顺序为:Ca2+ > Mg2+ >Na+。电荷分析结果表明水化层在十二烷基苯磺酸钠(SDBS)头基与阳离子的相互作用中起了重要作用。 相似文献
3.
摘要 采用荧光探针法和电导法研究了正离子偶联表面活性剂(C12H25(CH3)2N-(CH2)6-N(CH3)2C12H25•2Br) (12-6-12•
2Br-)和带相反电荷聚电解质聚丙烯酸钠(NaPA)的相互作用, 结果表明: 由于静电相互作用, 12-6-12•2Br-和NaPA之间可以形成类胶束或复合物. 对比十二烷基三甲基溴化铵(DTMAB)与NaPA复配体系的荧光光谱, 发现偶联表面活性剂与NaPA的相互作用强于传统表面活性剂. 此外, 还研究了盐和醇对偶联表面活性剂/聚丙烯酸钠的复配体系微极性的影响, 发现盐和醇对表面活性剂在聚电解质上形成类胶束和复合物的溶解都有一定的促进作用. 相似文献
4.
通过硅烷化反应在氧化石墨烯(Graphene oxide, GO) 表面嫁接螯合官能团N-(三甲氧基硅丙烷)乙二胺三酸(EDTA-Si), 得到改性氧化石墨烯(GO-EDTA), 采用分子动力学模拟在分子水平上研究了Pb2+在GO-EDTA 表面的动态吸附分布、 构象及动力学性质, 比较了Pb2+和单价Na+离子在氧化石墨烯上的吸附行为, 模拟了GO-EDTA与Ca2+相互作用, 与Pb2+的吸附行为进行了对比. 模拟结果表明, Pb2+和Na+的吸附位点是GO-EDTA 体系中的羧基, 而非氧化石墨烯表面的羟基; Pb2+和 Na+ 与羧基的吸附构象不同, 前者吸附构象以摩尔比2:1为主, 即两个羧基对一个Pb2+离子, 而后者更多倾向于摩尔比1:1的吸附模式, 即一个羧基对一个Na+离子; Pb2+离子相对于Ca2+和Na+离子, 形成的COO--Pb2+离子对构象越过的能垒最低, 但是破坏该离子对构象时能垒较高, 表明Pb2+离子在氧化石墨烯膜上表现出良好的吸附性. 相似文献
5.
聚电解质与两亲分子间相互作用近年备受关注[1,2].其原因之一是这种作用与作为形成生物膜基础的类脂间的相互作用极其相似,并可看作细胞中蛋白质-核酸相互作用的一种模式[3].对众多水溶性高分子尤其是聚电解质与表面活性剂间相互作用研究表明,这种作用不仅有重要的学术意义,而且在实际应用方面也非常重要,如应用于泥浆凝聚,油井采油以及膜分离技术[4]等. 相似文献
6.
采用密度泛函理论和经典分子动力学模拟研究了盐水溶液中Na+、Cu2+、Zn2+、Cl-与丙氨酸分子间的相互作用对丙氨酸分子缔合的影响. 密度泛函理论的计算结果显示丙氨酸分子与Na+、Cu2+、Zn2+、Cl-之间的相互作用可增强其电荷分离. 经典分子动力学模拟结果显示在水溶液中两性离子形式的丙氨酸存在三种缔合结构.盐水溶液中, 阳离子、阴离子与丙氨酸间的相互作用均能一定程度上减弱丙氨酸分子的缔合. 但是阳离子与丙氨酸间的相互作用明显受离子水合作用的影响. 由于Cu2+水合作用较强, 虽在气相中Cu2+与丙氨酸分子之间相互作用明显比Na+强, 但是在水溶液中则情况刚好相反. 在ZnCl2稀溶液中, Zn2+与丙氨酸间的相互作用被其第一水合壳层隔开. 但这种相互作用仍能明显影响丙氨酸分子的缔合, 这与Zn2+的水合壳层特征有关. 另外, 离子与丙氨酸之间的相互作用, 不仅会削弱丙氨酸的缔合, 也可导致丙氨酸分子间的缔合结构发生转变. 离子浓度也会影响其与丙氨酸分子间的缔合形式以及丙氨酸的缔合结构. 相似文献
7.
聚合物PVP与表面活性剂AOT相互作用的介观模拟 总被引:8,自引:0,他引:8
用耗散颗粒动力学模拟(DPD)方法研究了聚乙烯吡咯烷酮(PVP)与2-乙基己基琥珀酸酯磺酸钠(AOT)之间的相互作用.在三维模拟格子中,聚合物链均方末端距〈r2〉随着表面活性剂浓度的增加呈现一种首先减小,接着增加,然后又减小的趋势.构型和结构分析表明,AOT的加入能够引起聚合物链的二面角分布发生改变,这意味着AOT与PVP产生了相互作用.同时表面活性剂/聚合物体系的聚集形态也可以在DPD三维模拟格子中直观显现出来. 相似文献
8.
按照组分荷电属性的不同,高分子/表面活性剂体系可大致划分为三种:中性高分子/离子表面活性剂体系、带电高分子/离子表面活性剂体系、高分子/非离子表面活性剂体系。本文对这三种体系在水相中的高分子/表面活性剂相互作用研究进行综述。在大多数情况下,水相中高分子与表面活性剂共存时都能发生相互作用并形成复合物,其驱动力主要包括疏水作用、静电作用和氢键作用。根据高分子与表面活性剂的荷电情况及结构性质(如疏水链长度)的不同,上述驱动力可以单独或组合作用。此外,温度、pH值、电解质等外界因素对复合物形成过程及结构也具有不同程度的影响。 相似文献
9.
混合表面活性剂在非极性溶剂中的聚集行为 总被引:1,自引:0,他引:1
表面活性剂在非极性溶剂中的聚集行为比在水溶液中复杂得多. 水溶液中表面活性剂有一明确的临界胶束浓度(CMC),而在非极性溶剂中至今对CM C概念仍有怀疑[1], 但已有多种手段如染料增溶法、水增溶法、光散射法、荧光偏振、紫外和核磁共振谱等证实并测定了非极性溶剂中 CMC 的存在[1~5]. 表面活性剂在非极性溶剂中以非离子化状态存在, 其缔合主要靠两亲分子之间的偶极-偶极以及离子对相互作用, 那么在一种表面活性剂溶液中加入另一种表面活性剂, 即表面活性剂的复配, 必然对其聚集行为产生重大影响, 但迄今为止, 尚未见关于混合表面活性剂在非极性溶剂中聚集行为的报道. 本文采用碘光谱法和水增溶法测定了阴离子表面活性剂AOT 和非离子表面活性剂 Brij30 混合后在正庚烷中形成反胶束的 CMC, 以期考察表面活性剂的复配对其聚集行为的影响。 相似文献
10.
采用分子动力学模拟方法研究了大离子与聚电解质/表面活性剂复合物的相互作用, 考察了大离子的电性、直径、表面电荷、浓度等对其与复合物相互作用的影响. 结果表明, 与聚电解质所带电性相同的大离子对复合物作用不明显, 只有当大离子所带电荷较多时, 才会引导少量表面活性剂从复合物中脱离. 当大离子所带电荷与聚电解质所带电荷电性相反时, 大离子的加入会诱导复合物的解离, 表面活性剂从复合物中释放出来, 甚至导致聚电解质/表面活性剂复合物的完全解离, 从而形成聚电解质/大离子复合物; 大离子所带电荷越多, 诱导作用越明显. 大离子的直径及浓度对其与复合物之间的作用也有很大的影响, 对于所带电荷数相同的大离子而言, 直径越小, 其与复合物的作用越显著, 越容易引导表面活性剂从复合物中解离, 若大离子的表面电荷密度相同, 大离子直径越小, 反而与复合物的作用越弱; 大离子浓度越高, 越易引起复合物的解离, 复合物中聚电解质链上结合的大离子数增多直至饱和, 相应的会出现电荷反转现象. 相似文献
11.
FANG Yue-e LU Xiao-bing WANG Huan-ting CHENG Qing CHEN Bo-jun CHEN Guo-jun WANG Yong-jie WANG Shao-gen 《高等学校化学研究》1998,14(4):408-413
IntroductionChitinandchitosanrepresentthesecondlargestclassofnaturalbiopolymers,whichhavebeenreportedtobepromisingpolymersnot... 相似文献
12.
Multilayer polyelectrolyte films as nanofiltration membranes for separating monovalent and divalent cations 总被引:1,自引:0,他引:1
Alternating adsorption of polyanions and polycations on porous supports provides a convenient way to prepare ion-selective nanofiltration membranes. This work examines optimization of ultrathin, multilayer polyelectrolyte films for monovalent/divalent cation separations relevant to water softening. Membranes composed of five bilayers of poly(styrene sulfonate)/poly(allylamine hydrochloride) (PSS/PAH) on porous alumina supports allow a solution flux of 0.85 m3/(m2 day) at 4.8 bar, and exhibit 95% rejection of MgCl2 along with a Na+/Mg2+ selectivity of 22. Similar results were obtained in Na+/Ca2+ separations. PSS/poly(diallyl-dimethylammonium chloride) (PDADMAC) films permit higher fluxes than PSS/PAH systems due to the higher swelling of films containing PDADMAC, but the Mg2+ rejection by PSS/PDADMAC membranes is less than 45%. However, capping PSS/PDADMAC films with a bilayer of PSS/PAH yields Mg2+ rejections and Na+/Mg2+ selectivities that are typical of pure PSS/PAH membranes. Separation performance can be optimized through control over deposition conditions (pH and supporting electrolyte concentration) and the charge of the outer layer since Donnan exclusion is a major factor in monovalent/divalent cation selectivity. Streaming potential measurements demonstrate that the magnitude of positive surface charge increases with increasing concentrations of Mg2+ in solution or when the outer polycation layer is deposited from a solution of high ionic strength. 相似文献
13.
淀粉-磺甲基化聚丙烯酰胺接枝共聚物的合成及性能 总被引:4,自引:0,他引:4
用淀粉-聚丙烯酰胺接枝共聚物(S-g-PAM)同多聚甲醛及亚硫酸钠反应,合成了淀粉-磺甲基化聚丙烯酰胺接枝共聚物(S-g-SPAM)。该磺化物的水溶液在试验浓度范围内(0.1~1.0%),为假塑性流体,对高岭土悬浮液的絮凝,由沉降速度,上层清液相对吸光度可知,S-g-SPAM(接枝链分子量为1.03×105,磺甲基化度30%)的絮凝能力优于相应的未磺化的S-g-PAM,也比聚丙烯酰胺(分子量2.5×106)强。 相似文献
14.
Raman spectra of the Li+, Na+, K+, NH+4, Mg2+, Ca2+, Sr2+, Ba2+, Pb2+ complexes of 12-crown-4 and also 12-crown-4 in various states are observed. The spectra of 12-crown-4 change remarkably by complex formation with cations. Normal vibration calculations of various conformations of 12-crown-4 are carried out. On the basis of the observed spectra and the results of the calculations, the conformation of 12-crown-4 in the Li+, Na+, K+, NH+4, Mg2+ complexes is found to have approximate D2d symmetry, while that in the Ca2+, Sr2+, Ba2+ complexes is found to have approximate C2V symmetry. 相似文献
15.
Maria G. Kiseleva Lubov V. Radchenko Pavel N. Nesterenko 《Journal of chromatography. A》2001,920(1-2):79-85
A novel bipolar stationary phase (HCPS–MO) was prepared by impregnation of hypercrosslinked polystyrene (HCPS) with methyl orange (MO; 4-dimethylamino-4′-sulfoazobenzene) and its ion-exchange properties were studied. Simultaneous separation of cations and anions on HCPS–MO is possible, although it behaves preferentially as a cation-exchanger. Unusual selectivity of HCPS-MO for alkali and alkaline-earth metal cations: Na++K++4++ and Mg2+2+2+2+ was observed. The effect of temperature on retention of alkali and alkaline-earth metal cations was studied. Separation of Na+, K+, Rb+, NH4+, Cs+, Mg2+ and Ca2+ on HCPS–MO with diluted cerium(III) nitrate solution as an eluent in single run is presented. 相似文献
16.
Data for coated-wire, ion selective electrodes (ISEs) are presented for cationic surfactant ions found in common cleaners including benzyldimethyltetradecylammonium, benzyldimethyldodecylammonium, and benzyldimethylhexadecylammonium. The ion exchangers dinonylnaphthalene sulfonic acid, tetraphenyborate, and tetrakis(4-chlorophenyl)borate are examined, showing dinonylnaphthalene sulfonic acid to be the favored species. The ISEs exhibit approximately Nernstian behavior down to the 10−6 M limit of detection with lifetimes in excess of 50 days when used continuously, and a shelf life of over 100 days. Reaching the upper detection limit at the critical micelle concentration requires use of polymeric-membrane reference electrodes including a new membrane cocktail, which allow response measurements of an order of magnitude higher than the traditional fritted-glass reference electrode. The surfactant ISEs show excellent selectivity over the common metal ions Na+, K+, Mg2+, Ca2+, and Cu2+ with selectivity coefficients less than 10−5.3. The ISEs are also selective over the lower molecular weight quaternary ammonium ions tetradecyltrimethylammonium, dodecyltrimethylammonium, benzyldimethyl(2-hydroxyethyl)ammonium, and tetrabutylammonium with selectivity coefficients ranging from 10−1.7 to 10−5.5. Use of a single electrode to determine accurately the total cationic surfactant concentration in common cleaning solutions is accomplished with information about concentration dependent interferences and a modified Nikolsky–Eisenman model. Finally, quaternary ammonium surfactants have a deleterious effect on the measurements of pH and common ions like K+, Mg2+ and Ca2+ with polymeric ISEs. This makes it critical to include surfactant electrodes in a detector array when cleaning agents are present. 相似文献
17.
William Shotyk 《Journal of chromatography. A》1993,640(1-2):317-322
Organic rich natural waters from peat bogs in continental (Switzerland) and maritime (Shetland Islands, Scotland) environments were analysed for Na+, NH4+, K+, Mg2+ and Ca2+ using ion chromatography. These cations were determined simultaneously in surface and pore water samples from the continental bogs using a 250-μl injection loop in an isocratic separation. Using this loop, detection limits of the order of 1 ng/g were achieved. An organics-removal cartridge (Dionex OnGuard P) was used to remove humic materials. Analyses of deionized water filtered through these cartridges showed acceptably low blank values (e.g., ca. 5 ng/g) and appeared to have no significant effect on the measured cation concentration. For the maritime bog waters, the low concentrations of NH4+ (ca. 1 μg/g) compared with Na+ (ca. 100 μg/g) required improved peak separation. This was accomplished using a gradient separation beginning with 40 mM HCl—1 mM
,
-2,3-diaminopropionic acid monochloride (DAP) and switching to 40 mM HCl-12 mM DAP after 2 min. Using a 25 μl injection loop, Na+, NH4+, K+, Mg2+ and Ca2+ were determined simultaneously in less than 25 min. In this instance, even with Na+/NH4+ > 100, there was no interference from Na+ in the determination of NH4+ (baseline separated). 相似文献
18.
The structure and stability of endohedral X@Si20H20 complexes (X = Li0/+, Na0/+, K0/+, Be0/2+, Mg0/2+, Ca0/2+) have been studied at the B3LYP/6-31G* level of density functional theory. It is found that complexes with X = Na0/+, K0/+, Mg and Ca0/2+ are energy minimum structures with X at the cage center in Ih symmetry, while those with X = Li0/+, Be0/2+, Mg2+ have off-centered structures with X towards one pentagon face in C5v symmetry. Large electron or charge transfer between the Si20H20 cage and the encapsulated X has been observed. 相似文献
19.
本文研制的钙离子选择性双管复合微电极尖端直径小至2.5μm,特别适用于活体组织细胞及临床微量试样中钙离子浓度的测定。用该电极测量了人体微量试样中钙离子浓度,并观察了大白鼠及家免心肌组织受激时钙离子活度的动态变化。 相似文献
20.
The effect of ions on the structure of water is discussed in terms of results for ionic hydration as derived from neutron diffraction isotopic substitution experiments. Results are presented for alkali ions (Li+, Na+ and K+), alkaline earth ions (Mg2+, Ca2+ and Sr2+) and for the anions Cl−, ClO−4) and NO−3, from which it is inferred that the water structure is disrupted more by cations with higher charge density. 相似文献